CN105778377A - Glass fiber reinforced polyacrylic resin composite material - Google Patents
Glass fiber reinforced polyacrylic resin composite material Download PDFInfo
- Publication number
- CN105778377A CN105778377A CN201610313348.5A CN201610313348A CN105778377A CN 105778377 A CN105778377 A CN 105778377A CN 201610313348 A CN201610313348 A CN 201610313348A CN 105778377 A CN105778377 A CN 105778377A
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- China
- Prior art keywords
- glass fiber
- parts
- fiber reinforced
- resin composite
- polyacrylic resin
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- 239000003365 glass fiber Substances 0.000 title claims abstract description 46
- 239000004925 Acrylic resin Substances 0.000 title claims abstract description 30
- 239000002131 composite material Substances 0.000 title abstract description 9
- -1 polyethylene Polymers 0.000 claims abstract description 41
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 34
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 34
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004698 Polyethylene Substances 0.000 claims abstract description 19
- 229920000573 polyethylene Polymers 0.000 claims abstract description 19
- GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 claims abstract description 17
- 239000011787 zinc oxide Substances 0.000 claims abstract description 17
- 239000005639 Lauric acid Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 6
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims description 23
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims description 23
- 239000004743 Polypropylene Substances 0.000 claims description 16
- GTDHYNXLIKNVTJ-UHFFFAOYSA-N n-(1-hydroxy-2-methylpropan-2-yl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NC(C)(C)CO GTDHYNXLIKNVTJ-UHFFFAOYSA-N 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 15
- 229920001155 polypropylene Polymers 0.000 claims description 15
- 239000000805 composite resin Substances 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims description 7
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 7
- 229930016911 cinnamic acid Natural products 0.000 claims description 7
- 235000013985 cinnamic acid Nutrition 0.000 claims description 7
- 239000012467 final product Substances 0.000 claims description 7
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 abstract description 6
- 229920001577 copolymer Polymers 0.000 abstract description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 abstract 2
- 239000010445 mica Substances 0.000 abstract 1
- 229910052618 mica group Inorganic materials 0.000 abstract 1
- 229940037312 stearamide Drugs 0.000 abstract 1
- 239000000463 material Substances 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 4
- 238000001514 detection method Methods 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000009967 tasteless effect Effects 0.000 description 2
- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000013500 performance material Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/016—Additives defined by their aspect ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
The invention discloses a glass fiber reinforced polyacrylic resin composite material. The glass fiber reinforced polyacrylic resin composite material is prepared from the following raw materials in parts by weight: 50 parts of polyacrylic resin, 30 to 50 parts of chopped glass fiber, 2 to 10 parts of stearamide, 15 to 25 parts of stryenemaleic anhydride copolymer, 6 to 12 parts of brominated polyethylene, 4 to 10 parts of mica, 2 to 8 parts of zinc oxide, 1 to 5 parts of barium sulfate, 1 to 5 parts of cupric iodide and 1 to 5 parts of lauric acid. Compared with the prior art, the glass fiber reinforced polyacrylic resin composite material disclosed by the invention has the advantages of low cost, simple process, high strength, predominant high temperature resistance and excellent overall properties of products.
Description
Technical field
The present invention relates to a kind of glass fiber reinforced polypropylene acid resin composite, belong to polymer composite technology neck
Territory.
Background technology
Polypropylene is polymer nontoxic, that odorless, tasteless milky are highly crystalline, and degree of crystallinity is high, compound with regular structure, thus
There is excellent mechanical property.The absolute value of Mechanical Properties of PP is higher than polyethylene, but still falls within a plastic material partially
Low kind, its hot strength only can reach the level of 30MPa or slightly higher.It is nontoxic, tasteless, and density is little, intensity,
Rigidity, hardness thermostability are superior to low-pressure polyethylene, can be about 100 DEG C uses.There is good dielectric properties and height
Frequently insulating properties and not affected by humidity, but become fragile during low temperature, the most wear-resisting, the most aging.Be suitable to make common mechanical part,
Corrosion-resistant part and insulating part.It is worked by the organic solvents such as common acid, alkali hardly, can be used for tableware.
For improving the performance of macromolecular material, macromolecular material is modified by expansive approach market, thus improves material and combine
Closing performance, the potential various functions of excavated material are human material's most popular methods of industry, extensively apply in many fields.
(English original name is glass fibre: glass fiber or fiberglass) be the inorganic non-metallic material of a kind of excellent performance
Material, of a great variety, advantage is good insulating, thermostability is strong, corrosion resistance good, and mechanical strength is high, but shortcoming is that property is crisp,
Wearability is poor.It is through high temperature melting, wire drawing, doff, the technique system such as weave cotton cloth with glass bead or discarded glass for raw material
Cause, a diameter of several microns of its monofilament to twenties meters micron, be equivalent to the 1/20-1/5 of a hairline,
Every bundle fiber precursor is all made up of hundreds of the most thousands of monofilament.The enhancing material that glass fibre is typically used as in composite
Material, electrically insulating material and heat-insulating material, the national economy every field such as circuit substrate.
At present, the research of existing a large amount of fiber glass reinforcements, but often there are some defects, as product strength is low,
Resistance to elevated temperatures difference etc., it is impossible to give full play to the advantage that glass fibre is compound.
Summary of the invention
Goal of the invention: in order to overcome the deficiencies in the prior art, the present invention provides a kind of glass fiber reinforced polypropylene
Acid resin composite.
Technical scheme: for achieving the above object, the present invention provides a kind of glass fiber reinforced polypropylene acid resin composite,
It is mainly by made by the raw material of following weight ratio:
Polyacrylic resin 50 parts, short glass fiber 30-50 part, stearmide 2-10 part,
Styrene maleic anhydride copolymer 15-25 part, brominated polyethylene 6-12 part, Muscovitum 4-10 part,
Zinc oxide 2-8 part, barium sulfate 1-5 part, Copper diiodide 1-5 part, lauric acid 1-5 part.
As preferably, described glass fiber reinforced polypropylene acid resin composite is mainly by following weight ratio
Made by raw material:
Polyacrylic resin 50 parts, short glass fiber 35-45 part, stearmide 4-8 part,
Styrene maleic anhydride copolymer 18-22 part, brominated polyethylene 8-10 part, Muscovitum 6-8 part,
Zinc oxide 4-6 part, barium sulfate 2-4 part, Copper diiodide 2-4 part, lauric acid 2-4 part.
Preferred as another kind, the mean molecule quantity of described polyacrylic resin is 80000-100000.
Preferred as another kind, the draw ratio of described short glass fiber is 4-8.
Preferred as another kind, the degree of polymerization of described styrene maleic anhydride copolymer is 80-100.
Preferred as another kind, described glass fiber reinforced polypropylene acid resin composite is mainly by following steps institute
Make:
(1) polyacrylic resin, stearmide, styrene maleic anhydride copolymer and brominated polyethylene mixing are taken, so
Rear melted, it is stirred continuously；
(2) add short glass fiber, Muscovitum, zinc oxide, barium sulfate, Copper diiodide and the moon under above-mentioned molten condition
Cinnamic acid, continues stirring；
(3) after stirring terminates, molding, to obtain final product.
As further preferably, described in step (2), mixing time is 2-4h.
Beneficial effect: relative to prior art, the glass fiber reinforced polypropylene acid resin composite of gained of the present invention,
Low cost, technique is simple, and not only intensity is high, and resistance to elevated temperatures highlights simultaneously, and product overall performance is excellent.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further described.
Embodiment 1:
Prescription:
Polyacrylic resin 50 parts, short glass fiber 30 parts, stearmide 2 parts,
Styrene maleic anhydride copolymer 15 parts, brominated polyethylene 6 parts, 4 parts of Muscovitum,
Zinc oxide 2 parts, 1 part of barium sulfate, Copper diiodide 1 part, lauric acid 1 part.
The mean molecule quantity of described polyacrylic resin is 80000；The draw ratio of described short glass fiber is 4；
The degree of polymerization of described styrene maleic anhydride copolymer is 80.
Preparation method:
(1) polyacrylic resin, stearmide, styrene maleic anhydride copolymer and brominated polyethylene mixing are taken, so
Rear melted, it is stirred continuously；
(2) add short glass fiber, Muscovitum, zinc oxide, barium sulfate, Copper diiodide and the moon under above-mentioned molten condition
Cinnamic acid, continues stirring；
(3) after stirring terminates, molding, to obtain final product.
Described in step (2), mixing time is 2h.
Embodiment 2:
Prescription:
Polyacrylic resin 50 parts, short glass fiber 50 parts, stearmide 10 parts,
Styrene maleic anhydride copolymer 25 parts, brominated polyethylene 12 parts, 10 parts of Muscovitum,
Zinc oxide 8 parts, 5 parts of barium sulfate, Copper diiodide 5 parts, lauric acid 5 parts.
The mean molecule quantity of described polyacrylic resin is 100000；The draw ratio of described short glass fiber is 8；
Preferred as another kind, the degree of polymerization of described styrene maleic anhydride copolymer is 100.
Preparation method:
(1) polyacrylic resin, stearmide, styrene maleic anhydride copolymer and brominated polyethylene mixing are taken, so
Rear melted, it is stirred continuously；
(2) add short glass fiber, Muscovitum, zinc oxide, barium sulfate, Copper diiodide and the moon under above-mentioned molten condition
Cinnamic acid, continues stirring；
(3) after stirring terminates, molding, to obtain final product.
Described in step (2), mixing time is 4h.
Embodiment 3:
Prescription:
Polyacrylic resin 50 parts, short glass fiber 40 parts, stearmide 6 parts,
Styrene maleic anhydride copolymer 20 parts, brominated polyethylene 9 parts, 7 parts of Muscovitum,
Zinc oxide 5 parts, 3 parts of barium sulfate, Copper diiodide 3 parts, lauric acid 3 parts.
The mean molecule quantity of described polyacrylic resin is 90000；The draw ratio of described short glass fiber is 6；
The degree of polymerization of described styrene maleic anhydride copolymer is 90.
Preparation method:
(1) polyacrylic resin, stearmide, styrene maleic anhydride copolymer and brominated polyethylene mixing are taken, so
Rear melted, it is stirred continuously；
(2) add short glass fiber, Muscovitum, zinc oxide, barium sulfate, Copper diiodide and the moon under above-mentioned molten condition
Cinnamic acid, continues stirring；
(3) after stirring terminates, molding, to obtain final product.
Described in step (2), mixing time is 3h.
Embodiment 4:
Prescription:
Polyacrylic resin 50 parts, short glass fiber 35 parts, stearmide 4 parts,
Styrene maleic anhydride copolymer 18 parts, brominated polyethylene 8 parts, 6 parts of Muscovitum,
Zinc oxide 4 parts, 2 parts of barium sulfate, Copper diiodide 2 parts, lauric acid 2 parts.
The mean molecule quantity of described polyacrylic resin is 90000；The draw ratio of described short glass fiber is 5；
Preferred as another kind, the degree of polymerization of described styrene maleic anhydride copolymer is 85.
Preparation method:
(1) polyacrylic resin, stearmide, styrene maleic anhydride copolymer and brominated polyethylene mixing are taken, so
Rear melted, it is stirred continuously；
(2) add short glass fiber, Muscovitum, zinc oxide, barium sulfate, Copper diiodide and the moon under above-mentioned molten condition
Cinnamic acid, continues stirring；
(3) after stirring terminates, molding, to obtain final product.
Described in step (2), mixing time is 3h.
Embodiment 5:
Prescription:
Polyacrylic resin 50 parts, short glass fiber 45 parts, stearmide 8 parts,
Styrene maleic anhydride copolymer 22 parts, brominated polyethylene 10 parts, 8 parts of Muscovitum,
Zinc oxide 6 parts, 4 parts of barium sulfate, Copper diiodide 4 parts, lauric acid 4 parts.
The mean molecule quantity of described polyacrylic resin is 90000；The draw ratio of described short glass fiber is 7；
Preferred as another kind, the degree of polymerization of described styrene maleic anhydride copolymer is 95.
Preparation method:
(1) polyacrylic resin, stearmide, styrene maleic anhydride copolymer and brominated polyethylene mixing are taken, so
Rear melted, it is stirred continuously；
(2) add short glass fiber, Muscovitum, zinc oxide, barium sulfate, Copper diiodide and the moon under above-mentioned molten condition
Cinnamic acid, continues stirring；
(3) after stirring terminates, molding, to obtain final product.
Described in step (2), mixing time is 3h.
Experimental example gained of the present invention composite property detects
Compareing 1 group and use the embodiment of the present invention 3 prescription and preparation method, difference is: described polyacrylic resin
Viscosity-average molecular weight be 70000 (not in the range of 80000-100000 of the present invention)；
Compareing 2 groups and use the embodiment of the present invention 3 prescription and preparation method, difference is: described styrene maleic acid
The degree of polymerization of anhydride copolymer is 110 (not in the range of 80-100 of the present invention)；
Compareing 3 groups and use the embodiment of the present invention 3 prescription and preparation method, difference is: described polyacrylic resin
Viscosity-average molecular weight be 110000 (not in the range of 80000-100000 of the present invention), described maleic anhydride of styrene copolymerization
The degree of polymerization of thing is 70 (not in the range of 80-100 of the present invention)；
Finally investigating properties of product, tensile property uses the detection of ISO527 method, and thermodynamic property uses ISO75 method
Detection, result see table 1.
Table 1 gained of the present invention composite property testing result (n=3)
Note: compare with matched group, * P < 0.05
By upper Biao Ke get, compared with compareing 1 group, 2 groups and 3 groups, the embodiment of the present invention 3,4 and 5 gained composite wood
Material is through detection, and result shows that its hot strength and heat distortion temperature are significantly increased, shows product strength and heat-resisting quantity
Can be prominent.
Claims (7)
1. a glass fiber reinforced polypropylene acid resin composite, it is characterised in that it is mainly by following weight
Made by the raw material of part ratio:
Polyacrylic resin 50 parts, short glass fiber 30-50 part, stearmide 2-10 part,
Styrene maleic anhydride copolymer 15-25 part, brominated polyethylene 6-12 part, Muscovitum 4-10 part,
Zinc oxide 2-8 part, barium sulfate 1-5 part, Copper diiodide 1-5 part, lauric acid 1-5 part.
Glass fiber reinforced polypropylene acid resin composite the most according to claim 1, it is characterised in that its
Mainly by made by the raw material of following weight ratio:
Polyacrylic resin 50 parts, short glass fiber 35-45 part, stearmide 4-8 part,
Styrene maleic anhydride copolymer 18-22 part, brominated polyethylene 8-10 part, Muscovitum 6-8 part,
Zinc oxide 4-6 part, barium sulfate 2-4 part, Copper diiodide 2-4 part, lauric acid 2-4 part.
Glass fiber reinforced polypropylene acid resin composite the most according to claim 1, it is characterised in that institute
The mean molecule quantity stating polyacrylic resin is 80000-100000.
Glass fiber reinforced polypropylene acid resin composite the most according to claim 1, it is characterised in that institute
The draw ratio stating short glass fiber is 4-8.
Glass fiber reinforced polypropylene acid resin composite the most according to claim 1, it is characterised in that institute
The degree of polymerization stating styrene maleic anhydride copolymer is 80-100.
Glass fiber reinforced polypropylene acid resin composite the most according to claim 1, it is characterised in that it
Mainly by made by following steps:
(1) polyacrylic resin, stearmide, styrene maleic anhydride copolymer and brominated polyethylene mixing are taken, so
Rear melted, it is stirred continuously；
(2) add short glass fiber, Muscovitum, zinc oxide, barium sulfate, Copper diiodide and the moon under above-mentioned molten condition
Cinnamic acid, continues stirring；
(3) after stirring terminates, molding, to obtain final product.
Glass fiber reinforced polypropylene acid resin composite the most according to claim 6, it is characterised in that step
Suddenly mixing time described in (2) is 2-4h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313348.5A CN105778377A (en) | 2016-05-11 | 2016-05-11 | Glass fiber reinforced polyacrylic resin composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313348.5A CN105778377A (en) | 2016-05-11 | 2016-05-11 | Glass fiber reinforced polyacrylic resin composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105778377A true CN105778377A (en) | 2016-07-20 |
Family
ID=56402173
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610313348.5A Pending CN105778377A (en) | 2016-05-11 | 2016-05-11 | Glass fiber reinforced polyacrylic resin composite material |
Country Status (1)
| Country | Link |
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| CN (1) | CN105778377A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109431817A (en) * | 2018-12-20 | 2019-03-08 | 四川华柚医疗器械有限公司 | A kind of new type resin tooth and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1450112A (en) * | 2002-04-10 | 2003-10-22 | 中国石油化工股份有限公司 | Composition of fiber reinforced polymer |
| CN102558728A (en) * | 2012-01-13 | 2012-07-11 | 上海多凯复合材料有限公司 | Reinforced acrylic resin compound material |
| CN103910962A (en) * | 2012-12-28 | 2014-07-09 | 奇美实业股份有限公司 | Polymethacrylate Composition |
| CN104072923A (en) * | 2014-06-18 | 2014-10-01 | 金发科技股份有限公司 | High-heat-resistant transparent reinforcing material as well as preparation method and application thereof |
-
2016
- 2016-05-11 CN CN201610313348.5A patent/CN105778377A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1450112A (en) * | 2002-04-10 | 2003-10-22 | 中国石油化工股份有限公司 | Composition of fiber reinforced polymer |
| CN102558728A (en) * | 2012-01-13 | 2012-07-11 | 上海多凯复合材料有限公司 | Reinforced acrylic resin compound material |
| CN103910962A (en) * | 2012-12-28 | 2014-07-09 | 奇美实业股份有限公司 | Polymethacrylate Composition |
| CN104072923A (en) * | 2014-06-18 | 2014-10-01 | 金发科技股份有限公司 | High-heat-resistant transparent reinforcing material as well as preparation method and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109431817A (en) * | 2018-12-20 | 2019-03-08 | 四川华柚医疗器械有限公司 | A kind of new type resin tooth and preparation method thereof |
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Application publication date: 20160720 |