CN105794820B - Mixed herbicide and application thereof containing flazasulfuron, carfentrazoneethyl and Flumetsulam - Google Patents
Mixed herbicide and application thereof containing flazasulfuron, carfentrazoneethyl and Flumetsulam Download PDFInfo
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- CN105794820B CN105794820B CN201410837088.2A CN201410837088A CN105794820B CN 105794820 B CN105794820 B CN 105794820B CN 201410837088 A CN201410837088 A CN 201410837088A CN 105794820 B CN105794820 B CN 105794820B
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- flumetsulam
- carfentrazoneethyl
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Abstract
The invention discloses a kind of mixed herbicide and application thereof containing flazasulfuron, carfentrazoneethyl and Flumetsulam, for the herbicide using flazasulfuron, carfentrazoneethyl and Flumetsulam as principle active component, the mass ratio of flazasulfuron, carfentrazoneethyl and Flumetsulam is 0.1~80：0.1~80：0.1~80.Application of the mixed herbicide of the present invention in Kill weeds, the application especially in Weeds in Turf in various grass family, Cyperaceae and broad leaved weed have remarkable result.Herbicide of the present invention under the premise of improving drug effect, delays Weed Resistance compared to single agent, and herbicidal spectrum is wide, and the lasting period is long, and has safety to lawn.
Description
Technical field
The invention belongs to technical field of pesticide, are related to a kind of herbicide, and in particular to a kind of flazasulfuron, carfentrazoneethyl with
The ternary of Flumetsulam mixes compounding agent, the herbicidal composition can be applied to lawn seedling before, postemergence weed control.
Background technology
With increasing substantially for the quickening of Urbanization in China, the promotion of urban afforestation standard and urban size, respectively
Kind lawn is come into being, and has caused the great demand to lawn, Development of Turf has good business opportunity.Ensureing highway, iron
The infrastructure such as road, airport, reservoir, riverbank, Hu Di are firm, aesthetic, and lawn is important auxiliary equipment；It is built in city
If, in terms of afforestation, " tropical island effect " that lawn can substantially improve living environment, effectively reduce city.Green grassland
Area, quality reflect The Surroundings in Cities quality and civilization degree.The city in some developed countries such as U.S., European Union is even more grass
Level ground industry is as one of national pillar industry.Currently, the Lawn Industry in China has large development, but not yet form complete integration
Industrial system.Lawn plays important in the spiritual civilization level of China's urban construction, living environment beautification and the raising people
Role, it not only has very high economic benefit, but also has huge ecological benefits and social benefit.
However, since management is improper, there is quality decline in many lawns, and turfgrass is dead, weedy, pest and disease damage
The problems such as occur again and again, the serious use value and landscape value for reducing lawn causes a large amount of fund to waste, so research grass
Level ground administrative skill, especially Kill weeds technology are the important measures for changing lawn present situation and improving ecological environment.
Artificial weeding, throwing work is big, weeding is not thorough, and has the disadvantage for trampleing on lawn, to reduce turf quality.Some places
It must not be changed without lawn, it is costly.Chemical weed control saving of work and time, low-cost high-efficiency, later stage weeds occurrence quantity is few, this is people
Work uprooting weed cannot than.And chemical weed control also has sealing process, and the weeds newly gone out later want much less.Chemical weed control is to grass
Level ground interference is few, and rational environment is provided for Turfgrass Growth.Weeding expense is low, and expense is the l/3-l/4 of labour cost, and one
The expense in year is the 1/4-1/5 of labour cost.Labor intensity is low, and a people can spray 7-9 mus of lawns, machine spraying effect daily
Rate higher has large area weeding advantage.In order to reduce the economic loss caused by crop smothering, reduce labor intensity, at the same also because
For chemical weed control is convenient, quick-acting, control time is long, chemical weed control is gradually received by people.
Flazasulfuron (flazasulfuron) is the sulfonylurea herbicide that the exploitation of industry chemical company is originated in by Japanese stone.
Chemical name 1- (4,6- dimethoxypyridin -2- bases) -3- (3- trifluoromethyl -2- pyridine sulfonyl sulfonyls) urea, structure are as follows：
Acetolactate synthestase (ALS) inhibitor.It is main to inhibit to generate side chain amino acid, leucine, isoleucine and figured silk fabrics
The reaction of the predecessor acetolactate synthestase of propylhomoserin.The medicament broad weed-killing spectrum, it is annual in Weeds in Turf that can not only be fabulous
Broad-leaved and grassy weed, and perennial broadleaf weed and sedge weed can also be prevented and kill off, such as lady's-grass, barnyard grass, eleusine indica, morning
Ripe standing grain, amur foxtail, green bristlegrass, the rhizome of nutgrass flatsedge, kyllinga brevifolia, cyperus iria, difformed galingale herb, alternanthera philoxeroides, Horseweed Herb, white axle
Grass, day recklessly appropriate, Tufted Cerastium, creeping oxalis, hairy tare, pale reddish brown mesh place, clover, pale persicaria, sheep hoof, euphorbia maculata, greater plantain,
Argy wormwood, sweet vernal grass, green amaranth, shepherd's purse, benbie, common vetch, chickweed etc., it is splendid to kyllinga brevifolia, lady's-grass and rhizome of nutgrass flatsedge preventive effect.
Under normal circumstances, weeds stop growing immediately after processing, the leaf chlorisis that newly sends out after absorbing 4-5 days, then by
Gradually necrosis and to spread to 20-30 days weeds of entire plant thoroughly withered.The medicament can be absorbed by weeds cauline leaf, and can inhibit soil
Suppressing weed seed germination in earth, control time is longer, and the lasting period is about 40 days or more in spring and summer, and autumn and winter is 120 days or more.
Flazasulfuron is that first, China formal registration is special on warm-season turf (Korea lawn grass class and Bermuda grass class)
Herbicide.Medicament can be decomposed rapidly after Korea lawn grass and Bermuda grass class turfgrass contact medicament, be converted into innocuous substance, Bu Huiying
The normal growth on lawn is rung, it is safe to turfgrass.It is used in lawn rest period, does not interfere with germination and growth in the future.
It is widely used in greening lawn, golf course etc..
Carfentrazoneethyl (carfentrazone-ethyl) is the triazolineone herbicide developed by FMC Corp., chemistry
Title：(RS) (the chloro- 5- of 2- (4- difluoromethyl -4,5- dihydro -3- methyl -5- oxygen -1H-1,2,4- triazol-1-yls)-of -2- chloro- 3
4- fluorophenyls) ethyl propionate, structure is as follows：
Carfentrazoneethyl is triazolineone selectivity herbicide after seedling.Proporphyrinogen oxidase inhibitor, by inhibiting leaf
Proporphyrinogen oxidase in green element biosynthetic process and destroy cell membrane, so that blade is dried up rapidly, is dead.Carfentrazoneethyl is being applied
It is absorbed by plant leaf blade in 15 minutes after medicine, not drenched with rain influences, and weeds occur as soon as poisoning symptom, 2-4 after 3-4 hours
It is dead.Prevent and kill off broad leaved weed and nutgrass flatsedge, as clearvers, white dead nettle, Veronica, chickweed, piemarker, red heart lamb's-quarters, blank pipe lead a cow,
The weeds such as lamb's-quarters, Amaranthus retroflexus, fruitlet flax, summer cypress, pale persicaria, benbie, black nightshade, sinapsis alba.Especially to clearvers, piemarker, red
Heart lamb's-quarters, the blank pipe weeds such as lead a cow have excellent preventive effect, and the certain weeds for generating antibody to sulfonylurea herbicide have good activity.
Recommend dosage 20-35g/hm2, to water spray processing.
Flumetsulam (Flumetsulam) is the triazole developed by road agricultural sciences (Dow Agroscience) company
And pyrimidine sulfonyl amine herbicide.Chemical name：2', 6'- bis- fluoro- 5- methyl (1,2,4)-triazol (1,5-a) pyrimidine -2- sulphurs
Its structure of anilide is as follows：
Flumetsulam is typical inhibitor of acetolactate synthetase.By inhibiting the synthesis of branched-chain amino acid to make albumen
Matter biosynthesis block, plant stop growing, final dead.Flumetsulam has very strong uptake and translocation, from plant absorption medicine
Agent start to occur damage symptoms, until Plant death be a slow process of comparison.Weeds absorb medicament after symptom be：
Blade middle arteries chlorosis, vein and blade tip fade, by lobus cardiacus yellowish-whiteization, purpleization, internode shorten, terminal bud death, final complete stool
It is dead.
Flumetsulam is a kind of broad spectrum weeding agent.Longevity of residure length, broad weed-killing spectrum, soil, cauline leaf process.It can be anti-
Except most of annual and perennial broadleaf weed, also have an inhibiting effect to young age grassy weed, such as to piemarker, lamb's-quarters, chickweed,
The preventive effects such as tattooing harvests, clearvers, Mandala, Amaranthus retroflexus, pineapple weed, corn radish are excellent, to knotweed, summer cypress, black nightshade, white dead nettle, grandmother
It receives, a variety of cruciferous weeds such as flowerofanhour root or herb, Siberian cocklebur and elegance and talent dish, penny cress also have significant preventive effect, to green bristlegrass, iron
Water chestnut has good activity.
Lawn herbicide is limited by safety at present, and herbicide controlling spectrum is also limited, and a kind of herbicide single dose is used alone cannot be complete
The full generation for efficiently controlling turf weed, furthermore some herbicides are since the water-soluble big or field lasting period is too long, dosage mistake
It is big or dispenser is uneven all be easy to cause residual hazard.Therefore, the present invention selects herbicide controlling spectrum different, the phonetic sulphur of pyridine of advantage and disadvantage complementation
It is made into mixture use after three kinds of herbicides of grand, carfentrazoneethyl and Flumetsulam suitably decrement, both expands herbicide controlling spectrum in this way, it is bright
It is aobvious to improve herbicidal effect, also avoid the possibility that poisoning and residual hazard are generated to lawn.
Invention content
The object of the present invention is to provide a kind of mixed herbicides containing flazasulfuron, carfentrazoneethyl and Flumetsulam.
It is a further object of the present invention to provide application of the herbicide before the seedling of lawn and/or in postemergence weed control.
A kind of mixed herbicide containing flazasulfuron, carfentrazoneethyl and Flumetsulam, it is characterised in that the herbicide with
Flazasulfuron, carfentrazoneethyl and Flumetsulam be principle active component, flazasulfuron, carfentrazoneethyl and Flumetsulam matter
Amount is than being 0.1~80：0.1~80：0.1~80.It is preferred that the mass ratio of flazasulfuron, carfentrazoneethyl and Flumetsulam be 1~
70：1~60：1~60, the mass ratio of further preferred flazasulfuron, carfentrazoneethyl and Flumetsulam is 1~5：1~60：1
~25, the most preferably mass ratio of flazasulfuron, carfentrazoneethyl and Flumetsulam is 1：1：18、3：2：25、5：4：1 or 3：60：
2。
In mixed herbicide, the quality percentage of flazasulfuron, carfentrazoneethyl and Flumetsulam three in herbicide
Content is 1~85%, and preferred mass percentage composition is 10~80%, and most preferably mass percentage is 10~65%.
In the flazasulfuron of the present invention, the ternary built preparation of carfentrazoneethyl and Flumetsulam, in addition to flazasulfuron, azoles
Outside the active ingredients such as ketone grass ester and Flumetsulam, the conventional surfactants allowed on pesticidal preparations, thickening can also be added
The auxiliary agents such as agent, solvent or solid packing are configured to any one dosage form allowed on pesticide.It is preferred that being processed into suspending agent, wettable
Pulvis, water dispersion granule, missible oil, microcapsule formulations.
Mixed herbicide of the present invention can be applied before the seedling of lawn and/or in postemergence weed control, especially in anti-weeding
Using with remarkable result in various grass family, Cyperaceae and broad leaved weed in level ground.
The herbicidal composition of the present invention has the following advantages：
1, activity of weeding is high.Flazasulfuron and Flumetsulam are all inhibitor of acetolactate synthetase.Mainly pass through root
Portion and stem absorb is transmitted to separate living tissue by conducting tissue, inhibits the biology of branched-chain amino acid (such as serine, isoleucine)
Synthesis.Carfentrazoneethyl proporphyrinogen oxidase inhibitor passes through proporphyrinogen oxidase during inhibition chlcrophyll biosynthesis
And cell membrane is destroyed, so that blade is dried up rapidly, is dead.The certain weeds for generating antibody to sulfonylurea herbicide have good work
Property.That is, the herbicidal composition of the present invention can kill weeds by three kinds of different approaches, it can greatly improve and remove
The removing activity of careless agent.
2, herbicidal spectrum is wide, and the lasting period is long.After flazasulfuron, carfentrazoneethyl are mixed with Flumetsulam three, action compensating,
Herbicidal spectrum is wider, moreover, because flazasulfuron is mainly effective to broad leaved weed and sedge weed, and can spread pesticide-clay mixture or spray
Mist；And carfentrazoneethyl is mainly used for preventing and kill off broad leaved weed and sedge weed, foliage-spray.And Flumetsulam can be prevented and kill off mostly
The annual and perennial broadleaf weed of number, also has inhibiting effect, soil, cauline leaf process to young age grassy weed.So
The herbicide of the present invention has the double action in foliar treatment and feud, extends the lasting period of medicament.So the weeding of the present invention
Agent has the double action in foliar treatment and feud, extends the lasting period of medicament.
3, delay Weed Resistance.Since weeds easily generate resistance to sulfonylurea herbicide, and in the herbicide of the present invention
Containing triazolineone herbicide carfentrazoneethyl and triazolopyrimidine sulfonamides herbicide Flumetsulam, medicament is enable to have
Prevent that the weeds in addition to anti-sulfonylurea extend the service life of medicament in addition, reducing resistance weed in effect ground.
4, safe.The herbicidal composition of the present invention is applied to Kill weeds, being capable of various standing grain in Weeds in Turf
Undergraduate course, Cyperaceae and broad leaved weed have safety under the premise of improving drug effect to lawn.
Therefore, mixed herbicide of the present invention can be applied in the herbicide for preparing Kill weeds, especially make
It is applied in the herbicide of various grass family, Cyperaceae and broad leaved weed in standby Weeds in Turf.
Specific implementation mode
Embodiment 1
Flazasulfuron 1%, carfentrazoneethyl 1%, Flumetsulam 18%, alkyl phenol polyoxyethylene ether 4%, polyoxyethylene are poly-
Oxygen propylene block compound 5%, thickener 2%, vegetable oil adds to 100%, and quality hundred is configured to according to conventional formulation method
It is 20% suspending agent to divide content.
Embodiment 2
Flazasulfuron 3%, carfentrazoneethyl 2%, Flumetsulam 25%, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 9%, alkyl
Phenol polyethenoxy ether 5%, sodium lignin sulfonate adds to 100%, and being configured to mass percentage according to conventional formulation method is
30% suspending agent.
Embodiment 3
Flazasulfuron 5%, carfentrazoneethyl 4%, Flumetsulam 1%, sodium lignin sulfonate 7%, dodecyl benzene sulfonic acid
Sodium 5%, ammonium sulfate 5%, diatomite complements to 100%, and it is 10% to be configured to mass percentage according to conventional formulation method
Water dispersion granule.
Embodiment 4
Flazasulfuron 3%, carfentrazoneethyl 60%, Flumetsulam 2%, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 6% are wooden
Plain sodium sulfonate 5%, white carbon 9%, kaolin complements to 100%, and mass percentage is configured to according to conventional formulation method
For 65% wettable powder.
Embodiment 5
Flazasulfuron 70%, carfentrazoneethyl 5%, Flumetsulam 5%, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 5% are wooden
Plain sodium sulfonate 4%, white carbon 5%, kaolin supplies 100%, and being configured to mass percentage according to conventional formulation method is
80% wettable powder.
Embodiment 6
Flazasulfuron 10%, carfentrazoneethyl 10%, Flumetsulam 60%, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 9%, alkane
Base phenol polyethenoxy ether 5%, sodium lignin sulfonate adds to 100%, and mass percentage is configured to according to conventional formulation method
For 80% missible oil.
Embodiment 7
1), toxicity determination test
Using the preparation in Examples 1 to 4, its co-toxicity coefficient to lawn common weed chickweed is measured.
Test method：The seed of quantitative chickweed is seeded in the disposable paper cup of 9cm respectively, in every glass sow 10~
15 seeds, are cultivated in illumination box, when 3~6 leaf phase of chickweed, are carried out at spraying in crawler crop spray
Reason.Continue to cultivate in greenhouse after processing, respectively processing weighs that each that treated is miscellaneous to the preventive effects of weeds to routine observation after 30d
Careless fresh weight calculates its toxicity regression curve and co-toxicity coefficient by the method that the nineteen sixties such as Sun Yunpei propose.Co-toxicity coefficient is more than
120, show that there is three kinds of active principles synergistic effect, co-toxicity coefficient to be less than 120, shows that three kinds of active principles are made with antagonism
With.Measurement result is as shown in table 1.
1 toxicity measurement result of table
As can be seen from the above table, the co-toxicity coefficient after three kinds of active principle compoundings is both greater than 100, and it is bright to illustrate that the present invention has
Aobvious synergistic effect.
2), field control effectiveness test
Reagent agent：
4 kinds of ternary built herbicides in Examples 1 to 4.
Comparison medicament：
25% flazasulfuron water dispersible granules (commercially available), 40% carfentrazoneethyl dry suspending agent (commercially available), 80% flumetsulam
Aqueous amine dispersible granule (commercially available).
For trying lawn：Bermuda grass
Bermuda grass was 3~5 leaf phases, was grown fine, robust plant, without other pest and disease damages.
Control object：
The lawns such as rhizoma alismatis, nutgrass flatsedge, apple, bog pondweed, arrowhead, difformed galingale herb, chickweed, lady's-grass, green bristlegrass, barnyard grass, eleusine indica
Gesture weeds.
Test method：
According to the area of experimental plot, good various medicaments of precise, and after being watered dilution, using knapsack sprayer,
Carry out even spraying, the dedicated Fan spray head of sprinkler selection herbicide.When spraying, it should be noted that it is small that liquid is uniformly sprayed application to experiment
Qu Zhong accomplishes no drain spray, the phenomenon that spraying more.
20d, 40d observe weeds death condition, and the activity of weeding of more various medicaments after medicine respectively after experiment.This
Outside, the growing state that also observe lawn in 1~15d after medicine, to investigate whether medicament has poisoning to lawn.
The embodiment of the present invention preparation Herbicidal Testing Trials effect see the table below 2 (20d after medicine) and table 3 (40d after medicine)
2 field control effectiveness test result of table (20d after medicine)
3 field control effectiveness test result of table (40d after medicine)
The present invention be can be seen that from table 2 and table 3 to grassy weed, sedge weed and broad leaved weed all with aobvious
The preventive effect of work, it is building performance notable, and also the lasting period is long.
Security survey result of 4 medicament of table to lawn
Lawn in each processing cell is grown fine, and is had no any medicine spot, is illustrated that various medicaments are safe to lawn.
Claims (8)
1. a kind of mixed herbicide containing flazasulfuron, carfentrazoneethyl and Flumetsulam, it is characterised in that the herbicide is with pyridine
Sulfometuron Methyl, carfentrazoneethyl and Flumetsulam are active ingredient, and the mass ratio of flazasulfuron, carfentrazoneethyl and Flumetsulam is
1：1：18、3：2：25、5：4：1、3：60：2.
2. mixed herbicide according to claim 1, it is characterised in that flazasulfuron, carfentrazoneethyl and Flumetsulam three
Mass percentage of the person in herbicide is 1~85%.
3. mixed herbicide according to claim 2, it is characterised in that flazasulfuron, carfentrazoneethyl and Flumetsulam three
Mass percentage of the person in herbicide is 10~80%.
4. mixed herbicide according to claim 3, it is characterised in that flazasulfuron, carfentrazoneethyl and Flumetsulam three
Mass percentage of the person in herbicide is 10~65%.
5. mixed herbicide according to claim 1, it is characterised in that it is with flazasulfuron, carfentrazoneethyl and flumetsulam
Amine is that the auxiliary agent allowed on principle active component and pesticide is configured to any one dosage form.
6. mixed herbicide according to claim 5, it is characterised in that the dosage form be suspending agent, wettable powder,
Water dispersible granules, missible oil.
7. application of the mixed herbicide described in claim 1 before the seedling of lawn and/or in postemergence weed control.
8. mixed herbicide described in claim 1 answering in various grass family, Cyperaceae and broad leaved weed in Weeds in Turf
With.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410837088.2A CN105794820B (en) | 2014-12-29 | 2014-12-29 | Mixed herbicide and application thereof containing flazasulfuron, carfentrazoneethyl and Flumetsulam |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410837088.2A CN105794820B (en) | 2014-12-29 | 2014-12-29 | Mixed herbicide and application thereof containing flazasulfuron, carfentrazoneethyl and Flumetsulam |
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| Publication Number | Publication Date |
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| CN105794820A CN105794820A (en) | 2016-07-27 |
| CN105794820B true CN105794820B (en) | 2018-08-03 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990002120A1 (en) * | 1988-08-31 | 1990-03-08 | Fmc Corporation | Herbicidal triazolinones |
| WO1996003878A1 (en) * | 1994-08-02 | 1996-02-15 | E.I. Du Pont De Nemours And Company | Herbicidal mixtures |
| CN103596437A (en) * | 2011-04-11 | 2014-02-19 | 石原产业株式会社 | Herbicidal composition comprising flazasulfuron and an inhibitor of protoporphyrinogen oxidase |
-
2014
- 2014-12-29 CN CN201410837088.2A patent/CN105794820B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990002120A1 (en) * | 1988-08-31 | 1990-03-08 | Fmc Corporation | Herbicidal triazolinones |
| WO1996003878A1 (en) * | 1994-08-02 | 1996-02-15 | E.I. Du Pont De Nemours And Company | Herbicidal mixtures |
| CN103596437A (en) * | 2011-04-11 | 2014-02-19 | 石原产业株式会社 | Herbicidal composition comprising flazasulfuron and an inhibitor of protoporphyrinogen oxidase |
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