CN105754183A - High-strength anti-algae fishing net - Google Patents

High-strength anti-algae fishing net Download PDF

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Publication number
CN105754183A
CN105754183A CN201610203368.7A CN201610203368A CN105754183A CN 105754183 A CN105754183 A CN 105754183A CN 201610203368 A CN201610203368 A CN 201610203368A CN 105754183 A CN105754183 A CN 105754183A
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China
Prior art keywords
fishing net
algae
minutes
high intensity
parts
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Pending
Application number
CN201610203368.7A
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Chinese (zh)
Inventor
凌必双
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CHAOHU RUI QIANG FISHING GEAR Co Ltd
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CHAOHU RUI QIANG FISHING GEAR Co Ltd
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Priority to CN201610203368.7A priority Critical patent/CN105754183A/en
Publication of CN105754183A publication Critical patent/CN105754183A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/10Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/16Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/001Treatment with visible light, infrared or ultraviolet, X-rays
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/13Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic System
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/1845Aromatic mono- or polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/12Applications used for fibers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/18Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/20Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups

Abstract

The invention discloses a high-strength anti-algae fishing net.The high-strength anti-algae fishing net is prepared from polyethylene fibers, glass fibers, an epoxy resin adhesive film, nanometer argil, nanometer alumina, dihydroxypropane,dibutyl phthalate and calcium stearate.The fishing net is simple in processing technology, the polyethylene fibers are adopted as raw materials for processing, the price of the fishing net is greatly lowered, and modification treatment is conducted on the polyethylene fibers in advance, so that performance of the obtained fishing net is greatly improved; intermittent ultraviolet irradiation treatment is conducted in the polyethylene fiber treatment process, the produced fishing net can have extremely high performance of preventing alga from adhesion; the treated glass fibers are adopted, and the modified nanometer argil is combined, so that strength and toughness of the fishing net are greatly enhanced, and water resistance of the fishing net is improved; the treated epoxy resin adhesive film is added, therefore compatibility among all components can be further improved, and comprehensive properties of the fishing net are increased.

Description

A kind of high intensity Algae-resistant fishing net
Technical field
The present invention relates to fishing gear field, particularly relate to a kind of high intensity Algae-resistant fishing net.
Background technology
Fishing lines refers to the diameter weaving mesh sheet and the tie net fishing gear line less than 4 millimeters, is the main material making fishing net.Present fishing lines mainly uses nylon raw material to prepare, but nylon processing technique is complicated, and to temperature, humidity requirement harshness, yield rate is low, and nylon is relatively costly, and water absorption rate is also higher, causes fishing net perishable;And existing fishing net, intensity is low, and the life-span is short;Fishing net is subject in sea water algae to be infected, and reduces the service life of fishing net, adds the cost of investment of fisherman.
Summary of the invention
It is an object of the invention to provide a kind of high intensity Algae-resistant fishing net, be achieved through the following technical solutions:
A kind of high intensity Algae-resistant fishing net, is made up of following component: polyethylene fibre 80 parts, glass fibre 10 parts, MBS resin 10 parts, calcium carbonate powder 0.5 part, 10 parts of epoxy resin glued membrane, nanoclay 0.5 part, nano aluminium oxide 0.5 part, dihydroxypropane 6 parts, dibutyl phthalate 4 parts, calcium stearate 1 part by weight.
Further, described polyethylene fibre is through modification in advance: by the mixed in hydrochloric acid of the benzoic acid of 1% concentration and 10% concentration, again polyethylene fibre is put in above-mentioned mixed solution, heating is to 65-70 DEG C, adopt ultraviolet to carry out discontinuity radiation treatment simultaneously, after continuing 40 minutes, filter, dry;Described ultraviolet irradiation is spaced apart 5 minutes.
Further, described glass fibre is first immersed in the sodium hydroxide solution of 1.5% concentration and heats to 70-80 DEG C, after 1-1.5 hour, adds the sodium carboxymethyl cellulose that weight portion is 0.1 part, and heating is to 85-90 DEG C, after continuing 40 minutes, filters, dry.
Further, described epoxy resin glued membrane is through pretreatment: be the dodecyltrimethoxysilane of 0.1 part Homogeneous phase mixing under alkaline environment by epoxy resin glued membrane and weight portion, heating is to 260 DEG C, after continuing 15 minutes, start Slow cooling, when being cooled to 155 DEG C, it is incubated 15 minutes, continue cool to 128 DEG C, be incubated 30 minutes, be finally cooled to till room temperature.
Further, described nanoclay is through modification: by nanoclay at 160 DEG C with the dibutyl tin laurate mixed processing that weight portion is 0.5 part 15 minutes.
Further, described nanoclay granularity is 15-20nm, and the granularity of described nano aluminium oxide is 30-40nm.
Further, described MBS resin and dihydroxypropane are through blended process: by MBS resin and the blended heating of dihydroxypropane, first continuous heating is to 120 DEG C, then is slowly cooled to room temperature, and stands 1-2 hour.
Further, after described calcium carbonate powder first adopts 1.5% concentration carboxylic acid washing outer surface, dry, place into and calcine 15 minutes under 250 DEG C of high temperature.
The invention has the beneficial effects as follows: the fishing net processing technique that the present invention makes is simple, polyethylene fibre is adopted to be processed as raw material, greatly reduce the price of fishing net, by polyethylene fibre is carried out modification in advance, greatly improve the performance of the fishing net produced, by, in the process that polyethylene fibre is processed, carrying out ultraviolet and be interrupted radiation treatment, it is possible to make the fishing net made have the extremely strong performance preventing Sargassum from adhering to;By adopting the blended process of MBS resin and dihydroxypropane, coordinate treated calcium carbonate powder, the anti-algae ability of fishing net can not only be strengthened, additionally it is possible to strengthen the toughness of fishing net, improve the bearing capacity of fishing net;By adopting glass fibre after treatment, coordinate modified Nano potter's clay, strengthen intensity and the toughness of fishing net greatly, improve the resistance to water of fishing net;By adding treated epoxy resin glued membrane, it is further able to improve the compatibility between each composition, increases the combination property of fishing net;Fishing net of the present invention has excellent bearing capacity, uses scope wide.
Detailed description of the invention
A kind of high intensity Algae-resistant fishing net, is made up of following component: polyethylene fibre 80 parts, glass fibre 10 parts, MBS resin 10 parts, calcium carbonate powder 0.5 part, 10 parts of epoxy resin glued membrane, nanoclay 0.5 part, nano aluminium oxide 0.5 part, dihydroxypropane 6 parts, dibutyl phthalate 4 parts, calcium stearate 1 part by weight.
Further, described polyethylene fibre is through modification in advance: by the mixed in hydrochloric acid of the benzoic acid of 1% concentration and 10% concentration, again polyethylene fibre is put in above-mentioned mixed solution, heating is to 65-70 DEG C, adopt ultraviolet to carry out discontinuity radiation treatment simultaneously, after continuing 40 minutes, filter, dry;Described ultraviolet irradiation is spaced apart 5 minutes.
Further, described glass fibre is first immersed in the sodium hydroxide solution of 1.5% concentration and heats to 70-80 DEG C, after 1-1.5 hour, adds the sodium carboxymethyl cellulose that weight portion is 0.1 part, and heating is to 85-90 DEG C, after continuing 40 minutes, filters, dry.
Further, described epoxy resin glued membrane is through pretreatment: be the dodecyltrimethoxysilane of 0.1 part Homogeneous phase mixing under alkaline environment by epoxy resin glued membrane and weight portion, heating is to 260 DEG C, after continuing 15 minutes, start Slow cooling, when being cooled to 155 DEG C, it is incubated 15 minutes, continue cool to 128 DEG C, be incubated 30 minutes, be finally cooled to till room temperature.
Further, described nanoclay is through modification: by nanoclay at 160 DEG C with the dibutyl tin laurate mixed processing that weight portion is 0.5 part 15 minutes.
Further, described nanoclay granularity is 15-20nm, and the granularity of described nano aluminium oxide is 30-40nm.
Further, described MBS resin and dihydroxypropane are through blended process: by MBS resin and the blended heating of dihydroxypropane, first continuous heating is to 120 DEG C, then is slowly cooled to room temperature, and stands 1-2 hour.
Further, after described calcium carbonate powder first adopts 1.5% concentration carboxylic acid washing outer surface, dry, place into and calcine 15 minutes under 250 DEG C of high temperature.
The manufacture method of a kind of high intensity Algae-resistant fishing net is:
1) following component is weighed by weight: polyethylene fibre 80 parts, glass fibre 10 parts, MBS resin 10 parts, calcium carbonate powder 0.5 part, 10 parts of epoxy resin glued membrane, nanoclay 0.5 part, nano aluminium oxide 0.5 part, dihydroxypropane 6 parts, dibutyl phthalate 4 parts, calcium stearate 1 part;
2) being mixed after treatment by above-mentioned raw materials and add in extruder, one section of temperature of extruder is 200 DEG C, and two-stage nitration temperature is 220 DEG C, and three sections of temperature are 225 DEG C, and latter end temperature is 230 DEG C;3) by 2) Raw adds in spray webbing case, uses spinning appts to carry out wire drawing, then carries out drawing-off, then dry at 85-90 DEG C, then uses winding roller to be wound collecting.

Claims (8)

1. a high intensity Algae-resistant fishing net, it is characterized in that, be made up of following component by weight: polyethylene fibre 80 parts, glass fibre 10 parts, MBS resin 10 parts, calcium carbonate powder 0.5 part, 10 parts of epoxy resin glued membrane, nanoclay 0.5 part, nano aluminium oxide 0.5 part, dihydroxypropane 6 parts, dibutyl phthalate 4 parts, calcium stearate 1 part.
2. a kind of high intensity Algae-resistant fishing net according to claim 1, it is characterized in that, described polyethylene fibre is through modification in advance: by the mixed in hydrochloric acid of the benzoic acid of 1% concentration and 10% concentration, again polyethylene fibre is put in above-mentioned mixed solution, heating, to 65-70 DEG C, adopts ultraviolet to carry out discontinuity radiation treatment, after continuing 40 minutes simultaneously, filter, dry;Described ultraviolet irradiation is spaced apart 5 minutes.
3. a kind of high intensity Algae-resistant fishing net according to claim 1, it is characterized in that, described glass fibre is first immersed in the sodium hydroxide solution of 1.5% concentration and heats to 70-80 DEG C, after 1-1.5 hour, adding the sodium carboxymethyl cellulose that weight portion is 0.1 part, heating is to 85-90 DEG C, after continuing 40 minutes, filter, dry.
4. a kind of high intensity Algae-resistant fishing net according to claim 1, it is characterized in that, described epoxy resin glued membrane is through pretreatment: be the dodecyltrimethoxysilane of 0.1 part Homogeneous phase mixing under alkaline environment by epoxy resin glued membrane and weight portion, and heating is to 260 DEG C, after continuing 15 minutes, start Slow cooling, when being cooled to 155 DEG C, it is incubated 15 minutes, continues cool to 128 DEG C, it is incubated 30 minutes, is finally cooled to till room temperature.
5. a kind of high intensity Algae-resistant fishing net according to claim 1, it is characterised in that described nanoclay is through modification: by nanoclay at 160 DEG C with the dibutyl tin laurate mixed processing that weight portion is 0.5 part 15 minutes.
6. a kind of high intensity Algae-resistant fishing net according to claim 1, it is characterised in that described nanoclay granularity is 15-20nm, and the granularity of described nano aluminium oxide is 30-40nm.
7. a kind of high intensity Algae-resistant fishing net according to claim 1, it is characterized in that, described MBS resin and dihydroxypropane are through blended process: by MBS resin and the blended heating of dihydroxypropane, first continuous heating is to 120 DEG C, it is slowly cooled to room temperature again, stands 1-2 hour.
8. a kind of high intensity Algae-resistant fishing net according to claim 1, it is characterised in that after described calcium carbonate powder first adopts 1.5% concentration carboxylic acid washing outer surface, dry, places into and calcines 15 minutes under 250 DEG C of high temperature.
CN201610203368.7A 2016-04-05 2016-04-05 High-strength anti-algae fishing net Pending CN105754183A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114457450A (en) * 2022-02-17 2022-05-10 山东惠民展鹏网业有限公司 High-strength antifouling salvage net and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5962655A (en) * 1982-10-04 1984-04-10 Mitsui Petrochem Ind Ltd Polyethylene composition
JPH07135872A (en) * 1993-08-20 1995-05-30 Toyobo Co Ltd Fish net
CN101230499A (en) * 2008-02-26 2008-07-30 山东爱地高分子材料有限公司 Coloured high-strength polyethylene fibre and method for manufacturing same
CN102050980A (en) * 2009-10-28 2011-05-11 中国石油化工股份有限公司 Ultra-high molecular weight polyethylene resin composition
CN105442085A (en) * 2015-12-18 2016-03-30 巢湖市天宇渔具有限公司 Anti-algae fishing net
CN105442086A (en) * 2015-12-18 2016-03-30 巢湖市天宇渔具有限公司 Anti-algae anti-aging fishing net

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5962655A (en) * 1982-10-04 1984-04-10 Mitsui Petrochem Ind Ltd Polyethylene composition
JPH07135872A (en) * 1993-08-20 1995-05-30 Toyobo Co Ltd Fish net
CN101230499A (en) * 2008-02-26 2008-07-30 山东爱地高分子材料有限公司 Coloured high-strength polyethylene fibre and method for manufacturing same
CN102050980A (en) * 2009-10-28 2011-05-11 中国石油化工股份有限公司 Ultra-high molecular weight polyethylene resin composition
CN105442085A (en) * 2015-12-18 2016-03-30 巢湖市天宇渔具有限公司 Anti-algae fishing net
CN105442086A (en) * 2015-12-18 2016-03-30 巢湖市天宇渔具有限公司 Anti-algae anti-aging fishing net

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114457450A (en) * 2022-02-17 2022-05-10 山东惠民展鹏网业有限公司 High-strength antifouling salvage net and preparation method thereof

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