CN105799194B - A kind of preparation method filled with the hollow microsphere expected in vain - Google Patents
A kind of preparation method filled with the hollow microsphere expected in vain Download PDFInfo
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- CN105799194B CN105799194B CN201610275128.8A CN201610275128A CN105799194B CN 105799194 B CN105799194 B CN 105799194B CN 201610275128 A CN201610275128 A CN 201610275128A CN 105799194 B CN105799194 B CN 105799194B
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- lower semisphere
- episphere
- printer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D22/00—Producing hollow articles
- B29D22/04—Spherical articles, e.g. balls
Abstract
The present invention provides a kind of preparation method filled with the hollow microsphere expected in vain, and step includes successively:The making of ball material, make lower hemisphere, the white material of filling, make upper hemisphere.Leftover pieces caused by cutting sheet material are carried out twice laid by the present invention, can not only reduce production cost, while being capable of the perfect inserts as polyurethane sheet;Produced by this method high filled with the hollow microsphere precision expected in vain, quality is outstanding, and added to that can be merged completely with black material during heating stirring in black material, ensure that the quality of production of polyurethane sheet.
Description
Technical field
Processed raw material field the invention belongs to polyurethane sheet, and in particular to a kind of making filled with the hollow microsphere expected in vain
Method.
Background technology
One of primary raw material of polyurethane sheet is hard polyurethane foam combination combined polyether, and hard polyurethane foam combined polyether is also known as
White material, with polymeric MDI nominal black and white material, is mixed black and white material by needing in the production process of polyurethane sheet.Simultaneously
The size needed for is needed to be cut when producing polyurethane sheet, leftover pieces caused by cutting are generally as waste material, so
Cause the lifting of production cost to a certain extent.
Therefore, it is the difficulty that those skilled in the art are badly in need of solving during how leftover pieces to be produced applied to polyurethane sheet
Topic.
The content of the invention
To solve the above problems, the invention discloses a kind of preparation method filled with the hollow microsphere expected in vain.
In order to achieve the above object, the present invention provides following technical scheme:
A kind of preparation method filled with the hollow microsphere expected in vain, step include successively:The making of ball material, under making
Hemisphere, the white material of filling, make upper hemisphere;Specific method is:
(1)Leftover pieces caused by collecting cutting sheet material, carry out drying and crushing after cleaning up, add hot melt powder,
And stir as ball material, and inject standby in 3D printer;
(2)The 3D models of hollow microsphere are established, and are decomposed by layer, form the horizontal frontal planes with sequence number a series of from the bottom to top
Figure, and while each horizontal frontal plane figure generate, all one corresponding antiplane figures of generation, i.e., every layer obtain it is positive and negative
Two figures;
(3)Positive and negative two figures generated by computer be converted into through chromacoder being loaded with respectively lower semisphere just,
The light beam of anti-graphics information and the light beam for being loaded with the positive and negative figure map information of episphere;
(4)Part photosensitive drum charging obtains current potential in 3D printer, through the light beam for being loaded with the positive figure map information of lower semisphere
Scanning, form the electrostatic latent image of the positive figure image of lower semisphere;
(5)The electrostatic latent image of the positive figure image of lower semisphere passes through magnetic brush, adsorbs one layer of ball material, and on-load voltage makes spheroid
Material falls into the model workbench of 3D printer, and the positive figure of lower semisphere being paved into by ball material is formed in model workbench;
(6)Residual photosensitive charging drum obtains current potential in 3D printer, through the light beam for being loaded with lower semisphere anti-graphics map information
Scanning, form the electrostatic latent image of lower semisphere anti-graphics image;
(7)The electrostatic latent image of lower semisphere anti-graphics image passes through magnetic brush, adsorbs one layer of ball material, and on-load voltage makes spheroid
Material falls into the model workbench of 3D printer, and the lower semisphere anti-graphics being paved into by ball material are formed in model workbench;
Anyway the printing of a layer pattern;
(8)Repeat step(4)-(7)Successively printed, until lower semisphere printing is completed;
(9)The model workbench of 3D printer is heated, up to the ball material shape of lower semisphere in model workbench
Into an entirety;The making of lower semisphere is completed after cooled and solidified;
(10)To step(9)After filling white material in the lower semisphere of acquisition, prepare to make episphere;
(11)Part photosensitive drum charging obtains current potential in 3D printer, through the light beam for being loaded with the positive figure map information of episphere
Scanning, form the electrostatic latent image of the positive figure image of episphere;
(12)The electrostatic latent image of the positive figure image of episphere passes through magnetic brush, adsorbs one layer of ball material, and on-load voltage makes ball
Body material is fallen on the lower semisphere of 3D printer model workbench, and the episphere being paved into by ball material is being formed on lower semisphere just
Figure;
(13)Residual photosensitive charging drum obtains current potential in 3D printer, through the light beam for being loaded with episphere anti-graphics map information
Scanning, form the electrostatic latent image of episphere anti-graphics image;
(14)The electrostatic latent image of episphere anti-graphics image passes through magnetic brush, adsorbs one layer of ball material, and on-load voltage makes ball
Body material is fallen on the lower semisphere of 3D printer model workbench, and it is anti-that the episphere being paved into by ball material is formed on lower semisphere
Figure;Anyway the printing of a layer pattern;
(15)Repeat step(11)-(14)Successively printed, until episphere printing is completed;
(16)The model workbench of 3D printer is heated, the ball material of lower semisphere and episphere is formed one
After entirety, the making of episphere and whole hollow microsphere is completed.
The invention provides a kind of preparation method filled with the hollow microsphere expected in vain, step includes successively:Ball material
Making, make lower hemisphere, the white material of filling, make upper hemisphere.The present invention by lower hemisphere and upper hemisphere separately sequentially
Make, and using the method for 3D printing, ensure to ensure lower hemisphere when making the lower hemisphere and upper hemisphere with cavity
And the integrality of upper hemisphere, while the size needs of lower hemisphere and upper hemisphere can be ensured, further ensure down
What hemisphere and upper hemisphere kept forming among hemispherical and lower hemisphere and upper hemisphere in heat fusion is used to fill out
Fill the sealing of the cavity of white material.
The material selection that lower hemisphere and upper hemisphere are made in the present invention is the cutting remaining leftover pieces of sheet material and hot melt
Property powder, select leftover pieces not only realize twice laid, can be used as the inserts in polyurethane sheet;The present invention is selecting
When selecting hot melt powder, it is desirable to it is low, only need to select not influenceing white material performance, while hot melt powder can also play it is viscous
The effect connect, viscosified, it is favorably improved the cohesive of forming laminated sheet material.
Lower hemisphere is when making, it is necessary first to establishes 3D models, and is decomposed by layer, is generating lower semisphere from the bottom to top just
Figure and therewith corresponding lower semisphere anti-graphics one by one, then by chromacoder be converted to lower semisphere just,
The light beam of anti-graphics information;3D printer is scanned to the light beam with the positive and negative graphical information of lower semisphere, is formed carry respectively
The electrostatic latent image of the positive and negative graphical information image of lower semisphere, sequentially charging obtains current potential to the photosensitive drums in 3D printer respectively, and
The electrostatic latent image of the positive and negative graphical information image of lower semisphere passes through magnetic brush successively, adsorbs ball material, and model work is fallen into after pressurization
In platform, the positive and negative figure of lower semisphere is paved into respectively, completes one layer of printing;Successively printed by above step, until whole lower semisphere
Body printing is completed, and after heating makes each layer mutually merge, cooled and solidified is into the lower hemisphere with hemispherical cavity;It will be ready to
White material fill into the cavity of lower hemisphere;Printing and making upper hemisphere in the same manner, formed with lower hemisphere whole
It is individual filled with the hollow microsphere expected in vain.
Preferably, step(1)In leftover pieces crush after size be 10-20 mesh.
The size of leftover pieces after being pulverized in the present invention is controlled in 10-20 mesh, can either be ensured and hot melt powder
Uniformly mixing, while can also ensure that there is certain filling effect as inserts.
Preferably, step(1)The mass ratio of middle leftover pieces and the hot melt powder of addition is 2~3:1.
Preferably, step(10)The white material of middle filling is not higher than 80% of hemispherical cavity height in lower semisphere.
It is that will not should be deformation during upper hemisphere fusion spills to ensure to fill the lower hemisphere after white material, the present invention
The height of the white material of middle filling keeps being not higher than 80% of hemispherical cavity height in lower semisphere.
The present invention carries out twice laid compared with prior art, by leftover pieces caused by cutting sheet material, can not only reduce
Production cost, while being capable of the perfect inserts as polyurethane sheet;Produced by this method hollow filled with expecting in vain
Microballoon precision is high, and quality is outstanding, and added to that can be merged completely with black material during heating stirring in black material, ensure that polyurethane
The quality of production of plate.
Embodiment
Technical scheme provided by the invention is described in detail below with reference to specific embodiment, it should be understood that following specific
Embodiment is only illustrative of the invention and is not intended to limit the scope of the invention.
The invention provides a kind of preparation method filled with the hollow microsphere expected in vain, it is characterised in that:Step is wrapped successively
Include:The making of ball material, make lower hemisphere, the white material of filling, make upper hemisphere;Specific method is:
(1)Leftover pieces caused by collecting cutting sheet material, carry out drying and crushing after cleaning up, after ensureing that leftover pieces crush
Size be 10 mesh, according to leftover pieces with addition hot melt powder 2:1 mass ratio addition hot melt powder, and stir
As ball material, and inject standby in 3D printer;
(2)The 3D models of hollow microsphere are established, and are decomposed by layer, form the horizontal frontal planes with sequence number a series of from the bottom to top
Figure, and while each horizontal frontal plane figure generate, all one corresponding antiplane figures of generation, i.e., every layer obtain it is positive and negative
Two figures;
(3)Positive and negative two figures generated by computer be converted into through chromacoder being loaded with respectively lower semisphere just,
The light beam of anti-graphics information and the light beam for being loaded with the positive and negative figure map information of episphere;
(4)Part photosensitive drum charging obtains current potential in 3D printer, through the light beam for being loaded with the positive figure map information of lower semisphere
Scanning, form the electrostatic latent image of the positive figure image of lower semisphere;
(5)The electrostatic latent image of the positive figure image of lower semisphere passes through magnetic brush, adsorbs one layer of ball material, and on-load voltage makes spheroid
Material falls into the model workbench of 3D printer, and the positive figure of lower semisphere being paved into by ball material is formed in model workbench;
(6)Residual photosensitive charging drum obtains current potential in 3D printer, through the light beam for being loaded with lower semisphere anti-graphics map information
Scanning, form the electrostatic latent image of lower semisphere anti-graphics image;
(7)The electrostatic latent image of lower semisphere anti-graphics image passes through magnetic brush, adsorbs one layer of ball material, and on-load voltage makes spheroid
Material falls into the model workbench of 3D printer, and the lower semisphere anti-graphics being paved into by ball material are formed in model workbench;
Anyway the printing of a layer pattern;
(8)Repeat step(4)-(7)Successively printed, until lower semisphere printing is completed;
(9)The model workbench of 3D printer is heated, up to the ball material shape of lower semisphere in model workbench
Into an entirety;The making of lower semisphere is completed after cooled and solidified;
(10)To step(9)After white material is filled in the lower semisphere of acquisition, and the white material filled is hemispherical in lower semisphere
The 80% of housing depth, and prepare to make episphere;
(11)Part photosensitive drum charging obtains current potential in 3D printer, through the light beam for being loaded with the positive figure map information of episphere
Scanning, form the electrostatic latent image of the positive figure image of episphere;
(12)The electrostatic latent image of the positive figure image of episphere passes through magnetic brush, adsorbs one layer of ball material, and on-load voltage makes ball
Body material is fallen on the lower semisphere of 3D printer model workbench, and the episphere being paved into by ball material is being formed on lower semisphere just
Figure;
(13)Residual photosensitive charging drum obtains current potential in 3D printer, through the light beam for being loaded with episphere anti-graphics map information
Scanning, form the electrostatic latent image of episphere anti-graphics image;
(14)The electrostatic latent image of episphere anti-graphics image passes through magnetic brush, adsorbs one layer of ball material, and on-load voltage makes ball
Body material is fallen on the lower semisphere of 3D printer model workbench, and it is anti-that the episphere being paved into by ball material is formed on lower semisphere
Figure;Anyway the printing of a layer pattern;
(15)Repeat step(11)-(14)Successively printed, until episphere printing is completed;
(16)The model workbench of 3D printer is heated, the ball material of lower semisphere and episphere is formed one
After entirety, the making of episphere and whole hollow microsphere is completed.
It is last it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and non-limiting technical side
Case, it will be understood by those within the art that, technical scheme is modified for those or equivalent substitution, and
The objective and scope of the technical program are not departed from, all should be covered among scope of the presently claimed invention.
Claims (4)
- A kind of 1. preparation method filled with the hollow microsphere expected in vain, it is characterised in that:Step includes successively:The system of ball material Make, make lower hemisphere, the white material of filling, make upper hemisphere;Specific method is:(1)Leftover pieces caused by collecting cutting sheet material, carry out drying and crushing after cleaning up, add hot melt powder, and stir Mix and be uniformly used as ball material, and inject standby in 3D printer;(2)The 3D models of hollow microsphere are established, and are decomposed by layer, form the horizontal frontal plane figures with sequence number a series of from the bottom to top, And while each horizontal frontal plane figure is generated, a corresponding antiplane figure is all generated, i.e., every layer obtains positive and negative two Figure;(3)Positive and negative two figures generated by computer are converted into being loaded with the positive and negative figure of lower semisphere respectively through chromacoder The light beam of shape map information and the light beam for being loaded with the positive and negative figure map information of episphere;(4)Part photosensitive drum charging obtains current potential in 3D printer, through the light beam for being loaded with the positive figure map information of lower semisphere Scanning, form the electrostatic latent image of the positive figure image of lower semisphere;(5)The electrostatic latent image of the positive figure image of lower semisphere passes through magnetic brush, adsorbs one layer of ball material, and on-load voltage makes spheroid Material falls into the model workbench of 3D printer, and the positive figure of lower semisphere being paved into by ball material is formed in model workbench;(6)Residual photosensitive charging drum obtains current potential in 3D printer, through the light beam for being loaded with lower semisphere anti-graphics map information Scanning, form the electrostatic latent image of lower semisphere anti-graphics image;(7)The electrostatic latent image of the lower semisphere anti-graphics image passes through magnetic brush, adsorbs one layer of ball material, and on-load voltage makes spheroid Material falls into the model workbench of 3D printer, and the lower semisphere anti-graphics being paved into by ball material are formed in model workbench; Anyway the printing of a layer pattern;(8)Repeat step(4)-(7)Successively printed, until lower semisphere printing is completed;(9)The model workbench of 3D printer is heated, until the ball material of lower semisphere forms one in model workbench Individual entirety;The making of lower semisphere is completed after cooled and solidified;(10)To step(9)After filling white material in the lower semisphere of acquisition, prepare to make episphere;(11)Part photosensitive drum charging obtains current potential in 3D printer, through the light beam for being loaded with the positive figure map information of episphere Scanning, form the electrostatic latent image of the positive figure image of episphere;(12)The electrostatic latent image of the positive figure image of episphere passes through magnetic brush, adsorbs one layer of ball material, and on-load voltage makes ball Body material is fallen on the lower semisphere of 3D printer model workbench, and the episphere being paved into by ball material is being formed on lower semisphere just Figure;(13)Residual photosensitive charging drum obtains current potential in 3D printer, through the light beam for being loaded with episphere anti-graphics map information Scanning, form the electrostatic latent image of episphere anti-graphics image;(14)The electrostatic latent image of the episphere anti-graphics image passes through magnetic brush, adsorbs one layer of ball material, and on-load voltage makes ball Body material is fallen on the lower semisphere of 3D printer model workbench, and it is anti-that the episphere being paved into by ball material is formed on lower semisphere Figure;Anyway the printing of a layer pattern;(15)Repeat step(11)-(14)Successively printed, until episphere printing is completed;(16)The model workbench of 3D printer is heated, the ball material of lower semisphere and episphere is formed an entirety Afterwards, the making of episphere and whole hollow microsphere is completed.
- A kind of 2. preparation method filled with the hollow microsphere expected in vain according to claim 1, it is characterised in that:The step Suddenly(1)In leftover pieces crush after size be 10-20 mesh.
- A kind of 3. preparation method filled with the hollow microsphere expected in vain according to claim 1, it is characterised in that:The step Suddenly(1)The mass ratio of middle leftover pieces and the hot melt powder of addition is 2~3:1.
- A kind of 4. preparation method filled with the hollow microsphere expected in vain according to claim 1, it is characterised in that:The step Suddenly(10)The white material of middle filling is not higher than 80% of hemispherical cavity height in lower semisphere.
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Effective date of registration: 20220307 Address after: 232100 east of No. 15 road, Fengtai Economic Development Zone, Huainan City, Anhui Province Patentee after: Anhui Ruijin Energy Saving Technology Co.,Ltd. Address before: 239000 No. 789, Xinglong Road, Wuyi Industrial Park, Nanqiao District, Chuzhou City, Anhui Province Patentee before: ANHUI RUILIAN ENERGY SAVING TECHNOLOGY CO.,LTD. |
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