CN105758883B - Oil content detection method and device in oily sludge water-washing process - Google Patents
Oil content detection method and device in oily sludge water-washing process Download PDFInfo
- Publication number
- CN105758883B CN105758883B CN201610204846.6A CN201610204846A CN105758883B CN 105758883 B CN105758883 B CN 105758883B CN 201610204846 A CN201610204846 A CN 201610204846A CN 105758883 B CN105758883 B CN 105758883B
- Authority
- CN
- China
- Prior art keywords
- msub
- oily sludge
- mrow
- oil content
- sludge sample
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N24/00—Investigating or analyzing materials by the use of nuclear magnetic resonance, electron paramagnetic resonance or other spin effects
- G01N24/08—Investigating or analyzing materials by the use of nuclear magnetic resonance, electron paramagnetic resonance or other spin effects by using nuclear magnetic resonance
- G01N24/081—Making measurements of geologic samples, e.g. measurements of moisture, pH, porosity, permeability, tortuosity or viscosity
Abstract
The invention discloses oil content detection method and device in a kind of oily sludge water-washing process, wherein method includes：Oily sludge sample is placed in washing instrument；Unilateral nuclear magnetic resonance apparatus is used outside washing instrument, using driving balanced pulse sequences as a kind of quick one-dimensional nuclear magnetic resonance measurement pulse train, nuclear magnetic resonance on-line measurement is carried out to oily sludge sample, obtains the echo string data of oily sludge sample；According to the echo string data of oily sludge sample, the oil content in oily sludge sample water-washing process is determined.The present invention can quickly complete the measure of oily sludge oil content, so as to realize the oil content in on-line checking oily sludge sample water-washing process, may also reach up the purpose of lossless detection.
Description
Technical field
The present invention relates to oil content detection method in technical field of petroleum industry, more particularly to oily sludge water-washing process and
Device.
Background technology
Oily sludge is an association discarded object main greatly of petroleum industry, itself has inflammable, high pollution, handles difficulty
Feature, it has been put at present《National Hazard waste register》In hazardous waste.Oily sludge from Petroleum Production, transport,
Storage and the overall process refined, mainly three kinds of components of the solid particle comprising crude oil, water and different proportion.In line with salvage property
The principle that source utilizes, carry out the harmless treatment of oily sludge and recycle correlative study, to holding for petroleum and petrochemical industry
Supervention exhibition is significant.Currently, crude oil recovery technology gradually causes the concern of common people, the document and reality delivered in recent years
A series of contained Mud Treatment Technologies are developed in production, these methods are broadly divided into two classes：One kind is recycling, another kind of
It is harmless treatment.In order to analyze the treatment effect of different disposal method, optimization operating parameter and the recovery for evaluating oily sludge
Value is, it is necessary to establish the quick and precisely analysis method for oily sludge sample oil content.Exactly analyze oil content for containing
The selection of greasy dirt processing method has important reference significance, for example, the oily sludge for low oil content, it is contemplated that processing
Cost, it is proper the methods of burning；For the oily sludge of high oil content, oily sludge can be realized by reclaiming crude oil
Recycling.
Oily sludge washing is the chemistry of a kind of conventional oily sludge oil content measurement and oily sludge three components separation
Method, its essence is use NaOH or Na2SiO3Aqueous solution soaking oily sludge, so as to improve the rate of recovery of crude oil and reduce original
The separation condition of oil and solid particle, the most crude oil at last in oily sludge extract.At present to Sludge in Oilfields batch
Tested before amount washing process, it is necessary to sample and washed through row laboratory, measure oily sludge oil content, experimentation is generally small one
When or so, the oil content of oily sludge is just can know that after experiment end extracts oily sludge, it is time-consuming longer, can not be online
Understand the change of oil content in whole water-washing process.Also, experimentation will cause the loss of oily sludge, it is unable to reach lossless
The purpose of detection.
The content of the invention
The embodiment of the present invention provides oil content detection method in a kind of oily sludge water-washing process, to realize oily sludge
The lossless audio coding of oil content, this method include in water-washing process：
Oily sludge sample is placed in washing instrument；
Unilateral nuclear magnetic resonance apparatus is used outside washing instrument, is surveyed driving balanced pulse sequences as one-dimensional nuclear magnetic resonance
Pulse train is measured, Nuclear Magnetic Resonance Measurement is carried out to oily sludge sample, obtains the echo string data of oily sludge sample；
According to the echo string data of oily sludge sample, the oil content in oily sludge sample water-washing process is determined；
The echo string data according to oily sludge sample, the oil content in oily sludge sample water-washing process is determined,
Including：
The echo string data and the correlation mathematical modeling of the oil content are established using PLS；
According to the correlation mathematical modeling, the oil content in oily sludge sample water-washing process is determined；
It is described that the echo string data and the correlation mathematical modeling of the oil content are established using PLS, bag
Include following self study process and prediction process：
Self study process：, will be corresponding using the echo string data of the oily sludge sample of premeasuring as argument data collection X
Oil content dependent variable data set Y, as follows carry out oily sludge sample principal component analysis：
Wherein, m1And n1Respectively X and Y one group of principal component；a11,a12,a13And β11Respectively X and Y are represented with principal component
When coefficient；ρ1And γ1Respectively X and Y coefficient matrix, by solving m1And n1Covariance cov (m1,n1) obtain；
Prediction process：Regression models of the Y to X is established as follows：
Wherein, X0And Y0For residual error；σ and τ is least-squares estimation, and T is matrix transposition symbol；
Circulation estimation is until X0And Y0As low as tolerance interval, determine the matching relationship between X and Y.
It is described to use unilateral nuclear magnetic resonance apparatus outside washing instrument in one embodiment, balanced pulse sequences will be driven
Pulse train is measured as one-dimensional nuclear magnetic resonance, Nuclear Magnetic Resonance Measurement is carried out to oily sludge sample, obtains oily sludge sample
Echo string data, including：
Washing instrument is placed on the probe of unilateral nuclear magnetic resonance apparatus, and the sensitizing range alignment of the probe is contained
Greasy dirt sample position.
It is described to use unilateral nuclear magnetic resonance apparatus outside washing instrument in one embodiment, balanced pulse sequences will be driven
Pulse train is measured as one-dimensional nuclear magnetic resonance, Nuclear Magnetic Resonance Measurement is carried out to oily sludge sample, obtains oily sludge sample
Echo string data, including：
The polarization window and echo acquirement window of triggering driving balanced pulse sequences act on simultaneously makes echo amplitude occur one
Secondary vibration, an echo data is gathered, circulate this process and gather one group of echo string data.
In one embodiment, the cycle-index for driving balanced pulse sequences is according to the sampling of default echo string data
Frequency determines.
The embodiment of the present invention also provides oil content detection means in a kind of oily sludge water-washing process, contains greasy dirt to realize
The lossless audio coding of oil content in mud water-washing process, the device include：
Echometric measurement module, for triggering unilateral nuclear magnetic resonance apparatus outside washing instrument, balanced pulse sequences will be driven
Pulse train is measured as one-dimensional nuclear magnetic resonance, Nuclear Magnetic Resonance Measurement is carried out to the oily sludge sample placed in washing instrument,
Obtain the echo string data of oily sludge sample；
Oil content determining module, for the echo string data according to oily sludge sample, determine that oily sludge sample is washed
During oil content；
The oil content determining module is specifically used for：
The echo string data and the correlation mathematical modeling of the oil content are established using PLS；
According to the correlation mathematical modeling, the oil content in oily sludge sample water-washing process is determined；
The oil content determining module be specifically used for using PLS establish the echo string data with it is described
During the correlation mathematical modeling of oil content, following self study process and prediction process are performed：
Self study process：, will be corresponding using the echo string data of the oily sludge sample of premeasuring as argument data collection X
Oil content dependent variable data set Y, as follows carry out oily sludge sample principal component analysis：
Wherein, m1And n1Respectively X and Y one group of principal component；a11,a12,a13And β11Respectively X and Y are represented with principal component
When coefficient；ρ1And γ1Respectively X and Y coefficient matrix, by solving m1And n1Covariance cov (m1,n1) obtain；
Prediction process：Regression models of the Y to X is established as follows：
Wherein, X0And Y0For residual error；σ and τ is least-squares estimation；T is matrix transposition symbol；
Circulation estimation is until X0And Y0As low as tolerance interval, determine the matching relationship between X and Y.
In one embodiment, the echometric measurement module is specifically used for control washing instrument and is placed on unilateral NMR
On the probe of device, and the sensitizing range of the probe is directed at oily sludge sample position.
In one embodiment, the echometric measurement module be specifically used for triggering driving balanced pulse sequences polarization window and
Echo acquirement window acts on simultaneously makes echo amplitude occur once to vibrate, and gathers an echo data, circulates the collection of this process
One group of echo string data.
In one embodiment, the echometric measurement module is true specifically for the sample frequency according to default echo string data
The cycle-index of the fixed driving balanced pulse sequences.
In the embodiment of the present invention, balanced pulse sequences will be driven as one-dimensional nuclear magnetic resonance using unilateral nuclear magnetic resonance apparatus
Pulse train is measured, Nuclear Magnetic Resonance Measurement is carried out to oily sludge sample, obtains the echo string data of oily sludge sample, according to
The echo string data of oily sludge sample, the oil content in oily sludge sample water-washing process is determined, oil-containing can be quickly completed
The measure of sludge oil content, so as to realize the oil content in on-line checking oily sludge sample water-washing process；Also, unilateral nuclear-magnetism
Resonance instrument is that the oily sludge sample being opposite to outside washing instrument in washing instrument carries out Nuclear Magnetic Resonance Measurement, can be reached
The purpose of lossless detection.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
There is the required accompanying drawing used in technology description to be briefly described, it should be apparent that, drawings in the following description are only this
Some embodiments of invention, for those of ordinary skill in the art, on the premise of not paying creative work, can be with
Other accompanying drawings are obtained according to these accompanying drawings.In the accompanying drawings：
Fig. 1 is the process chart of oil content detection method in oily sludge water-washing process in the embodiment of the present invention；
Fig. 2 is the schematic diagram that balanced pulse sequences are driven in the embodiment of the present invention；
Fig. 3 is that the oily sludge content oil cut rate based on one-dimensional nuclear magnetic resonance measures modeled example figure in the embodiment of the present invention；
Fig. 4 is the schematic diagram of oil content detection means in oily sludge water-washing process in the embodiment of the present invention.
Embodiment
For the purpose, technical scheme and advantage of the embodiment of the present invention are more clearly understood, below in conjunction with the accompanying drawings to this hair
Bright embodiment is described in further details.Here, the schematic description and description of the present invention is used to explain the present invention, but simultaneously
It is not as a limitation of the invention.
In order to realize the lossless audio coding of oil content in oily sludge water-washing process, the embodiment of the present invention provides one kind and contained
Oil content detection method in greasy dirt water-washing process, as shown in figure 1, this method can include：
Step 101, oily sludge sample is placed in and washed in instrument；
Step 102, unilateral nuclear magnetic resonance apparatus is used outside washing instrument, using driving balanced pulse sequences as one-dimensional core
Magnetic resonance measurement pulse train, Nuclear Magnetic Resonance Measurement is carried out to oily sludge sample, obtains the echo number of oily sludge sample
According to；
Step 103, the echo string data according to oily sludge sample, determine the oil-containing in oily sludge sample water-washing process
Rate.
Specifically, in embodiments of the present invention, it is that oily sludge sample is placed in washing instrument, is adopted outside washing instrument
Nuclear Magnetic Resonance Measurement is carried out to oily sludge sample with unilateral nuclear magnetic resonance apparatus, can so reach the purpose of lossless detection.
When it is implemented, in order to obtain more accurate measurement result, washing instrument can be placed on unilateral nuclear magnetic resonance apparatus
On probe, and the sensitizing range of probe is directed at oily sludge sample position.Unilateral nmr probe uses external magnetic
Field measurement mode, investigation depth are adjustable.
Unilateral nuclear magnetic resonance apparatus is used in the embodiment of the present invention, using driving balanced pulse sequences as one-dimensional nuclear magnetic resonance
Pulse train is measured, Nuclear Magnetic Resonance Measurement is carried out to oily sludge sample, obtains the echo string data of oily sludge sample.Wherein
Balanced pulse sequences are driven to measure pulse train for a kind of quick one-dimensional nuclear magnetic resonance, the sequence only needs the time of several seconds just
A Nuclear Magnetic Resonance Measurement can be completed, the survey of oily sludge oil content can be quickly completed based on Nuclear Magnetic Resonance Measurement result
It is fixed, so as to realize the oil content in on-line checking oily sludge sample water-washing process.Driving balanced pulse sequences can make oil-containing
The echo amplitude of mud sample up-down vibration repeatedly, completing a signal acquisition using driving balanced pulse sequences only needs 10 millis
The time of or so second.On-line checking is to when after the oil content in oily sludge sample water-washing process, can also draw out with washing
Between elapse oily sludge oil content change curve.
In embodiment, when carrying out Nuclear Magnetic Resonance Measurement to oily sludge sample, driving balanced pulse sequences can be triggered
Polarization window and echo acquirement window simultaneously act on make echo amplitude occur once vibrate, gather an echo data, circulation
This process gathers one group of echo string data.Fig. 2 is the schematic diagram of driving balance (DE) pulse train in the embodiment of the present invention.Such as
Shown in Fig. 2, driving balanced pulse sequences include two windows, and one is polarization window, alternatively referred to as longitudinal relaxation time (T1)
Correlation window, one is echo acquirement window, alternatively referred to as T2 (T2) correlation window, corresponds to τ respectively1And τ2Two
The individual duration.In actual mechanical process, the two windows act on simultaneously makes echo amplitude occur once to vibrate, and collection one is returned
Wave number evidence, one group of echo string data can be collected by circulating this process.τ in Fig. 2DERepresented for half echo sounding time, 90X+Table
Show 90 degree of pulses along the X-axis positive direction of three-dimensional cartesian coordinate system (X, Y, Z), 90X-Represent along three-dimensional cartesian coordinate system (X,
Y, Z) X-axis negative direction 90 degree of pulses, 180Y+Represent the 180 degree along the Y-axis positive direction of three-dimensional cartesian coordinate system (X, Y, Z)
Pulse.
In embodiment, drive the cycle-index of balanced pulse sequences can be according to the sample frequency of default echo string data
It is determined that.For example, the cycle-index of driving balanced pulse sequences determines according to the sample frequency of the echo string data needed for experiment, typically
The echo string data of the more collections of cycle-index is more, and the sample set data of oil content evaluation are more, and accuracy is also higher.
In embodiment, driving balanced pulse sequences make the echo amplitude of oily sludge sample up-down vibration repeatedly, these times
The change of wave amplitude can reflect the longitudinal relaxation time of sample and the information of T2.Drive equalizing pulse sequence
Row can quickly measure by single sweep operation to obtain the relaxation information of sample in 10 milliseconds or so of time, its rapidity measured
Meet the requirement of chemical reaction flow on-line measurement.
After echo string data is obtained, first it can be determined according to echo string data vertical in oily sludge sample water-washing process
To relaxation time and T2, further according to longitudinal relaxation time and T2, oily sludge sample water is determined
Oil content during washing.The constituent of oily sludge is complicated, and the T1 and T2 of different component are different, in fact it could happen that different
Component T1 is identical but situation that T2 is different, individually studies the problem of T1 and T2 may cause individual components to be difficult to and occurs,
Influence the measurement explanation results of oil content.Due to the obtained echo data of driving balanced pulse sequences measurement while contain sample
T1 and T2 information, therefore its better than traditional T1 edit pulses sequence that can only measure T1 and measure T2 CPMG pulse sequence.
Oil content detection method can include being total to based on one-dimensional nuclear-magnetism in the oily sludge water-washing process of the embodiment of the present invention
The oil content modeling method for measurement data of shaking.Quick one-dimensional nuclear magnetic resonance pulse train can quickly be surveyed within the time of several seconds
Measure to one group of echo string data, and oil content modeling method will go out sample according to this group of echo string data direct derivation
Oil content.Specifically it is determined that during oil content in oily sludge sample water-washing process, PLS can be used to establish
Echo string data and the correlation mathematical modeling of oil content, determine that oily sludge sample is water washed according to the correlation mathematical modeling
Oil content in journey.
The correlation mathematical modeling of above-mentioned carry out oil content explanation is established based on PLS algorithm, will be more
The one-dimensional echo amplitude data that kind oily sludge sample measures will use chemical method to survey as independent variable after different washing times
The oil content data measured are as dependent variable, and so as to build oil content interpretation model, the oil content for completing pre-detection sample exists
Line is tested.Fig. 3 is that the oily sludge content oil cut rate based on one-dimensional nuclear magnetic resonance measures modeled example figure in the embodiment of the present invention, such as
Shown in Fig. 3, oily sludge sample collection is first carried out, then carries out oily sludge sample washing, carries out quick one-dimensional core respectively afterwards
Magnetic resonance measurement, the one-dimensional echo amplitude data that a variety of oily sludge samples are measured are established independent variable collection, entered as independent variable
Row soxhlet extraction methods measure, the oil content data that will be obtained after different washing times using chemical method measurement as dependent variable,
Dependent variable collection is established, finally builds oil content interpretation model.
In embodiment, the echo string data and the correlation mathematics of the oil content are being established using PLS
During model, following self study process and prediction process can be performed：
Self study process：, will be corresponding using the echo string data of the oily sludge sample of premeasuring as argument data collection X
Oil content operation dependent variable data set Y, as follows carry out oily sludge sample principal component analysis：
Wherein, m1And n1Respectively X and Y one group of principal component；a11,a12,a13And β11Respectively X and Y are represented with principal component
When coefficient；ρ1And γ1Respectively X and Y coefficient matrix, by solving m1And n1Covariance cov (m1,n1) obtain；So,
Can realizes the principal component expression formula to X and Y；
During self study, a collection of premeasuring region oily sludge sample can be chosen, often washing a period of time, measurement one
Secondary nuclear magnetic resonance echo, and the oil content for calculating and now washing is recorded, by the echo number of the oily sludge sample of premeasuring
According to as argument data collection X, by corresponding oil content operation dependent variable data set Y, principal component analysis is carried out；
Prediction process：Regression models of the Y to X is established as follows, that is, finds the functional relation between X and Y：
Wherein, X0And Y0For residual error；σ and τ is least-squares estimation；T is matrix transposition symbol；
Circulation estimation is until X0And Y0As low as tolerance interval (such as X0=0.01X), determine that the matching between X and Y is closed
System.Next the measurement of progress nuclear magnetic resonance echo online in oily sludge water-washing process is only needed, it is possible to pass through mould
Type calculates the real-time oil content change curve of the oily sludge.
As described above, oil content detection method realizes several aspects in the oily sludge water-washing process of the embodiment of the present invention
Purpose：First, quick online purpose, this method is based on a kind of quick nuclear magnetic resonance Detection Techniques, can complete once within several seconds
The measurement of oil content；Second, lossless detection purpose, the nuclear magnetic resonance technique that this method uses is a kind of lossless detection technology, in reality
Washing instrument (such as beaker or flask of washing) need to be only placed in the measurement process of border on unilateral nmr probe i.e.
On-line measurement can be started；Third, realizing the purpose of nuclear magnetic resonance detection oil content, build and be based on one-dimensional quick nuclear magnetic resonance
The greasy filth oil content interpretation model of measurement data.
Based on same inventive concept, oil content in a kind of oily sludge water-washing process is additionally provided in the embodiment of the present invention and is examined
Device is surveyed, as described in the following examples.Because the device solves the principle of problem and oil content in oily sludge water-washing process
Detection method is similar, therefore the implementation of the device may refer to the implementation of oil content detection method in oily sludge water-washing process,
Part is repeated to repeat no more.
Fig. 4 is the schematic diagram of oil content detection means in oily sludge water-washing process in the embodiment of the present invention, such as Fig. 4 institutes
Show, the device can include：
Echometric measurement module 401, for triggering unilateral nuclear magnetic resonance apparatus outside washing instrument, equalizing pulse sequence will be driven
Row carry out nuclear magnetic resonance survey as one-dimensional nuclear magnetic resonance measurement pulse train to the oily sludge sample placed in washing instrument
Amount, obtain the echo string data of oily sludge sample；
Oil content determining module 402, for the echo string data according to oily sludge sample, determine oily sludge sample water
Oil content during washing.
When it is implemented, echometric measurement module 401, which specifically can be used for control washing instrument, is placed on unilateral nuclear magnetic resonance
On the probe of instrument, and the sensitizing range of the probe is directed at oily sludge sample position.
When it is implemented, echometric measurement module 401 specifically can be used for the polarization window of triggering driving balanced pulse sequences
Being acted on simultaneously with echo acquirement window makes echo amplitude occur once to vibrate, and gathers an echo data, circulates this process and adopt
Collect one group of echo string data.
When it is implemented, echometric measurement module 401 specifically can be used for the sample frequency according to default echo string data
Determine the cycle-index of the driving balanced pulse sequences.
When it is implemented, oil content determining module 402 specifically can be used for：
Longitudinal relaxation time in oily sludge sample water-washing process and transverse relaxation are determined according to the echo string data
Time；
According to the longitudinal relaxation time and T2, the oil-containing in oily sludge sample water-washing process is determined
Rate.
When it is implemented, oil content determining module 402 specifically can be used for：
The echo string data and the correlation mathematical modeling of the oil content are established using PLS；
According to the correlation mathematical modeling, the oil content in oily sludge sample water-washing process is determined.
When it is implemented, oil content determining module 402 specifically can be used for establishing described return using PLS
When wave train data and the correlation mathematical modeling of the oil content, following self study process and prediction process are performed：
Self study process：, will be corresponding using the echo string data of the oily sludge sample of premeasuring as argument data collection X
Oil content operation dependent variable data set Y, as follows carry out oily sludge sample principal component analysis：
Wherein, m1And n1Respectively X and Y one group of principal component；a11,a12,a13And β11Respectively X and Y are represented with principal component
When coefficient；ρ1And γ1Respectively X and Y coefficient matrix, by solving m1And n1Covariance cov (m1,n1) obtain；
Prediction process：Regression models of the Y to X is established as follows：
Wherein, X0And Y0For residual error；σ and τ is least-squares estimation；T is matrix transposition symbol；
Circulation estimation is until X0And Y0As low as tolerance interval, determine the matching relationship between X and Y.
In summary, the embodiment of the present invention is based on the blank for solving existing online oily sludge oil content e measurement technology,
Oil content detection method and device in the oily sludge water-washing process based on nuclear magnetic resonance technique are proposed, use unilateral core during implementation
Magnetic resonance tool will drive balanced pulse sequences to measure pulse train as one-dimensional nuclear magnetic resonance, and core is carried out to oily sludge sample
Magnetic resonance measurement, the echo string data of oily sludge sample is obtained, according to the echo string data of oily sludge sample, determines oil-containing
Oil content in mud sample water-washing process, the measure of oily sludge oil content can be quickly completed, so as to realize on-line checking
Oil content in oily sludge sample water-washing process；Also, unilateral nuclear magnetic resonance apparatus is to be opposite to washing outside washing instrument
Oily sludge sample in instrument carries out Nuclear Magnetic Resonance Measurement, can reach the purpose of lossless detection.
Can on-line checking to the oil content in oily sludge sample water-washing process, also help and extensive greasy filth washed
Industrial flow provides the technical parameters such as rational washing time, chemical levels, temperature, pressure.
It should be understood by those skilled in the art that, embodiments of the invention can be provided as method, system or computer program
Product.Therefore, the present invention can use the reality in terms of complete hardware embodiment, complete software embodiment or combination software and hardware
Apply the form of example.Moreover, the present invention can use the computer for wherein including computer usable program code in one or more
The computer program production that usable storage medium is implemented on (including but is not limited to magnetic disk storage, CD-ROM, optical memory etc.)
The form of product.
The present invention is the flow with reference to method according to embodiments of the present invention, equipment (system) and computer program product
Figure and/or block diagram describe.It should be understood that can be by every first-class in computer program instructions implementation process figure and/or block diagram
Journey and/or the flow in square frame and flow chart and/or block diagram and/or the combination of square frame.These computer programs can be provided
The processors of all-purpose computer, special-purpose computer, Embedded Processor or other programmable data processing devices is instructed to produce
A raw machine so that produced by the instruction of computer or the computing device of other programmable data processing devices for real
The device for the function of being specified in present one flow of flow chart or one square frame of multiple flows and/or block diagram or multiple square frames.
These computer program instructions, which may be alternatively stored in, can guide computer or other programmable data processing devices with spy
Determine in the computer-readable memory that mode works so that the instruction being stored in the computer-readable memory, which produces, to be included referring to
Make the manufacture of device, the command device realize in one flow of flow chart or multiple flows and/or one square frame of block diagram or
The function of being specified in multiple square frames.
These computer program instructions can be also loaded into computer or other programmable data processing devices so that counted
Series of operation steps is performed on calculation machine or other programmable devices to produce computer implemented processing, so as in computer or
The instruction performed on other programmable devices is provided for realizing in one flow of flow chart or multiple flows and/or block diagram one
The step of function of being specified in individual square frame or multiple square frames.
Particular embodiments described above, the purpose of the present invention, technical scheme and beneficial effect are carried out further in detail
Describe in detail it is bright, should be understood that the foregoing is only the present invention specific embodiment, the guarantor being not intended to limit the present invention
Scope is protected, within the spirit and principles of the invention, any modification, equivalent substitution and improvements done etc., should be included in this
Within the protection domain of invention.
Claims (8)
- A kind of 1. oil content detection method in oily sludge water-washing process, it is characterised in that including：Oily sludge sample is placed in washing instrument；Unilateral nuclear magnetic resonance apparatus is used outside washing instrument, arteries and veins is measured using driving balanced pulse sequences as one-dimensional nuclear magnetic resonance Sequence is rushed, Nuclear Magnetic Resonance Measurement is carried out to oily sludge sample, obtains the echo string data of oily sludge sample；According to the echo string data of oily sludge sample, the oil content in oily sludge sample water-washing process is determined；The echo string data according to oily sludge sample, the oil content in oily sludge sample water-washing process is determined, including：The echo string data and the correlation mathematical modeling of the oil content are established using PLS；According to the correlation mathematical modeling, the oil content in oily sludge sample water-washing process is determined；It is described that the echo string data and the correlation mathematical modeling of the oil content are established using PLS, including such as Lower self study process and prediction process：Self study process：Using the echo string data of the oily sludge sample of premeasuring as argument data collection X, will contain accordingly Oil cut rate dependent variable data set Y, the principal component analysis of oily sludge sample is carried out as follows：<mrow> <mtable> <mtr> <mtd> <mrow> <msub> <mi>m</mi> <mn>1</mn> </msub> <mo>=</mo> <msub> <mi>a</mi> <mn>11</mn> </msub> <msub> <mi>X</mi> <mn>1</mn> </msub> <mo>+</mo> <msub> <mi>a</mi> <mn>12</mn> </msub> <msub> <mi>X</mi> <mn>2</mn> </msub> <mo>+</mo> <msub> <mi>a</mi> <mn>13</mn> </msub> <msub> <mi>X</mi> <mn>3</mn> </msub> <mo>=</mo> <msub> <mi>&rho;</mi> <mn>1</mn> </msub> <mi>X</mi> </mrow> </mtd> </mtr> <mtr> <mtd> <mrow> <msub> <mi>n</mi> <mn>1</mn> </msub> <mo>=</mo> <msub> <mi>&beta;</mi> <mn>11</mn> </msub> <msub> <mi>Y</mi> <mn>1</mn> </msub> <mo>=</mo> <msub> <mi>&gamma;</mi> <mn>1</mn> </msub> <mi>Y</mi> </mrow> </mtd> </mtr> </mtable> <mo>;</mo> </mrow>Wherein, m1And n1Respectively X and Y one group of principal component；a11,a12,a13And β11When respectively representing X and Y with principal component Coefficient；ρ1And γ1Respectively X and Y coefficient matrix, by solving m1And n1Covariance cov (m1,n1) obtain；Prediction process：Regression models of the Y to X is established as follows：<mrow> <mfenced open = "{" close = "}"> <mtable> <mtr> <mtd> <mrow> <mi>X</mi> <mo>=</mo> <msub> <mi>m</mi> <mn>1</mn> </msub> <msup> <mi>&sigma;</mi> <mrow> <mo>(</mo> <mn>1</mn> <mo>)</mo> <mi>T</mi> </mrow> </msup> <mo>+</mo> <msub> <mi>X</mi> <mn>0</mn> </msub> </mrow> </mtd> </mtr> <mtr> <mtd> <mrow> <mi>Y</mi> <mo>=</mo> <msub> <mi>n</mi> <mn>1</mn> </msub> <msup> <mi>&tau;</mi> <mrow> <mo>(</mo> <mn>1</mn> <mo>)</mo> <mi>T</mi> </mrow> </msup> <mo>+</mo> <msub> <mi>Y</mi> <mn>0</mn> </msub> </mrow> </mtd> </mtr> </mtable> </mfenced> <mo>;</mo> </mrow>Wherein, X0And Y0For residual error；σ and τ is least-squares estimation, and T is matrix transposition symbol；Circulation estimation is until X0And Y0As low as tolerance interval, determine the matching relationship between X and Y.
- 2. the method as described in claim 1, it is characterised in that it is described to use unilateral nuclear magnetic resonance apparatus outside washing instrument, Driving balanced pulse sequences are measured into pulse train as one-dimensional nuclear magnetic resonance, nuclear magnetic resonance survey is carried out to oily sludge sample Amount, the echo string data of oily sludge sample is obtained, including：Washing instrument is placed on the probe of unilateral nuclear magnetic resonance apparatus, and the sensitizing range alignment of the probe is contained into greasy dirt Mud sample product position.
- 3. the method as described in claim 1, it is characterised in that it is described to use unilateral nuclear magnetic resonance apparatus outside washing instrument, Driving balanced pulse sequences are measured into pulse train as one-dimensional nuclear magnetic resonance, nuclear magnetic resonance survey is carried out to oily sludge sample Amount, the echo string data of oily sludge sample is obtained, including：The polarization window and echo acquirement window of triggering driving balanced pulse sequences act on simultaneously makes echo amplitude occur once to shake Swing, gather an echo data, circulate this process and gather one group of echo string data.
- 4. method as claimed in claim 3, it is characterised in that the cycle-index of the driving balanced pulse sequences is according to default Echo string data sample frequency determine.
- A kind of 5. oil content detection means in oily sludge water-washing process, it is characterised in that including：Echometric measurement module, for trigger unilateral nuclear magnetic resonance apparatus washing instrument outside, will driving balanced pulse sequences as One-dimensional nuclear magnetic resonance measures pulse train, carries out Nuclear Magnetic Resonance Measurement to the oily sludge sample placed in washing instrument, obtains The echo string data of oily sludge sample；Oil content determining module, for the echo string data according to oily sludge sample, determine oily sludge sample water-washing process In oil content；The oil content determining module is specifically used for：The echo string data and the correlation mathematical modeling of the oil content are established using PLS；According to the correlation mathematical modeling, the oil content in oily sludge sample water-washing process is determined；The oil content determining module is specifically used for establishing the echo string data and the oil-containing using PLS During the correlation mathematical modeling of rate, following self study process and prediction process are performed：Self study process：Using the echo string data of the oily sludge sample of premeasuring as argument data collection X, will contain accordingly Oil cut rate dependent variable data set Y, the principal component analysis of oily sludge sample is carried out as follows：<mrow> <mtable> <mtr> <mtd> <mrow> <msub> <mi>m</mi> <mn>1</mn> </msub> <mo>=</mo> <msub> <mi>a</mi> <mn>11</mn> </msub> <msub> <mi>X</mi> <mn>1</mn> </msub> <mo>+</mo> <msub> <mi>a</mi> <mn>12</mn> </msub> <msub> <mi>X</mi> <mn>2</mn> </msub> <mo>+</mo> <msub> <mi>a</mi> <mn>13</mn> </msub> <msub> <mi>X</mi> <mn>3</mn> </msub> <mo>=</mo> <msub> <mi>&rho;</mi> <mn>1</mn> </msub> <mi>X</mi> </mrow> </mtd> </mtr> <mtr> <mtd> <mrow> <msub> <mi>n</mi> <mn>1</mn> </msub> <mo>=</mo> <msub> <mi>&beta;</mi> <mn>11</mn> </msub> <msub> <mi>Y</mi> <mn>1</mn> </msub> <mo>=</mo> <msub> <mi>&gamma;</mi> <mn>1</mn> </msub> <mi>Y</mi> </mrow> </mtd> </mtr> </mtable> <mo>;</mo> </mrow>Wherein, m1And n1Respectively X and Y one group of principal component；a11,a12,a13And β11When respectively representing X and Y with principal component Coefficient；ρ1And γ1Respectively X and Y coefficient matrix, by solving m1And n1Covariance cov (m1,n1) obtain；Prediction process：Regression models of the Y to X is established as follows：<mrow> <mfenced open = "{" close = "}"> <mtable> <mtr> <mtd> <mrow> <mi>X</mi> <mo>=</mo> <msub> <mi>m</mi> <mn>1</mn> </msub> <msup> <mi>&sigma;</mi> <mrow> <mo>(</mo> <mn>1</mn> <mo>)</mo> <mi>T</mi> </mrow> </msup> <mo>+</mo> <msub> <mi>X</mi> <mn>0</mn> </msub> </mrow> </mtd> </mtr> <mtr> <mtd> <mrow> <mi>Y</mi> <mo>=</mo> <msub> <mi>n</mi> <mn>1</mn> </msub> <msup> <mi>&tau;</mi> <mrow> <mo>(</mo> <mn>1</mn> <mo>)</mo> <mi>T</mi> </mrow> </msup> <mo>+</mo> <msub> <mi>Y</mi> <mn>0</mn> </msub> </mrow> </mtd> </mtr> </mtable> </mfenced> <mo>;</mo> </mrow>Wherein, X0And Y0For residual error；σ and τ is least-squares estimation；T is matrix transposition symbol；Circulation estimation is until X0And Y0As low as tolerance interval, determine the matching relationship between X and Y.
- 6. device as claimed in claim 5, it is characterised in that the echometric measurement module is specifically used for control washing instrument and put Put on the probe of unilateral nuclear magnetic resonance apparatus, and the sensitizing range of the probe is directed at oily sludge sample position.
- 7. device as claimed in claim 5, it is characterised in that the echometric measurement module is specifically used for triggering driving parallel vein Rush sequence polarization window and echo acquirement window at the same effect make echo amplitude occur once vibrate, gather a number of echoes According to, circulate this process gather one group of echo string data.
- 8. device as claimed in claim 7, it is characterised in that the echometric measurement module is specifically used for according to default echo The sample frequency of string data determines the cycle-index of the driving balanced pulse sequences.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610204846.6A CN105758883B (en) | 2016-04-05 | 2016-04-05 | Oil content detection method and device in oily sludge water-washing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610204846.6A CN105758883B (en) | 2016-04-05 | 2016-04-05 | Oil content detection method and device in oily sludge water-washing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105758883A CN105758883A (en) | 2016-07-13 |
| CN105758883B true CN105758883B (en) | 2018-01-02 |
Family
ID=56345337
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610204846.6A Active CN105758883B (en) | 2016-04-05 | 2016-04-05 | Oil content detection method and device in oily sludge water-washing process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105758883B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106908370B (en) * | 2017-03-22 | 2019-08-06 | 中国石油天然气股份有限公司 | Seep determination method for parameter and device in sandstone hole |
| CN107064057A (en) * | 2017-04-18 | 2017-08-18 | 中国石油化工股份有限公司 | A kind of method for rapidly testing of low-water-content oil field sludge oil content |
| CN109142264A (en) * | 2017-06-16 | 2019-01-04 | 中国石油天然气股份有限公司 | The method that oil field sludge oil content determines |
| CN107907911A (en) | 2017-10-17 | 2018-04-13 | 中国石油天然气股份有限公司 | Compact reservoir determination method for oil content based on nuclear magnetic resonance |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU934422A1 (en) * | 1980-12-10 | 1982-06-07 | Всесоюзный Научно-Исследовательский Институт Ядерной Геофизики И Геохимии | Method of evaluating degree of mud injection into drilled rocks |
| US6107796A (en) * | 1998-08-17 | 2000-08-22 | Numar Corporation | Method and apparatus for differentiating oil based mud filtrate from connate oil |
| CN104730099A (en) * | 2015-04-09 | 2015-06-24 | 上海理工大学 | Method of simultaneously measuring water content and oil content of oily sludge |
| CN105116001A (en) * | 2015-09-23 | 2015-12-02 | 中国石油大学(北京) | Method and device for determining oil and water contents of oil sludge on basis of two-dimensional nuclear magnetic resonance |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7049815B2 (en) * | 2004-01-27 | 2006-05-23 | Baker Hughes Incorporated | Method and apparatus for multi-frequency NMR diffusion measurements in the presence of internal magnetic field gradients |
-
2016
- 2016-04-05 CN CN201610204846.6A patent/CN105758883B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU934422A1 (en) * | 1980-12-10 | 1982-06-07 | Всесоюзный Научно-Исследовательский Институт Ядерной Геофизики И Геохимии | Method of evaluating degree of mud injection into drilled rocks |
| US6107796A (en) * | 1998-08-17 | 2000-08-22 | Numar Corporation | Method and apparatus for differentiating oil based mud filtrate from connate oil |
| CN104730099A (en) * | 2015-04-09 | 2015-06-24 | 上海理工大学 | Method of simultaneously measuring water content and oil content of oily sludge |
| CN105116001A (en) * | 2015-09-23 | 2015-12-02 | 中国石油大学(北京) | Method and device for determining oil and water contents of oil sludge on basis of two-dimensional nuclear magnetic resonance |
Non-Patent Citations (1)
| Title |
|---|
| 高君恒 等.基于核磁共振测井DE脉冲序列的回波串正演模拟.《内蒙古石油化工》.2010,(第9期), * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105758883A (en) | 2016-07-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105758883B (en) | Oil content detection method and device in oily sludge water-washing process | |
| RU2367981C2 (en) | Method for detection of reservoir fluid properties | |
| Li et al. | Damage detection of bridges using response of vehicle considering road surface roughness | |
| Shi et al. | Non-destructive testing of full-length bonded rock bolts based on HHT signal analysis | |
| Yang et al. | Hybrid two‐step method of damage detection for plate‐like structures | |
| NO20052675L (en) | Method and apparatus for using pulsed field gradient NMR paints to determine fluid properties in a fluid sampling well logging tool. | |
| CN105469049A (en) | Leakage sound emission signal identification method based on multi-scale morphological decomposition energy spectrum entropy and support vector machine | |
| Brunt et al. | Intrinsic, observed, and retrieved properties of interstellar turbulence | |
| CN109254255A (en) | Nuclear magnetic resonance lateral relaxation time spectrometry method, apparatus and readable storage medium storing program for executing | |
| CN103424420A (en) | Fitting-based nuclear magnetic resonance signal processing method | |
| CN113409284A (en) | Circuit board fault detection method, device, equipment and storage medium | |
| CN106644879A (en) | Method and device for determining permeability contribution values of different pore components of core | |
| CN103995147B (en) | A kind of Data Post Processing System being applicable to acoustic Doppler velocimetry and application | |
| CN109060760A (en) | Analysis model method for building up, gas analyzing apparatus and method | |
| CN104484740B (en) | A kind of Confidence Analysis method of digital control system in nuclear power plant response time test | |
| CN106338767A (en) | Multi-parameter seismic attribute analysis method and system | |
| CN108956410A (en) | The recognition methods of rock sample pore structure fast qualitative and device | |
| CN105352986B (en) | Low-field nuclear magnetic resonance rock organic matter detection method and device | |
| CN110609332B (en) | Stratum data acquisition method, device and system | |
| CN113779330B (en) | Ultrasonic detection process parameter intelligent computing system based on similarity measurement | |
| Portone et al. | A stochastic operator approach to model inadequacy with applications to contaminant transport | |
| CN114240899B (en) | Guided wave dispersion curve modal tracking method and system based on image registration | |
| Wang et al. | Comparison of sparse representation and fourier discriminant methods: damage location classification in indirect lab-scale bridge structural health monitoring | |
| CN106291697A (en) | A kind of method and system of the value of the Q of interval quality factors definitely | |
| US20220381714A1 (en) | Digital retort measurement systems and methods |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |