CN105799292A - Flexible pipe material used for packing daily chemical products and preparing method thereof - Google Patents

Flexible pipe material used for packing daily chemical products and preparing method thereof Download PDF

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Publication number
CN105799292A
CN105799292A CN201610269218.6A CN201610269218A CN105799292A CN 105799292 A CN105799292 A CN 105799292A CN 201610269218 A CN201610269218 A CN 201610269218A CN 105799292 A CN105799292 A CN 105799292A
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CN
China
Prior art keywords
layer
tack coat
composite
heat
hose material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610269218.6A
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Chinese (zh)
Inventor
杜德熙
黄志国
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Ruiyuan New Material Co Ltd
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Guangzhou Ruiyuan New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Ruiyuan New Material Co Ltd filed Critical Guangzhou Ruiyuan New Material Co Ltd
Publication of CN105799292A publication Critical patent/CN105799292A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/10Interconnection of layers at least one layer having inter-reactive properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties

Abstract

The invention discloses a flexible pipe material used for packing daily chemical products and a preparing method thereof. The flexible pipe material is a multilayer composite material and comprises an outer layer, a first adhesive layer, a middle layer, a second adhesive layer and a hot-seal inner layer which are sequentially arranged in a layered mode and integrally bonded. The outer layer is a textile fiber layer, the middle layer is a polyethylene film layer, the first adhesive layer and the second adhesive layer are polyurethane glue layer, and the hot-seal inner layer is a polyethylene material layer; the outer layer, the first adhesive layer, the middle layer, the second adhesive layer and the hot-seal inner layer are integrally combined in a dry mode. Or the outer layer is a polyethylene film layer, the middle layer is a textile fiber layer, the first adhesive layer and the second adhesive layer are polyethylene resin layers or terpolymer resin layers, and the hot-seal inner layer is a polyethylene material layer; the outer layer, the first adhesive layer, the middle layer, the second adhesive layer and the hot-seal inner layer are integrally combined in an extruding mode. The flexible pipe material is rich in textile fiber, unique in appearance and capable of improving the mechanical strength of a pipe body.

Description

A kind of hose material for cosmetics of everyday use packaging and preparation method thereof
Technical field
The present invention relates to a kind of hose material for cosmetics of everyday use packaging and preparation method thereof.
Background technology
Composite soft tube is to occur successively in the nineties in last century, is used for replacing original aluminum pipe, due to the advantage of its cost, develops very fast in daily use chemicals are packed.But rest on aluminium-plastic pipe, full-plastic tube before multiple tube technology always, aluminize highlighted pipe and paper pipe, it is simply that contained material respectively aluminium foil, PE, aluminum plated PET, kraft paper in type pipe;In the face of the day by day diversified market demand of daily use chemicals packaging industry, it is necessary to a kind of containing textile fabric composite soft tube.The variation of abundant outward appearance while, body intensity can be made again to get a greater increase.
Summary of the invention
The technical problem to be solved is: provide a kind of hose material for cosmetics of everyday use packaging and preparation method thereof.
Solving above-mentioned technical problem, the technical solution adopted in the present invention is as follows:
A kind of hose material for cosmetics of everyday use packaging, it is characterized in that: described hose material is multilayer materials, this multilayer materials is provided with outer layer, the first tack coat, intermediate layer, the second tack coat and the heat-sealing internal layer being combined into one that be cascading and bond, wherein, described outer layer is as the outermost layer of composite soft tube, and described heat-sealing internal layer is as the innermost layer of composite soft tube;Described outer layer is textile fibre layer, described intermediate layer is film layer, described first tack coat and the second tack coat are polyurethane adhesive water layer, described heat-sealing internal layer is polythene material layer, and described outer layer, the first tack coat, intermediate layer, the second tack coat and heat-sealing internal layer are combined into one by dry type.
As a kind of embodiment of patent of the present invention, described textile fibre layer is any one in natural textile fiber, natural degradable fiber and chemical fibre.
A kind of preparation method of above-mentioned hose material, including:
First time composite steps: adopt dry-lamination process, with described first tack coat described outer layer together with described interlayer cohesive;Wherein, the parameter of dry-lamination process in first time composite steps is: processing temperature 60-100 DEG C, unwinding tension 15-25kg, winding tension 20-35kg, composite pressure 4-6kg;
Second time composite steps: adopt dry-lamination process, with the second tack coat, described intermediate layer and described heat-sealing internal layer are bonded together, become hose material;Wherein, in second time composite steps, the parameter of dry-lamination process is: processing temperature 220-320 DEG C, unwinding tension 15-25kg, winding tension 20-35kg, composite pressure 4-6kg.
A kind of hose material for cosmetics of everyday use packaging, it is characterized in that: described hose material is multilayer materials, this multilayer materials is provided with outer layer, the first tack coat, intermediate layer, the second tack coat and the heat-sealing internal layer being combined into one that be cascading and bond, wherein, described outer layer is as the outermost layer of composite soft tube, and described heat-sealing internal layer is as the innermost layer of composite soft tube;Described outer layer is film layer, described intermediate layer is textile fibre layer, described first tack coat and the second tack coat are polyvinyl resin layer or ter-polymer resin layer, described heat-sealing internal layer is polythene material layer, and described outer layer, the first tack coat, intermediate layer, the second tack coat and heat-sealing internal layer are combined into one by extrusion.
As a kind of embodiment of patent of the present invention, described textile fibre layer is any one in natural textile fiber, natural degradable fiber and chemical fibre.
A kind of preparation method of above-mentioned hose material, including:
First time composite steps: adopt extrusion composite technology, with described first tack coat described outer layer together with described interlayer cohesive;Wherein, in first time composite steps, the parameter of extrusion composite technology is: processing temperature 220-320 DEG C, unwinding tension 15-25kg, winding tension 20-35kg, composite pressure 4-6kg;
Second time composite steps: adopt extrusion composite technology, with described second tack coat, described intermediate layer and described heat-sealing internal layer are bonded together, become hose material;Wherein, in second time composite steps, the parameter of extrusion composite technology is: processing temperature 220-320 DEG C, unwinding tension 15-25kg, winding tension 20-35kg, composite pressure 4-6kg.
Compared with prior art, the method have the advantages that
The hose material of the present invention is multilayer materials, this multilayer materials is provided with outer layer, the first tack coat, intermediate layer, the second tack coat and the heat-sealing internal layer being combined into one that be cascading and bond, and by dry-lamination process, outer layer can be set to textile fibre layer or intermediate layer can be set to textile fibre layer by extrusion composite technology.Therefore, the composite soft tube body making patent of the present invention is obtained in that textile fabric is abundant, unique outward appearance improve the mechanical strength of body, thus, it is ensured that whole flexible pipe has sufficiently high intensity, contain more content, it is ensured that the daily chemical products of more than 200ml can be packed.Also ensure that the impact being amenable to harsher external environment in circulation and packaging field, it is ensured that product is indeformable, not damaged, it is prevented that content infiltrates and causes that shelf life of products declines simultaneously.Additionally natural degradable fibrous layer can realize most degraded and recovery, and the cost of degraded and recovery is also low, and environmental protection is practical, is of value to trend and the requirement of Sustainable Development in Future.
Accompanying drawing explanation
Below in conjunction with the drawings and specific embodiments, the present invention is described in further detail:
Fig. 1 is the structural representation of the hose material of the present invention.
Detailed description of the invention
Embodiment one
As shown in Figure 1, the hose material for cosmetics of everyday use packaging of the embodiment of the present invention one is multilayer materials, this multilayer materials is provided with outer layer the 1, first tack coat 2, intermediate layer the 3, second tack coat 4 and the heat-sealing internal layer 5 being combined into one that be cascading and bond, and, outer layer 1 is as the outermost layer of composite soft tube, and heat-sealing internal layer 5 is as the innermost layer of composite soft tube.
Wherein, above-mentioned outer layer 1 is textile fibre layer, this textile fibre layer is any one in natural textile fiber, natural degradable fiber and chemical fibre, intermediate layer 3 is film layer, first tack coat 2 and the second tack coat 4 are polyurethane adhesive water layer, heat-sealing internal layer 5 is heat sealable polythene material layer, and it primarily serves the heat-sealing effect of body, and outer layer the 1, first tack coat 2, intermediate layer the 3, second tack coat 4 and heat-sealing internal layer 5 are combined into one by dry type.
The preparation method of the hose material of the embodiment of the present invention one is compound-compound-tubulation-injection moulding, including:
First time composite steps: adopt dry-lamination process, with the first tack coat 2 i.e. polyurethane glue, outer layer 1 i.e. textile fibre layer and intermediate layer 3 i.e. film layer are bonded together.Wherein, the dry-lamination process selected parameter in first time composite steps is: processing temperature 60-100 DEG C;Unwinding tension 15-25kg;Winding tension 20-35kg;Composite pressure 4-6kg.
Second time composite steps: adopt dry-lamination process, with the second tack coat 4 i.e. polyurethane adhesive water layer, the intermediate layer 3 i.e. film layer and heat-sealing internal layer 5 i.e. polythene material layer completing first time compound is bonded together, becomes the hose material of the embodiment of the present invention one.Wherein, in second time composite steps, dry-lamination process selected parameter is: processing temperature 220-320 DEG C;Unwinding tension 15-25kg;Winding tension 20-35kg;Composite pressure 4-6kg.
After prepared by the hose material of above-described embodiment one, hose material is made flexible pipe;Corresponding multiple tube can also be made with overlap joint with docking;Selected parameter is high-frequency energy 30%-100%;Chilling temperature 15-22 DEG C;Pressure 2-5kg;Pipe in injection moulding on flexible pipe being takeed on, selected parameter is injection temperature 200-260 DEG C again;Pressure 20-50bar;Chilling temperature 10-20 DEG C.
Embodiment two
As shown in Figure 1, the hose material for cosmetics of everyday use packaging of the embodiment of the present invention two is essentially identical with embodiment one, they are distinctive in that: in the present embodiment two, outer layer 1 is film layer, intermediate layer 3 is textile fibre layer, this textile fibre layer is natural textile fiber, any one in natural degradable fiber and chemical fibre, first tack coat 2 and the second tack coat 4 are polyvinyl resin layer or ter-polymer resin layer, heat-sealing internal layer 5 is heat sealable polythene material layer, it primarily serves the heat-sealing effect of body, outer layer 1, first tack coat 2, intermediate layer 3, second tack coat 4 and heat-sealing internal layer 5 are combined into one by extrusion.
The preparation method of the hose material of the embodiment of the present invention two is compound-compound-tubulation-injection moulding, including:
First time composite steps: adopt extrusion composite technology, namely extrude film ter-polymer resin or polyvinyl resin layer with the first tack coat 2 and outer layer 1 i.e. film layer and intermediate layer 3 i.e. textile fibre layer are bonded together.Wherein, in first time composite steps, extrusion composite technology selected parameter is processing temperature 220-320 DEG C;Unwinding tension 15-25kg;Winding tension 20-35kg;Composite pressure 4-6kg.
Second time composite steps: adopt extrusion composite technology, namely extrude film ter-polymer resin or polyvinyl resin layer with the second tack coat 4 the intermediate layer 3 i.e. textile fibre layer and heat-sealing internal layer 5 i.e. polythene material layer completing first time compound is bonded together, become the hose material of the embodiment of the present invention two.Wherein, in second time composite steps, the extrusion composite technology selected parameter of extrusion composite technology is processing temperature 220-320 DEG C;Unwinding tension 15-25kg;Winding tension 20-35kg;Composite pressure 4-6kg.
After prepared by the hose material of above-described embodiment two, hose material is made flexible pipe;Corresponding multiple tube can also be made with overlap joint with docking;Selected parameter is high-frequency energy 30%-100%;Chilling temperature 15-22 DEG C;Pressure 2-5kg.Pipe in injection moulding on flexible pipe being takeed on, selected parameter is injection temperature 200-260 DEG C again;Pressure 20-50bar;Chilling temperature 10-20 DEG C.
The finished product that the composite soft tube of above-described embodiment one and embodiment two is made, through test, the data of 10 samples are as follows:
The present invention is not limited to above-mentioned detailed description of the invention; according to foregoing; ordinary technical knowledge and customary means according to this area; without departing under the above-mentioned basic fundamental thought premise of the present invention; the present invention can also make the equivalent modifications of other various ways, replacement or change, all falls among protection scope of the present invention.

Claims (6)

1. the hose material for cosmetics of everyday use packaging, it is characterized in that: described hose material is multilayer materials, this multilayer materials is provided with outer layer (1), the first tack coat (2), intermediate layer (3), the second tack coat (4) and heat-sealing internal layer (5) being combined into one that be cascading and bond, wherein, described outer layer (1) is as the outermost layer of composite soft tube, and described heat-sealing internal layer (5) is as the innermost layer of composite soft tube;Described outer layer (1) is textile fibre layer, described intermediate layer (3) is film layer, described first tack coat (2) and the second tack coat (4) are polyurethane adhesive water layer, described heat-sealing internal layer (5) is polythene material layer, and described outer layer (1), the first tack coat (2), intermediate layer (3), the second tack coat (4) and heat-sealing internal layer (5) are combined into one by dry type.
2. hose material according to claim 1, it is characterised in that: described textile fibre layer is any one in natural textile fiber, natural degradable fiber and chemical fibre.
3. a preparation method for hose material described in claim 1 or 2, including:
First time composite steps: adopt dry-lamination process, with described first tack coat (2), described outer layer (1) and described intermediate layer (3) are bonded together;Wherein, the parameter of dry-lamination process in first time composite steps is: processing temperature 60-100 DEG C, unwinding tension 15-25kg, winding tension 20-35kg, composite pressure 4-6kg;
Second time composite steps: adopt dry-lamination process, with the second tack coat (4), described intermediate layer (3) and described heat-sealing internal layer (5) are bonded together, become hose material;Wherein, in second time composite steps, the parameter of dry-lamination process is: processing temperature 220-320 DEG C, unwinding tension 15-25kg, winding tension 20-35kg, composite pressure 4-6kg.
4. the hose material for cosmetics of everyday use packaging, it is characterized in that: described hose material is multilayer materials, this multilayer materials is provided with outer layer (1), the first tack coat (2), intermediate layer (3), the second tack coat (4) and heat-sealing internal layer (5) being combined into one that be cascading and bond, wherein, described outer layer (1) is as the outermost layer of composite soft tube, and described heat-sealing internal layer (5) is as the innermost layer of composite soft tube;Described outer layer (1) is film layer, described intermediate layer (3) is textile fibre layer, described first tack coat (2) and the second tack coat (4) are polyvinyl resin layer or ter-polymer resin layer, described heat-sealing internal layer (5) is polythene material layer, and described outer layer (1), the first tack coat (2), intermediate layer (3), the second tack coat (4) and heat-sealing internal layer (5) are combined into one by extrusion.
5. hose material according to claim 4, it is characterised in that: described textile fibre layer is any one in natural textile fiber, natural degradable fiber and chemical fibre.
6. a preparation method for hose material described in claim 4 or 5, including:
First time composite steps: adopt extrusion composite technology, with described first tack coat (2), described outer layer (1) and described intermediate layer (3) are bonded together;Wherein, in first time composite steps, the parameter of extrusion composite technology is: processing temperature 220-320 DEG C, unwinding tension 15-25kg, winding tension 20-35kg, composite pressure 4-6kg;
Second time composite steps: adopt extrusion composite technology, with described second tack coat (4), described intermediate layer (3) and described heat-sealing internal layer (5) are bonded together, become hose material;Wherein, in second time composite steps, the parameter of extrusion composite technology is: processing temperature 220-320 DEG C, unwinding tension 15-25kg, winding tension 20-35kg, composite pressure 4-6kg.
CN201610269218.6A 2016-01-26 2016-04-26 Flexible pipe material used for packing daily chemical products and preparing method thereof Pending CN105799292A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2016200781405 2016-01-26
CN201620078140 2016-01-26

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CN201620368236.5U Active CN205588739U (en) 2016-01-26 2016-04-26 A hose material for cosmetics of everyday use packing

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109435341A (en) * 2018-11-22 2019-03-08 广东瑞远新材料有限公司 The composite soft tube of superelevation peel strength, composite hose sheet material and preparation method thereof
CN110181871A (en) * 2019-05-07 2019-08-30 广东瑞远新材料有限公司 A kind of environment-friendly biodegradable composite soft tube and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105799292A (en) * 2016-01-26 2016-07-27 广州瑞远新材料有限公司 Flexible pipe material used for packing daily chemical products and preparing method thereof

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Publication number Priority date Publication date Assignee Title
US20100218839A1 (en) * 2009-02-27 2010-09-02 Flexpipe Systems Inc. High temperature fiber reinfoced pipe
CN101941013A (en) * 2009-07-03 2011-01-12 湛江合力塑胶有限公司 Hose for high-pressure cleaning machine
CN104797409A (en) * 2012-11-16 2015-07-22 康斯博格驱动系统第二公司 Method of forming a hose assembly
CN204622716U (en) * 2015-04-27 2015-09-09 广州瑞远新材料有限公司 The false proof composite soft tube of printing-type
CN205588739U (en) * 2016-01-26 2016-09-21 广州瑞远新材料有限公司 A hose material for cosmetics of everyday use packing

Patent Citations (5)

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Publication number Priority date Publication date Assignee Title
US20100218839A1 (en) * 2009-02-27 2010-09-02 Flexpipe Systems Inc. High temperature fiber reinfoced pipe
CN101941013A (en) * 2009-07-03 2011-01-12 湛江合力塑胶有限公司 Hose for high-pressure cleaning machine
CN104797409A (en) * 2012-11-16 2015-07-22 康斯博格驱动系统第二公司 Method of forming a hose assembly
CN204622716U (en) * 2015-04-27 2015-09-09 广州瑞远新材料有限公司 The false proof composite soft tube of printing-type
CN205588739U (en) * 2016-01-26 2016-09-21 广州瑞远新材料有限公司 A hose material for cosmetics of everyday use packing

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109435341A (en) * 2018-11-22 2019-03-08 广东瑞远新材料有限公司 The composite soft tube of superelevation peel strength, composite hose sheet material and preparation method thereof
CN109435341B (en) * 2018-11-22 2023-12-01 广东瑞远新材料有限公司 Composite hose with ultrahigh peel strength, composite hose sheet and preparation method thereof
CN110181871A (en) * 2019-05-07 2019-08-30 广东瑞远新材料有限公司 A kind of environment-friendly biodegradable composite soft tube and preparation method thereof

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