CN105754258A - PVC (polyvinyl chloride)/ABS (acrylonitrile-butadiene-styrene) alloy material for front windshield lower fastening strip for car and preparation method thereof - Google Patents
PVC (polyvinyl chloride)/ABS (acrylonitrile-butadiene-styrene) alloy material for front windshield lower fastening strip for car and preparation method thereof Download PDFInfo
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- CN105754258A CN105754258A CN201610217736.3A CN201610217736A CN105754258A CN 105754258 A CN105754258 A CN 105754258A CN 201610217736 A CN201610217736 A CN 201610217736A CN 105754258 A CN105754258 A CN 105754258A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention relates to a PVC (polyvinyl chloride)/ABS (acrylonitrile-butadiene-styrene) alloy material for a front windshield lower fastening strip for a car and preparation method thereof. The PVC/ABS alloy material comprises the following components in parts by mass: 60 parts of PVC, 40 parts of ABS resin, 6-7 parts of a solubilizer, 8-10 parts of calcium carbonate, 10-15 parts of a plasticizer, 1.5-3 parts of carbon black, 0.5-1 part of a rare-earth stabilizer, 6-15 parts of a brominated flame retardant, 3-7.5 parts of Sb2O3 and 0-1 part of graphene nanoplatelet. According to the front windshield lower fastening strip material, the combustion speed is obviously reduced, and LOI is higher than 36.1 and reaches UL94 V0 level in a vertical combustion test; the flame resistance is improved, and the material is improved to a certain extent in the aspect of Vica softening temperature and odor assessment; and the preparation method is simple and is good in stability, and can effectively improve the flame resistance of the PVC/ABS alloy material.
Description
Technical field
The invention belongs to card article Material Field under front windshield, block particularly under a kind of PVC/ABS alloy automobile front windshield
Strip material and preparation method thereof.
Background technology
PVC/ABS alloy is because having good resistance to impact, molding processibility, good stability of the dimension and products formed rough surface
Spend the performance such as little under the front windshield of automobile, card strip material to have broad application prospects.But in recent years with advanced persons such as auto industrys
PVC/ABS alloy material is proposed in terms of application performance more to come in terms of materials used in auto manufacturing by the development that manufacturing industry is advanced by leaps and bounds
The highest requirement, the performance such as the most fire-retardant is particularly important.Although it is certain fire-retardant that PVC makes PVC/ABS alloy have
Performance, but the limited oxygen index of PVC/ABS alloy (LOI) only 23.1, run into burning things which may cause a fire disaster and easily burn and cause the intensity of a fire fast
Speed spreads.
At present, domestic the research of card strip material under PVC/ABS alloy automobile front windshield is related to flame-retardant modified less.
Halogenated flame retardant (particularly bromine system) have good flame retardation effect, addition is few, compatibility good, thermal stability is excellent, right
Fire-retardant product performance impact is little, price advantage etc., is one of yield is maximum the most in the world organic fire-retardant.Graphene is micro-
Sheet refers to that carbon-coating number is more than 10 layers, the thickness ultra-thin Graphene stratiform accumulation body in 5-100 nanometer range.There is excellence
Mechanical strength, conduction, heat conductivility, and good lubrication, high temperature resistant, high temperature resistant and anticorrosion properties, and produce
Low cost, application prospect is extensive.Meanwhile, its layer structure can stop fuel gas to escape into flame zone, stop energy
Return and promote into charcoal, being expected to become the BACN of efficient few additive.
Summary of the invention
The technical problem to be solved be to provide under a kind of PVC/ABS alloy automobile front windshield card strip material and
Preparation method, the method can make the fire resistance of card strip material under PVC/ABS alloy automobile front windshield significantly improve.
Card strip material under a kind of PVC/ABS alloy automobile front windshield of the present invention, by mass fraction, component includes: poly-
Vinyl chloride PVC 60 parts, acrylonitrile-butadiene-styrene resin ABS 40 parts, solubilizer 6～7 parts, calcium carbonate 6～10
Part (as filler), plasticizer 10～15 parts, carbon black 1.5～3 parts, rare-earth stabilizer 0.5～1 part, bromide fire retardant 6～15
Part, Sb2O33～7.5 parts, graphene microchip 0～1 part.
Described solubilizer is methyl methacrylate-butadiene-styrene resin MBS；Wherein, raw material consists of: methyl-prop
The content of e pioic acid methyl ester is 40%, and the content of styrene-butadiene latex is 30%, and cinnamic content is 30%；It it is a kind of excellent height
Molecule solubilizer and anti-impact modifier.
Described plasticizer is dioctyl phthalate DOP, decanedioic acid two (2-ethyl) own ester DOS or diphenyl phosphate different pungent
Ester DPOP.
Described rare-earth stabilizer is XT-1, XT-2 or XT-3.
Described bromide fire retardant is deca-BDE FR-10, tetrabromophthalic anhydride TBPA or tetrabromo dipentaerythritol
TBDPE。
By mass fraction, component includes: PVC 60 parts, ABS 40 parts, MBS 7 parts, 10 parts of calcium carbonate, DPOP 15
Part, carbon black 3 parts, XT-3 1 part, TBDPE 15 parts, Sb2O37.5 parts, graphene microchip 1 part.
By mass fraction, component includes: PVC 60 parts, ABS 40 parts, MBS 7 parts, 10 parts of calcium carbonate, DOS 15
Part, carbon black 3 parts, XT-3 1 part, TBPA 15 parts, Sb2O37.5 parts, graphene microchip 1 part.
By mass fraction, component includes: PVC 60 parts, ABS 40 parts, MBS 7 parts, 10 parts of calcium carbonate, DOS 15
Part, carbon black 3 parts, XT-3 1 part, FR-10 15 parts, Sb2O37.5 parts, graphene microchip 1 part.
The preparation method of card strip material under a kind of PVC/ABS alloy automobile front windshield of the present invention, including:
Weigh each raw material in proportion, first by PVC, ABS, solubilizer, calcium carbonate, plasticizer, carbon black, rare-earth stabilizer
High speed mixing smelting machine premixes 5～10 minutes, is subsequently adding bromide fire retardant, Sb2O35～10 are premixed again with graphene microchip
Minute, then the raw material mixed is put into double screw extruder melt extrudes granulation, to obtain final product.
Described melt extrude granulation process conditions be: melt temperature 90～170 DEG C, compression ratio 3:1.
The present invention utilizes bromide fire retardant, Sb2O3And graphene microchip improves card under PVC/ABS alloy automobile front windshield
The fire resistance of strip material, solves its incendive problem.Bromide fire retardant also has the anti-ultraviolet property of excellence, with
Sb2O3Coordinate, the flame retardant effect of excellence can be realized under conditions of less addition.
Beneficial effect
(1) bromide fire retardant in the present invention, Sb2O3With graphene microchip cooperative flame retardant PVC/ABS alloy automobile front windshield
Lower card strip material has good flame retardant effect, and LOI is higher than 36.1, and testing vertical flammability has passed through UL94 V0 level, reaches
Arrive the requirement of more high flame resistance, also widen PVC/ABS alloy range simultaneously.
(2) rare-earth stabilizer in the present invention and MBS, carbon black, the compounding use of plasticizer, strengthen various auxiliary agents in formula
Dispersed in matrix plastic, the stability of protection PVC molecule, make PVC/ABS alloy improve flame retardant effect
Meanwhile, make material other physical property and processing characteristics can be maximally maintained.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is expanded on further.Should be understood that these embodiments be merely to illustrate the present invention and
It is not used in restriction the scope of the present invention.In addition, it is to be understood that after having read the content that the present invention lectures, people in the art
The present invention can be made various changes or modifications by member, and these equivalent form of values fall within the application appended claims equally and limited
Scope.
Embodiment 1
Material is by weight, composed of the following components: PVC 60 parts, ABS 40 parts, MBS 6 parts, 6 parts of calcium carbonate,
DOP 10 parts, carbon black 1.5 parts, XT-1 0.5 part, TBDPE 6 parts, Sb2O33 parts, graphene microchip 0 part.
Preparation method is as follows:
Weigh each raw material according to formula rate, first PVC, ABS, MBS, calcium carbonate, DOP, carbon black, XT-1 are existed
High speed mixing smelting machine premixes 5 minutes, is subsequently adding TBDPE, Sb2O3Premix in high speed mixing smelting machine again with graphene microchip
5 minutes, then the raw material mixed is put in double screw extruder, in temperature 90～170 DEG C of (double screw extruder charging zones
Temperature 90 DEG C, melted 170 DEG C, mixed material area, extrusion mould-outlet temperature 160 DEG C), under the conditions of compression ratio 3:1, through melt extruding
Granulation after being blended.
Sample sample preparation granulation in embodiment 1 obtained carries out vicat softening temperature, smell, formaldehyde radiation heat, limit oxygen
Index (LOI) and the test of vertical combustion performance, its test result is as shown in table 1.
Embodiment 2
Material is by weight, composed of the following components: PVC 60 parts, ABS 40 parts, MBS 7 parts, 8 parts of calcium carbonate,
DOS 15 parts, carbon black 2 parts, XT-2 0.5 part, TBDPE 15 parts, Sb2O37.5 parts, graphene microchip 0 part.
Preparation method is as follows:
Weigh each raw material according to formula rate, first PVC, ABS, MBS, calcium carbonate, DOS, carbon black, XT-2 are existed
High speed mixing smelting machine premixes 5 minutes, is subsequently adding TBDPE, Sb2O3Premix in high speed mixing smelting machine again with graphene microchip
5 minutes, then the raw material mixed is put in double screw extruder, in temperature 90～170 DEG C of (double screw extruder charging zones
Temperature 90 DEG C, melted 170 DEG C, mixed material area, extrusion mould-outlet temperature 160 DEG C), under the conditions of compression ratio 3:1, through melt extruding
Granulation after being blended.
Sample sample preparation granulation in embodiment 2 obtained carries out vicat softening temperature, smell, formaldehyde radiation heat, limit oxygen
Index (LOI) and the test of vertical combustion performance, its test result is as shown in table 1.
Embodiment 3
Material is by weight, composed of the following components: PVC 60 parts, ABS 40 parts, MBS 7 parts, calcium carbonate 10
Part, DPOP 15 parts, carbon black 3 parts, XT-3 1 part, TBDPE 15 parts, Sb2O37.5 parts, graphene microchip 1 part.
Preparation method is as follows:
Weigh each raw material according to formula rate, first PVC, ABS, MBS, calcium carbonate, DPOP, carbon black, XT-3 are existed
High speed mixing smelting machine premixes 5 minutes, is subsequently adding TBDPE, Sb2O3Premix in high speed mixing smelting machine again with graphene microchip
5 minutes, then the raw material mixed is put in double screw extruder, in temperature 90～170 DEG C of (double screw extruder charging zones
Temperature 90 DEG C, melted 170 DEG C, mixed material area, extrusion mould-outlet temperature 160 DEG C), under the conditions of compression ratio 3:1, through melt extruding
Granulation after being blended.
Sample sample preparation granulation in embodiment 3 obtained carries out vicat softening temperature, smell, formaldehyde radiation heat, limit oxygen
Index (LOI) and the test of vertical combustion performance, its test result is as shown in table 1.
Embodiment 4
Material is by weight, composed of the following components: PVC 60 parts, ABS 40 parts, MBS 7 parts, calcium carbonate 10
Part, DOS 15 parts, carbon black 3 parts, XT-3 1 part, TBPA 15 parts, Sb2O37.5 parts, graphene microchip 1 part.
Preparation method is as follows:
Weigh each raw material according to formula rate, first PVC, ABS, MBS, calcium carbonate, DOS, carbon black, XT-3 are existed
High speed mixing smelting machine premixes 5 minutes, is subsequently adding TBPA, Sb2O3In high speed mixing smelting machine, 5 are premixed again with graphene microchip
Minute, then the raw material mixed is put in double screw extruder, in temperature 90～170 DEG C of (double screw extruder charging zone temperature
Spend 90 DEG C, melted 170 DEG C, mixed material area, extrusion mould-outlet temperature 160 DEG C), under the conditions of compression ratio 3:1, through melt extruding altogether
Granulation after mixed.
Sample sample preparation granulation in embodiment 4 obtained carries out vicat softening temperature, smell, formaldehyde radiation heat, limit oxygen
Index (LOI) and the test of vertical combustion performance, its test result is as shown in table 1.
Embodiment 5
Material is by weight, composed of the following components: PVC 60 parts, ABS 40 parts, MBS 7 parts, calcium carbonate 10
Part, DOS 15 parts, carbon black 3 parts, XT-3 1 part, FR-10 15 parts, Sb2O37.5 parts, graphene microchip 1 part.
Preparation method is as follows:
Weigh each raw material according to formula rate, first PVC, ABS, MBS, calcium carbonate, DOS, carbon black, XT-3 are existed
High speed mixing smelting machine premixes 5 minutes, is subsequently adding FR-10, Sb2O3In high speed mixing smelting machine, 5 are premixed again with graphene microchip
Minute, then the raw material mixed is put in double screw extruder, in temperature 90～170 DEG C of (double screw extruder charging zone temperature
Spend 90 DEG C, melted 170 DEG C, mixed material area, extrusion mould-outlet temperature 160 DEG C), under the conditions of compression ratio 3:1, through melt extruding altogether
Granulation after mixed.
Sample sample preparation granulation in embodiment 5 obtained carries out vicat softening temperature, smell, formaldehyde radiation heat, limit oxygen
Index (LOI) and the test of vertical combustion performance, its test result is as shown in table 1.
Comparative example
This comparative example is without fire retardant, Sb2O3And graphene microchip.By weight, composed of the following components: PVC 60
Part, ABS 40 parts, MBS 7 parts, 10 parts of calcium carbonate, DOP 15 parts, carbon black 3 parts, XT-1 1 part.
Preparation method is as follows:
Weigh each raw material according to formula rate, first PVC, ABS, MBS, calcium carbonate, DOP, carbon black, XT-1 are existed
High speed mixing smelting machine premixes 5 minutes, the most again the raw material mixed is put in double screw extruder, temperature 90～170 DEG C
(double screw extruder charging zone temperature 90 DEG C, melted 170 DEG C, mixed material area, extrusion mould-outlet temperature 160 DEG C), compression ratio 3:
Under the conditions of 1, granulation after melt extruding and being blended.
Sample sample preparation granulation in comparative example obtained carries out vicat softening temperature, smell, formaldehyde radiates heat, limit oxygen refers to
Number (LOI) and the test of vertical combustion performance, its test result is as shown in table 1.
The each embodiment of table 1 and the test performance of comparative example
As shown in Table 1, the present invention flame-retardant modified after PVC/ABS alloy automobile front windshield under card article material combustion speed
Degree substantially slows down, and LOI is higher than 36.1, has reached UL94 V0 level, further relate to material in testing vertical flammability is tested
Fire resistance is significantly improved.While improving fire resistance, the vicat softening temperature of material improves,
A certain degree of improvement is also obtain in terms of odor gradings.
It is GB/T 1633-2000 that vicat softening temperature of the present invention tests the testing standard of institute's foundation, the survey of odor gradings institute foundation
Test-object standard is popular standard PV3900, and it is GB/T2408-2008 that burning velocity tests the testing standard of institute's foundation, and limit oxygen refers to
It is GB/T 2406.2-2009 that number tests the testing standard of institute's foundation, and the testing standard of testing vertical flammability institute foundation is ASTM
D6413。
The above, only the preferred embodiments of the present invention, it is noted that those skilled in the art are come
Saying, on the premise of without departing from the core technology of the present invention, it is also possible to make improvements and modifications, these improvements and modifications also should
Belong to the scope of patent protection of the present invention.Any change in the implication suitable with claims of the present invention and scope, all
It is considered as being included within the scope of the claims.
Claims (10)
1. card strip material under a PVC/ABS alloy automobile front windshield, it is characterised in that: by mass fraction, component includes:
Polyvinylchloride 60 parts, acrylonitrile-butadiene-styrene resin ABS 40 parts, solubilizer 6～7 parts, calcium carbonate 6～10
Part, plasticizer 10～15 parts, carbon black 1.5～3 parts, rare-earth stabilizer 0.5～1 part, bromide fire retardant 6～15 parts, Sb2O33～7.5
Part, graphene microchip 0～1 part.
Card strip material under a kind of PVC/ABS alloy automobile front windshield the most according to claim 1, it is characterised in that: institute
Stating solubilizer is methyl methacrylate-butadiene-styrene resin MBS；Wherein, raw material consists of: methyl methacrylate
The content of ester is 40%, and the content of styrene-butadiene latex is 30%, and cinnamic content is 30%.
Card strip material under a kind of PVC/ABS alloy automobile front windshield the most according to claim 1, it is characterised in that: institute
State plasticizer be dioctyl phthalate DOP, decanedioic acid two (2-ethyl) own ester DOS or diphenylisooctyl phosphate
DPOP。
Card strip material under a kind of PVC/ABS alloy automobile front windshield the most according to claim 1, it is characterised in that: institute
Stating rare-earth stabilizer is XT-1, XT-2 or XT-3.
Card strip material under a kind of PVC/ABS alloy automobile front windshield the most according to claim 1, it is characterised in that: institute
State bromide fire retardant be deca-BDE FR-10, tetrabromophthalic anhydride TBPA or tetrabromo dipentaerythritol TBDPE.
Card strip material under a kind of PVC/ABS alloy automobile front windshield the most according to claim 1, it is characterised in that: press
Mass fraction, component includes: PVC 60 parts, ABS 40 parts, MBS 7 parts, 10 parts of calcium carbonate, DPOP 15 parts,
Carbon black 3 parts, XT-3 1 part, TBDPE 15 parts, Sb2O37.5 parts, graphene microchip 1 part.
Card strip material under a kind of PVC/ABS alloy automobile front windshield the most according to claim 1, it is characterised in that: press
Mass fraction, component includes: PVC 60 parts, ABS 40 parts, MBS 7 parts, 10 parts of calcium carbonate, DOS 15 parts, charcoal
Black 3 parts, XT-3 1 part, TBPA 15 parts, Sb2O37.5 parts, graphene microchip 1 part.
Card strip material under a kind of PVC/ABS alloy automobile front windshield the most according to claim 1, it is characterised in that: press
Mass fraction, component includes: PVC 60 parts, ABS 40 parts, MBS 7 parts, 10 parts of calcium carbonate, DOS 15 parts, charcoal
Black 3 parts, XT-3 1 part, FR-10 15 parts, Sb2O37.5 parts, graphene microchip 1 part.
9. a preparation method for card strip material under PVC/ABS alloy automobile front windshield as claimed in claim 1, including:
Weigh each raw material in proportion, first by PVC, ABS, solubilizer, calcium carbonate, plasticizer, carbon black, rare-earth stabilizer
High speed mixing smelting machine premixes 5～10 minutes, is subsequently adding bromide fire retardant, Sb2O35～10 are premixed again with graphene microchip
Minute, then the raw material mixed is put into double screw extruder melt extrudes granulation, to obtain final product.
The preparation method of card strip material under a kind of PVC/ABS alloy automobile front windshield the most according to claim 9, it is special
Levy and be: described in melt extrude the process conditions of granulation and be: melt temperature 90～170 DEG C, compression ratio 3:1.
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| CN201610217736.3A CN105754258A (en) | 2016-04-07 | 2016-04-07 | PVC (polyvinyl chloride)/ABS (acrylonitrile-butadiene-styrene) alloy material for front windshield lower fastening strip for car and preparation method thereof |
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| CN201610217736.3A CN105754258A (en) | 2016-04-07 | 2016-04-07 | PVC (polyvinyl chloride)/ABS (acrylonitrile-butadiene-styrene) alloy material for front windshield lower fastening strip for car and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107141659A (en) * | 2017-07-03 | 2017-09-08 | 魏科峰 | Polyvinyl chloride heat-resistant fireproof composite material and preparation method thereof |
| CN110527211A (en) * | 2019-07-30 | 2019-12-03 | 重庆春光高分子材料有限公司 | A kind of PVC high flame retardant sealing bar composition and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747568A (en) * | 2008-12-16 | 2010-06-23 | 金发科技股份有限公司 | PVC/ABS alloy material and preparation method thereof |
| CN102040786A (en) * | 2010-12-30 | 2011-05-04 | 佛山市顺德区圆融新材料有限公司 | Antiflaming PVC (poly vinyl chloride)/ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof |
| CN102321314A (en) * | 2011-08-19 | 2012-01-18 | 镇江育达复合材料有限公司 | Antistatic low-smoke flame-retardant polyvinyl chloride-acrylonitrile butadiene styrene (PVC-ABS) composite material and preparation method thereof |
| CN102382388A (en) * | 2010-09-01 | 2012-03-21 | 中国石油化工股份有限公司 | PVC/ABS alloy material with high anti-impact strength and preparation method thereof |
| CN102964715A (en) * | 2011-09-01 | 2013-03-13 | 合肥杰事杰新材料股份有限公司 | Flame-retardant cold-resistant PVC/ABS alloy and preparation method thereof |
-
2016
- 2016-04-07 CN CN201610217736.3A patent/CN105754258A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747568A (en) * | 2008-12-16 | 2010-06-23 | 金发科技股份有限公司 | PVC/ABS alloy material and preparation method thereof |
| CN102382388A (en) * | 2010-09-01 | 2012-03-21 | 中国石油化工股份有限公司 | PVC/ABS alloy material with high anti-impact strength and preparation method thereof |
| CN102040786A (en) * | 2010-12-30 | 2011-05-04 | 佛山市顺德区圆融新材料有限公司 | Antiflaming PVC (poly vinyl chloride)/ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof |
| CN102321314A (en) * | 2011-08-19 | 2012-01-18 | 镇江育达复合材料有限公司 | Antistatic low-smoke flame-retardant polyvinyl chloride-acrylonitrile butadiene styrene (PVC-ABS) composite material and preparation method thereof |
| CN102964715A (en) * | 2011-09-01 | 2013-03-13 | 合肥杰事杰新材料股份有限公司 | Flame-retardant cold-resistant PVC/ABS alloy and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| M.N.PRABHAKAR ET AL: "A Review on the Flammability and Flame Retardant Properties of Natural Fibers and Polymer Matrix Based Composites", 《COMPOSITES RESEARCH》 * |
| SHIYA RAN ET AL: "Effect of Friedel-Crafts reaction on the thermal stability and flammability of high-density polyethylene/brominated polystyrene/graphene nanoplatelet composites", 《POLYMER INTERNATIONAL》 * |
| 张丽等: "石墨烯/ABS树脂复合体系的阻燃性能", 《高分子材料科学与工程》 * |
| 杨有财等: "EG和DBDPE/Sb2O3协同阻燃ABS的阻燃性能及机理研究", 《塑料科技》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107141659A (en) * | 2017-07-03 | 2017-09-08 | 魏科峰 | Polyvinyl chloride heat-resistant fireproof composite material and preparation method thereof |
| CN110527211A (en) * | 2019-07-30 | 2019-12-03 | 重庆春光高分子材料有限公司 | A kind of PVC high flame retardant sealing bar composition and preparation method thereof |
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