CN105774149A - Composite filtering material capable of being used for gas-liquid separation - Google Patents

Composite filtering material capable of being used for gas-liquid separation Download PDF

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Publication number
CN105774149A
CN105774149A CN201610176347.0A CN201610176347A CN105774149A CN 105774149 A CN105774149 A CN 105774149A CN 201610176347 A CN201610176347 A CN 201610176347A CN 105774149 A CN105774149 A CN 105774149A
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China
Prior art keywords
gas
liquid separation
filter material
layer
composite filter
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Granted
Application number
CN201610176347.0A
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Chinese (zh)
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CN105774149B (en
Inventor
曾影
秦大江
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CHONGQING ZAISHENG PURIFICATION EQUIPMENT Co Ltd
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CHONGQING ZAISHENG PURIFICATION EQUIPMENT Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0223Vinyl resin fibres
    • B32B2262/0238Vinyl halide, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0253Polyolefin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0261Polyamide fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres

Landscapes

  • Separation Using Semi-Permeable Membranes (AREA)
  • Filtering Materials (AREA)

Abstract

The invention discloses a composite filtering material capable of being used for gas-liquid separation. The filtering material consists of a contact layer, a trapping layer and a hydrophobic membrane layer. The contact layer is composed of synthetic fibers with a diameter of 5Mu m to 15Mu m, the thickness of the contact layer is 3mm to 150mm, the trapping layer is composed of double-component fibers with a diameter of 15Mu m to 20Mu m and microfibers with a diameter of 0.1Mu m to 4.5Mu m, the thickness of the trapping layer is 6mm to 300mm, the hydrophobic membrane layer is composed of polyethylene, polypropylene, polyvinylidene fluoride or polyether sulfone, and the thickness of the hydrophobic membrane layer is 0.1mm to 0.5mm. The composite filtering material disclosed by the invention not only can keep high separation efficiency, but also can keep a long service life.

Description

A kind of composite filter material that can be used for gas-liquid separation
Technical field
The invention belongs to gas-liquid separation field, be specifically related to a kind of composite filter material that can be used for gas-liquid separation.
Background technology
Gas-liquid separation device is usually used in petrochemical industry, chemical industry, such as the purification separation of unstripped gas, sky in synthesis ammonia, nitric acid, methanol production So exploitation of gas, storing and the technical process such as deep processing, diesel oil hydrogenation tail gas recycle.Its purpose is to prevent harmful liquid pair The equipment such as gas is processed, stored, transport cause damage.
Conventional gas-liquid separation device principle has following several, is settling methods, impaction, centrifugal process and filtration method respectively. First three methods belongs to Mechanical Method, needs to use large-scale experiment device, and its volume is big, efficiency is low, requires gas filter plate relatively Low technical process can use.Filtration method has higher filter effect, can remove the drop about 1 μm, and acid-mist-removing is imitated Rate can reach 98%~99%.But usually there is blocking the phenomenon of mesh in traditional filtering material, and therefore service life is the longest, takes Often clean or change.
Therefore, the gas-liquid separation material that a kind of good filtration effect of invention, life-span are long and easy to use seems the most urgent.
Summary of the invention
In view of this, it is an object of the invention to provide a kind of composite filter material that can be used for gas-liquid separation,
For reaching above-mentioned purpose, the invention provides following technical scheme:
A kind of composite filter material that can be used for gas-liquid separation, described filtering material includes contact layer, trapping layer and hydrophobic film layer.
Preferably, described contact layer is made up of the synthetic fibers of a diameter of 5~15 μm, and its thickness is 3mm-150mm, described conjunction One-tenth fiber is polypropylene, polyether sulfone, polytetrafluoroethylene (PTFE), polyethylene, Kynoar, polyacrylonitrile, polyamide or polyester, Described synthetic fibers carry out hydrophilic modifying process before using.
Preferably, described trapping layer is made up of the bicomponent fibers of a diameter of 15-20 μm and the microfibre of a diameter of 0.1-4.5 μm, Its thickness is 6mm-300mm, counts in mass ratio, and in described trapping layer, bicomponent fibers accounting is 40-60%.
Preferably, described bicomponent fibers is skin-core structure, and top layer has hydrophobicity, and outer layer fiber fusing point melts less than inner fiber Point, described microfibre passes from the cortex of bicomponent fibers.
Preferably, described bicomponent fibers is PE/PP, CO-PET/PET or PE/PET.
Preferably, described microfibre is natural fiber, has hydrophily.
Preferably, described microfibre is glass fibre, cellulose, wool or silk.
Preferably, described hydrophobic film layer is made up of polyethylene, polypropylene, Kynoar or polyether sulfone, and it is uniformly distributed aperture Aperture for 0.4-10 μm.
Preferably, described hydrophobic film layer thickness is 0.1~0.5mm.
The beneficial effects of the present invention is: composite filter material disclosed in this invention can keep higher separative efficiency, also can Keep longer service life.
Accompanying drawing explanation
In order to make the purpose of the present invention, technical scheme and beneficial effect clearer, the present invention provides drawings described below:
Fig. 1 represents the structural representation of composite filter material;
Fig. 2 represents the structural representation of trapping layer.
Detailed description of the invention
Below the preferred embodiments of the present invention are described in detail.The experimental technique of unreceipted actual conditions in embodiment is logical Often according to normal condition or according to the condition proposed by manufacturer.
Embodiment 1
With reference to Fig. 1, Fig. 2, the implementation case will provide a kind of composite filter material that can be used for gas-liquid separation.Wherein Fig. 1 represents The structural representation of composite filter material, Fig. 2 represents the structural representation of trapping layer.
Composite filter material has contact layer, trapping layer, hydrophobic film layer 3 part.Contact layer thickness 40mm, uses polypropylene Doughnut, average fibre diameter is 8 μm, uses and have relatively strongly hydrophilic before using.Trapping layer thickness is 60mm, uses PE/PP double-component core skin structure fiber and glass are fiber compound structure, and a diameter of 15 μm of bicomponent fibers have hydrophobicity, Accounting 42%, glass fiber diameter is 5 μm, has hydrophily, accounting 58%.Hydrophobic film layer thickness is 0.2mm, uses Polythene material, aperture 2 μm.
Embodiment 2
With reference to Fig. 1, Fig. 2, the implementation case will provide a kind of composite filter material that can be used for gas-liquid separation.Wherein Fig. 1 represents The structural representation of composite filter material, Fig. 2 represents the structural representation of trapping layer.
Composite filter material has contact layer, trapping layer, hydrophobic film layer 3 part.Contact layer thickness 20mm, uses polyether sulfone Doughnut, average fibre diameter is 5 μm, uses and have relatively strongly hydrophilic before using.Trapping layer thickness is 50mm, uses CO-PET/PET double-component core skin structure fiber and cellulose fibre composite construction, a diameter of 15 μm of bicomponent fibers, have Hydrophobicity, accounting 40%, a diameter of 4 μm of cellulose fibre, there is hydrophily, accounting 60%.Hydrophobic film layer thickness is 0.3mm, Use polythene material, aperture 2 μm.
Embodiment 3
With reference to Fig. 1, Fig. 2, the implementation case will provide a kind of composite filter material that can be used for gas-liquid separation.Wherein Fig. 1 represents The structural representation of composite filter material, Fig. 2 represents the structural representation of trapping layer.
Composite filter material has contact layer, trapping layer, hydrophobic film layer 3 part.Contact layer thickness 100mm, uses polyethylene Doughnut, average fibre diameter is 10 μm, uses and have relatively strongly hydrophilic before using.Trapping layer thickness is 250mm, adopts By PE/PET double-component core skin structure fiber and silk fiber composite construction, a diameter of 15 μm of bicomponent fibers, have hydrophobic Property, accounting 55%, a diameter of 10 μm of silk fiber, there is hydrophily, accounting 45%.Hydrophobic film layer thickness is 0.5mm, Use polyvinylidene fluoride material, aperture 4 μm.
Composite filter material prepared by above-described embodiment has good separative efficiency, and service life is the longest.
Finally illustrating, preferred embodiment above is only in order to illustrate technical scheme and unrestricted, although by above-mentioned The present invention is described in detail by preferred embodiment, it is to be understood by those skilled in the art that can in form and In details, it is made various change, without departing from claims of the present invention limited range.

Claims (9)

1. the composite filter material that can be used for gas-liquid separation, it is characterised in that described filtering material include contact layer, trapping layer and Hydrophobic film layer.
A kind of composite filter material that can be used for gas-liquid separation, it is characterised in that described contact layer is by directly Footpath is that the synthetic fibers of 5~15 μm are constituted, and its thickness is 3mm-150mm, and described synthetic fibers are polypropylene, polyether sulfone, gather Tetrafluoroethene, polyethylene, Kynoar, polyacrylonitrile, polyamide or polyester, described synthetic fibers carry out hydrophilic before using Modification.
A kind of composite filter material that can be used for gas-liquid separation, it is characterised in that described trapping layer is by directly Footpath is bicomponent fibers and the microfibre composition of a diameter of 0.1-4.5 μm of 15-20 μm, and its thickness is 6mm-300mm, by matter Amount is than meter, and in described trapping layer, bicomponent fibers accounting is 40-60%.
A kind of composite filter material that can be used for gas-liquid separation, it is characterised in that described bicomponent fibers For skin-core structure, top layer has hydrophobicity, and outer layer fiber fusing point is less than inner fiber fusing point, and described microfibre is from bicomponent fibers Cortex pass.
A kind of composite filter material that can be used for gas-liquid separation, it is characterised in that described bicomponent fibers For PE/PP, CO-PET/PET or PE/PET.
A kind of composite filter material that can be used for gas-liquid separation, it is characterised in that described microfibre is sky So fiber, has hydrophily.
A kind of composite filter material that can be used for gas-liquid separation, it is characterised in that described microfibre is glass Glass fiber, cellulose, wool or silk.
A kind of composite filter material that can be used for gas-liquid separation, it is characterised in that described hydrophobic film layer by Polyethylene, polypropylene, Kynoar or polyether sulfone are constituted, and it is uniformly distributed the aperture that aperture is 0.4-10 μm.
A kind of composite filter material that can be used for gas-liquid separation, it is characterised in that described hydrophobic membrane is layer by layer Thickness is 0.1~0.5mm.
CN201610176347.0A 2016-03-25 2016-03-25 A kind of composite filter material available for gas-liquid separation Active CN105774149B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108744720A (en) * 2018-06-19 2018-11-06 杭州帝凡过滤技术有限公司 A kind of filter core and its production method applied to high viscosity occasion
CN112829410A (en) * 2021-01-29 2021-05-25 泉州师范学院(石狮)生态智能织物工程技术研究院 Efficient oil-water separation filter membrane and preparation method thereof
CN115121046A (en) * 2022-08-25 2022-09-30 中国船舶重工集团公司第七0七研究所 Gas-water separation filter material and preparation method thereof

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EP1266681A2 (en) * 2001-06-13 2002-12-18 Nitto Denko Corporation Filter medium for turbine and methods of using and producing the same
CN1712100A (en) * 2005-05-12 2005-12-28 孙熙 Production of high-density topping filtering material from three gradient
CN101098741A (en) * 2004-11-05 2008-01-02 唐纳森公司 Filter medium and structure
DE202008012976U1 (en) * 2008-10-01 2010-03-11 Hengst Gmbh & Co.Kg Separator for separating liquid droplets from a gas stream
CN101861196A (en) * 2007-10-19 2010-10-13 日本奥亚特克斯股份有限公司 Air filter and air filter assebly for cleaner made by using the filter
CN103764251A (en) * 2011-08-31 2014-04-30 大金工业株式会社 Filter medium for air filter, air filter unit, and method for producing filter medium for air filter
CN103768866A (en) * 2012-10-19 2014-05-07 东丽纤维研究所(中国)有限公司 Filter material with high capture efficiency, and application thereof
CN104144734A (en) * 2012-02-23 2014-11-12 日东电工株式会社 Blended nonwaven fabric, filter filtration material, and filter unit
US20150328565A1 (en) * 2014-05-15 2015-11-19 Hollingsworth & Vose Company Surface modified filter media

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1266681A2 (en) * 2001-06-13 2002-12-18 Nitto Denko Corporation Filter medium for turbine and methods of using and producing the same
CN101098741A (en) * 2004-11-05 2008-01-02 唐纳森公司 Filter medium and structure
CN1712100A (en) * 2005-05-12 2005-12-28 孙熙 Production of high-density topping filtering material from three gradient
CN101861196A (en) * 2007-10-19 2010-10-13 日本奥亚特克斯股份有限公司 Air filter and air filter assebly for cleaner made by using the filter
DE202008012976U1 (en) * 2008-10-01 2010-03-11 Hengst Gmbh & Co.Kg Separator for separating liquid droplets from a gas stream
CN103764251A (en) * 2011-08-31 2014-04-30 大金工业株式会社 Filter medium for air filter, air filter unit, and method for producing filter medium for air filter
CN104144734A (en) * 2012-02-23 2014-11-12 日东电工株式会社 Blended nonwaven fabric, filter filtration material, and filter unit
CN103768866A (en) * 2012-10-19 2014-05-07 东丽纤维研究所(中国)有限公司 Filter material with high capture efficiency, and application thereof
US20150328565A1 (en) * 2014-05-15 2015-11-19 Hollingsworth & Vose Company Surface modified filter media

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108744720A (en) * 2018-06-19 2018-11-06 杭州帝凡过滤技术有限公司 A kind of filter core and its production method applied to high viscosity occasion
CN108744720B (en) * 2018-06-19 2020-11-24 杭州帝凡过滤技术有限公司 Filter element applied to high-viscosity occasions and production method thereof
CN112829410A (en) * 2021-01-29 2021-05-25 泉州师范学院(石狮)生态智能织物工程技术研究院 Efficient oil-water separation filter membrane and preparation method thereof
CN115121046A (en) * 2022-08-25 2022-09-30 中国船舶重工集团公司第七0七研究所 Gas-water separation filter material and preparation method thereof

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