CN105735007A - Textile printing thickening agent and production process thereof - Google Patents
Textile printing thickening agent and production process thereof Download PDFInfo
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- CN105735007A CN105735007A CN201610285201.XA CN201610285201A CN105735007A CN 105735007 A CN105735007 A CN 105735007A CN 201610285201 A CN201610285201 A CN 201610285201A CN 105735007 A CN105735007 A CN 105735007A
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5292—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Polymerisation Methods In General (AREA)
Abstract
The invention discloses a textile printing thickening agent. The textile printing thickening agent is prepared by processing the following raw materials in parts by weight: 150-220 parts of acrylic acid, 20-60 parts of methacrylic acid, 50-80 parts of acrylamide, 1-10 parts of octadecyl acrylate, 0.01-0.5 part of N,N'-methylene-bisacrylamide, 120-250 parts of white oil or aviation kerosene, 15-50 parts of sorbitan monooleate, 0.2-2 parts of an initiator, 0.01-1 part of sodium hydrogensulfite, 10-50 parts of fatty alcohol polyoxyethylene ether, 5-50 parts of hydrophilic silicon oil and 200-500 parts of a sodium hydroxide solution. The thickening agent has good water holding performance, strong electrolyte resistance capability and high color yield. A production process comprises the following steps of: (1) neutralizing the acrylic acid and the methacrylic acid until the pH value is 5.2-6.5; (2) adding the acrylamide, the N,N'-methylene-bisacrylamide and the initiator to prepare a water phase; (3) mixing the white oil or the aviation kerosene, the sorbitan monooleate and the octadecyl acrylate to form an oil phase; and (4) adding the water phase into the oil phase and emulsifying, and adding sodium hydrogensulfite to carry out a polymerization reaction; and (5) adding the fatty alcohol polyoxyethylene ether and the hydrophilic silicon oil and mixing.
Description
Technical field
The present invention relates to a kind of printing in textiles thickening agent and production technology thereof.
Background technology
Tradition thickening agent needs to consume the substantial amounts of energy in process of production, produces APEO simultaneously, and environment is produced bad shadow
Ring, and product not electrolyte-resistant, usage amount is relatively big, and use cost is higher, and the textile color and luster of printing is partially dark and feel is poor.And
The deficiencies such as the natural polymer thickeners such as Na-alginate exist slurrying cycle length, prepared slurry easily goes mouldy.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of armful of textile that aqueous is good, electrolyte-resistant ability is strong, color yield is high
Printing thickening agent.
The printing in textiles thickening agent that the present invention provides, by including that following Raw material processing by weight is prepared from:
Acrylic acid 150-220 part
Methacrylic acid 20-60 part
Acrylamide 50-80 part
Octadecyl acrylate 1-10 part
N-N ' methylene-bisacrylamide 0.01-0.5 part
White oil or boat coal 120-250 part
Sorbitan mono-oleic acid ester 15-50 part
Initiator 0.2-2 part
Sodium sulfite 0.01-1 part
Fatty alcohol-polyoxyethylene ether 10-50 part
Hydrophilic silicon oil 5-50 part
Sodium hydroxide solution 200-500 part.
Further improve as the present invention, by including that following Raw material processing by weight is prepared from:
Acrylic acid 180-210 part
Methacrylic acid 30-50 part
Acrylamide 55-70 part
Octadecyl acrylate 5-7 part
N-N ' methylene-bisacrylamide 0.1-0.4 part
White oil or boat coal 180-200 part
Sorbitan mono-oleic acid ester 20-40 part
Initiator 0.1-1.8 part
Sodium sulfite 0.5-0.8 part
Fatty alcohol-polyoxyethylene ether 30-40 part
Hydrophilic silicon oil 30-40 part
Sodium hydroxide solution 300-400 part.
Further improve as the present invention, by including that following Raw material processing by weight is prepared from:
200 parts of acrylic acid
Methacrylic acid 40 parts
Acrylamide 60 parts
Octadecyl acrylate 5 parts
N-N ' methylene-bisacrylamide 0.3 part
White oil or 200 parts of coal of boat
Sorbitan mono-oleic acid ester 30 parts
Initiator 1.4 parts
Sodium sulfite 0.4 part
Fatty alcohol-polyoxyethylene ether 30 parts
Hydrophilic silicon oil 20 parts
Sodium hydroxide solution 350 parts.
Further improve as the present invention: the quality of sodium hydroxide and the gross mass of solution in described sodium hydroxide solution
Ratio is 28-35%.
Further improve as the present invention: your quality of sodium hydroxide and total matter of solution in described sodium hydroxide solution
Amount ratio is 32%.
Further improve as the present invention: described initiator is in potassium peroxydisulfate, sodium peroxydisulfate and Ammonium persulfate.
The mixture of one or more.
The present invention also provides for the production technology that a kind of technique is simple and environmentally-friendly, save the printing in textiles thickening agent of the energy, bag
Include following steps:
1), above-mentioned acrylic acid by weight and methacrylic acid sodium hydroxide solution are neutralized to pH value 5.2-6.5；
2) in the product that step 1) obtains, it is sequentially added into above-mentioned acrylamide by weight, N-N ' methylene bisacrylamide acyl
Amine and initiator are hybridly prepared into aqueous phase；
3) in reactor, add above-mentioned white oil by weight or boat coal, sorbitan mono-oleic acid ester, octadecyl acrylate
It is allowed to be mixed into oil phase；
4), by aqueous phase add emulsifying 5-20 minute in oil phase, add above-mentioned sodium sulfite by weight, start polymerization anti-
Should, it is warming up to 70-110 DEG C, is incubated 0.5-1.5 hour, is then cooled to 30-60 DEG C；
5), above-mentioned fatty alcohol-polyoxyethylene ether by weight, hydrophilic silicon oil are added react in the complete material lowered the temperature
It is sufficiently mixed, must disperse and reactive printing universal thickening agent.
Further improve as the present invention: in described step 1), pH value is 5.8-6.0.
Further improve as the present invention: in described step 4), emulsifying 10 minutes；It is warming up to 90 DEG C, is incubated 1 hour,
Then 40 DEG C it are cooled to.
Compared with prior art, the present invention provides printing in textiles thickening agent and production technology thereof have following Patent Law
The beneficial effect of meaning:
1, owing to the present invention is by optimized production process, the acrylic copolymer structure viscosity making formation is strong, has good simultaneously
Dispersibility and surface activity so that the thickening agent prepared embraces that aqueous is good, electrolyte-resistant ability is strong, color yield is high.
2, owing to production technology of the present invention is without heating, the consumed energy is less, will not produce APEO simultaneously, has technique letter
List, environmental protection, the feature of energy conservation.
Detailed description of the invention
A kind of printing in textiles thickening agent present invention provided below by way of specific embodiment and production technology thereof do into
One step more detailed description；
Embodiment 1
Printing in textiles thickening agent, by following Raw material processing by weight is prepared from:
150 parts of acrylic acid
Methacrylic acid 20 parts
Acrylamide 50 parts
Octadecyl acrylate 1 part
N-N ' methylene-bisacrylamide 0.01 part
White oil or 120 parts of coal of boat
Sorbitan mono-oleic acid ester 15 parts
Initiator 0.2 part
Sodium sulfite 0.01 part
Fatty alcohol-polyoxyethylene ether 10 parts
Hydrophilic silicon oil 5 parts
Sodium hydroxide solution 200 parts.
In sodium hydroxide solution, the quality of sodium hydroxide is 28% with the total mass ratio of solution.Initiator is potassium peroxydisulfate.
The production technology of printing in textiles thickening agent, comprises the following steps:
1), above-mentioned acrylic acid by weight and methacrylic acid sodium hydroxide solution are neutralized to pH value 5.2；
2) in the product that step 1) obtains, it is sequentially added into above-mentioned acrylamide by weight, N-N ' methylene bisacrylamide acyl
Amine and initiator are hybridly prepared into aqueous phase；
3) in reactor, add above-mentioned white oil by weight or boat coal, sorbitan mono-oleic acid ester, octadecyl acrylate
It is allowed to be mixed into oil phase；
4), by aqueous phase add emulsifying 5 minutes in oil phase, add above-mentioned sodium sulfite by weight, start polyreaction,
It is warming up to 70 DEG C, is incubated 0.5 hour, is then cooled to 30 DEG C；
5), above-mentioned fatty alcohol-polyoxyethylene ether by weight, hydrophilic silicon oil are added react in the complete material lowered the temperature
It is sufficiently mixed, must disperse and reactive printing universal thickening agent.
Embodiment 2
Printing in textiles thickening agent, by following Raw material processing by weight is prepared from:
220 parts of acrylic acid
Methacrylic acid 60 parts
Acrylamide 80 parts
Octadecyl acrylate 10 parts
N-N ' methylene-bisacrylamide 0.5 part
White oil or 250 parts of coal of boat
Sorbitan mono-oleic acid ester 50 parts
Initiator 2 parts
Sodium sulfite 1 part
Fatty alcohol-polyoxyethylene ether 50 parts
Hydrophilic silicon oil 50 parts
Sodium hydroxide solution 500 parts.
In sodium hydroxide solution, the quality of sodium hydroxide is 35% with the total mass ratio of solution.Initiator is sodium peroxydisulfate.
The production technology of printing in textiles thickening agent, comprises the following steps:
1), above-mentioned acrylic acid by weight and methacrylic acid sodium hydroxide solution are neutralized to pH value 6.5；
2) in the product that step 1) obtains, it is sequentially added into above-mentioned acrylamide by weight, N-N ' methylene bisacrylamide acyl
Amine and initiator are hybridly prepared into aqueous phase；
3) in reactor, add above-mentioned white oil by weight or boat coal, sorbitan mono-oleic acid ester, octadecyl acrylate
It is allowed to be mixed into oil phase；
4), by aqueous phase add emulsifying 20 minutes in oil phase, add above-mentioned sodium sulfite by weight, start polymerization anti-
Should, it is warming up to 110 DEG C, is incubated 1.5 hours, is then cooled to 60 DEG C；
5), above-mentioned fatty alcohol-polyoxyethylene ether by weight, hydrophilic silicon oil are added react in the complete material lowered the temperature
It is sufficiently mixed, must disperse and reactive printing universal thickening agent.
Embodiment 3
Printing in textiles thickening agent, by following Raw material processing by weight is prepared from:
180 parts of acrylic acid
Methacrylic acid 40 parts
Acrylamide 60 parts
Octadecyl acrylate 5 parts
N-N ' methylene-bisacrylamide 0.2 part
White oil or 150 parts of coal of boat
Sorbitan mono-oleic acid ester 30 parts
Initiator 1 part
Sodium sulfite 0.5 part
Fatty alcohol-polyoxyethylene ether 30 parts
Hydrophilic silicon oil 30 parts
Sodium hydroxide solution 300 parts.
In sodium hydroxide solution, the quality of sodium hydroxide is 30% with the total mass ratio of solution.Initiator is selected from persulfuric acid
Potassium and the mixture of sodium peroxydisulfate.
The production technology of printing in textiles thickening agent, comprises the following steps:
1), above-mentioned acrylic acid by weight and methacrylic acid sodium hydroxide solution are neutralized to pH value 5.7；
2) in the product that step 1) obtains, it is sequentially added into above-mentioned acrylamide by weight, N-N ' methylene bisacrylamide acyl
Amine and initiator are hybridly prepared into aqueous phase；
3) in reactor, add above-mentioned white oil by weight or boat coal, sorbitan mono-oleic acid ester, octadecyl acrylate
It is allowed to be mixed into oil phase；
4), by aqueous phase add emulsifying 10 minutes in oil phase, add above-mentioned sodium sulfite by weight, start polymerization anti-
Should, it is warming up to 80 DEG C, is incubated 1 hour, is then cooled to 40 DEG C；
5), above-mentioned fatty alcohol-polyoxyethylene ether by weight, hydrophilic silicon oil are added react in the complete material lowered the temperature
It is sufficiently mixed, must disperse and reactive printing universal thickening agent.
Embodiment 4
Printing in textiles thickening agent, by following Raw material processing by weight is prepared from:
180 parts of acrylic acid
Methacrylic acid 30 parts
Acrylamide 55 parts
Octadecyl acrylate 5 parts
N-N ' methylene-bisacrylamide 0.1 part
White oil or 180 parts of coal of boat
Sorbitan mono-oleic acid ester 20 parts
Initiator 0.1 part
Sodium sulfite 0.5 part
Fatty alcohol-polyoxyethylene ether 30 parts
Hydrophilic silicon oil 30 parts
Sodium hydroxide solution 300 parts.
In sodium hydroxide solution, the quality of sodium hydroxide is 28% with the total mass ratio of solution.Initiator is selected from persulfuric acid
Potassium, sodium peroxydisulfate, the mixture of Ammonium persulfate..
The production technology of printing in textiles thickening agent, comprises the following steps:
1), above-mentioned acrylic acid by weight and methacrylic acid sodium hydroxide solution are neutralized to pH value 5.2-6.5；
2) in the product that step 1) obtains, it is sequentially added into above-mentioned acrylamide by weight, N-N ' methylene bisacrylamide acyl
Amine and initiator are hybridly prepared into aqueous phase；
3) in reactor, add above-mentioned white oil by weight or boat coal, sorbitan mono-oleic acid ester, octadecyl acrylate
It is allowed to be mixed into oil phase；
4), by aqueous phase add emulsifying 8 minutes in oil phase, add above-mentioned sodium sulfite by weight, start polymerization anti-
Should, it is warming up to 80 DEG C, is incubated 1 hour, is then cooled to 50 DEG C；
5), above-mentioned fatty alcohol-polyoxyethylene ether by weight, hydrophilic silicon oil are added react in the complete material lowered the temperature
It is sufficiently mixed, must disperse and reactive printing universal thickening agent.
Embodiment 5
Printing in textiles thickening agent, by following Raw material processing by weight is prepared from:
210 parts of acrylic acid
Methacrylic acid 50 parts
Acrylamide 70 parts
Octadecyl acrylate 7 parts
N-N ' methylene-bisacrylamide 0.4 part
White oil or 200 parts of coal of boat
Sorbitan mono-oleic acid ester 40 parts
Initiator 1.8 parts
Sodium sulfite 0.8 part
Fatty alcohol-polyoxyethylene ether 40 parts
Hydrophilic silicon oil 40 parts
Sodium hydroxide solution 400 parts.
In sodium hydroxide solution, the quality of sodium hydroxide is 31% with the total mass ratio of solution.Initiator was for being selected from over cure
Acid sodium and the mixture of Ammonium persulfate..
The production technology of printing in textiles thickening agent, comprises the following steps:
1), above-mentioned acrylic acid by weight and methacrylic acid sodium hydroxide solution are neutralized to pH value 5.5；
2) in the product that step 1) obtains, it is sequentially added into above-mentioned acrylamide by weight, N-N ' methylene bisacrylamide acyl
Amine and initiator are hybridly prepared into aqueous phase；
3) in reactor, add above-mentioned white oil by weight or boat coal, sorbitan mono-oleic acid ester, octadecyl acrylate
It is allowed to be mixed into oil phase；
4), by aqueous phase add emulsifying 8 minutes in oil phase, add above-mentioned sodium sulfite by weight, start polymerization anti-
Should, it is warming up to 80 DEG C, is incubated 1.2 hours, is then cooled to 45 DEG C；
5), above-mentioned fatty alcohol-polyoxyethylene ether by weight, hydrophilic silicon oil are added react in the complete material lowered the temperature
It is sufficiently mixed, must disperse and reactive printing universal thickening agent.
Embodiment 6
Printing in textiles thickening agent, by following Raw material processing by weight is prepared from:
190 parts of acrylic acid
Methacrylic acid 40 parts
Acrylamide 60 parts
Octadecyl acrylate 6 parts
N-N ' methylene-bisacrylamide 0.3 part
White oil or 190 parts of coal of boat
Sorbitan mono-oleic acid ester 30 parts
Initiator 1 part
Sodium sulfite 0.58 part
Fatty alcohol-polyoxyethylene ether 35 parts
Hydrophilic silicon oil 302 parts
Sodium hydroxide solution 380 parts.
In sodium hydroxide solution, your quality of sodium hydroxide is 29% with the total mass ratio of solution.Initiator is selected from over cure
Acid potassium, sodium peroxydisulfate and the mixture of Ammonium persulfate..
The production technology of printing in textiles thickening agent, comprises the following steps:
1), above-mentioned acrylic acid by weight and methacrylic acid sodium hydroxide solution are neutralized to pH value 6.0；
2) in the product that step 1) obtains, it is sequentially added into above-mentioned acrylamide by weight, N-N ' methylene bisacrylamide acyl
Amine and initiator are hybridly prepared into aqueous phase；
3) in reactor, add above-mentioned white oil by weight or boat coal, sorbitan mono-oleic acid ester, octadecyl acrylate
It is allowed to be mixed into oil phase；
4), by aqueous phase add emulsifying 7 minutes in oil phase, add above-mentioned sodium sulfite by weight, start polymerization anti-
Should, it is warming up to 90 DEG C, is incubated 1 hour, is then cooled to 50 DEG C；
5), above-mentioned fatty alcohol-polyoxyethylene ether by weight, hydrophilic silicon oil are added react in the complete material lowered the temperature
It is sufficiently mixed, must disperse and reactive printing universal thickening agent.
Embodiment 7
Printing in textiles thickening agent, by following Raw material processing by weight is prepared from:
Acrylic acid 200
Methacrylic acid 40
Acrylamide 60
Octadecyl acrylate 5
N-N ' methylene-bisacrylamide 0.3
White oil or boat coal 200
Sorbitan mono-oleic acid ester 30
Initiator 1.4
Sodium sulfite 0.4
Fatty alcohol-polyoxyethylene ether 30
Hydrophilic silicon oil 20
Sodium hydroxide solution 350.
In sodium hydroxide solution, your quality of sodium hydroxide is 32% with the total mass ratio of solution.
Initiator is the mixture of one or more in potassium peroxydisulfate, sodium peroxydisulfate, Ammonium persulfate..
The production technology of printing in textiles thickening agent, comprises the following steps:
1), above-mentioned acrylic acid by weight and methacrylic acid sodium hydroxide solution are neutralized to pH value 5.8；
2) in the product that step 1) obtains, it is sequentially added into above-mentioned acrylamide by weight, N-N ' methylene bisacrylamide acyl
Amine and initiator are hybridly prepared into aqueous phase；
3) in reactor, add above-mentioned white oil by weight or boat coal, sorbitan mono-oleic acid ester, octadecyl acrylate
It is allowed to be mixed into oil phase；
4), by aqueous phase add emulsifying 10 minutes in oil phase, add above-mentioned sodium sulfite by weight, start polymerization anti-
Should, it is warming up to 90 DEG C, is incubated 1 hour, is then cooled to 40 DEG C；
5), above-mentioned fatty alcohol-polyoxyethylene ether by weight, hydrophilic silicon oil are added react in the complete material lowered the temperature
It is sufficiently mixed, must disperse and reactive printing universal thickening agent.
Claims (9)
1. printing in textiles thickening agent, it is characterised in that by including that following Raw material processing by weight is prepared from:
Acrylic acid 150-220 part
Methacrylic acid 20-60 part
Acrylamide 50-80 part
Octadecyl acrylate 1-10 part
N-N ' methylene-bisacrylamide 0.01-0.5 part
White oil or boat coal 120-250 part
Sorbitan mono-oleic acid ester 15-50 part
Initiator 0.2-2 part
Sodium sulfite 0.01-1 part
Fatty alcohol-polyoxyethylene ether 10-50 part
Hydrophilic silicon oil 5-50 part
Sodium hydroxide solution 200-500 part.
Printing in textiles thickening agent the most according to claim 1, it is characterised in that by will include following by weight
Raw material processing be prepared from:
Acrylic acid 180-210 part
Methacrylic acid 30-50 part
Acrylamide 55-70 part
Octadecyl acrylate 5-7 part
N-N ' methylene-bisacrylamide 0.1-0.4 part
White oil or boat coal 180-200 part
Sorbitan mono-oleic acid ester 20-40 part
Initiator 0.1-1.8 part
Sodium sulfite 0.5-0.8 part
Fatty alcohol-polyoxyethylene ether 30-40 part
Hydrophilic silicon oil 30-40 part
Sodium hydroxide solution 300-400 part.
Printing in textiles thickening agent the most according to claim 1, it is characterised in that by will include following by weight
Raw material processing be prepared from:
200 parts of acrylic acid
Methacrylic acid 40 parts
Acrylamide 60 parts
Octadecyl acrylate 5 parts
N-N ' methylene-bisacrylamide 0.3 part
White oil or 200 parts of coal of boat
Sorbitan mono-oleic acid ester 30 parts
Initiator 1.4 parts
Sodium sulfite 0.4 part
Fatty alcohol-polyoxyethylene ether 30 parts
Hydrophilic silicon oil 20 parts
Sodium hydroxide solution 350 parts.
Printing in textiles thickening agent the most according to claim 2, it is characterised in that: hydroxide in described sodium hydroxide solution
Your quality of sodium is 28-35% with the total mass ratio of solution.
Printing in textiles thickening agent the most according to claim 2, it is characterised in that: hydroxide in described sodium hydroxide solution
The quality of sodium and the total mass ratio of solution are 32%.
Printing in textiles thickening agent the most according to claim 1, it is characterised in that: described initiator is selected from persulfuric acid
The mixture of one or more in potassium, sodium peroxydisulfate and Ammonium persulfate..
7. according to the production technology of the arbitrary described printing in textiles thickening agent of claim 1-6, it is characterised in that include with
Lower step:
1), above-mentioned acrylic acid by weight and methacrylic acid sodium hydroxide solution are neutralized to pH value 5.2-6.5；
2) in the product that step 1) obtains, it is sequentially added into above-mentioned acrylamide by weight, N-N ' methylene bisacrylamide acyl
Amine and initiator are hybridly prepared into aqueous phase；
3) in reactor, add above-mentioned white oil by weight or boat coal, sorbitan mono-oleic acid ester, octadecyl acrylate
It is allowed to be mixed into oil phase；
4), by aqueous phase add emulsifying 5-20 minute in oil phase, add above-mentioned sodium sulfite by weight, start polymerization anti-
Should, it is warming up to 70-110 DEG C, is incubated 0.5-1.5 hour, is then cooled to 30-60 DEG C；
5), above-mentioned fatty alcohol-polyoxyethylene ether by weight, hydrophilic silicon oil are added react in the complete material lowered the temperature
It is sufficiently mixed, must disperse and reactive printing universal thickening agent.
The production technology of printing in textiles thickening agent the most according to claim 7, it is characterised in that: pH in described step 1)
Value is 5.8-6.0.
The production technology of printing in textiles thickening agent the most according to claim 7, it is characterised in that: in described step 4),
Emulsifying 10 minutes；It is warming up to 90 DEG C, is incubated 1 hour, is then cooled to 40 DEG C.
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| CN201610285201.XA CN105735007A (en) | 2016-05-04 | 2016-05-04 | Textile printing thickening agent and production process thereof |
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| CN201610285201.XA CN105735007A (en) | 2016-05-04 | 2016-05-04 | Textile printing thickening agent and production process thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107142755A (en) * | 2017-06-26 | 2017-09-08 | 王蒙 | A kind of thickener |
| CN107503193A (en) * | 2017-08-21 | 2017-12-22 | 东莞市钟亿阻燃粘胶实业有限公司 | A kind of bleeding agent, the golden green onion slurry comprising the bleeding agent and its preparation method and application |
| CN109575294A (en) * | 2018-12-05 | 2019-04-05 | 四川省纺织科学研究院 | A kind of V-arrangement dimethyl silicone polymer polyoxyethylene ether mono acrylic ester and preparation method thereof |
| CN114080216A (en) * | 2019-06-26 | 2022-02-22 | 住友精化株式会社 | Adhesive composition |
| CN115677908A (en) * | 2022-09-23 | 2023-02-03 | 青岛科润生物科技有限公司 | Preparation method of reversed phase emulsifying thickener based on oil phase emulsifier |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107142755A (en) * | 2017-06-26 | 2017-09-08 | 王蒙 | A kind of thickener |
| CN107503193A (en) * | 2017-08-21 | 2017-12-22 | 东莞市钟亿阻燃粘胶实业有限公司 | A kind of bleeding agent, the golden green onion slurry comprising the bleeding agent and its preparation method and application |
| CN107503193B (en) * | 2017-08-21 | 2020-08-07 | 东莞市钟亿阻燃粘胶实业有限公司 | Penetrating agent, glitter paste containing penetrating agent, and preparation method and application of glitter paste |
| CN109575294A (en) * | 2018-12-05 | 2019-04-05 | 四川省纺织科学研究院 | A kind of V-arrangement dimethyl silicone polymer polyoxyethylene ether mono acrylic ester and preparation method thereof |
| CN109575294B (en) * | 2018-12-05 | 2021-02-23 | 四川省纺织科学研究院 | V-shaped polydimethylsiloxane polyoxyethylene ether monoacrylate and preparation method thereof |
| CN114080216A (en) * | 2019-06-26 | 2022-02-22 | 住友精化株式会社 | Adhesive composition |
| EP3991799A4 (en) * | 2019-06-26 | 2023-07-26 | Sumitomo Seika Chemicals Co., Ltd. | Viscous composition |
| CN115677908A (en) * | 2022-09-23 | 2023-02-03 | 青岛科润生物科技有限公司 | Preparation method of reversed phase emulsifying thickener based on oil phase emulsifier |
| CN115677908B (en) * | 2022-09-23 | 2023-07-18 | 青岛科润生物科技有限公司 | Preparation method of reverse emulsion thickener based on oil phase emulsifier |
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