CN105750032A - Anti-abrasion lining board for cement ball mill and manufacturing method of anti-abrasion lining board - Google Patents

Anti-abrasion lining board for cement ball mill and manufacturing method of anti-abrasion lining board Download PDF

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Publication number
CN105750032A
CN105750032A CN201610199238.0A CN201610199238A CN105750032A CN 105750032 A CN105750032 A CN 105750032A CN 201610199238 A CN201610199238 A CN 201610199238A CN 105750032 A CN105750032 A CN 105750032A
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CN
China
Prior art keywords
base material
ball mill
tungsten carbide
resistant coating
wear
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610199238.0A
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Chinese (zh)
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CN105750032B (en
Inventor
周俊华
尹方勇
王峰
王征
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Tohelm Grinding Wear-Resistant Technology Development Co Ltd
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Shandong Tohelm Grinding Wear-Resistant Technology Development Co Ltd
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Application filed by Shandong Tohelm Grinding Wear-Resistant Technology Development Co Ltd filed Critical Shandong Tohelm Grinding Wear-Resistant Technology Development Co Ltd
Priority to CN201610199238.0A priority Critical patent/CN105750032B/en
Publication of CN105750032A publication Critical patent/CN105750032A/en
Application granted granted Critical
Publication of CN105750032B publication Critical patent/CN105750032B/en
Expired - Fee Related legal-status Critical Current
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C17/00Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls
    • B02C17/18Details
    • B02C17/22Lining for containers
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material

Abstract

The invention discloses an anti-abrasion lining board for a cement ball mill.The work face of a lining board base material is wavy or in a concave-convex grid shape or in a step shape.The surface of the work face of the base material is further coated with an anti-abrasion coating which is a tungsten carbide anti-abrasion coating coated through supersonic flame spraying.The level of tungsten carbide powder particles adopted in the coating ranges from WC10 to WC100.The base material is manufactured from low-carbon steel.The invention further discloses a manufacturing method of the anti-abrasion lining board for the cement ball mill.The method includes the steps of base material selection, size processing, work face processing, coating raw material preparation, supersonic flame spraying and the like.The surface of the work face of the manufactured lining board is high in strength, good in abrasion resistance and impact resistance, low in cost, good in corrosion resistance, low in work loss, long in service life, good in economic efficiency, capable of assisting in material cutting, not prone to falling off and capable of improving work efficiency of the ball mill, and a prepared material is high in purity.

Description

A kind of cement ball mill abrasion-proof backing block and manufacture method thereof
Technical field
The present invention relates to cement manufacture field, particularly relate to a kind of cement ball mill abrasion-proof backing block and manufacture method thereof.
Background technology
Ball mill is the milling equipment that the industries such as metallurgical ore grinding, cement, generating are conventional.The Main Function of ball grinding machine lining board is protection grinding machine and drives abrading-ball be ground material and pulverize.The main failure forms of ball grinding machine lining board is the abrasive wear under small capacity hump, and according to statistics, the iron and steel that China consumes every year on ball mill reaches millions of tons.The most how to improve the focus of the wearability always research of ball grinding machine lining board.
Now commonly using lining material is high strength steel, but its wearability is the most poor, and service life is short, and due to the poor toughness that high strength steel is general, liner plate the most easily ftractures, it is broken to collapse so that repair demolition is extremely difficult;And with low-carbon alloy steel making ball grinding machine lining board, there is again intensity and hardness is low, the deficiency that wears no resistance;In order to improve obdurability and the wearability of steel alloy, generally will add the alloying elements such as molybdenum, nickel, chromium, tungsten, vanadium, the most in short supply along with alloy resource, molybdenum, nickel, chromium, tungsten, vanadium etc. are becoming tight alloy supply day, price rapidly goes up, and causes common iron and steel high-abrasive material production cost constantly to rise;Meanwhile, current main flow liner plate mostly is martensite steel sections, easily undergoes phase transition more than 250 DEG C, causes liner plate hydraulic performance decline, is therefore not suitable for working under the operating mode of long-time, high intensity.It addition, many of existing liner plate considers the intensity of liner plate itself, toughness and corrosion resistance etc., do not account for the ability of liner plate secondary process material, and material easily sticks on liner plate;Meanwhile, stainless steel cost is high and the most wear-resisting, and high strength steel is wear-resisting but the most corrosion-resistant, all easily due to abrasion or corrosion impact working face, reduces the degree of purity of made material simultaneously.
In the Patents the most applied for, patent " a kind of large-size ball mill liner plate and casting method thereof " (application number: 201010294909.4, publication date: 2011-01-26), disclose a kind of anti-wear performance excellent, hardness is high, good toughness, the preparation method of intensity height liner plate, in conventional steel liner plate, add the multiple alloying elements such as silicon, chromium, molybdenum, boron, niobium promote wearability and the toughness of liner plate, but this liner plate is the most corrosion-resistant;It addition, remain martensite steel sections, non-refractory;Simultaneously as matrix limits, its impact resistance is the most poor, and work long hours cracky.Patent " lining sheet for ball mill of a kind of high-wear resistance " (application number: 201410364512.6, publication date: 2014-10-29), disclose a kind of essence high-strength stainless steel liner plate as base material, and the average tempering technique used, high temperature resistant, but it have employed the alloying element such as chromium, titanium in a large number, raw material are smelted difficult and expensive, simultaneously result in this liner plate Castability poor, cannot be used for manufacturing large-scale liner plate, range of application is not wide, meanwhile, the addition of a large amount of carbon also make this liner plate cannot complete austenitizing, corrosion resistance is the best.It addition, above-mentioned two parts of patents the most only consider the intensity of liner plate itself, toughness and corrosion resistance etc., do not account for the ability of liner plate secondary process material, and material easily sticks on liner plate.
Summary of the invention
For drawbacks described above present in prior art, it is desirable to provide a kind of wear-resisting, high temperature resistant, corrosion-resistant, impact resistance, good economy performance, length in service life, material are difficult to adhere to, can secondary process material and the cement ball mill abrasion-proof backing block of made material high purity.
To achieve these goals, the present invention by the following technical solutions: a kind of cement ball mill abrasion-proof backing block, including the base material possessing installed surface and working face, it is characterised in that: described base material working face undulate or concavo-convex latticed;Described base material face surface is also coated with wear-resistant coating, and this wear-resistant coating is the tungsten carbide system wear-resistant coating using HVAF coating.
Above-mentioned cement ball mill abrasion-proof backing block, wherein: described tungsten carbide system wear-resistant coating is preferably WC-CoCr or WC-Co, and tungsten carbide powder particle grades contained by it is WC10-WC100.
Above-mentioned cement ball mill abrasion-proof backing block, wherein: the composition of tungsten carbide system wear-resistant coating also includes the one in tantalum carbide powder, titanium carbide powder or combinations thereof thing;A kind of or combinations thereof thing in described tantalum carbide powder, titanium carbide powder accounts for the 3-5% of tungsten carbide system wear-resistant coating gross mass the most altogether.
Above-mentioned cement ball mill abrasion-proof backing block, wherein: described base material uses mild steel manufacture, described mild steel includes that carbon content is less than carbon steel and the carbon content steel alloy less than 0.25% of 0.25%.
The manufacture method of the cement ball mill abrasion-proof backing block of above-mentioned water, it comprises the following steps:
(1) select the carbon content carbon steel less than 0.25% and the carbon content steel alloy less than 0.25% as mild steel base material;
(2) mild steel base material is processed as the size needed;
(3) base material working face is processed as the shape needed, such as waveform or concavo-convex latticed or stepped;
(4) raw material of configuration tungsten carbide system wear-resistant coating: select tungsten carbide powder WC-CoCr or WC-Co, it is ensured that its particle grades is WC10-WC100;
(5) using HVAF technique, fire flame speed >=2100m/s, material powder step (3) configured sends into combustion flame, produces fusing or the particle of semi-molten, and high-speed impact, on base material face surface, forms wear-resistant coating.
The manufacture method of above-mentioned cement ball mill abrasion-proof backing block, in its step (3) in addition to selecting tungsten carbide powder, the 3-5% also pressing tungsten carbide system wear-resistant coating gross mass mixes the one in tantalum carbide powder, titanium carbide powder or combinations thereof thing, mixes.
Compared with the prior art, due to the fact that and have employed such scheme, prepared liner plate working face wearability is high, and case hardness is at more than 2200HV, far above the hardness of conventional High Intensity steel about 700HV;Mild steel strong shock resistance, and low cost, although itself not wear-and corrosion-resistant, but owing to working face is coated with wear-resisting, anti-corrosion tungsten carbide coating, solve its working face wear-and corrosion-resistant problem, installed surface is fitted with shell, the most perishable, even if there being slight erosion to nor affect on its service behaviour and the degree of purity of made material;Tungsten carbide material high abrasion resistance, have concurrently shock resistance, good toughness mild steel as base material, working loss is low, and adaptability is good, and service life is long, good economy performance;Base material working face is wavy or textured, and the coating being coated in its surface also thus presents same form, can assisted machining material, preferred coating composition further increases the antiknock ability of coating, is beneficial to cut cement granules;Meanwhile, tungsten carbide coating uses HVAF to be coated in the surface of low-carbon steel that affinity is good, and adhesion is good, difficult drop-off, furthermore tungsten carbide cutting power is strong, wearability good, and the operating efficiency of ball mill can be greatly improved, and makes prepared material high purity simultaneously.
Accompanying drawing explanation
Fig. 1 is the partial schematic diagram of the waveform working face of base material of the present invention;
Fig. 2 is the partial schematic diagram of the stepped working face of base material of the present invention;
Fig. 3 is the partial schematic diagram of the concavo-convex latticed working face of base material of the present invention.
Detailed description of the invention
Embodiment 1:
A kind of cement ball mill abrasion-proof backing block, including possessing the base material of installed surface and working face and being coated in the wear-resistant coating of substrate surface, wherein: described base material working face undulate;Described wear-resistant coating is the WC-Co coating that with the addition of 3% tantalum carbide powder using HVAF coating, and the powder particle grade that this coating uses is WC10;Described base material uses 10#Steel making.Its manufacture method comprises the following steps:
(1) 10 are selected#Steel is as mild steel base material;
(2) mild steel base material is processed as the size needed;
(3) base material working face is processed as waveform;
(4) raw material of configuration tungsten carbide system wear-resistant coating: select tungsten carbide powder WC-Co, it is ensured that its particle grades is WC10;And press tungsten carbide system wear-resistant coating gross mass 3% incorporation tantalum carbide powder, mix;
(5) using HVAF technique, fire flame speed >=2100m/s, material powder step (3) configured sends into combustion flame, produces fusing or the particle of semi-molten, and high-speed impact, on base material face surface, forms wear-resistant coating.
Wherein, the method that the method for HVAF, liner plate are installed is prior art, repeats no more, lower same.
Embodiment 2:
A kind of cement ball mill abrasion-proof backing block, including possessing the base material of installed surface and working face and being coated in the wear-resistant coating of substrate surface, wherein: described base material working face is concavo-convex latticed;Described wear-resistant coating is the WC-CoCr coating that with the addition of 5% titanium carbide powder using HVAF coating, and the powder particle grade that this coating uses is WC100;Described base material uses 20Cr steel making.Its manufacture method comprises the following steps:
(1) select 20Cr steel as mild steel base material;
(2) mild steel base material is processed as the size needed;
(3) base material working face is processed as concavo-convex latticed;
(4) raw material of configuration tungsten carbide system wear-resistant coating: select tungsten carbide powder WC-CoCr, it is ensured that its particle grades is WC100;
(5) using HVAF technique, fire flame speed >=2100m/s, material powder step (3) configured sends into combustion flame, produces fusing or the particle of semi-molten, and high-speed impact, on base material face surface, forms wear-resistant coating.
Embodiment 3:
A kind of cement ball mill abrasion-proof backing block, including possessing the base material of installed surface and working face and being coated in the wear-resistant coating of substrate surface, wherein: described base material working face undulate;Described wear-resistant coating is the WC-CoCr coating that with the addition of 2% titanium carbide powder and 2% tantalum carbide powder using HVAF coating, and the powder particle grade that this coating uses is WC20;Described base material uses 20Cr steel making.
Its manufacture method comprises the following steps:
(1) select 20Cr steel as mild steel base material;
(2) mild steel base material is processed as the size needed;
(3) base material working face is processed as waveform;
(4) raw material of configuration tungsten carbide system wear-resistant coating: select tungsten carbide powder WC-CoCr, it is ensured that its particle grades is WC20;And press 2% interpolation titanium carbide powder and tantalum carbide powder of tungsten carbide system wear-resistant coating gross mass respectively, mix;
(5) using HVAF technique, fire flame speed >=2100m/s, material powder step (3) configured sends into combustion flame, produces fusing or the particle of semi-molten, and high-speed impact, on base material face surface, forms wear-resistant coating.
Embodiment 4:
A kind of cement ball mill abrasion-proof backing block, including possessing the base material of installed surface and working face and being coated in the wear-resistant coating of substrate surface, wherein: described base material working face is concavo-convex latticed or stepped;Described wear-resistant coating is the WC-CoCr coating using HVAF coating, and the powder particle grade that this coating uses is WC100;Described base material uses 20Cr steel making.Its manufacture method comprises the following steps:
(1) select 20Cr steel as mild steel base material;
(2) mild steel base material is processed as the size needed;
(3) base material working face is processed as concavo-convex latticed or stepped;
(4) raw material of configuration tungsten carbide system wear-resistant coating: select tungsten carbide powder WC-CoCr, it is ensured that its particle grades is WC100;
(5) using HVAF technique, fire flame speed >=2100m/s, material powder step (3) configured sends into combustion flame, produces fusing or the particle of semi-molten, and high-speed impact, on base material face surface, forms wear-resistant coating.
Embodiment 5:
A kind of cement ball mill abrasion-proof backing block, including possessing the base material of installed surface and working face and being coated in the wear-resistant coating of substrate surface, wherein: described base material working face undulate or stepped;Described wear-resistant coating is the WC-Co coating using HVAF coating, and the powder particle grade that this coating uses is WC10;Described base material uses 25#Steel making.Its manufacture method comprises the following steps:
(1) 25 are selected#Steel is as mild steel base material;
(2) mild steel base material is processed as the size needed;
(3) base material working face is processed as waveform or stepped;
(4) raw material of configuration tungsten carbide system wear-resistant coating: select tungsten carbide powder WC-Co, it is ensured that its particle grades is WC10;
(5) using HVAF technique, fire flame speed >=2100m/s, material powder step (3) configured sends into combustion flame, produces fusing or the particle of semi-molten, and high-speed impact, on base material face surface, forms wear-resistant coating.
Described above to the disclosed embodiments, only for making professional and technical personnel in the field be capable of or using the present invention.Multiple amendment to these embodiments will be apparent from for those skilled in the art, and generic principles defined herein can realize without departing from the spirit or scope of the present invention in other embodiments.Therefore, the present invention is not intended to be limited to the embodiments shown herein, and is to fit to the widest scope consistent with principles disclosed herein and features of novelty.

Claims (6)

1. a cement ball mill abrasion-proof backing block, including the base material possessing installed surface and working face, it is characterised in that: described base material working face undulate or concavo-convex latticed or stepped;Described base material face surface is also coated with wear-resistant coating, and this wear-resistant coating is the tungsten carbide system wear-resistant coating using HVAF coating.
A kind of cement ball mill abrasion-proof backing block the most according to claim 1, it is characterised in that: described tungsten carbide system wear-resistant coating is preferably WC-CoCr or WC-Co, and tungsten carbide powder particle grades contained by it is WC10-WC100.
A kind of cement ball mill abrasion-proof backing block the most according to claim 1 and 2, it is characterised in that: the composition of tungsten carbide system wear-resistant coating also includes the one in tantalum carbide powder, titanium carbide powder or combinations thereof thing;A kind of or combinations thereof thing in described tantalum carbide powder, titanium carbide powder accounts for the 3-5% of tungsten carbide system wear-resistant coating gross mass the most altogether.
A kind of cement ball mill abrasion-proof backing block the most according to claim 3, it is characterised in that: described base material uses mild steel manufacture, and described mild steel includes that carbon content is less than carbon steel and the carbon content steel alloy less than 0.25% of 0.25%.
The manufacture method of a kind of cement ball mill abrasion-proof backing block described in the most any of the above-described claim, it is characterised in that: comprise the following steps:
(1) select the carbon content carbon steel less than 0.25% and the carbon content steel alloy less than 0.25% as mild steel base material;
(2) mild steel base material is processed as the size needed;
(3) base material working face is processed as the shape needed, such as waveform or concavo-convex latticed or stepped;
(4) raw material of configuration tungsten carbide system wear-resistant coating: select tungsten carbide powder WC-CoCr or WC-Co, it is ensured that its particle grades is WC10-WC100;
(5) using HVAF technique, fire flame speed >=2100m/s, material powder step (3) configured sends into combustion flame, produces fusing or the particle of semi-molten, and high-speed impact, on base material face surface, forms wear-resistant coating.
The manufacture method of a kind of cement ball mill abrasion-proof backing block the most according to claim 5, it is characterized in that: in step (3) in addition to selecting tungsten carbide powder, the 3-5% also pressing tungsten carbide system wear-resistant coating gross mass mixes the one in tantalum carbide powder, titanium carbide powder or combinations thereof thing, mixes.
CN201610199238.0A 2016-04-02 2016-04-02 A kind of cement ball mill wear-resistant liner and its manufacturing method Expired - Fee Related CN105750032B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109127101A (en) * 2018-08-09 2019-01-04 北京天山新材料技术有限公司 The means of defence and coal pulverizer of coal pulverizer
CN109808214A (en) * 2019-02-18 2019-05-28 北京固本科技有限公司 A kind of wear-resisting squeezing item
CN110404638A (en) * 2019-08-29 2019-11-05 盐城工学院 A kind of ball mill lining plate structure suitable for ultra-fine ball milling
CN110512164A (en) * 2019-09-06 2019-11-29 武汉苏伯曼科技有限公司 Improve the method and mineral fine powder steam dryer of the anti-wear abrasive capacity of thermally conductive coil pipe in mineral fine powder steam dryer

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04158866A (en) * 1990-10-23 1992-06-01 Masaru Ogiwara Heat treating machine for sterilization of industrial waste
CN2517488Y (en) * 2001-06-25 2002-10-23 姚雷雨 Hard surface durable element made of Ti carbide
CN201603585U (en) * 2010-01-08 2010-10-13 三河市科大博德粉末有限公司 Ball mill lining plate with wear resistance coating layer
CN105063539A (en) * 2015-07-20 2015-11-18 安徽工程大学 Method for preparing wear-resistant coating of ball mill lining plate
CN105289805A (en) * 2015-10-30 2016-02-03 姜殿付 Ball grinding mill

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04158866A (en) * 1990-10-23 1992-06-01 Masaru Ogiwara Heat treating machine for sterilization of industrial waste
CN2517488Y (en) * 2001-06-25 2002-10-23 姚雷雨 Hard surface durable element made of Ti carbide
CN201603585U (en) * 2010-01-08 2010-10-13 三河市科大博德粉末有限公司 Ball mill lining plate with wear resistance coating layer
CN105063539A (en) * 2015-07-20 2015-11-18 安徽工程大学 Method for preparing wear-resistant coating of ball mill lining plate
CN105289805A (en) * 2015-10-30 2016-02-03 姜殿付 Ball grinding mill

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109127101A (en) * 2018-08-09 2019-01-04 北京天山新材料技术有限公司 The means of defence and coal pulverizer of coal pulverizer
CN109808214A (en) * 2019-02-18 2019-05-28 北京固本科技有限公司 A kind of wear-resisting squeezing item
CN110404638A (en) * 2019-08-29 2019-11-05 盐城工学院 A kind of ball mill lining plate structure suitable for ultra-fine ball milling
CN110404638B (en) * 2019-08-29 2021-04-20 盐城工学院 Ball mill lining plate structure suitable for superfine ball milling
CN110512164A (en) * 2019-09-06 2019-11-29 武汉苏伯曼科技有限公司 Improve the method and mineral fine powder steam dryer of the anti-wear abrasive capacity of thermally conductive coil pipe in mineral fine powder steam dryer

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