CN105778455A - High-performance sheet molding compound - Google Patents
High-performance sheet molding compound Download PDFInfo
- Publication number
- CN105778455A CN105778455A CN201610154572.4A CN201610154572A CN105778455A CN 105778455 A CN105778455 A CN 105778455A CN 201610154572 A CN201610154572 A CN 201610154572A CN 105778455 A CN105778455 A CN 105778455A
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- CN
- China
- Prior art keywords
- parts
- molding compound
- sheet molding
- performance
- polystyrene
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
The invention relates to new materials, in particular to a sheet molding compound, and aims to provide a high-performance sheet molding compound which is simple in formulation. The high-performance sheet molding compound is composed of, by weight, 80 parts of unsaturated polyester resin, 23 parts of polystyrene, 17 parts of polymethyl methacrylate, 85 parts of porous powder quartz, 120 parts of long glass fiber, 6.5 parts of barium stearate, 3 parts of tert-butyl perobenzoate, 2.5 parts of N-phenyl maleimide, 4.5 parts of vinyl distearamide, 2.5 parts of molybdenum disulfide and 2 parts of calcium oxide. The high-performance sheet molding compound (SMC) has excellent physical performance index. High structural strength of a plastic product made of the SMC is guaranteed, weight of the plastic product is lowered greatly, and material cost is reduced remarkably.
Description
Technical field
The present invention relates to new material, be specifically related to a kind of sheet molding compound.
Background technology
SMC is the abbreviation of Sheet molding compound, i.e. sheet molding compound.The most former
Expect by SMC special yarn, unsaturated-resin, low shrinkage additive, filler and various auxiliary agent composition.
It primarily occur ins Europe in earlier 1960s, about nineteen sixty-five, and beautiful, day phase
Secondary has opened up this technique.China, the end of the eighties, has introduced the SMC production line of external advanced person
And production technology.SMC has superior electric property, decay resistance, light weight and engineering design
Easily, the advantage such as flexibly, its mechanical performance can compare favourably with part metals material, thus extensively
It is applied in the industries such as haulage vehicle, building, electronic/electrical gas.
These advantages based on sheet molding compound, field such as municipal administration rainwater treatment etc. makes the most more and more
Use laminar film plastic.But because the physical properties such as sheet molding compound structural strength are the highest, so
As when being embedded into the products such as the tank of underground, pipeline, the thickness of product is thicker, on the one hand
The heaviest, the most also waste processing cost.
Summary of the invention
It is an object of the invention to provide a kind of simple high-performance sheet molding compound of filling a prescription.
For achieving the above object, the technical solution adopted in the present invention is: a kind of high-performance sheet
Shape moulding compound, is made up of following weight portion: unsaturated polyester resin 80 parts, polystyrene 23 parts,
Polymethyl methacrylate 17 parts, 85 parts of periporate quartz, roving glass fiber 120 parts, barium stearate
6.5 parts, peroxidized t-butyl perbenzoate 3 parts, N-phenylmaleimide 2.5 parts, vinyl
Double stearic amides 4.5 parts, molybdenum bisuphide 2.5 parts, 2 parts of calcium oxide.
Preferably, described SMC material is processed into by the following method:
A. by described weight portion by polystyrene, polymethyl methacrylate, perbenzoic acid uncle
The double stearic amide of butyl ester, N-phenylmaleimide, vinyl and molybdenum bisuphide join not
In saturated polyester resin, mix;It is subsequently adding periporate quartz, barium stearate and calcium oxide
Powder, mixes, and obtains resin paste.
B. step a gained resin paste is coated on upper and lower two layers of polyethylene film uniformly, in
Between uniform settlement through silane coupler process after roving glass fiber, through extruding, make resin paste and long glass
Rolling after fine fully infiltration;
C. sheet material step b wound, thickening more than 45 hours at 35-45 DEG C.
The method have the advantages that the SMC material of the present invention, its physical performance index is excellent
Different.The plastic product being made up of the SMC material of the present invention is ensureing on the premise of high structural strength it
Weight will greatly reduce, and material cost substantially reduces.
Detailed description of the invention
The present invention provides the engineering plastics that can be used for making the plastic products such as Plastic Drum, plastic well.
Embodiment one
Described SMC material is i.e. sheet molding compound.It is made up of following weight portion: unsaturated polyester (UP)
Resin 80 parts, polystyrene 23 parts, polymethyl methacrylate 17 parts, periporate quartz 85
Part, roving glass fiber 120 parts, barium stearate 6.5 parts, peroxidized t-butyl perbenzoate 3 parts, N-benzene
Base maleimide 2.5 parts, the double stearic amide 4.5 parts of vinyl, molybdenum bisuphide 2.5 parts,
2 parts of calcium oxide.
Described SMC material is processed into by the following method:
A. by described weight portion by polystyrene, polymethyl methacrylate, perbenzoic acid uncle
The double stearic amide of butyl ester, N-phenylmaleimide, vinyl and molybdenum bisuphide join not
In saturated polyester resin, mix;
It is subsequently adding periporate quartz, barium stearate and lime powder, mixes, set
Fat is stuck with paste.
B. step a gained resin paste is coated on upper and lower two layers of polyethylene film uniformly, in
Between uniform settlement through silane coupler process after roving glass fiber, through extruding, make resin paste and long glass
Rolling after fine fully infiltration;
C. sheet material step b wound, thickening 48 hours at 35-45 DEG C.
SMC material performance indications such as following table is obtained through said method:
Test event | Unit | Testing standard | Numerical value |
Bending strength | MPa | ISO178-2001E | 190 |
Impact strength | KJ/m2 | ISO179-2000E | 93 |
Molding shrinkage | % | ISO2577-1984E | 0.15 |
Finished product density | g/cm3 | ISO1183-2004E | 1.75 |
In conjunction with upper table it can be seen that the SMC material of present invention employing, its performance indications are excellent.By
Its weight will be big on the premise of ensureing high structural strength for the tank body 1 that the SMC material of the present invention is made
Big reduction.
Embodiment two
It is made up of following weight portion: unsaturated polyester resin 80 parts, polystyrene 23 parts, poly-first
Base methyl acrylate 17 parts, 85 parts of periporate quartz, roving glass fiber 120 parts, barium stearate 6.5
Part, peroxidized t-butyl perbenzoate 3 parts, N-phenylmaleimide 2.5 parts, vinyl is double hard
Resin acid acid amides 4.5 parts, molybdenum bisuphide 2.5 parts, 2 parts of calcium oxide.
Described SMC material is processed into by the following method:
A. by described weight portion by polystyrene, polymethyl methacrylate, perbenzoic acid uncle
The double stearic amide of butyl ester, N-phenylmaleimide, vinyl and molybdenum bisuphide join not
In saturated polyester resin, mix;
It is subsequently adding periporate quartz, barium stearate and lime powder, mixes, set
Fat is stuck with paste.
B. step a gained resin paste is coated on upper and lower two layers of polyethylene film uniformly, in
Between uniform settlement through silane coupler process after roving glass fiber, through extruding, make resin paste and long glass
Rolling after fine fully infiltration;
C. sheet material step b wound, thickening 45 hours at 35-45 DEG C.
SMC material performance indications such as following table is obtained through said method:
Test event | Unit | Testing standard | Numerical value |
Bending strength | MPa | ISO178-2001E | 195 |
Impact strength | KJ/m2 | ISO179-2000E | 96 |
Molding shrinkage | % | ISO2577-1984E | 0.14 |
Finished product density | g/cm3 | ISO1183-2004E | 1.73 |
In conjunction with upper table it can be seen that the SMC material of present invention employing, its performance indications are excellent.By
Its weight will be big on the premise of ensureing high structural strength for the tank body 1 that the SMC material of the present invention is made
Big reduction.And above-mentioned repetition embodiment proves that the technique effect of the present invention can industrialize repetition.
Claims (2)
1. a high-performance sheet molding compound, it is characterised in that: it is made up of following weight portion: no
Saturated polyester resin 80 parts, polystyrene 23 parts, polymethyl methacrylate 17 parts, porous
Konilite 85 parts, roving glass fiber 120 parts, barium stearate 6.5 parts, peroxidized t-butyl perbenzoate 3
Part, N-phenylmaleimide 2.5 parts, the double stearic amide 4.5 parts of vinyl, molybdenum bisuphide
2.5 parts, 2 parts of calcium oxide.
The processing method of high-performance sheet molding compound the most according to claim 1, it is characterised in that:
Described SMC material is processed into by the following method:
A. by described weight portion by polystyrene, polymethyl methacrylate, perbenzoic acid uncle
The double stearic amide of butyl ester, N-phenylmaleimide, vinyl and molybdenum bisuphide join not
In saturated polyester resin, mix;It is subsequently adding periporate quartz, barium stearate and calcium oxide
Powder, mixes, and obtains resin paste;
B. step a gained resin paste is coated on upper and lower two layers of polyethylene film uniformly, in
Between uniform settlement through silane coupler process after roving glass fiber, through extruding, make resin paste and long glass
Rolling after fine fully infiltration;
C. sheet material step b wound, thickening more than 45 hours at 35-45 DEG C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610154572.4A CN105778455A (en) | 2016-03-17 | 2016-03-17 | High-performance sheet molding compound |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610154572.4A CN105778455A (en) | 2016-03-17 | 2016-03-17 | High-performance sheet molding compound |
Publications (1)
Publication Number | Publication Date |
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CN105778455A true CN105778455A (en) | 2016-07-20 |
Family
ID=56394109
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610154572.4A Pending CN105778455A (en) | 2016-03-17 | 2016-03-17 | High-performance sheet molding compound |
Country Status (1)
Country | Link |
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CN (1) | CN105778455A (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1110216A (en) * | 1993-11-25 | 1995-10-18 | 龙烜华 | Special unsaturated polyester film plastics and making method thereof |
CN102848652A (en) * | 2012-09-04 | 2013-01-02 | 江苏兆鋆新材料科技有限公司 | Antistatic flaky mold plastic, preparation method and application thereof |
CN105111555A (en) * | 2015-09-24 | 2015-12-02 | 界首市芮齐塑胶有限公司 | Acid and alkali resistant rubber material |
-
2016
- 2016-03-17 CN CN201610154572.4A patent/CN105778455A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1110216A (en) * | 1993-11-25 | 1995-10-18 | 龙烜华 | Special unsaturated polyester film plastics and making method thereof |
CN102848652A (en) * | 2012-09-04 | 2013-01-02 | 江苏兆鋆新材料科技有限公司 | Antistatic flaky mold plastic, preparation method and application thereof |
CN105111555A (en) * | 2015-09-24 | 2015-12-02 | 界首市芮齐塑胶有限公司 | Acid and alkali resistant rubber material |
Non-Patent Citations (3)
Title |
---|
由井浩: "《复合塑料的材料设计》", 30 September 1986, 上海科学技术文献出版社 * |
钱祥䴦: "《润滑剂与添加剂》", 31 August 1993, 高等教育出版社 * |
齐贵亮: "《塑料成型物料配制工》", 31 January 2012, 机械工业出版社 * |
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PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160720 |