CN105778163A - High polymer material for preparing environment-friendly Christmas ball and preparation method of high polymer material - Google Patents
High polymer material for preparing environment-friendly Christmas ball and preparation method of high polymer material Download PDFInfo
- Publication number
- CN105778163A CN105778163A CN201610332364.9A CN201610332364A CN105778163A CN 105778163 A CN105778163 A CN 105778163A CN 201610332364 A CN201610332364 A CN 201610332364A CN 105778163 A CN105778163 A CN 105778163A
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- high polymer
- macromolecular material
- polymer material
- christmas ball
- preparing
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/005—Lignin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
The invention discloses a high polymer material for preparing an environment-friendly Christmas ball and a preparation method of the high polymer material. The high polymer material is prepared from the following raw materials: biomass high polymer materials, ceramic powder, plastic, glycerol, epoxidized soybean oil and maleic anhydride. The high polymer material can be applied to the blow molding of the environment-friendly Christmas ball. According to the formula, the reutilization of waste plastic is realized, and furthermore, the obtained high polymer material has partial biodegradability, so that the environmental pollution can be reduced, and the environmental friendliness can be realized; and the environment-friendly Christmas ball prepared from the high polymer material has the advantages of good wear resistance, flame retardance and the like.
Description
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of macromolecular material for preparing environmental protection Christmas ball and preparation method thereof.
Background technology
Christmas ball, as a kind of ornament of Christmas Day, has very tempting market.China is as the main supply country of Christmas ball in America, Europe and Asia, and the annual plastics for preparing Christmas ball easily cause serious environmental pollution.Adopt biomass macromolecular material and waste or used plastics as the raw material of the plastics preparing Christmas ball, achieve waste or used plastics again with, and owing to the macromolecular material of gained has part biodegradable, therefore, environmental pollution can be reduced, it is achieved the purpose of environmental protection.
Summary of the invention
It is an object of the invention to provide a kind of macromolecular material for preparing environmental protection Christmas ball and preparation method thereof.Achieve waste or used plastics again with, reduce environmental pollution, it is achieved the purpose of environmental protection.And make gained Christmas ball have the advantages such as wearability is good and fire-retardant.
For achieving the above object, the present invention adopts the following technical scheme that
A kind of macromolecular material for preparing environmental protection Christmas ball, is made up of following raw material: biomass macromolecular material 30-50 part, ceramics 10-20 part, plastics 10-20 part, glycerol 20-30 part, epoxy soybean oil 2-10 part, maleic anhydride 1-5 part.Described biomass macromolecular material is the one in starch, lignin or cellulose；Described plastics are waste and old thermoplastic.This is used for the preparation method preparing the macromolecular material of environmental protection Christmas ball；Comprise the following steps:
(1) by biomass macromolecular material, glycerol and epoxy soybean oil mix homogeneously, mixture is obtained；
(2) by the mixture of step (1) gained, plastifying 5-8min, obtain modified biomass macromolecular material in banbury, described plasticization temperature is 100-120 DEG C；
(3) take modified biomass macromolecular material, maleic anhydride, ceramics and plastics that step (2) obtains to be uniformly mixed according to a ratio；Then, again in banbury, at 120-200 DEG C, banburying obtains material；
(4) by step (3) resulting materials, Christmas ball is obtained by blow molding.
The remarkable advantage of the present invention:
Present invention achieves waste or used plastics again with, and owing to the macromolecular material of gained has part biodegradable, therefore, it is possible to reduce environmental pollution, it is achieved the purpose of environmental protection.The Christmas ball that gained Polymer materialspreparation obtains is had the advantages such as wearability is good and fire-retardant.
Detailed description of the invention
Embodiment 1
A kind of macromolecular material for preparing environmental protection Christmas ball, with starch, ceramics, waste or used plastics polyethylene, glycerol, epoxy soybean oil and maleic anhydride for raw material, its preparation process is as follows:
(1) by starch 40 parts, 25 parts and 5 parts epoxy soybean oil mix homogeneously of glycerol, mixture is obtained；
(2) by the mixture of step (1) gained, plastifying 5min, obtain modified biomass macromolecular material in banbury, described plasticization temperature is 100 DEG C；
(3) take the modified biomass macromolecular material of step (2) gained, 3 parts of maleic anhydrides, ceramics 20 parts and plastic polyethylene 20 parts to be uniformly mixed according to a ratio；Then, again in banbury, at 120 DEG C, banburying obtains material；
(4) by step (3) resulting materials, Christmas ball is obtained by blow molding.
Embodiment 2
A kind of macromolecular material for preparing environmental protection Christmas ball, with lignin, ceramics, waste or used plastics acrylonitrile-butadiene-styrene (ABS) plastics (ABS), glycerol and antioxidant for raw material, its preparation process is as follows:
(1) by lignin 50 parts, 30 parts and 10 parts epoxy soybean oil mix homogeneously of glycerol, mixture is obtained；
(2) by the mixture of step (1) gained, plastifying 8min, obtain modified biomass macromolecular material in banbury, described plasticization temperature is 120 DEG C；
(3) take the modified biomass macromolecular material of step (2) gained, 5 parts of maleic anhydrides, ceramics 10 parts and plastics ABS 10 parts to be uniformly mixed according to a ratio；Then, again in banbury, at 200 DEG C, banburying obtains material；
(4) by step (3) resulting materials, Christmas ball is obtained by blow molding.
Embodiment 3
A kind of macromolecular material for preparing environmental protection Christmas ball, with cellulose, ceramics, waste or used plastics Merlon (PC), glycerol and antioxidant for raw material, its preparation process is as follows:
(1) by cellulose 30 parts, 20 parts and 2 parts epoxy soybean oil mix homogeneously of glycerol, mixture is obtained；
(2) by the mixture of step (1) gained, plastifying 7min, obtain modified biomass macromolecular material in banbury, described plasticization temperature is 120 DEG C；
(3) take the modified biomass macromolecular material of step (2) gained, 1 part of maleic anhydride, ceramics 15 parts and plastics PC15 part to be uniformly mixed according to a ratio；Then, again in banbury, at 190 DEG C, banburying obtains material；
(4) by step (3) resulting materials, Christmas ball is obtained by blow molding.
Present invention achieves waste or used plastics again with, and owing to the macromolecular material of gained has part biodegradable, therefore, it is possible to reduce environmental pollution, it is achieved the purpose of environmental protection.Above example gained Christmas ball has the advantages such as wearability is good and fire-retardant.
The foregoing is only presently preferred embodiments of the present invention, all equalizations done according to the present patent application the scope of the claims change and modify, and all should belong to the covering scope of the present invention.
Claims (4)
1. the macromolecular material being used for preparing environmental protection Christmas ball, it is characterised in that: it is made up of following raw material: biomass macromolecular material 30-50 part, ceramics 10-20 part, plastics 10-20 part, glycerol 20-30 part, epoxy soybean oil 2-10 part, maleic anhydride 1-5 part.
2. according to claim 1 for preparing the macromolecular material of environmental protection Christmas ball, it is characterised in that: described biomass macromolecular material is the one in starch, lignin or cellulose.
3. according to claim 1 for preparing the macromolecular material of environmental protection Christmas ball, it is characterised in that: described plastics are waste and old thermoplastic.
4. the preparation method of the macromolecular material for preparing environmental protection Christmas ball as claimed in claim 1, it is characterised in that: comprise the following steps:
(1) by biomass macromolecular material, glycerol and epoxy soybean oil mix homogeneously, mixture is obtained；
(2) by the mixture of step (1) gained, plastifying 5-8min, obtain modified biomass macromolecular material in banbury, described plasticization temperature is 100-120 DEG C；
(3) take modified biomass macromolecular material, maleic anhydride, ceramics and plastics that step (2) obtains to be uniformly mixed according to a ratio；Then, again in banbury, at 120-200 DEG C, banburying obtains material；
(4) by step (3) resulting materials, Christmas ball is obtained by blow molding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610332364.9A CN105778163B (en) | 2016-05-19 | 2016-05-19 | It is a kind of to be used to prepare high polymer material of environmentally friendly Christmas ball and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610332364.9A CN105778163B (en) | 2016-05-19 | 2016-05-19 | It is a kind of to be used to prepare high polymer material of environmentally friendly Christmas ball and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105778163A true CN105778163A (en) | 2016-07-20 |
| CN105778163B CN105778163B (en) | 2017-08-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610332364.9A Active CN105778163B (en) | 2016-05-19 | 2016-05-19 | It is a kind of to be used to prepare high polymer material of environmentally friendly Christmas ball and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115403893A (en) * | 2022-09-05 | 2022-11-29 | 润业(重庆)新材料有限公司 | Low-carbon emission new material and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1597751A (en) * | 2004-08-03 | 2005-03-23 | 王茜 | Raw material of fully bios degradation plastic and preparation process thereof |
| CN102746683A (en) * | 2012-07-24 | 2012-10-24 | 东北林业大学 | Wood-residue fiber foamed cushion packaging material and preparation method thereof |
| CN104231331A (en) * | 2014-09-18 | 2014-12-24 | 孙彦升 | Degradable decoration material and preparation method thereof |
| CN104892999A (en) * | 2015-05-22 | 2015-09-09 | 铜陵方正塑业科技有限公司 | High-water-resistance full-degradable plastic film and preparation method thereof |
| CN105348713A (en) * | 2015-10-19 | 2016-02-24 | 界首市佳宝包装材料有限公司 | Packing belt used for packaging carton |
-
2016
- 2016-05-19 CN CN201610332364.9A patent/CN105778163B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1597751A (en) * | 2004-08-03 | 2005-03-23 | 王茜 | Raw material of fully bios degradation plastic and preparation process thereof |
| CN102746683A (en) * | 2012-07-24 | 2012-10-24 | 东北林业大学 | Wood-residue fiber foamed cushion packaging material and preparation method thereof |
| CN104231331A (en) * | 2014-09-18 | 2014-12-24 | 孙彦升 | Degradable decoration material and preparation method thereof |
| CN104892999A (en) * | 2015-05-22 | 2015-09-09 | 铜陵方正塑业科技有限公司 | High-water-resistance full-degradable plastic film and preparation method thereof |
| CN105348713A (en) * | 2015-10-19 | 2016-02-24 | 界首市佳宝包装材料有限公司 | Packing belt used for packaging carton |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115403893A (en) * | 2022-09-05 | 2022-11-29 | 润业(重庆)新材料有限公司 | Low-carbon emission new material and preparation method thereof |
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| Publication number | Publication date |
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| CN105778163B (en) | 2017-08-29 |
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Address after: 355200 Shuangyue Road, Shuangyue Industrial Park, Fuding City, Ningde City, Fujian Province Patentee after: FUJIAN YINGHAO CULTURAL AND CREATIVE Co.,Ltd. Address before: 355200 E-5, Shuangyue Industrial Concentration Zone, Lantian Mountain Front, Fuding City, Ningde City, Fujian Province Patentee before: FUJIAN YINGHAO CRAFT PRODUCTS Co.,Ltd. |
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Denomination of invention: High polymer material for preparing environment-friendly Christmas ball and preparation method of high polymer material Effective date of registration: 20191122 Granted publication date: 20170829 Pledgee: China Co. truction Bank Corp Fuding branch Pledgor: FUJIAN YINGHAO CULTURAL AND CREATIVE Co.,Ltd. Registration number: Y2019350000073 |
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Date of cancellation: 20230908 Granted publication date: 20170829 Pledgee: China Co. truction Bank Corp Fuding branch Pledgor: FUJIAN YINGHAO CULTURAL AND CREATIVE Co.,Ltd. Registration number: Y2019350000073 |