CN105800561B - Base unit component, Ozone generator module and the big plate-type Modular ozone generator unit of panel type ozone producer - Google Patents

Base unit component, Ozone generator module and the big plate-type Modular ozone generator unit of panel type ozone producer Download PDF

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Publication number
CN105800561B
CN105800561B CN201610116606.0A CN201610116606A CN105800561B CN 105800561 B CN105800561 B CN 105800561B CN 201610116606 A CN201610116606 A CN 201610116606A CN 105800561 B CN105800561 B CN 105800561B
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China
Prior art keywords
ozone
ozone generator
base unit
coldplate
panel type
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CN201610116606.0A
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CN105800561A (en
Inventor
罗范生
王保东
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Beijing Tianze Changning Environment Technology Co Ltd
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Beijing Tianze Changning Environment Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/10Preparation of ozone
    • C01B13/11Preparation of ozone by electric discharge
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00Preparation of ozone by electrical discharge
    • C01B2201/10Dischargers used for production of ozone
    • C01B2201/12Plate-type dischargers
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00Preparation of ozone by electrical discharge
    • C01B2201/60Feed streams for electrical dischargers
    • C01B2201/64Oxygen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00Preparation of ozone by electrical discharge
    • C01B2201/70Cooling of the discharger; Means for making cooling unnecessary
    • C01B2201/74Cooling of the discharger; Means for making cooling unnecessary by liquid
    • C01B2201/76Water

Abstract

The invention discloses a kind of base unit component of panel type ozone producer, it includes dielectric barrier discharge plate and is respectively arranged at the coldplate on its positive and negative two sides, wherein, the dielectric barrier discharge plate includes plate body, it is provided with oxygen intake and ozone outlet, the positive and negative two sides of the plate body is also respectively provided with an elastomer, and the outer surface of elastomer is respectively provided with a combination electrode;The coldplate includes coldplate body, it includes being respectively arranged at the coolant inlet at its both ends, cooling liquid outlet and the hot switching path of inside, the coldplate also includes being arranged on the ground electrode on the surface of coldplate and the pad located at ground electrode surface, and the pad forms ionisation chamber between the combination electrode and ground electrode.In addition, invention additionally discloses a kind of panel type ozone producer module for including at least one set of base unit component, and the large-scale panel type ozone producer unit by least one set of panel type ozone producer module composition.

Description

Base unit component, Ozone generator module and the big template of panel type ozone producer Formula Modular ozone generator unit
Technical field
The present invention relates to a kind of base unit component of panel type ozone producer, and in particular to one kind is with dielectric barrier discharge (Dielectric Barrier Discharge, DBD) mode produces the base unit component of the panel type ozone producer of ozone. Moreover, it relates to a kind of Ozone generator module including the base unit component and big plate-type modularization are smelly Oxygen Generator unit, belong to ozone production equipment manufacturing field.
Background technology
Than traditional tubular ozone generator, Modular plate-type ozone generator is because its is simple in construction, spaces compact, makes The advantages that valency is relatively low, flexible in configuration, high gas producing efficiency, it is widely used in the industries such as environmental protection, water process, medicine, and application prospect Extensively.However, relative to after many decades, already very ripe tubular ozone generator, panel type ozone producer are still deposited It is urgently to be resolved hurrily in great number of issues.Wherein, the maximization of panel type ozone producer is current line one of urgent problem to be solved in the industry.
Patent CN103387212B discloses a kind of Modular plate-type ozone generator, its integration packaging in DBD modules High frequency/high-field electrode, water cooling ground electrode, block media, electric discharge air chamber and gas passage and cooling passage etc. substantially will Element.Each basic component adds external modular high frequency/high voltage power supply, can form one it is complete, minimizing, can be only The board-like DBD Ozone generator modules of vertical work.However, the patent is to be laminated DBD Ozone generator modules in a one-dimensional fashion Extension structure, i.e.,:The DBD sequence of modules stacking of several standardization, and form an ozone generator unit with end cap.Due to it The yield of the DBD Ozone generator modules of standardization only has 100g/h, and can increase the difficulty of intermodule sealing after stacking number increase Degree, thus it is difficult to build Large-scale machine set.Furthermore the building mode of such order stacking destroys modular advantage, to peace Dress and maintenance all bring difficulty.And this is also to restrict the problem of such panel type ozone producer moves towards maximization place.
Patent CN102602896B discloses a kind of ozone generator, and it specifically discloses a kind of with by the multiple of lamination Flat high-field electrode and low-field electrode, therebetween superposition alternating voltage make so that electric discharge occurs so as to generate the flat board of ozone gas Stack-up type ozone generating-device.The patent is more particularly to seeking the slim of ozone generator, high capacity and cutting device While number of components, the ozone generating-device of equipment miniaturization construction is sought.The patent is used multiple tabular high-tension electricities The method of pole lamination builds ozone generator unit.However, the patent by all components it is several assembling in a casing, lose Gone the benefit that modularization is brought, but had a similar part with the building mode of tubular ozone generator, whole unit weight compared with Greatly, it is difficult to transport and maintenance.
Therefore, exploitation it is a kind of it is compact-sized, space availability ratio is high, energy density is concentrated, and flexible in configuration, be easy to what is safeguarded Big plate-type Modular ozone generator is one of study hotspot in the art.
The content of the invention
It is smelly to be applied to the big plate-type modularization of structure it is an object of the invention to overcome the deficiencies of the prior art and provide one kind The base unit component of Oxygen Generator.In addition, contain the base unit component another object of the present invention is to provide one kind Ozone generator module.It is still another object of the present invention to provide it is a kind of assembled by the Ozone generator module it is big Plate-type Modular ozone generator unit.
To achieve the above object, the present invention uses following technical scheme:
A kind of base unit component of panel type ozone producer, including dielectric barrier discharge plate and be respectively arranged at its just, Two pieces of coldplates on anti-two sides, wherein:The dielectric barrier discharge plate includes plate body, and being provided with oxygen on the plate body enters Mouth and ozone outlet, the positive and negative two sides of the plate body is also respectively provided with an elastomer, and the outer surface of the elastomer is respectively provided with One combination electrode;The coldplate includes coldplate body, and it includes coolant inlet, cooling liquid outlet and positioned at coolant Hot switching path between entrance and cooling liquid outlet, the coldplate also include be arranged on the coldplate it is surface, with The ground electrode and the pad located at ground electrode surface that combination electrode faces, and the pad is in the combination electrode and ground electricity Ionisation chamber is formed between pole.
Preferably:The dielectric barrier discharge plate also includes being respectively arranged at the positive and negative two sides of plate body and oxygen The oxygen channel that gas entrance communicates, and it is respectively arranged at the ozone communicated with ozone outlet on the positive and negative two sides of plate body Passage.
Preferably:The dielectric barrier discharge plate also includes the power outlet being arranged on plate body.
Preferably:The elastomer includes but is not limited to fluorubber elastomer, ethylene-propylene-diene monomer glue elastomer.
Preferably:Ceramic treatment is passed through on the surface of the ground electrode.
Another object of the present invention, a kind of panel type ozone producer module, it includes at least one set of basis as described above Unit member.
Preferably:Each group base unit component is arranged symmetrically in the panel type ozone producer module.
Preferably:Each panel type ozone producer module includes four groups or six groups of base unit components.
Another object of the present invention, a kind of big plate-type Modular ozone generator unit, it includes at least one set as above Described Ozone generator module.
Preferably:Each Ozone generator module is individually packaged, and the adjacent intermodule of ozone generator two leaves gap.
Preferably:Each Ozone generator module is each configured with independent power supply.
Preferably:Each Ozone generator module sequential layer stacked group dress, and adjacent Ozone generator module shares one group Coldplate.
The beneficial effects of the present invention are the present invention is with " sandwich " of " coldplate+dielectric barrier discharge plate+coldplate " Based on the base unit component of formula structure, the panel type ozone producer mould for including at least one set of base unit component is constructed Block, and can finally be formed by multigroup panel type ozone producer module assembled suitable for different scales, the big template of different application Formula Modular ozone generator unit.It is compact-sized, space availability ratio is high by the way of the present invention is built using 3-D stacks, gram The drawbacks of having taken conventional one-dimensional stacked system so that build large-scale panel type ozone producer and be possibly realized.Occur for board-like ozone Standardization, seriation, maximization and the industrialized production of device product are laid a good foundation.
Brief description of the drawings
Fig. 1 shows the various views of the base unit component of panel type ozone producer of the present invention, wherein, Fig. 1 a For plan, Fig. 1 b are side view, and Fig. 1 c are sectional view;
Fig. 2 shows the sectional view of dielectric barrier discharge plate of the present invention (DBD plates);
Fig. 3 shows the sectional view of coldplate of the present invention;
Fig. 4 shows that the ozone including four base unit components occurs according to one embodiment of the present invention The various views of device module, wherein, Fig. 4 a are plan, and Fig. 4 b are side view, and Fig. 4 c are sectional view;
Fig. 5 shows the arrangement figure of the dielectric barrier discharge plate in Ozone generator module as shown in Figure 4;
Fig. 6 shows the structure chart of the coldplate in Ozone generator module as shown in Figure 4;
Fig. 7 shows that the ozone including six base unit components occurs according to another embodiment of the present invention The various views of device module, wherein, Fig. 7 a are plan, and Fig. 7 b are side view, and Fig. 7 c are sectional view;
Fig. 8 shows the big pattern containing 10 Ozone generator modules according to one embodiment of the present invention The assembly structure diagram of block ozone generator unit;
Fig. 9 shows the another of the large modular ozone generator unit according to another embodiment of the present invention Assembly structure diagram.
Embodiment
The embodiment of the present invention is described further below in conjunction with the accompanying drawings.
As shown in figure 1, the base unit component of panel type ozone producer of the present invention includes dielectric barrier discharge plate (DBD plates) 1, and the positive and negative two sides of the dielectric barrier discharge plate 1 is respectively provided with a coldplate 2.In the present invention, it is arranged on Jie Two pieces of coldplates 2 of the both sides of matter barrier discharge plate 1 can use identical structure.Wherein, as shown in Fig. 2 the dielectric impedance is put Electroplax 1 includes plate body 11, and oxygen intake 12 and ozone outlet 13, the plate body 11 are respectively arranged with the plate body 11 Positive and negative two sides be also respectively provided with an elastomer 14 between oxygen intake 12 and ozone outlet 13, the elastomer 14 is excellent Fluorubber elastomer or ethylene-propylene-diene monomer glue elastomer are selected, the outer surface of the elastomer 14 is respectively provided with a combination electrode 15;Institute Stating dielectric barrier discharge plate 1 also includes (high frequency/high pressure) power outlet 16 on plate body 11.
As shown in figure 3, described coldplate 2 includes coldplate body 21, the He of coolant inlet 22 is respectively arranged with thereon Cooling liquid outlet 23, and be arranged at it is inside the coldplate body 21, positioned at coolant inlet 22 and cooling liquid outlet 23 Between, the hot switching path 24 that is communicated with the coolant inlet 22 and cooling liquid outlet 23, in the present invention, the heat exchange 24 preferred turbulence structure of passage.The coldplate 2 also includes the table relative with block media discharge electrode 1 for being arranged at coldplate 2 The pad 26 of the ground electrode 25 in face and outwardly convex located at the surface of ground electrode 25.In the present invention, the ground electrode 25 Surface is through ceramic treatment, and its locus on coldplate 2 is relative two-by-two with the combination electrode 14 of DBD plates.According to need Ask, the pad 26 there can be different thickness, it is preferable that thickness≤0.2mm of the pad 26.The pad 26 is compound Narrow discharge space is formed between electrode 15 and ground electrode 25, i.e. the ionisation chamber 17 shown in Fig. 2.And elastomer 14 is then sharp With the elasticity of its own, combination electrode 15 is tightly pressed into ground electrode 25, to ensure the dimensional accuracy of discharging gap.
The course of work of the base unit component of panel type ozone producer of the invention as described above is:The oxygen come from source of the gas Corresponding two oxygen channel 18 of the gas through oxygen intake 12 and positioned at 11 positive and negative two sides of plate body enters ionisation chamber 17, It is changed into the mixed gas of ozone and oxygen under plasmoid, then from positioned at corresponding two of 11 positive and negative two sides of plate body Ozone channel 19 is sent out through ozone outlet 13.At the same time, coldplate 2 of the coolant through the both sides of dielectric barrier discharge plate 1 is cold But liquid entrance 22 enters hot switching path 24, and is sent out via cooling liquid outlet 23.In the present invention, the dielectric barrier discharge Plate 1 is formed by aluminum profile extrusion, and the passage of all contact gases sets the cavity of high voltage device only with aluminium surface Passivation Treatment Inside one layer of Al of differential of the arc chemical industry skill uniform fold2O3Ceramics, there are good insulating properties and corrosion resistance.It is described cold But plate 2 uses cold soldering or Friction stir welding after can using aluminium essence casting one-shot forming, or parts processing shaping, makes one Individual entirety, this is prior art, be will not be repeated here.
The base unit component of panel type ozone producer of the invention as described above, not only can used aloned, can also be multiple Assembling uses, with the board-like DBD Ozone generator modules for forming different scales, being suitable for different application.Preferably, the ozone In generator module, multiple base unit components are arranged symmetrically.For example, according to one embodiment of the present invention, Fig. 4 is shown The structural representation of Ozone generator module including four base unit components as described above.Ozone hair as shown in Figure 4 Raw device module, its integration packaging 4 DBD base unit components as described above, its yield are 1 DBD base unit component 4 times.Wherein, as shown in figure 5, the dielectric barrier discharge plate 1 in four DBD base unit components is arranged into sphere of movements for the elephants type, water It is flat to be arranged on module central, because the positive and negative two sides of each dielectric barrier discharge plate 1 is symmetrical structure, map each other, and then form Tow sides upper and lower, left and right totally eight ionisation chambers 17.Fig. 6 shows that the ozone for being packaged with 4 DBD base unit components occurs The structural representation of coldplate 2 in device module, every piece of coldplate 2 include four hot switching paths 24, four hot switching paths 24 are distributed in sphere of movements for the elephants type, and its locus and the combination electrode 15 in dielectric barrier discharge plate 1 are relative two-by-two.In this implementation In mode, the hot switching path 24 can use including but not limited to serpentine configuration.
Similar, the envelope shown in Fig. 4 with the course of work of the base unit component of panel type ozone producer as described above The course of work of Ozone generator module equipped with four base unit components is:From source of the gas come oxygen through oxygen intake 12, Oxygen channel 18 enters corresponding oxygen slit 18a, 18b, 18c, 18d, subsequently enters what is communicated with each oxygen slit 18a-18 Corresponding ionisation chamber 17, is changed into the mixed gas of ozone and oxygen under plasmoid, and subsequent ozone enters and each ionisation chamber 17 Ozone slit 19a, the 19b communicated, sent out through ozone channel 19 from ozone outlet 13.At the same time, coolant is through coldplate 2 Coolant inlet 22 is entered by coolant inlet passage 21a and led to coolant inlet passage 21a four heat exchanges communicated In road 24.Then, the coolant after the heat exchange of hot switching path 24 passes through exports the cooling liquid outlet communicated with hot switching path 24 Passage 23a, 23b are sent out from corresponding cooling liquid outlet 23.
According to one embodiment of the present invention, Fig. 7 is shown including the smelly of six base unit components as described above The structural representation of Oxygen Generator module.Ozone generator module as shown in Figure 7, its integration packaging 6 are as described above DBD base unit components, its yield are 6 times of 1 DBD base unit component.Wherein, six base unit components are with " axis Line is symmetrical " mode be arranged at module central, including six blocks of dielectric barrier discharge plates 1 and correspond and be arranged on each medium resistance 12 pieces of coldplates 2 (positive and negative respectively set six pieces of coldplates 2) on 1 positive and negative two sides of discharge electrode are kept off, form upper, middle and lower-ranking " sandwich " structure, and then formed symmetrical 12 ionisation chambers 17 in upper and lower, left and right.The Ozone generator module it is worked Journey and the course of work of the Ozone generator module of above-mentioned 4 base unit components of encapsulation are similar, will not be repeated here.
Present invention Ozone generator module as described above, not only can used aloned, can also multiple assemblings use, to be formed Different scales, the large modular ozone generator unit towards different application.A kind of for example, embodiment party according to the present invention Formula, Fig. 8 show that the package assembly of the large-scale ozone generator unit containing 10 Ozone generator modules as described above is shown It is intended to.As illustrated, each Ozone generator module is " " sandwich " knot of coldplate 2+ block media plate 1+ coldplates 2 " Structure, and for ease of the independence plug of each module, in assembling, gap is left between adjacent two module.In addition, each module is equal It is connected with oxygen hose 5, ozonizer 6 and the coolant oral siphon 3 and coolant outlet pipe 4 of outside.In the ozone generator machine In group, each module is preferably independently-powered, i.e. each Ozone generator module respectively configures corresponding power supply, meets so as to be formed The large modular ozone generator unit of " plug and pull " demand.It is highly preferred that each Ozone generator module built-in with CPU electricity Source.Assembling mode as shown in Figure 8, it can carry out the assembling of any amount Ozone generator module in theory, and in large-scale system In system application, several Ozone generator modules can be assembled into a unit, then multiple such machine component layers are loaded into rack.
According to another embodiment of the present invention, Fig. 9 shows large modular ozone generator unit as described above Another assembly structure diagram.As illustrated, the structure uses the assembling mode of compact, according to " coldplate 2, stop The order stacking of dielectric-slab 1, coldplate 2, block media plate 1 ... coldplate 2 ", i.e. adjacent Ozone generator module shares one Group coldplate 2, it is very close to each other between each Ozone generator module, so as to can be less with 9 groups of coolings compared with the assembling mode shown in Fig. 8 Plate, the volume of ozone generator unit is reduced, be applicable to require unit volume, and use centrally connected power supply (multiple moulds Block shares a power supply) large modular ozone generator unit in.In addition, oxygen hose 5, smelly of each module with outside Oxygen pipe 6 and coolant oral siphon 3 are connected with coolant outlet pipe 4.Assembling mode as shown in Figure 9, it can be carried out in theory The assembling of any amount Ozone generator module, and in large scale system application, several Ozone generator modules can be assembled into One unit, then multiple such machine component layers are loaded into rack.
The present invention has carried out detailed explanation by preferred embodiment.However, by studying carefully above, to each Apparent to the change of embodiment and increase and those of ordinary skill in the art.It is intended that it is all this A little changes and increase fall in the protection domain of the claims in the present invention.
Similar numbering refers to similar element.For clarity, may have some lines, layer, member in the accompanying drawings The situation of part, part or feature amplification.
Term used herein is only that specific embodiment is illustrated, and it, which is not intended to, limits the present invention System.Unless otherwise defined, all terms (including technical term and scientific terminology) used herein with the present invention belonging to neck The understanding of the those skilled in the art in domain is identical.Must also it is clear that, definition is outer except having herein clearly, logical in such as dictionary The term often defined should be construed in the linguistic context of this specification and correlation technique can have the consistent meaning, without that should solve The idealization released or undue formalization.Known function or structure are in briefly and clearly consider or repeat no more.

Claims (12)

  1. A kind of 1. base unit component of panel type ozone producer, it is characterised in that:Set including dielectric barrier discharge plate and respectively Two pieces of coldplates on its positive and negative two sides are placed in, wherein:The dielectric barrier discharge plate includes plate body, is set on the plate body Oxygen intake and ozone outlet are equipped with, the positive and negative two sides of the plate body is also respectively provided with an elastomer, and the elastomer is outer Surface is respectively provided with a combination electrode;The coldplate includes coldplate body, it include coolant inlet, cooling liquid outlet and Hot switching path between coolant inlet and cooling liquid outlet, the coldplate also include being arranged on the coldplate Ground electrode surface and that combination electrode faces and the pad located at ground electrode surface, and the pad is described compound Ionisation chamber is formed between electrode and ground electrode.
  2. 2. base unit component according to claim 1, it is characterised in that:The dielectric barrier discharge plate also includes difference The oxygen channel communicated with oxygen intake on the positive and negative two sides of plate body is arranged at, and is respectively arranged at the plate body The ozone channel communicated with ozone outlet on positive and negative two sides.
  3. 3. base unit component according to claim 1, it is characterised in that:The dielectric barrier discharge plate also includes setting Power outlet on plate body.
  4. 4. the base unit component according to any one in claim 1-3, it is characterised in that:The elastomer include but Fluorubber elastomer, ethylene-propylene-diene monomer glue elastomer are not limited to, the hot switching path is turbulence structure.
  5. 5. the base unit component according to any one in claim 1-3, it is characterised in that:The surface of the ground electrode By ceramic treatment.
  6. A kind of 6. panel type ozone producer module, it is characterised in that:Including at least one set of base unit as claimed in claim 1 Component.
  7. 7. panel type ozone producer module according to claim 6, it is characterised in that:Each group base unit component is in the plate It is arranged symmetrically in formula Ozone generator module.
  8. 8. the panel type ozone producer module according to claim 6 or 7, it is characterised in that:Each panel type ozone producer Module includes four groups or six groups of base unit components.
  9. A kind of 9. big plate-type Modular ozone generator unit, it is characterised in that:Including at least one set of as claimed in claim 6 Ozone generator module.
  10. 10. big plate-type Modular ozone generator unit according to claim 9, it is characterised in that:Each ozone occurs Device module is individually packaged, and the adjacent intermodule of ozone generator two leaves gap.
  11. 11. big plate-type Modular ozone generator unit according to claim 10, it is characterised in that:Each ozone occurs Device module is each configured with independent power supply.
  12. 12. big plate-type Modular ozone generator unit according to claim 9, it is characterised in that:Each ozone occurs The stacking assembling of device sequence of modules, and adjacent Ozone generator module shares one group of coldplate.
CN201610116606.0A 2016-03-02 2016-03-02 Base unit component, Ozone generator module and the big plate-type Modular ozone generator unit of panel type ozone producer Active CN105800561B (en)

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CN106241745A (en) * 2016-10-11 2016-12-21 北京天择昌宁环境技术股份有限公司 The Base member unit of panel type ozone producer and Intelligent ozone generator module
CN112930226A (en) * 2018-10-22 2021-06-08 上海必修福企业管理有限公司 Engine tail gas ozone purification system and method

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JP3607905B2 (en) * 2002-10-22 2005-01-05 東芝三菱電機産業システム株式会社 Ozone generator
WO2009028084A1 (en) * 2007-08-31 2009-03-05 Toshiba Mitsubishi-Electric Industrial Systems Corporation Apparatus for generating dielectric barrier discharge gas
CN103387212B (en) * 2013-07-24 2015-04-22 北京奥隆环保科技有限责任公司 Modular plate-type ozone generator
CN104192809B (en) * 2014-08-26 2016-08-17 深圳市信诚高科科技开发有限公司 A kind of Modular plate-type ozone generator
CN205398114U (en) * 2016-03-02 2016-07-27 北京天择昌宁环境技术股份有限公司 Plate -type ozone generator's base unit component and ozone generator module

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