CN105776779A - Comprehensive pesticide wastewater treatment method - Google Patents

Comprehensive pesticide wastewater treatment method Download PDF

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Publication number
CN105776779A
CN105776779A CN201610356523.9A CN201610356523A CN105776779A CN 105776779 A CN105776779 A CN 105776779A CN 201610356523 A CN201610356523 A CN 201610356523A CN 105776779 A CN105776779 A CN 105776779A
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wastewater
waste water
air
liquid storage
water
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CN201610356523.9A
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王卓
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Tianjin Zhuosheng Technology Development Co Ltd
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Tianjin Zhuosheng Technology Development Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5209Regulation methods for flocculation or precipitation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/74Treatment of water, waste water, or sewage by oxidation with air
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/76Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/306Pesticides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/343Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the pharmaceutical industry, e.g. containing antibiotics
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/10Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/14NH3-N
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/22Eliminating or preventing deposits, scale removal, scale prevention
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • C02F2305/026Fenton's reagent
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes

Abstract

The invention relates to a comprehensive pesticide wastewater treatment method.The treatment method comprises the following steps that wastewater and compressed air are guided into air floating equipment; the treated wastewater is pumped into an oxidation pond to fully react and then enters a settling pond after reacting is completed, part of the wastewater enters a second liquid storage pond through a filter pond, and part of the wastewater enters a first liquid storage pond to be continuously cyclically treated; cooling water and domestic sewage are added in the second liquid storage pond, the wastewater in the liquid storage pond is pumped into a hydrolytic acidification pond with a lift pump, the wastewater subjected to hydrolytic acidification flows into the settling pond, and the settled wastewater is pumped into a BIOFOR biofilter with a pump; the treated wastewater is delivered into a sodium hypochlorite oxidation pond, and the reacted wastewater is delivered into a clear water pond.According to the comprehensive pesticide wastewater treatment method, the ammonia nitrogen concentration of the drained wastewater is decreased to 0.1 mg/L, the ammonia nitrogen removal rate can reach 99.8%, and the ammonia nitrogen concentration of effluent meets the primary standard of the 'integrated wastewater discharge standard' (GB8979-1996).

Description

A kind of pesticide integrated waste water treatment method
Technical field
The present invention relates to technical field of sewage, particularly relate to a kind of pesticide integrated waste water treatment method.
Background technology
In recent years, along with socioeconomic fast development, the ecological environment of China is subject to increasingly severe destruction, and the destruction of environment is increasingly sharpened by the daily production activity of the mankind.More ammonia nitrogen and CODcr is discharged in particular from the wastewater from chemical industry producing the industry such as chemical fertilizer, food, iron and steel, the excessive entrance water body environment of this type of high pollution waste water, the ecosystem that water environment is intrinsic can be destroyed, the growing environment making aqueous bio is damaged, and can cause that the eutrophication of water body increases the weight of day by day.Data according to ASSOCIATE STATISTICS department of Chinese Ministry of Environmental Protection shows, the river of China, section pollute quite serious, has the water body of 25% all to cannot be used for irrigation, the economic development of this safe drinking water having a strong impact on we people and society because of seriously polluted;The whole nation has more than the waters of half and occurs in that serious eutrophication, and freshwater lake as main in Dian Chi, Poyang Lake, Taihu Lake etc. pollutes just very serious, and water field of big area all occurs in that eutrophication, the basic function losing water body having.In order to make the Ecoenvironment and social economy of China develop in harmony, China must formulate stricter integrated wastewater discharge standard and special industry wastewater discharge standard, and the therefore more efficient and economic each pollutant contained in waste water of removing has become as focus and the difficulties of water treatment field.
Pesticide wastewater mostlys come from production process concentrating under reduced pressure, filtration, waste gas treatment process, CODcr, BOD5 in waste water, ammonia-nitrogen content is higher, biodegradability is poor, have strong impulse abnormal smells from the patient, general wastewater treatment measure is adopted to be difficult to waste water is made directly process, therefore, in view of these problems, pesticide wastewater can thoroughly be processed by research one, make waste water discharge index and reach the pesticide integrated waste water treatment method of the requirement in integrated wastewater discharge standard, have important practical significance.
Summary of the invention
It is an object of the invention to the deficiency existed for prior art, it is provided that pesticide wastewater can thoroughly be processed by one, make waste water discharge index and reach the pesticide integrated waste water treatment method of the requirement in integrated wastewater discharge standard.
The technical scheme is that a kind of pesticide integrated waste water treatment method, process step and include following:
(1) by physical and chemical parameter it is: pH:8~9, SS=150mg/L, COD:5000mg/L, NH3The pesticide comprehensive wastewater of-N=150mg/L and compressed air import in airfloat equipment, air is made to be dissolved in water and become small bubble, form dissolved air water, in airfloat equipment, dissolved air water is released by the reduction of release pressure, at normal temperatures and pressures, it is dissolved in the air in water just to overflow from water, form the mixed system of air, waste water, in the basic conditions, the dynamic equilibrium between molecular state NH3 and ionic state NH4+ is moved to the direction generating NH3, now with air bubble for carrier, NH3, through gas-liquid interface, is gradually diffused in air;
(2) the pesticide comprehensive wastewater after step (1) processes is collected in the first liquid storage tank, be filled with air, make waste water be sufficiently mixed, with elevator pump, the waste water in liquid storage tank is squeezed into oxidation pond, in oxidation pond, add H2O2、FeSO4, hydrochloric acid, and it is filled with air, so as to fully react, Calx, PAC, PAM is added after having reacted, make the iron ion in waste water and ferrous ion flocculation sediment, the mud screw pump that flocculation sediment produces squeezes into sludge dewatering equipment, and waste water is partially into the second liquid storage tank through filtering ponds, is partially into the first liquid storage tank and continues cycling through process;
(3) in the second liquid storage tank, add cooling water and the sanitary sewage of 800t/d, and supplementary nitrogenous source, phosphorus source, it is filled with air, waste water is made to be sufficiently mixed, with elevator pump, the waste water in liquid storage tank being squeezed into hydrolysis acidification pool, in hydrolysis acidification pool, difficult degradation larger molecular organics can be decomposed into degradable small organic molecule by the microorganism in waste water, waste water after hydrolysis acidification flows into sedimentation tank to reduce the SS concentration in waste water, with pump, the waste water after precipitation is squeezed into BIOFOR biofilter;
(4) sending into hypochlorite oxidation pond through the waste water after step (3) processes, and regulate wastewater pH 7~8, put into sodium hypochlorite, the response time is 0.5~2h, and wastewater treatment system is stirred, and reacted waste water is sent into clear water reserviors.
Further, the alr mode in described step (4), wastewater treatment system being stirred is aeration agitation or mechanical agitation.
The beneficial effects of the present invention is:
The waste water of the present invention discharges index: pH=6-9, CODcr=80mg/L, BOD5=5mg/L, SS=10mg/L, ammonia nitrogen concentration reduces to 0.1mg/L, and ammonia nitrogen removal frank is up to 99.8%, the ammonia nitrogen concentration of water outlet meets the primary standard in " integrated wastewater discharge standard " (GB8978-1996), it is possible to effective and economical removes each pollutant contained in waste water.
Detailed description of the invention
Below the specific embodiment of the present invention is made brief description.
Embodiment 1
A kind of pesticide integrated waste water treatment method, processes step as follows:
(1) by physical and chemical parameter it is: pH:8~9, SS=150mg/L, COD:5000mg/L, NH3The pesticide comprehensive wastewater of-N=150mg/L and compressed air import in airfloat equipment, air is made to be dissolved in water and become small bubble, form dissolved air water, in airfloat equipment, dissolved air water is released by the reduction of release pressure, at normal temperatures and pressures, it is dissolved in the air in water just to overflow from water, form the mixed system of air, waste water, in the basic conditions, the dynamic equilibrium between molecular state NH3 and ionic state NH4+ is moved to the direction generating NH3, now with air bubble for carrier, NH3, through gas-liquid interface, is gradually diffused in air;
(2) the pesticide comprehensive wastewater after step (1) processes is collected in the first liquid storage tank, be filled with air, make waste water be sufficiently mixed, with elevator pump, the waste water in liquid storage tank is squeezed into oxidation pond, in oxidation pond, add H2O2、FeSO4, hydrochloric acid, and it is filled with air, so as to fully react, Calx, PAC, PAM is added after having reacted, make the iron ion in waste water and ferrous ion flocculation sediment, the mud screw pump that flocculation sediment produces squeezes into sludge dewatering equipment, and waste water is partially into the second liquid storage tank through filtering ponds, is partially into the first liquid storage tank and continues cycling through process;
(3) in the second liquid storage tank, add cooling water and the sanitary sewage of 800t/d, and supplementary nitrogenous source, phosphorus source, it is filled with air, waste water is made to be sufficiently mixed, with elevator pump, the waste water in liquid storage tank being squeezed into hydrolysis acidification pool, in hydrolysis acidification pool, difficult degradation larger molecular organics can be decomposed into degradable small organic molecule by the microorganism in waste water, waste water after hydrolysis acidification flows into sedimentation tank to reduce the SS concentration in waste water, with pump, the waste water after precipitation is squeezed into BIOFOR biofilter;
(4) sending into hypochlorite oxidation pond through the waste water after step (3) processes, and regulate wastewater pH 7~8, put into sodium hypochlorite, the response time is 1h, and wastewater treatment system is carried out aeration agitation, and reacted waste water is sent into clear water reserviors.
After testing, waste water discharge index is: pH=6-9, CODcr=80mg/L, BOD5=5mg/L, SS=10mg/L, ammonia nitrogen concentration reduces to 0.1mg/L, and ammonia nitrogen removal frank is up to 99.8%, and the ammonia nitrogen concentration of water outlet meets the primary standard in " integrated wastewater discharge standard " (GB8978-1996).
Above one embodiment of the present of invention is described in detail, but described content has been only presently preferred embodiments of the present invention, it is impossible to be considered the practical range for limiting the present invention.All equalizations made according to the present patent application scope change and improvement etc., all should still belong within the patent covering scope of the present invention.

Claims (2)

1. a pesticide integrated waste water treatment method, it is characterised in that process step and include following:
(1) by physical and chemical parameter it is: pH:8~9, SS=150mg/L, COD:5000mg/L, NH3The pesticide comprehensive wastewater of-N=150mg/L and compressed air import in airfloat equipment, air is made to be dissolved in water and become small bubble, form dissolved air water, in airfloat equipment, dissolved air water is released by the reduction of release pressure, at normal temperatures and pressures, it is dissolved in the air in water just to overflow from water, form the mixed system of air, waste water, in the basic conditions, the dynamic equilibrium between molecular state NH3 and ionic state NH4+ is moved to the direction generating NH3, now with air bubble for carrier, NH3, through gas-liquid interface, is gradually diffused in air;
(2) the pesticide comprehensive wastewater after step (1) processes is collected in the first liquid storage tank, be filled with air, make waste water be sufficiently mixed, with elevator pump, the waste water in liquid storage tank is squeezed into oxidation pond, in oxidation pond, add H2O2、FeSO4, hydrochloric acid, and it is filled with air, so as to fully react, Calx, PAC, PAM is added after having reacted, make the iron ion in waste water and ferrous ion flocculation sediment, the mud screw pump that flocculation sediment produces squeezes into sludge dewatering equipment, and waste water is partially into the second liquid storage tank through filtering ponds, is partially into the first liquid storage tank and continues cycling through process;
(3) in the second liquid storage tank, add cooling water and the sanitary sewage of 800t/d, and supplementary nitrogenous source, phosphorus source, it is filled with air, waste water is made to be sufficiently mixed, with elevator pump, the waste water in liquid storage tank being squeezed into hydrolysis acidification pool, in hydrolysis acidification pool, difficult degradation larger molecular organics can be decomposed into degradable small organic molecule by the microorganism in waste water, waste water after hydrolysis acidification flows into sedimentation tank to reduce the SS concentration in waste water, with pump, the waste water after precipitation is squeezed into BIOFOR biofilter;
(4) sending into hypochlorite oxidation pond through the waste water after step (3) processes, and regulate wastewater pH 7~8, put into sodium hypochlorite, the response time is 0.5~2h, and wastewater treatment system is stirred, and reacted waste water is sent into clear water reserviors.
2. a kind of pesticide integrated waste water treatment method according to claim 1, it is characterised in that: the alr mode in described step (4), wastewater treatment system being stirred is aeration agitation or mechanical agitation.
CN201610356523.9A 2016-05-26 2016-05-26 Comprehensive pesticide wastewater treatment method Pending CN105776779A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110240306A (en) * 2019-05-30 2019-09-17 西安建筑科技大学 A method of reducing wastewater toxicity containing organophosphorus pesticide
CN110803799A (en) * 2019-11-16 2020-02-18 湖南省波恩贝竹木科技有限公司 Method for treating waste liquid from heat treatment of bamboo wood

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995021794A1 (en) * 1994-02-14 1995-08-17 Envirex, Inc. Integrated adsorption/advanced oxidation fluidized bed reactor
CN101302073A (en) * 2008-06-13 2008-11-12 吴江市运东邱舍污水处理有限公司 Electroplating sewerage advanced treatment process
CN104609665A (en) * 2015-01-21 2015-05-13 四川省环境保护科学研究院 Glyphosate-producing wastewater treatment integration technology
CN104891739A (en) * 2015-05-28 2015-09-09 湖北仙隆化工股份有限公司 Method for treating pesticide sewage

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995021794A1 (en) * 1994-02-14 1995-08-17 Envirex, Inc. Integrated adsorption/advanced oxidation fluidized bed reactor
CN101302073A (en) * 2008-06-13 2008-11-12 吴江市运东邱舍污水处理有限公司 Electroplating sewerage advanced treatment process
CN104609665A (en) * 2015-01-21 2015-05-13 四川省环境保护科学研究院 Glyphosate-producing wastewater treatment integration technology
CN104891739A (en) * 2015-05-28 2015-09-09 湖北仙隆化工股份有限公司 Method for treating pesticide sewage

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110240306A (en) * 2019-05-30 2019-09-17 西安建筑科技大学 A method of reducing wastewater toxicity containing organophosphorus pesticide
CN110240306B (en) * 2019-05-30 2021-12-14 西安建筑科技大学 Method for reducing toxicity of wastewater containing organophosphorus pesticides
CN110803799A (en) * 2019-11-16 2020-02-18 湖南省波恩贝竹木科技有限公司 Method for treating waste liquid from heat treatment of bamboo wood

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