CN105753279A - Silt/sludge solidifying agent and application thereof - Google Patents

Silt/sludge solidifying agent and application thereof Download PDF

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Publication number
CN105753279A
CN105753279A CN201610235059.8A CN201610235059A CN105753279A CN 105753279 A CN105753279 A CN 105753279A CN 201610235059 A CN201610235059 A CN 201610235059A CN 105753279 A CN105753279 A CN 105753279A
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China
Prior art keywords
silt
sludge
solidifying agent
sludge solidifying
activity
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Application number
CN201610235059.8A
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Chinese (zh)
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CN105753279B (en
Inventor
陈士强
罗昕
黄鹏
刘亚威
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China Power Jianshui Environmental Technology Co.,Ltd.
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Wuhan Meilidongfang Environment Protection Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/008Sludge treatment by fixation or solidification
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/06Sludge reduction, e.g. by lysis

Abstract

The invention particularly relates to a silt/sludge solidifying agent and application thereof.The silt/sludge solidifying agent is characterized by being mainly prepared by mixing, by mass, 60-75% of nano-micron modified binding material, 5-10% of poly-aluminum-ferric silicate, 10-20% of zeolite powder or bentonite and 5-15% of quicklime.Paving construction of road filling can be performed by adding the silt/sludge solidifying agent accounting for 10-20% of total amount of silt/sludge into the silt/sludge, mixing and stirring in a stirrer for 10-30 min and placing under sunlight for sufficient irradiation and solidification after stirring is finished.The silt/sludge solidifying agent can lower water content of high-water-content silt/sludge, is high in solidifying strength and capable of effectively solidifying heavy metals in the silt/sludge and reaches requirements of filling and building earth filling.

Description

A kind of silt/sludge solidifying agent and application thereof
Technical field:
This relates to a kind of silt/sludge solidifying agent and application thereof.
Background technology:
Numerous for river course, inland city lake, the bottom has substantial amounts of mud to pile up.And to the collection of mud with process past Big toward quantities, cost is surprising.Such as in South-to-North Water Transfer Project, the land expropriation cost of the dredging silt of generation is just Up to 6.4 hundred million yuan.And these mud moisture content stacked are high, intensity is low, possibly together with toxic chemical substance, cause of disease Biology waits some harmful components.External many developed countries manufacture the business such as high-efficient purification fuel, construction material with mud Mode carries out comprehensive development and utilization to mud.But at home, due to technology and funds, the lake training of channel Mud most or as filling material, reduce the moisture content of mud, improve the intensity of mud and meet the earthwork and fill Requirement.Therefore, the inorganic material of domestic commonly used cement class carries out solidification process to mud, but cement class material Material is when silt consolidation, and addition is relatively big, and poor to the solidification effect of High water cut mud.
CN105367009A discloses a kind of sludge curing agent and its preparation method and application, and mass parts pressed by this curing agent The component of number meter consists of: cement 9~18 parts, lime 2~5 parts, gypsum 2~5 parts, bentonite 2~5 parts, causticity Sodium 0.4~1 part.After said components being dried 6~8 hours in drying oven, after grinding, it is uniformly mixing to obtain curing agent. But this invention is longer for hardening time, to high-moisture percentage sludge solidification DeGrain.
Accordingly, it would be desirable to a kind of silt/sludge curing material of a kind of high efficiency, low cost.
Summary of the invention:
In order to solve technical problem in existing sludge solidification material, for silt from the bottom of lake contains substantial amounts of organic matter and weight The characteristics such as metal, silt/sludge solidifying agent that the invention provides a kind of excellent performance and application thereof, enters High water cut mud The materials such as row solidification processes, and effectively reduces the moisture content of mud, the heavy metal in curing sludge, and improve mud Intensity, reaches the requirement that the earthwork is filled.
The technical scheme is that
A kind of silt/sludge solidifying agent, by percentage to the quality, it is characterised in that mainly comprise for: micron modification of receiving is gelled Material 60%-75%, polymeric aluminium ferrum silicate 5%-10%, zeolite powder is or/and bentonite 10%-20%, quick lime 5%-15% Mix.
Each component is based on percent mass, and a described micron modified adhesive gel material of receiving obtains according to the following steps: (1) will Activity SiO225%-40%, activity Al2O35%-10%, activity CaO 40%-50%, active Fe2O35%-10%, Activity MgO 3%-5% is blended in 1450 DEG C of stoves calcining and obtains sinter in 20 minutes;(2) sinter that will obtain With CaSO4Mix in 1:0.05:0.02 ratio with nano silicon, levigate to D95≤15 μm, obtain institute That states receives a micron modified adhesive gel material.
Described zeolite powder is or/and bentonitic fineness is 400 mesh.
The purposes of the silt/sludge solidifying agent described in utilization, it is characterised in that: add in silt/mud and account for silt/mud total amount The silt/sludge solidifying agent of 10%-20%, stir in stirrer for mixing, stir 10-30 minute, stir after terminating, Put into irradiation completion of cure under sunlight, the making construction of road filler can be carried out.
Silt/the sludge solidifying agent of the present invention can reduce the moisture content of high-moisture percentage silt/mud, and solidification intensity is high, and can have Heavy metal in the solidification silt/mud of effect, reaches landfill and builds the requirement banketed.
Detailed description of the invention:
In conjunction with example, the present invention is described further.
By activity SiO230%, activity Al2O310%, activity CaO 50%, active Fe2O35%, activity MgO 5% It is blended in stove calcining and obtains sinter in 20 minutes;
By the sinter obtained and CaSO4Mix in 1:0.05:0.02 ratio with nano silicon, levigate To D95≤15 μm, obtain receiving a micron modified adhesive gel material.
The each embodiment of table 1 is raw materials used and proportioning unit %
Table 2. is the result that the embodiment 1~7 as shown in table 1 is raw materials used and silt from the bottom of lake dehydrating and curing is processed by proportioning.
The table 2 dehydrating and curing treatment effect to mud

Claims (4)

1. silt/sludge solidifying agent, by percentage to the quality, it is characterised in that mainly comprise for: receive a micron modified adhesive Gel material 60%-75%, polymeric aluminium ferrum silicate 5%-10%, zeolite powder is or/and bentonite 10%-20%, quick lime 5%-15% mixes.
Silt/sludge solidifying agent the most as claimed in claim 1, it is characterised in that: each component is based on percent mass, described A micron modified adhesive gel material of receiving obtain according to the following steps: (1) is by activity SiO225%-40%, activity Al2O3 5%-10%, activity CaO 40%-50%, active Fe2O35%-10%, activity MgO 3%-5% are blended in 1450 DEG C In stove, calcining obtains sinter in 20 minutes;(2) by the sinter obtained and CaSO4With nano silicon by 1: 0.05:0.02 ratio mixes, levigate to D95≤15 μm, obtains a described micron modified adhesive gel material of receiving.
Silt/sludge solidifying agent the most as claimed in claim 1, it is characterised in that: described zeolite powder is or/and bentonitic Fineness is 400 mesh.
4. utilize the purposes of the described silt/sludge solidifying agent of one of claim 1-3, it is characterised in that: at silt/mud Middle addition accounts for the silt/sludge solidifying agent of the 10%-20% of silt/mud total amount, stirs in stirrer for mixing, stirs 10- 30 minutes, after stirring terminates, put into irradiation completion of cure under sunlight, the making construction of road filler can be carried out.
CN201610235059.8A 2016-04-15 2016-04-15 A kind of silt/sludge solidifying agent and its application method Active CN105753279B (en)

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Application Number Priority Date Filing Date Title
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CN105753279B CN105753279B (en) 2018-05-22

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106277711A (en) * 2016-08-16 2017-01-04 中电建水环境治理技术有限公司 Lake, river is gushed polluted bed mud and is processed quenched composite of conditioning and preparation method thereof
CN107129129A (en) * 2017-05-24 2017-09-05 田仕明 A kind of efficient conditioner of deeply dehydrating sludge of zeolite improvement and preparation method thereof
WO2018032807A1 (en) * 2016-08-16 2018-02-22 中电建水环境治理技术有限公司 Binding material with nanoscale modification for treating contaminated river or lake sediment
CN108085015A (en) * 2017-12-22 2018-05-29 桑德生态科技有限公司 Bed mud heavy metal deactivator and preparation method thereof
CN108314280A (en) * 2018-01-12 2018-07-24 广州市水电建设工程有限公司 A kind of sludge curing agent and preparation method thereof
CN109796112A (en) * 2019-03-26 2019-05-24 哈尔滨工业大学 A kind of micro-nano curing agent and preparation method and application for black and odorous water high organic bed mud
CN112321101A (en) * 2020-10-20 2021-02-05 上海交通建设总承包有限公司 Silt tracing curing agent and using method thereof
CN113307590A (en) * 2021-05-12 2021-08-27 浙江交工宏途交通建设有限公司 Pile foundation drilling residue soil curing material and use method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS577105B2 (en) * 1972-10-27 1982-02-08
CN101172749A (en) * 2007-10-12 2008-05-07 河海大学 Solidifying agent for solidifying and stabilizing treatment of generated dewatered sludge in sewage plant
JP4450519B2 (en) * 2001-02-01 2010-04-14 宇部興産株式会社 Construction sludge treatment method
CN104803656A (en) * 2015-02-14 2015-07-29 广州市正源环境工程有限公司 Method used for preparing sintered bricks with modified sludge
CN105217925A (en) * 2015-10-12 2016-01-06 北京高能时代环境技术股份有限公司 Solidifying agent of a kind of sludge in-situ solidification and stabilization and its preparation method and application
CN105367009A (en) * 2015-10-26 2016-03-02 广东工业大学 Sludge curing agent and preparing method and application thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS577105B2 (en) * 1972-10-27 1982-02-08
JP4450519B2 (en) * 2001-02-01 2010-04-14 宇部興産株式会社 Construction sludge treatment method
CN101172749A (en) * 2007-10-12 2008-05-07 河海大学 Solidifying agent for solidifying and stabilizing treatment of generated dewatered sludge in sewage plant
CN104803656A (en) * 2015-02-14 2015-07-29 广州市正源环境工程有限公司 Method used for preparing sintered bricks with modified sludge
CN105217925A (en) * 2015-10-12 2016-01-06 北京高能时代环境技术股份有限公司 Solidifying agent of a kind of sludge in-situ solidification and stabilization and its preparation method and application
CN105367009A (en) * 2015-10-26 2016-03-02 广东工业大学 Sludge curing agent and preparing method and application thereof

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106277711A (en) * 2016-08-16 2017-01-04 中电建水环境治理技术有限公司 Lake, river is gushed polluted bed mud and is processed quenched composite of conditioning and preparation method thereof
WO2018032807A1 (en) * 2016-08-16 2018-02-22 中电建水环境治理技术有限公司 Binding material with nanoscale modification for treating contaminated river or lake sediment
WO2018032810A1 (en) * 2016-08-16 2018-02-22 中电建水环境治理技术有限公司 Composite material for treating, conditioning, and remediating contaminated river or lake sediment, and manufacturing method thereof
CN107129129A (en) * 2017-05-24 2017-09-05 田仕明 A kind of efficient conditioner of deeply dehydrating sludge of zeolite improvement and preparation method thereof
CN107129129B (en) * 2017-05-24 2020-12-15 田仕明 Zeolite-modified sludge deep dehydration high-efficiency conditioner and preparation method thereof
CN108085015A (en) * 2017-12-22 2018-05-29 桑德生态科技有限公司 Bed mud heavy metal deactivator and preparation method thereof
CN108314280A (en) * 2018-01-12 2018-07-24 广州市水电建设工程有限公司 A kind of sludge curing agent and preparation method thereof
CN109796112A (en) * 2019-03-26 2019-05-24 哈尔滨工业大学 A kind of micro-nano curing agent and preparation method and application for black and odorous water high organic bed mud
CN109796112B (en) * 2019-03-26 2021-11-09 哈尔滨工业大学 Micro-nano curing agent for black and odorous water body high organic matter bottom mud and preparation method and application thereof
CN112321101A (en) * 2020-10-20 2021-02-05 上海交通建设总承包有限公司 Silt tracing curing agent and using method thereof
CN113307590A (en) * 2021-05-12 2021-08-27 浙江交工宏途交通建设有限公司 Pile foundation drilling residue soil curing material and use method thereof
CN113307590B (en) * 2021-05-12 2024-02-02 浙江交工宏途交通建设有限公司 Pile foundation drilling residue soil curing material and application method thereof

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Address after: 430014 Hubei Wuhan Wuhan national biological industrial base project, B, C, D, R & D building, B1, No. 666 hi-tech Avenue, Wuhan Development Zone, Wuhan.

Patentee after: Wuhan Beautiful Oriental Sludge Treatment Technology Co., Ltd.

Address before: 430074 No. 666 High-tech Avenue, Donghu Hi-tech Development Zone, Wuhan City, Hubei Province, B1 R&D Building, Area B, C and D, Wuhan National Biological Industrial Base Project

Patentee before: WUHAN MEILIDONGFANG ENVIRONMENT PROTECTION CO., LTD.

CP03 Change of name, title or address
CP03 Change of name, title or address

Address after: 415, Yanluo Anxin building, Shanmen community, Yanluo street, Bao'an District, Shenzhen City, Guangdong Province

Patentee after: China Power Jianshui Environmental Technology Co.,Ltd.

Address before: 430014 Hubei Wuhan Wuhan national biological industrial base project, B, C, D, R & D building, B1, No. 666 hi-tech Avenue, Wuhan Development Zone, Wuhan.

Patentee before: WUHAN BEAUTIFUL ORIENTAL ENVIRONMENTAL PROTECTION Co.,Ltd.