CN105754255A - Composite for manufacturing packing case and preparation method of composite - Google Patents
Composite for manufacturing packing case and preparation method of composite Download PDFInfo
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- CN105754255A CN105754255A CN201610174912.XA CN201610174912A CN105754255A CN 105754255 A CN105754255 A CN 105754255A CN 201610174912 A CN201610174912 A CN 201610174912A CN 105754255 A CN105754255 A CN 105754255A
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- phenyl ester
- acid phenyl
- oxybenzoic acid
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Gasket Seals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a composite for manufacturing a packing case and a preparation method of the composite. The composite is prepared from the following constituents in parts by mass: 45-65 parts of polyvinyl chloride resin, 15-35 parts of aluminum oxide whiskers, 20-35 parts of polyacrylate rubber, 10-22 parts of aramid fibers, 0.5-1.5 parts of methyl methacrylate, 0.3-1 part of zinc stearate, 0.2-0.6 parts of phenyl salicylate, 0.1-0.5 parts of triphenyl phosphite, 3-9 parts of asbestos powder, 1-7 parts of coumarone resin, 0.2-0.8 parts of alkyl sodium sulfonate, 0.1-0.5 parts of phenyl salicylate and 0.1-0.5 parts of dimethicone. The packing case prepared from the composite provided by the invention has good anti-ageing performance, fire resistance, cushioning performance and impact resistance.
Description
Technical field
The present invention relates to technical field of composite materials, particularly relate to a kind of manufacture packing crates composite and preparation method thereof.
Background technology
Along with the development of carrier, to the demand of transportation and packing material also in continuous increase, and the prescription of packaging material is also improved constantly.The existing material for packing crates has timber, bamboo wood, engineering plastics, corrugated paper, composite etc. at present.Wooden, the complex manufacturing technology of bamboo matter packing crates, shape are fixed and weight is big, and movement requirement is high；The resistance to impact of plastics matter packing crates is low, and easily aging, abrasion；Concha Arcae paper packaging box is water funk, and weak to collision.
Packing crates that currently used composite prepares uses also extensive, and the aging resistance of existing packing crates, fire resistance are poor, and meanwhile, its shock-absorbing capacity, impact resistance are also undesirable.
Summary of the invention
Solving the technical problem that: poor for existing composite package aging resistance, fire resistance, resiliency, resistance to impact need the shortcoming improved, and the present invention provides a kind of and manufactures packing crates composite and preparation method thereof.
Technical scheme: a kind of manufacture packing crates composite, in mass parts containing following component: Corvic 45～65 parts, alumina whisker 15～35 parts, lactoprene 20～35 parts, aramid fiber 10～22 parts, methyl methacrylate 0.5～1.5 part, zinc stearate 0.3～1 part, oxybenzoic acid phenyl ester 0.2～0.6 part, triphenyl phosphite 0.1～0.5 part, flake asbestos 3～9 parts, coumarone indene resin 1～7 part, sodium alkyl sulfonate 0.2～0.8 part, oxybenzoic acid phenyl ester 0.1～0.5 part, dimethicone 0.1～0.5 part.
One described above manufactures packing crates composite, in mass parts containing following component: Corvic 50～60 parts, alumina whisker 20～30 parts, lactoprene 23～32 parts, aramid fiber 12～20 parts, methyl methacrylate 0.7～1.2 part, zinc stearate 0.4～0.9 part, oxybenzoic acid phenyl ester 0.3～0.5 part, triphenyl phosphite 0.2～0.4 part, flake asbestos 4～8 parts, coumarone indene resin 2～6 parts, sodium alkyl sulfonate 0.3～0.7 part, oxybenzoic acid phenyl ester 0.2～0.4 part, dimethicone 0.25～0.45 part.
One described above manufactures packing crates composite, in mass parts containing following component: Corvic 53 parts, and alumina whisker 23 parts, lactoprene 25 parts, aramid fiber 14 parts, methyl methacrylate 0.8 part, zinc stearate 0.5 part, oxybenzoic acid phenyl ester 0.35 part, triphenyl phosphite 0.25 part, flake asbestos 5 parts, coumarone indene resin 3.5 parts, sodium alkyl sulfonate 0.4 part, oxybenzoic acid phenyl ester 0.25 part, dimethicone 0.3 part.
One described above manufactures packing crates composite, in mass parts containing following component: Corvic 55 parts, and alumina whisker 25 parts, lactoprene 27 parts, aramid fiber 16 parts, methyl methacrylate 1 part, zinc stearate 0.65 part, oxybenzoic acid phenyl ester 0.4 part, triphenyl phosphite 0.3 part, flake asbestos 6 parts, coumarone indene resin 4 parts, sodium alkyl sulfonate 0.5 part, oxybenzoic acid phenyl ester 0.3 part, dimethicone 0.35 part.
A kind of preparation method manufacturing packing crates composite described above, the step of this preparation method is as follows:
The first step: first Corvic, alumina whisker, lactoprene, aramid fiber being added in mixer, rotating speed is that 400～600r/min is uniformly mixed；
Second step: add methyl methacrylate, zinc stearate, oxybenzoic acid phenyl ester, triphenyl phosphite, flake asbestos, coumarone indene resin, sodium alkyl sulfonate, oxybenzoic acid phenyl ester, dimethicone again in mixer, temperature be 160～200 DEG C, rotating speed be 350～450r/min, be uniformly mixed；
3rd step: be extruding pelletization at 300～340 DEG C by double screw extruder in temperature by the material in high-speed mixer, must manufacture packing crates composite.
In the first step described above, mixing speed is 500r/min.
In second step described above whipping temp be 180 DEG C, rotating speed be 300r/min.
In the 3rd step described above, extruding pelletization temperature is 320 DEG C.
Beneficial effect: a kind of manufacture packing crates composite provided by the invention and preparation method thereof, the packing crates prepared with this composite has good ageing resistace, fire resistance, shock-absorbing capacity and impact resistance, its packaging weight is more wooden, bamboo matter light, relatively the impact resistance of plastics matter, ageing resistace are good, compared with the collision water-fast, resistance to of Concha Arcae papery, more existing composite matter packaging material have more excellent ageing resistace, fire resistance, shock-absorbing capacity and impact resistance.
Detailed description of the invention
Embodiment 1
A kind of manufacture packing crates composite, in mass parts containing following component: Corvic 45 parts, alumina whisker 15 parts, lactoprene 20 parts, aramid fiber 10 parts, methyl methacrylate 0.5 part, zinc stearate 0.3 part, oxybenzoic acid phenyl ester 0.2 part, triphenyl phosphite 0.1 part, flake asbestos 3 parts, coumarone indene resin 1 part, sodium alkyl sulfonate 0.2 part, oxybenzoic acid phenyl ester 0.1 part, dimethicone 0.1 part.
A kind of preparation method manufacturing packing crates composite, the step of this preparation method is as follows:
The first step: first Corvic, alumina whisker, lactoprene, aramid fiber being added in mixer, rotating speed is that 400r/min is uniformly mixed；
Second step: add methyl methacrylate, zinc stearate, oxybenzoic acid phenyl ester, triphenyl phosphite, flake asbestos, coumarone indene resin, sodium alkyl sulfonate, oxybenzoic acid phenyl ester, dimethicone again in mixer, temperature be 160 DEG C, rotating speed be 350r/min, be uniformly mixed；
3rd step: be extruding pelletization at 300 DEG C by double screw extruder in temperature by the material in high-speed mixer, must manufacture packing crates composite.
Embodiment 2
A kind of manufacture packing crates composite, in mass parts containing following component: Corvic 65 parts, alumina whisker 35 parts, lactoprene 35 parts, aramid fiber 22 parts, methyl methacrylate 1.5 parts, zinc stearate 1 part, oxybenzoic acid phenyl ester 0.6 part, triphenyl phosphite 0.5 part, flake asbestos 9 parts, coumarone indene resin 7 parts, sodium alkyl sulfonate 0.8 part, oxybenzoic acid phenyl ester 0.5 part, dimethicone 0.5 part.
A kind of preparation method manufacturing packing crates composite, the step of this preparation method is as follows:
The first step: first Corvic, alumina whisker, lactoprene, aramid fiber being added in mixer, rotating speed is that 600r/min is uniformly mixed；
Second step: add methyl methacrylate, zinc stearate, oxybenzoic acid phenyl ester, triphenyl phosphite, flake asbestos, coumarone indene resin, sodium alkyl sulfonate, oxybenzoic acid phenyl ester, dimethicone again in mixer, temperature be 200 DEG C, rotating speed be 450r/min, be uniformly mixed；
3rd step: be extruding pelletization at 340 DEG C by double screw extruder in temperature by the material in high-speed mixer, must manufacture packing crates composite.
Embodiment 3
A kind of manufacture packing crates composite, in mass parts containing following component: Corvic 60 parts, alumina whisker 30 parts, lactoprene 32 parts, aramid fiber 20 parts, methyl methacrylate 1.2 parts, zinc stearate 0.9 part, oxybenzoic acid phenyl ester 0.5 part, triphenyl phosphite 0.4 part, flake asbestos 8 parts, coumarone indene resin 6 parts, sodium alkyl sulfonate 0.7 part, oxybenzoic acid phenyl ester 0.4 part, dimethicone 0.45 part.
A kind of preparation method manufacturing packing crates composite, the step of this preparation method is as follows:
The first step: first Corvic, alumina whisker, lactoprene, aramid fiber being added in mixer, rotating speed is that 500r/min is uniformly mixed；
Second step: add methyl methacrylate, zinc stearate, oxybenzoic acid phenyl ester, triphenyl phosphite, flake asbestos, coumarone indene resin, sodium alkyl sulfonate, oxybenzoic acid phenyl ester, dimethicone again in mixer, temperature be 180 DEG C, rotating speed be 400r/min, be uniformly mixed；
3rd step: be extruding pelletization at 320 DEG C by double screw extruder in temperature by the material in high-speed mixer, must manufacture packing crates composite.
Embodiment 4
A kind of manufacture packing crates composite, in mass parts containing following component: Corvic 53 parts, alumina whisker 23 parts, lactoprene 25 parts, aramid fiber 14 parts, methyl methacrylate 0.8 part, zinc stearate 0.5 part, oxybenzoic acid phenyl ester 0.35 part, triphenyl phosphite 0.25 part, flake asbestos 5 parts, coumarone indene resin 3.5 parts, sodium alkyl sulfonate 0.4 part, oxybenzoic acid phenyl ester 0.25 part, dimethicone 0.3 part.
A kind of preparation method manufacturing packing crates composite, the step of this preparation method is as follows:
The first step: first Corvic, alumina whisker, lactoprene, aramid fiber being added in mixer, rotating speed is that 500r/min is uniformly mixed；
Second step: add methyl methacrylate, zinc stearate, oxybenzoic acid phenyl ester, triphenyl phosphite, flake asbestos, coumarone indene resin, sodium alkyl sulfonate, oxybenzoic acid phenyl ester, dimethicone again in mixer, temperature be 180 DEG C, rotating speed be 400r/min, be uniformly mixed；
3rd step: be extruding pelletization at 320 DEG C by double screw extruder in temperature by the material in high-speed mixer, must manufacture packing crates composite.
Embodiment 5
A kind of manufacture packing crates composite, in mass parts containing following component: Corvic 55 parts, alumina whisker 25 parts, lactoprene 27 parts, aramid fiber 16 parts, methyl methacrylate 1 part, zinc stearate 0.65 part, oxybenzoic acid phenyl ester 0.4 part, triphenyl phosphite 0.3 part, flake asbestos 6 parts, coumarone indene resin 4 parts, sodium alkyl sulfonate 0.5 part, oxybenzoic acid phenyl ester 0.3 part, dimethicone 0.35 part.
A kind of preparation method manufacturing packing crates composite, the step of this preparation method is as follows:
The first step: first Corvic, alumina whisker, lactoprene, aramid fiber being added in mixer, rotating speed is that 500r/min is uniformly mixed；
Second step: add methyl methacrylate, zinc stearate, oxybenzoic acid phenyl ester, triphenyl phosphite, flake asbestos, coumarone indene resin, sodium alkyl sulfonate, oxybenzoic acid phenyl ester, dimethicone again in mixer, temperature be 180 DEG C, rotating speed be 400r/min, be uniformly mixed；
3rd step: be extruding pelletization at 320 DEG C by double screw extruder in temperature by the material in high-speed mixer, must manufacture packing crates composite.
The technical performance index manufacturing packing crates composite of above-described embodiment 1～embodiment 5, its testing result is as follows:
Above the embodiment of the present invention is described in detail, for one of ordinary skill in the art, according to the thought of the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this specification content should not be construed as limitation of the present invention.
Claims (8)
1. one kind manufactures packing crates composite, it is characterized in that in mass parts containing following component: Corvic 45～65 parts, alumina whisker 15～35 parts, lactoprene 20～35 parts, aramid fiber 10～22 parts, methyl methacrylate 0.5～1.5 part, zinc stearate 0.3～1 part, oxybenzoic acid phenyl ester 0.2～0.6 part, triphenyl phosphite 0.1～0.5 part, flake asbestos 3～9 parts, coumarone indene resin 1～7 part, sodium alkyl sulfonate 0.2～0.8 part, oxybenzoic acid phenyl ester 0.1～0.5 part, dimethicone 0.1～0.5 part.
2. a kind of manufacture packing crates composite according to claim 1, it is characterized in that in mass parts containing following component: Corvic 50～60 parts, alumina whisker 20～30 parts, lactoprene 23～32 parts, aramid fiber 12～20 parts, methyl methacrylate 0.7～1.2 part, zinc stearate 0.4～0.9 part, oxybenzoic acid phenyl ester 0.3～0.5 part, triphenyl phosphite 0.2～0.4 part, flake asbestos 4～8 parts, coumarone indene resin 2～6 parts, sodium alkyl sulfonate 0.3～0.7 part, oxybenzoic acid phenyl ester 0.2～0.4 part, dimethicone 0.25～0.45 part.
3. a kind of manufacture packing crates composite according to claim 1, it is characterized in that in mass parts containing following component: Corvic 53 parts, alumina whisker 23 parts, lactoprene 25 parts, aramid fiber 14 parts, methyl methacrylate 0.8 part, zinc stearate 0.5 part, oxybenzoic acid phenyl ester 0.35 part, triphenyl phosphite 0.25 part, flake asbestos 5 parts, coumarone indene resin 3.5 parts, sodium alkyl sulfonate 0.4 part, oxybenzoic acid phenyl ester 0.25 part, dimethicone 0.3 part.
4. a kind of manufacture packing crates composite according to claim 1, it is characterised in that in mass parts containing following component: Corvic 55 parts, alumina whisker 25 parts, lactoprene 27 parts, aramid fiber 16 parts, methyl methacrylate 1 part, zinc stearate 0.65 part, oxybenzoic acid phenyl ester 0.4 part, triphenyl phosphite 0.3 part, flake asbestos 6 parts, coumarone indene resin 4 parts, sodium alkyl sulfonate 0.5 part, oxybenzoic acid phenyl ester 0.3 part, dimethicone 0.35 part.
5. a kind of preparation method manufacturing packing crates composite described in claim 1, it is characterised in that the step of this preparation method is as follows:
The first step: first Corvic, alumina whisker, lactoprene, aramid fiber being added in mixer, rotating speed is that 400～600r/min is uniformly mixed；
Second step: add methyl methacrylate, zinc stearate, oxybenzoic acid phenyl ester, triphenyl phosphite, flake asbestos, coumarone indene resin, sodium alkyl sulfonate, oxybenzoic acid phenyl ester, dimethicone again in mixer, temperature be 160～200 DEG C, rotating speed be 350～450r/min, be uniformly mixed；
3rd step: be extruding pelletization at 300～340 DEG C by double screw extruder in temperature by the material in high-speed mixer, must manufacture packing crates composite.
6. a kind of preparation method manufacturing packing crates composite according to claim 5, it is characterised in that: in the described first step, mixing speed is 500r/min.
7. a kind of preparation method manufacturing packing crates composite according to claim 5, it is characterised in that: in described second step whipping temp be 180 DEG C, rotating speed be 300r/min.
8. a kind of preparation method manufacturing packing crates composite according to claim 5, it is characterised in that: in described 3rd step, extruding pelletization temperature is 320 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610174912.XA CN105754255A (en) | 2016-03-25 | 2016-03-25 | Composite for manufacturing packing case and preparation method of composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610174912.XA CN105754255A (en) | 2016-03-25 | 2016-03-25 | Composite for manufacturing packing case and preparation method of composite |
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| Publication Number | Publication Date |
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| CN105754255A true CN105754255A (en) | 2016-07-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610174912.XA Pending CN105754255A (en) | 2016-03-25 | 2016-03-25 | Composite for manufacturing packing case and preparation method of composite |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109251438A (en) * | 2018-07-04 | 2019-01-22 | 安徽省金正塑业有限公司 | A kind of packing box pvc material |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1618866A (en) * | 2004-10-11 | 2005-05-25 | 华东理工大学 | Preparation method of polyvinyl chloride/inorganic rigid particle composite resin |
| US20080194736A1 (en) * | 2007-02-13 | 2008-08-14 | Minqiu Lu | PVC nanocomposite manufacturing technology and applications |
| CN103396623A (en) * | 2013-07-15 | 2013-11-20 | 安徽济峰节能材料有限公司 | PVC (polyvinyl chloride) micro-foam floor and preparation method thereof |
| CN103554714A (en) * | 2013-10-11 | 2014-02-05 | 吴江市天源塑胶有限公司 | Antistatic plastic |
| CN104647842A (en) * | 2015-02-28 | 2015-05-27 | 广东源盛生态环保科技有限公司 | Composite geotechnical cloth and preparation method thereof |
| CN105175943A (en) * | 2015-09-25 | 2015-12-23 | 苏州莱特复合材料有限公司 | Composite for manufacturing trash can and preparation method of composite |
-
2016
- 2016-03-25 CN CN201610174912.XA patent/CN105754255A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1618866A (en) * | 2004-10-11 | 2005-05-25 | 华东理工大学 | Preparation method of polyvinyl chloride/inorganic rigid particle composite resin |
| US20080194736A1 (en) * | 2007-02-13 | 2008-08-14 | Minqiu Lu | PVC nanocomposite manufacturing technology and applications |
| CN103396623A (en) * | 2013-07-15 | 2013-11-20 | 安徽济峰节能材料有限公司 | PVC (polyvinyl chloride) micro-foam floor and preparation method thereof |
| CN103554714A (en) * | 2013-10-11 | 2014-02-05 | 吴江市天源塑胶有限公司 | Antistatic plastic |
| CN104647842A (en) * | 2015-02-28 | 2015-05-27 | 广东源盛生态环保科技有限公司 | Composite geotechnical cloth and preparation method thereof |
| CN105175943A (en) * | 2015-09-25 | 2015-12-23 | 苏州莱特复合材料有限公司 | Composite for manufacturing trash can and preparation method of composite |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109251438A (en) * | 2018-07-04 | 2019-01-22 | 安徽省金正塑业有限公司 | A kind of packing box pvc material |
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Application publication date: 20160713 |
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