CN105762406A - Organic zinc ion secondary battery - Google Patents
Organic zinc ion secondary battery Download PDFInfo
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- CN105762406A CN105762406A CN201610305459.1A CN201610305459A CN105762406A CN 105762406 A CN105762406 A CN 105762406A CN 201610305459 A CN201610305459 A CN 201610305459A CN 105762406 A CN105762406 A CN 105762406A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/42—Alloys based on zinc
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
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- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Abstract
The invention discloses an organic zinc ion secondary battery. The battery comprises an anode, a cathode, a membrane between the anode and the cathode, electrolyte with ion conductivity and a surfactant, wherein active materials adopted by the anode include one or more of black phosphorus, black phosphorus/graphite, compound of graphene carbon nanotube or coal, phosphorene and phosphorene/graphite; the active materials adopted by the cathode comprise simple substances, compounds or complexes focusing on zinc element; the electrolyte with ion conductivity comprises a liquid-state or gel-state material which takes soluble salt of zinc as a solute and takes an organic solvent as a solution; the surfactant comprises an ionic surfactant, a nonionic surfactant and a mixture of the ionic surfactant and the nonionic surfactant. The battery has the characteristics of being high capacity density and power density and excellent in cycling stability, and can be widely applied to different fields of electronics, communication, traffic and transportation.
Description
Technical field
The present invention relates to technical field of new energies, particularly relate to a kind of organic type zinc ion secondary cell.
Background technology
At present, existing Zinc ion battery is the secondary ion battery of a kind of repeatable discharge and recharge, has the feature of safety and environmental protection and low cost, and in electronics, communication, many fields such as energy have very high potential using value.
But prior art is in preparing Zinc ion battery process, using aqueous solution as electrolyte, in cyclic process, zinc ion can be deposited in zinc electrode and zinc electrode is passivated, and the zinc dendrite concurrently formed can penetrate barrier film and cause battery short circuit；The additionally easy liberation of hydrogen of water electrolysis liquid, produces battery flatulence phenomenon.
Summary of the invention
It is an object of the invention to provide a kind of organic type zinc ion secondary cell, this battery has the features such as high capacity density, high power density, and excellent cycle stability, can be widely applied to the different field such as electronics, communication, transportation.
A kind of organic type zinc ion secondary cell, described battery includes positive pole, negative pole, marginal barrier film, the electrolyte with ionic conductivity and surfactant, wherein:
The active material that described positive pole adopts includes one or more among black phosphorus, black phosphorus and the complex of graphite, Graphene, CNT or charcoal, phosphorus alkene, phosphorus alkene and graphite；
The active material that described negative pole adopts includes the simple substance based on zinc element, compound or complex；
The described electrolyte with ionic conductivity includes with the soluble-salt of zinc for solute, and organic solvent is liquid or the gel state material of solution；
Described surfactant includes ionic surfactant, nonionic surfactant and mixture thereof.
Described positive pole also includes collector, and described collector is made up of the material with carbon element of various metal formings or high conductivity.
The active material that described positive pole adopts is made up of positive electrode active materials, conductive agent and binding agent further, wherein:
Described conductive agent includes one or more in graphite, acetylene black, white carbon black, carbon fiber, Graphene and CNT, and addition is in less than the 30% of described positive electrode active materials gross weight；
Described binding agent includes one or more in politef, poly-inclined tetrafluoroethene, carboxymethyl cellulose, sodium carboxymethyl cellulose, polyacrylic acid and cyclodextrin, and addition is in less than the 30% of described positive electrode active materials gross weight.
In the described electrolyte with ionic conductivity:
The soluble-salt of described zinc includes one or more in zinc sulfate, zinc chloride, zinc phosphate, zinc nitrate, zinc acetate and zinc nitrate.
In the described electrolyte with ionic conductivity:
Described organic solvent includes N, one or more in N '-dimethyl Methanamide, ethylene carbonate, Allyl carbonate, dimethyl sulfoxide, methanol, ethanol, oxolane, acetonitrile, dichloromethane, dichloroethanes, dichloropropane, chloroform, trichloroethane, oxolane, diphenyl ether.
Described battery makes column type, square or button cell.
Described battery makes rigidity or flexible battery.
As seen from the above technical solution provided by the invention, above-mentioned battery has the features such as high capacity density, high power density, and excellent cycle stability, can be widely applied to the different field such as electronics, communication, transportation.
Accompanying drawing explanation
In order to be illustrated more clearly that the technical scheme of the embodiment of the present invention, below the accompanying drawing used required during embodiment is described is briefly described, apparently, accompanying drawing in the following describes is only some embodiments of the present invention, for those of ordinary skill in the art, under the premise not paying creative work, it is also possible to obtain other accompanying drawings according to these accompanying drawings.
Fig. 1 is the structural representation of the be provided with type zinc ion secondary cell of the embodiment of the present invention；
Fig. 2 is the cyclic voltammetry curve figure of zinc ion secondary cell prepared by the embodiment of the present invention.
Detailed description of the invention
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Based on embodiments of the invention, the every other embodiment that those of ordinary skill in the art obtain under not making creative work premise, broadly fall into protection scope of the present invention.
The embodiment of the present invention, by using elemental phosphorous or phosphide as Zinc ion battery positive pole, prepares into the novel organic type Zinc ion battery with high capacity density, high power density and excellent cycle.Below in conjunction with accompanying drawing, the embodiment of the present invention is described in further detail, it is illustrated in figure 1 the structural representation of the be provided with type zinc ion secondary cell of the embodiment of the present invention, described battery includes positive pole 1, negative pole 2, marginal barrier film 3, the electrolyte 4 with ionic conductivity and surfactant 5, wherein:
The active material that described positive pole 1 adopts includes one or more among black phosphorus, black phosphorus and the complex of graphite, Graphene, CNT or charcoal, phosphorus alkene, phosphorus alkene and graphite；
The active material that described negative pole 2 adopts includes the simple substance based on zinc element, compound or complex；
The described electrolyte 4 with ionic conductivity includes with the soluble-salt of zinc for solute, and organic solvent is liquid or the gel state material of solution；
Described surfactant 5 includes ionic surfactant, nonionic surfactant and mixture thereof.Specifically can include sodium lauryl sulphate, cetyl trimethylammonium bromide, spans surfactant, Tweens surfactant, polyoxyethylene-type surfactant or Pluronic F68 class surfactant etc..
It addition, in implementing, described positive pole can also include collector further, and described collector is made up of the material with carbon element of various metal formings or high conductivity.
The active material that above-mentioned positive pole adopts is made up of positive electrode active materials, conductive agent and binding agent further, wherein:
Described conductive agent includes one or more in graphite, acetylene black, white carbon black, carbon fiber, Graphene and CNT, and addition is in less than the 30% of described positive electrode active materials gross weight；
Described binding agent includes one or more in politef, poly-inclined tetrafluoroethene, carboxymethyl cellulose, sodium carboxymethyl cellulose, polyacrylic acid and cyclodextrin, and addition is in less than the 30% of described positive electrode active materials gross weight.
Described negative pole may also comprise collector, and this collector is identical with the current collector material that described positive pole uses；The active material that described negative pole adopts also can be made up of negative active core-shell material, conductive agent and binding agent, and wherein conductive agent is consistent with described in positive pole with addition with the kind of binding agent.
In implementing, the positive pole of this battery and negative pole can be directly prepared into by positive electrode active materials and negative active core-shell material respectively, can be added without collector as required.
It addition, in the described electrolyte with ionic conductivity:
The soluble-salt of described zinc includes one or more in zinc sulfate, zinc chloride, zinc phosphate, zinc nitrate, zinc acetate and zinc nitrate.
Described organic solvent includes N, one or more in N '-dimethyl Methanamide, ethylene carbonate, Allyl carbonate, dimethyl sulfoxide, methanol, ethanol, oxolane, acetonitrile, dichloromethane, dichloroethanes, dichloropropane, chloroform, trichloroethane, oxolane, diphenyl ether.
In implementing, the battery of the invention described above can make column type, square or button cell；And this battery may be alternatively configured rigidity or flexible battery.
With concrete example, the preparation process of above-mentioned battery is described in detail below:
Example 1, by 7g black phosphorus, 1.5g acetylene black and after 1.5g Teflon stir coating with on Copper Foil, be cut into the electrode slice of certain size vacuum drying to constant weight, using this electrode slice as positive pole, negative pole is zinc paper tinsel 25 microns thick；
Then zinc sulfate and dodecylbenzene sodium sulfonate are dissolved in DMF, are made into the solution of 0.01mol/L, and using this solution as electrolyte, be then assembled into zinc ion secondary cell.
Example 2, by 7g phosphorus alkene, 1.5g graphite and 1.5g gather the stirring of inclined tetrafluoroethene after coating with on Copper Foil, be cut into the electrode slice of certain size vacuum drying to constant weight, using this electrode slice as positive pole, negative pole is zinc paper tinsel 50 microns thick；
Then zinc chloride and polyethylene glycol propylene glycol-Polyethylene Glycol triblock copolymer are dissolved in Allyl carbonate, are made into the solution of 0.01mol/L, and using this solution as electrolyte, be then assembled into zinc ion secondary cell.
Example 3, by the complex of 7g black phosphorus and Graphene, it is coated with and on Copper Foil after 2g CNT and the stirring of 1g carboxymethyl cellulose, being cut into the electrode slice of certain size vacuum drying to constant weight, using this electrode slice as positive pole, negative pole is 7g zinc and the complex of 3g graphite；Then zinc acetate is dissolved in the mixed solution of Allyl carbonate that volume ratio is 2:1 and DMF, is made into the solution of 0.01mol/L, and using this solution as electrolyte, is then assembled into zinc ion secondary cell.
Example 4, by the complex of 7g black phosphorus and carbon fiber, it is coated with and on Copper Foil after 1.5g carbon fiber and the stirring of 0.5g carboxymethyl cellulose, being cut into the electrode slice of certain size vacuum drying to constant weight, using this electrode slice as positive pole, negative pole is 7g zinc and the complex of 3g graphite；Then zinc sulfate and Dodecyl trimethyl ammonium chloride are dissolved in DMF, are made into the solution of 0.05mol/L, and using this solution as electrolyte, be then assembled into zinc ion secondary cell.
Example 5, by the complex of 7g phosphorus alkene and acetylene black, it is coated with and on Copper Foil after 1.5g acetylene black and the stirring of 1.5g polyacrylic acid, being cut into the electrode slice of certain size vacuum drying to constant weight, using this electrode slice as positive pole, negative pole is 7g zinc and the complex of 3g CNT；Then zinc chloride and sodium lauryl sulphate are dissolved in Allyl carbonate, are made into the solution of 0.01mol/L, and using this solution as electrolyte, be then assembled into zinc ion secondary cell.
It is illustrated in figure 2 the cyclic voltammetry curve figure of zinc ion secondary cell prepared by the embodiment of the present invention, as shown in Figure 2: after first time discharge and recharge activates, system has good charge-discharge performance.
In sum, the battery that the embodiment of the present invention provides has the features such as high capacity density, high power density, and excellent cycle stability, can be widely applied to the different field such as electronics, communication, transportation.
The above; being only the present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, any those familiar with the art is in the technical scope of present disclosure; the change that can readily occur in or replacement, all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claims.
Claims (7)
1. an organic type zinc ion secondary cell, it is characterised in that described battery includes positive pole, negative pole, marginal barrier film, the electrolyte with ionic conductivity and surfactant, wherein:
The active material that described positive pole adopts includes one or more among black phosphorus, black phosphorus and the complex of graphite, Graphene, CNT or charcoal, phosphorus alkene, phosphorus alkene and graphite；
The active material that described negative pole adopts includes the simple substance based on zinc element, compound or complex；
The described electrolyte with ionic conductivity includes with the soluble-salt of zinc for solute, and organic solvent is liquid or the gel state material of solution；
Described surfactant includes ionic surfactant, nonionic surfactant and mixture thereof.
2. organic type zinc ion secondary cell according to claim 1, it is characterised in that
Described positive pole also includes collector, and described collector is made up of the material with carbon element of various metal formings or high conductivity.
3. organic type zinc ion secondary cell according to claim 1, it is characterised in that the active material that described positive pole adopts is made up of positive electrode active materials, conductive agent and binding agent further, wherein:
Described conductive agent includes one or more in graphite, acetylene black, white carbon black, carbon fiber, Graphene and CNT, and addition is in less than the 30% of described positive electrode active materials gross weight；
Described binding agent includes one or more in politef, poly-inclined tetrafluoroethene, carboxymethyl cellulose, sodium carboxymethyl cellulose, polyacrylic acid and cyclodextrin, and addition is in less than the 30% of described positive electrode active materials gross weight.
4. organic type zinc ion secondary cell according to claim 1, it is characterised in that in the described electrolyte with ionic conductivity:
The soluble-salt of described zinc includes one or more in zinc sulfate, zinc chloride, zinc phosphate, zinc nitrate, zinc acetate and zinc nitrate.
5. organic type zinc ion secondary cell according to claim 1, it is characterised in that in the described electrolyte with ionic conductivity:
Described organic solvent includes N, one or more in N '-dimethyl Methanamide, ethylene carbonate, Allyl carbonate, dimethyl sulfoxide, methanol, ethanol, oxolane, acetonitrile, dichloromethane, dichloroethanes, dichloropropane, chloroform, trichloroethane, oxolane, diphenyl ether.
6. according to one of them described organic type zinc ion secondary cell of claim 1-5, it is characterised in that
Described battery makes column type, square or button cell.
7. according to one of them described organic type zinc ion secondary cell of claim 1-5, it is characterised in that
Described battery makes rigidity or flexible battery.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610305459.1A CN105762406A (en) | 2016-05-10 | 2016-05-10 | Organic zinc ion secondary battery |
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| CN201610305459.1A CN105762406A (en) | 2016-05-10 | 2016-05-10 | Organic zinc ion secondary battery |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106629641A (en) * | 2016-11-14 | 2017-05-10 | 深圳大学 | Black phosphorus carbon nanotube composite as well as preparation method and application thereof |
| CN107666015A (en) * | 2017-09-04 | 2018-02-06 | 天津理工大学 | A kind of aqueous phase electrolyte system zinc iodine secondary cell and preparation method thereof |
| WO2018176981A1 (en) * | 2017-03-31 | 2018-10-04 | 比亚迪股份有限公司 | Electrolyte solution for lithium ion battery, and battery |
| CN109616699A (en) * | 2018-11-27 | 2019-04-12 | 恩力能源科技有限公司 | A kind of battery electrolyte and water system ion battery and preparation method thereof |
| CN109962289A (en) * | 2017-12-22 | 2019-07-02 | 财团法人工业技术研究院 | Electrolyte composition and metal ion battery comprising it |
| CN112038683A (en) * | 2020-09-14 | 2020-12-04 | 西南大学 | Liquid organic zinc battery and application thereof |
| WO2021017551A1 (en) * | 2019-07-26 | 2021-02-04 | 瑞新材料科技(香港)有限公司 | Electrolyte solution, battery and battery pack |
| US20230155179A1 (en) * | 2021-11-17 | 2023-05-18 | U.S. Army DEVCOM, Army Research Laboratory | Alcohol-based electrolytes for highly reversible zn metal batteries |
| CN116565216A (en) * | 2023-05-26 | 2023-08-08 | 中能鑫储(北京)科技有限公司 | Three-dimensional current collector for zinc ion battery, preparation and application thereof |
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| CN103181016A (en) * | 2010-09-13 | 2013-06-26 | 加利福尼亚大学董事会 | Ionic gel electrolyte, energy storage devices, and methods of manufacture thereof |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106629641A (en) * | 2016-11-14 | 2017-05-10 | 深圳大学 | Black phosphorus carbon nanotube composite as well as preparation method and application thereof |
| CN106629641B (en) * | 2016-11-14 | 2019-04-16 | 深圳大学 | A kind of black phosphorus carbon nano tube compound material and its preparation method and application |
| WO2018176981A1 (en) * | 2017-03-31 | 2018-10-04 | 比亚迪股份有限公司 | Electrolyte solution for lithium ion battery, and battery |
| CN107666015A (en) * | 2017-09-04 | 2018-02-06 | 天津理工大学 | A kind of aqueous phase electrolyte system zinc iodine secondary cell and preparation method thereof |
| CN107666015B (en) * | 2017-09-04 | 2019-08-27 | 天津理工大学 | A kind of water phase electrolyte system zinc iodine secondary cell and preparation method thereof |
| CN109962289B (en) * | 2017-12-22 | 2022-03-11 | 财团法人工业技术研究院 | Electrolyte composition and metal ion battery comprising same |
| CN109962289A (en) * | 2017-12-22 | 2019-07-02 | 财团法人工业技术研究院 | Electrolyte composition and metal ion battery comprising it |
| CN109616699A (en) * | 2018-11-27 | 2019-04-12 | 恩力能源科技有限公司 | A kind of battery electrolyte and water system ion battery and preparation method thereof |
| CN109616699B (en) * | 2018-11-27 | 2021-07-16 | 恩力能源科技有限公司 | Battery electrolyte, aqueous ion battery and preparation method thereof |
| WO2021017551A1 (en) * | 2019-07-26 | 2021-02-04 | 瑞新材料科技(香港)有限公司 | Electrolyte solution, battery and battery pack |
| CN112038683A (en) * | 2020-09-14 | 2020-12-04 | 西南大学 | Liquid organic zinc battery and application thereof |
| US20230155179A1 (en) * | 2021-11-17 | 2023-05-18 | U.S. Army DEVCOM, Army Research Laboratory | Alcohol-based electrolytes for highly reversible zn metal batteries |
| CN116565216A (en) * | 2023-05-26 | 2023-08-08 | 中能鑫储(北京)科技有限公司 | Three-dimensional current collector for zinc ion battery, preparation and application thereof |
| CN116565216B (en) * | 2023-05-26 | 2024-03-26 | 中能鑫储(北京)科技有限公司 | Three-dimensional current collector for zinc ion battery, preparation and application thereof |
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