CN105735043B - A kind of coating composition for improving art paper high speed printing performance - Google Patents
A kind of coating composition for improving art paper high speed printing performance Download PDFInfo
- Publication number
- CN105735043B CN105735043B CN201610189593.XA CN201610189593A CN105735043B CN 105735043 B CN105735043 B CN 105735043B CN 201610189593 A CN201610189593 A CN 201610189593A CN 105735043 B CN105735043 B CN 105735043B
- Authority
- CN
- China
- Prior art keywords
- coating composition
- art paper
- nano
- high speed
- calcium carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/52—Cellulose; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/54—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
Abstract
The invention provides a kind of coating composition for improving art paper high speed printing performance, including 0.2 0.8 parts of 15 30 parts of nano-calcium carbonate microcapsules, 1 0.5 parts of microcrystalline cellulose, 20 40 parts of starch, 10 20 parts of styrene-butadiene latex, 40 60 parts of titanium dioxide, 20 30 parts of kaolin, 0.5 1.5 parts of dispersant and defoamer, the coating composition makes art paper have more preferable ink absorption, higher surface printing intensity.
Description
Technical field
The present invention relates to papermaking chemical product field, more particularly to a kind of Coating material composition for improving art paper high speed printing performance
Thing.
Background technology
Generally, gone forward side by side by applying the coating solution being mainly made up of pigment and adhesive at least one side of raw material paper
Row drying and prepare coated paper for printing.In recent years, in progress, it prints for high-quality for the visualization of printing item and colorization
Ink absorption, glossiness, smoothness and the whiteness of the increase in demand of brush art paper, particularly coated paper for printing will determine
The quality of printed matter.
In print production, the art paper of offset press is because ink absorption poor performance, ink dried speed are slow, in high print duplication
Brush machine using when the printing defects such as bleeding, mottled occur.It is weaker that the adhesive force of image is printed simultaneously, in follow-up receipts
Substantial amounts of scratch can be produced in the operating process such as volume, cutting, packaging, it is impossible to produce the printed matter of high quality.Therefore art paper
Surface ink absorbent properties are the problem of needing concern.
In the prior art, CN103757989A is by adding polymer microballoon, inorganic powdered filler, paint ink fixative
With adhesive as art paper ink-absorbed coated layer, there is preferable Scratch Resistance energy, but it is mainly for inkjet printing, the scope of application
It is narrow.
The content of the invention
The problem of present invention is overcomes art paper ink absorption in the prior art and printing intensity, there is provided one kind improves copper
The coating composition of millboard high speed printing performance, the coating composition assigns the preferable ink absorption of art paper and ink is strong
Degree, and make it be more suitable for high speed rotary printing.
1st, a kind of coating composition for improving art paper high speed printing performance, the raw material of following parts by weight is included：
Described nano-calcium carbonate microcapsules are using nano-calcium carbonate as capsule-core, and hydroxyethyl cellulose is prepared for cyst wall
Microcapsules；
The preparation technology of the coating composition is：
1) nano-calcium carbonate particles are dispersed in the ethanol solution of hydroxyethyl cellulose, form stable suspension, so
After be spray-dried, formed nano-calcium carbonate microcapsules；
2) 40-60 parts titanium dioxide and 20-30 parts kaolin are added in dispersion slot, and adds 15-30 part nano-calcium carbonates
Calcium microcapsules, 0.2-0.8 part defoamers, start to stir, while add appropriate water, and regulation pH value is 7-9, then add scattered
5-9min is stirred in agent；
3) add 20-40 parts starch in dispersion slot and 10-20 part styrene-butadiene latexes continue to stir；
4) 1-0.5 part microcrystalline celluloses are added in the dispersion slot in step 3), and add appropriate water adjustment coating
The mass fraction of Solid content is 50-70%, obtains the coating composition.
Described nano-calcium carbonate Microcapsules Size is 1-3 microns, and one layer is coated with the hydroxyethyl cellulose surface
The degree of polymerization of thickness 1-5 nanometers is 3000~10000 glucose molecule film layers.
The core of the nano-calcium carbonate microcapsules and the mass ratio of wall material are (75-85): (15-25).
The titanium dioxide is rutile titanium dioxide, and particle diameter is 0.5-2 microns, and Zeta potential is -20.3mV.
The kaolin, dioxide-containing silica 48%, particle diameter are 0.5-2 microns.
The dispersant is Sodium Polyacrylate, the number-average molecular weight 3500-4000 of the Sodium Polyacrylate, and viscosity is
2250-2300mPa.s。
The mass fraction of the Solid content of the coating composition is 50%-70%.
Compared with prior art, the beneficial effects of the invention are as follows：
1. the addition of nano-calcium carbonate is all greatly improved to ink absorption and art paper surface printing intensity, overcome
The defects of prior art printing performance is relatively low.
2. nano-calcium carbonate is as cloth filler is applied, because it is Nano grade, inequality is disperseed in coating fluid preparation process
It is even to cause to reunite, microcapsule structure is made, it is not only scattered beneficial to it, moreover it is possible to its effectively retention to be improved, by scraping
The effect of painting, cyst wall can be ruptured, discharge nano-calcium carbonate, played and improve paper printing ink absorbability and surface printing intensity
Effect.
3. adding microcrystalline cellulose in coating, interacted with paper fibre, increase paper strength, and fill up paper table
Face space so that the paper surface after coating is smooth, and roughness declines.The tensile strength of paper after microcrystalline cellulose is coated with
Uncoated paper is better than with pop strength.
On the hydroxyethyl cellulose surface, the degree of polymerization coated with a layer thickness 1-5 nanometers is 3000~10000 Portugals
Grape glycan molecule film layer, Hydrogenbond is formed with microcrystalline cellulose, improves the stability of coating composition.
Embodiment
Illustrate the present invention with reference to specific embodiment.
Embodiment 1
A kind of coating composition for improving art paper high speed printing performance, include the raw material of following parts by weight：
The capsule-core of nano-calcium carbonate microcapsules is nano-calcium carbonate, and cyst wall is hydroxy ethyl fiber, and particle diameter is 1-3 microns, is received
The core of rice calcium carbonate microcapsules and the mass ratio of wall material are 75: 25, and a layer thickness is coated with hydroxyethyl cellulose surface
The 3nm degree of polymerization is 4000 glucose molecule film layers.
The preparation technology of the coating composition is：
1) 25g hydroxyethyl celluloses are taken, one layer of glucose molecule film is coated on its surface by solwution method, controls coating
Thickness 3nm, the ethanol solution of mass fraction 25% is then configured to, adds 75g nano-calcium carbonate particles, form stable suspension
Liquid, then it is spray-dried, forms nano-calcium carbonate microcapsules；
2) 50g titanium dioxide and 30g kaolin are added in dispersion slot, and adds 20g nano-calcium carbonate microcapsules, 0.3g
Polysiloxane defoaming agent, start to stir, while add appropriate water, regulation pH value is 7-9, then adds dispersant stirring
6min；
3) 20g tapiocas are added in dispersion slot and 15g styrene-butadiene latexes continues to stir；
4) 0.5g microcrystalline celluloses are added in the dispersion slot in step 3), and adds appropriate water consolidating for coating of adjustment and contains
Measure as 65%, obtain the coating composition.
Gained coating composition is used for the coating process stage of the art paper body paper after press polish really up to the mark and drying process,
Dry again, supercalendering, obtain art paper body paper.
Embodiment 2
A kind of coating composition for improving art paper high speed printing performance, include the raw material of following parts by weight：
The capsule-core of nano-calcium carbonate microcapsules is nano-calcium carbonate, and cyst wall is hydroxy ethyl fiber, and particle diameter is 1-3 microns, is received
The core of rice calcium carbonate microcapsules and the mass ratio of wall material are 75: 25, and a layer thickness is coated with hydroxyethyl cellulose surface
The 3nm degree of polymerization is 4000 glucose molecule film layers.
The preparation technology of the coating composition is：
1) 25g hydroxyethyl celluloses are taken, one layer of glucose molecule film is coated on its surface by solwution method, controls coating
Thickness 3nm, the ethanol solution of mass fraction 25% is then configured to, adds 75g nano-calcium carbonate particles, form stable suspension
Liquid, then it is spray-dried, forms nano-calcium carbonate microcapsules；
2) 45g titanium dioxide and 25g kaolin are added in dispersion slot, and adds 15g nano-calcium carbonate microcapsules, 0.5g
Polysiloxane defoaming agent, start to stir, while add appropriate water, regulation pH value is 7-9, then adds dispersant stirring
6min；
3) add 30g maize oxidized starch in dispersion slot and 20g styrene-butadiene latexes continue to stir；
4) 0.8g microcrystalline celluloses are added in the dispersion slot in step 3), and adds appropriate water consolidating for coating of adjustment and contains
Measure as 60%, obtain the coating composition.
Gained coating composition is used for the coating process stage of the art paper body paper after press polish really up to the mark and drying process,
Dry again, supercalendering, obtain art paper body paper.
Comparative example 1
A kind of coating composition for improving art paper high speed printing performance, include the raw material of following parts by weight：
The preparation technology of the coating composition is：
1) 50g titanium dioxide and 30g kaolin are added in dispersion slot, and adds 0.3g polysiloxane defoaming agents, started
Stirring, while appropriate water is added, regulation pH value is 7-9, then adds dispersant stirring 6min；
2) 20g tapiocas are added in dispersion slot and 15g styrene-butadiene latexes continues to stir；
3) 0.5g microcrystalline celluloses are added in the dispersion slot in step 3), and adds appropriate water consolidating for coating of adjustment and contains
Measure as 65%, obtain the coating composition.
Gained coating composition is used for the coating process stage of the art paper body paper after press polish really up to the mark and drying process,
Dry again, supercalendering, obtain art paper body paper.
Comparative example 2
A kind of coating composition for improving art paper high speed printing performance, include the raw material of following parts by weight：
The capsule-core of nano-calcium carbonate microcapsules is nano-calcium carbonate, and cyst wall is hydroxy ethyl fiber, and particle diameter is 1-3 microns, is received
The core of rice calcium carbonate microcapsules and the mass ratio of wall material are 75: 25, and a layer thickness is coated with hydroxyethyl cellulose surface
The 3nm degree of polymerization is 4000 glucose molecule film layers.
The preparation technology of the coating composition is：
1) 25g hydroxyethyl celluloses are taken, one layer of glucose molecule film is coated on its surface by solwution method, controls coating
Thickness 3nm, the ethanol solution of mass fraction 25% is then configured to, adds 75g nano-calcium carbonate particles, form stable suspension
Liquid, then it is spray-dried, forms nano-calcium carbonate microcapsules；
2) 45g titanium dioxide and 25g kaolin are added in dispersion slot, and adds 15g nano-calcium carbonate microcapsules, 0.5g
Polysiloxane defoaming agent, start to stir, while add appropriate water, regulation pH value is 7-9, then adds dispersant stirring
6min；
3) add 30g maize oxidized starch in dispersion slot and 20g styrene-butadiene latexes continue to stir；
4) solid content for adding appropriate water adjustment coating is 60%, obtains the coating composition.
Gained coating composition is used for the coating process stage of the art paper body paper after press polish really up to the mark and drying process,
Dry again, supercalendering, obtain art paper body paper.
Table one
By above-mentioned experiment, copper coated can be made by adding the coating composition of nano-calcium carbonate microcapsules and microcrystalline cellulose
Millboard has more excellent ink absorption.
Claims (6)
- A kind of 1. coating composition for improving art paper high speed printing performance, it is characterised in thatInclude the raw material of following parts by weight：Described nano-calcium carbonate microcapsules are using nano-calcium carbonate as capsule-core, and hydroxyethyl cellulose is prepared micro- for cyst wall Capsule；The preparation technology of the coating composition of described raising art paper high speed printing performance is：1) nano-calcium carbonate particles are dispersed in the ethanol solution of hydroxyethyl cellulose, form stable suspension, Ran Houjin Row spray drying, forms nano-calcium carbonate microcapsules；2) 40-60 parts titanium dioxide and 20-30 parts kaolin are added in dispersion slot, and it is micro- to add 15-30 part nano-calcium carbonates Capsule, 0.2-0.8 part defoamers, starts to stir, while adds appropriate water, and regulation pH value is 7-9, then adds dispersant and stirs Mix 5-9min；3) add 20-40 parts starch in dispersion slot and 10-20 part styrene-butadiene latexes continue to stir；4) 1-0.5 part microcrystalline celluloses are added in the dispersion slot in step 3), and adds appropriate water consolidating for coating of adjustment and contains The mass fraction of thing is 50-70%, obtains the coating composition.
- 2. the coating composition according to claim 1 for improving art paper high speed printing performance, it is characterised in that：Described Nano-calcium carbonate Microcapsules Size is 1-3 microns, poly- coated with a layer thickness 1-5 nanometers on the hydroxyethyl cellulose surface Right is 3000~10000 glucose molecule film layers.
- 3. the coating composition according to claim 1 for improving art paper high speed printing performance, it is characterised in that described The core of nano-calcium carbonate microcapsules and the mass ratio of wall material are (75-85): (15-25).
- 4. the coating composition according to claim 1 for improving art paper high speed printing performance, it is characterised in that：Described two Titanium oxide is rutile titanium dioxide, and particle diameter is 0.5-2 microns, and Zeta potential is -20.3mV.
- 5. the coating composition according to claim 1 for improving art paper high speed printing performance, it is characterised in that：The height Ridge soil, dioxide-containing silica 48%, particle diameter is 0.5-2 microns.
- 6. the coating composition according to claim 1 for improving art paper high speed printing performance, it is characterised in that：Described point Powder is Sodium Polyacrylate, the number-average molecular weight 3500-4000 of the Sodium Polyacrylate, and viscosity is 2250-2300mPa s.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610189593.XA CN105735043B (en) | 2016-03-30 | 2016-03-30 | A kind of coating composition for improving art paper high speed printing performance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610189593.XA CN105735043B (en) | 2016-03-30 | 2016-03-30 | A kind of coating composition for improving art paper high speed printing performance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105735043A CN105735043A (en) | 2016-07-06 |
| CN105735043B true CN105735043B (en) | 2018-01-02 |
Family
ID=56252273
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610189593.XA Active CN105735043B (en) | 2016-03-30 | 2016-03-30 | A kind of coating composition for improving art paper high speed printing performance |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105735043B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106497225B (en) * | 2016-11-25 | 2019-05-17 | 河南工程学院 | A kind of high adhesion force printing ink adhesive and preparation method thereof |
| CN110886131A (en) * | 2018-09-11 | 2020-03-17 | 友元办公联盟(天津)股份有限公司 | Durable antibacterial white cardboard and preparation method thereof |
| CN110886136A (en) * | 2018-09-11 | 2020-03-17 | 友元办公联盟(天津)股份有限公司 | Coated paper and processing method thereof |
| CN110886132A (en) * | 2018-09-11 | 2020-03-17 | 友元办公联盟(天津)股份有限公司 | Mildew-proof antibacterial white cardboard and processing technology thereof |
| CN110886135A (en) * | 2018-09-11 | 2020-03-17 | 友元办公联盟(天津)股份有限公司 | Processing method of high-glossiness mothproof coated paper |
| CN110714360A (en) * | 2019-10-24 | 2020-01-21 | 齐鲁工业大学 | Coating for white drawings and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102092209A (en) * | 2010-10-29 | 2011-06-15 | 哈尔滨工业大学 | Ink-jet recording material and preparation method thereof as well as method for preparing ink absorption layer coating liquid |
| CN104594121A (en) * | 2015-01-07 | 2015-05-06 | 浙江理工大学 | Coated paper coating containing nano particle modified adhesive and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05321195A (en) * | 1992-05-11 | 1993-12-07 | Asahi Chem Ind Co Ltd | Composition for coating paper |
| WO2005103377A1 (en) * | 2004-04-27 | 2005-11-03 | Vertech Specialty Chemicals Pte. Ltd. | Coating-paper composition and method for the preparation thereof |
| US20100163195A1 (en) * | 2008-12-30 | 2010-07-01 | North Pacific Paper Corporation (Norpac) | High-Yield Paper and Methods of Making Same |
-
2016
- 2016-03-30 CN CN201610189593.XA patent/CN105735043B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102092209A (en) * | 2010-10-29 | 2011-06-15 | 哈尔滨工业大学 | Ink-jet recording material and preparation method thereof as well as method for preparing ink absorption layer coating liquid |
| CN104594121A (en) * | 2015-01-07 | 2015-05-06 | 浙江理工大学 | Coated paper coating containing nano particle modified adhesive and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105735043A (en) | 2016-07-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105735043B (en) | A kind of coating composition for improving art paper high speed printing performance | |
| CN105274897B (en) | A kind of preparation method of ink-jet measurements of Digital Printing Papers coating | |
| CN102470682B (en) | Print media for high speed, digital inkjet printing and manufacture method thereof | |
| EP2459663B1 (en) | Coating compositions | |
| JP2011073368A (en) | Cast coated paper for ink jet recording | |
| EP2493696B2 (en) | Coated medium for inkjet printing | |
| JP2011148194A (en) | Ink jet recording paper | |
| CN105862502B (en) | A kind of decorating base paper preparation method | |
| JP2010100039A (en) | Inkjet recording paper | |
| CN102782216B (en) | Coated printing paper and process for producing same | |
| JP2007254914A (en) | Coated white board paper | |
| JP4738023B2 (en) | Low density paper for offset printing | |
| AU2008219820B2 (en) | Pigment composition | |
| EP2024563B1 (en) | Composition for improving the printability of coated paper | |
| JP5535419B2 (en) | Pigment complex and method for producing the same | |
| US20070227402A1 (en) | Coating-Paper Composition and Method for the Preparation Thereof | |
| CN105839458B (en) | A kind of thin page printing paper coating composition | |
| JP2010076118A (en) | Recording paper for inkjet | |
| US20210348337A1 (en) | Print-medium paper and method | |
| JPH0229515B2 (en) | ||
| JP2011246838A (en) | Coated paper for printing | |
| JP3328922B2 (en) | Coated paper for offset printing and method for producing the same | |
| Wild et al. | A novel coating formulation for silica inkjet layer coatings | |
| JP2005096437A (en) | Method of manufacturing ink jet recording medium | |
| CN116289292A (en) | Soft color artistic paper and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Liu Renquan Inventor before: Yuan Bin Inventor before: Lv Yun Inventor before: Yin Hongxia |
|
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20171127 Address after: 510000, No. eleven, building A, No. 2, new industrial zone, Xia Mao, Guangzhou street, Shijing street, Baiyun District, Guangdong, China Applicant after: Guangzhou Fuchen Packaging Product Co., Ltd. Address before: 315000 Zhejiang province Ningbo City Jiangdong District Qixin Road No. 167 on the third. Applicant before: NINGBO ACWIT INTELLIGENT TECHNOLOGY CO., LTD. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP02 | Change in the address of a patent holder | ||
| CP02 | Change in the address of a patent holder |
Address after: 510000 self compiled buildings B1 and B2, No. 17, Xiamao songyuanheng Road, Baiyun Lake Street, Baiyun District, Guangzhou, Guangdong Patentee after: GUANGZHOU FUCHEN PACKAGE PRODUCT Co.,Ltd. Address before: 510000 first floor, building a, No. 2 self compiled new industrial zone, Xiamao 11th community, Shijing street, Baiyun District, Guangzhou, Guangdong Patentee before: GUANGZHOU FUCHEN PACKAGE PRODUCT Co.,Ltd. |