CN105734984B - Pure-cotton antimicrobial fabric plus material producing method - Google Patents

Pure-cotton antimicrobial fabric plus material producing method Download PDF

Info

Publication number
CN105734984B
CN105734984B CN201610167925.4A CN201610167925A CN105734984B CN 105734984 B CN105734984 B CN 105734984B CN 201610167925 A CN201610167925 A CN 201610167925A CN 105734984 B CN105734984 B CN 105734984B
Authority
CN
China
Prior art keywords
fabric
degree
wax
coating
waxing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201610167925.4A
Other languages
Chinese (zh)
Other versions
CN105734984A (en
Inventor
岳维华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jihua 3543 Knitting Garment Co Ltd
Original Assignee
Jihua 3543 Knitting Garment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jihua 3543 Knitting Garment Co Ltd filed Critical Jihua 3543 Knitting Garment Co Ltd
Priority to CN201610167925.4A priority Critical patent/CN105734984B/en
Priority claimed from CN201410809036.4A external-priority patent/CN104404773B/en
Publication of CN105734984A publication Critical patent/CN105734984A/en
Application granted granted Critical
Publication of CN105734984B publication Critical patent/CN105734984B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/02Processes in which the treating agent is releasably affixed or incorporated into a dispensing means
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/05Cellulose or derivatives thereof
    • D06M15/09Cellulose ethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of pure-cotton antimicrobial fabric plus material producing method, is invented to solve the problems such as existing web process complexity.This method is fixed with Nano Silver in bottom fabric by wax.A kind of cost of present invention offer is low, the simple antibiotic facing material of technique, while the fabric has advantage, its economic benefit such as one-way wet-guide strong, good permeability, comfortable program height more notable.

Description

Pure-cotton antimicrobial fabric plus material producing method
This case is December 22 2014 applying date, the denomination of invention of application number 201410809036.4:Antibiotic facing material and its The divisional application of production method
Technical field
The present invention relates to a kind of antibiotic facing material and its production method.
Background technology
Antibiotic facing material refers to there is good security, and it can efficiently remove bacterium on fabric, fungi and mould completely Bacterium, clean fabric is kept, and bacteriological aftergrowth and breeding can be prevented.The processing mode of main flow has two kinds in the market:One kind is Built-in silver-ion antibiotic fabric, antiseptic is directly accomplished inside chemical fibre using spinning-grade antimicrobial technology;Another kind is Post-processing technology is added by the follow-up setting process of fabric.
This two ways complex process cost is high, and as the increase of fabric washing times, antiseptic understand immediate loss, So that antibacterial effect also rapid decrease.
The content of the invention
To overcome drawbacks described above, it is an object of the invention to provide a kind of cost is low, the simple pure-cotton antimicrobial fabric of technique Production method.
To reach above-mentioned purpose, pure-cotton antimicrobial fabric plus material producing method of the present invention, described method comprises the steps:
Fabric is pre-processed;
Pretreated fabric is carried out into bath with Nano silver solution to wash;
Fabric after being washed to bath is dried;
Netted wax layer is coated with fabric with waxer, described wax layer area accounts for the 50%-90% of the cloth face area.
Fabric after waxing is incubated 50-80 degree 3-10 minutes;
Wherein, described waxer by positioned at fabric upper surface surface temperature for 8-20 degree pressure roll and positioned at fabric The surface temperature of lower surface for 60-70 degree waxing roller group into, be provided with dewaxing groove below described waxing roller, the 1/ of roller of waxing 4-1/6 is located in the wax liquor of dewaxing groove;The temperature of the wax liquor is 60-75 degree, and waxing roller surface has the projection of net distribution, Formed with leading wax pan between adjacent two projection.
To reach above-mentioned purpose, pure-cotton antimicrobial fabric plus material producing method of the present invention, described method comprises the steps:
Fabric is pre-processed;
Fabric is placed on heating roller and is heated to 50-70 degree;
Netted wax coating will be coated with the cloth after heating with coating roll, the area of described wax coating accounts for fabric should The 50%-90% of face area.
Fabric after coating is incubated 50-80 degree 3-10 minutes;
Wherein, described coating roll for the pressure roll of 10-20 degree and is located at by the surface temperature on fabric upper surface The temperature of fabric lower surface for 60-70 degree waxing roller group into, be provided with coatings tank below described waxing roller, the 1/ of coating roll 4-1/6 is located in the coating of coatings tank;The feed temperature is 60-75 degree;Waxing roller surface has the projection of net distribution, phase Formed with deflector chute between adjacent two projections;
Described coating is made up of the raw material of following weight parts;20 parts of sodium hydroxyethyl cellulose HEC
6 parts of water repellent EX, 5 parts of wax 20-50 parts thickener Nano Silver 10-50 part water 10-50 parts.
The fabric produced using the above method, there is obvious antibacterial, anti-inflammatory, deodorization, mould proof, antipruritic, astriction, can To kill the staphylococcus aureus of contact fabric, MRSE, gonococcus (domestic epidemic strain), gonococcus (state completely Border standard persister), streptococcus, pneumococcus, meningococcus, Escherichia coli, shigella dysenteriae, typhoid bacillus, pneumobacillus, Pseudomonas aeruginosa, hay bacillus, wax printing fabric, Candida albicans, acrothesium floccosum, trichophyton gypseum, red hair tinea The harmful bacterias such as bacterium, Penicillium notatum, black-koji mould, to bacteriostasis rates such as staphylococcus aureuses still up to more than 99.9% after washing 100 times. Simultaneously as scribbling netted wax point in fabric bottom, and certain density is formed the gap between wax point using fabric waxing point Lead wet channel, by fabric ectonexine hydrophilic and hydrophobic difference, realize and obtain that one-way wet-guide is strong, gas permeability on pure cotton fabric Good, comfortable program height and other effects.
Brief description of the drawings
Fig. 1 is the structural representation of one-way wet-guide pure-cotton fabric embodiment 1 of the present invention.
Fig. 2 is one-way wet-guide pure-cotton fabric production technology schematic diagram of the present invention.
Fig. 3 is the schematic cross-sectional view of fabric in embodiment illustrated in fig. 1.
Embodiment
The present invention is further illustrated below in conjunction with the accompanying drawings.
The antibiotic facing material of the present invention, can use pure-cotton fabric, and the fabric comprises at least a bottom fabric 1 and is woven in institute State the surface material in bottom fabric;Wherein, it is fixed with Nano Silver in the bottom fabric.
Above-mentioned Nano Silver is to be fixed on by the wax 2 of net distribution in bottom fabric.
Nano Silver, bacterium DAN molecular structures can be caused to deform, inactivate germ.By fixing Nano Silver in fabric, The fabric for making to produce has good anti-microbial property, and such fabric is after 100 washings, still to fabric aberration feel Without influence.
1st, there is efficiently durable antibiotic property, low concentration has outstanding antibacterial effect;
2nd, broad-spectrum antiseptic, have excellent resist to 650 kinds of bacterium such as Escherichia coli, Candida albicans, staphylococcus aureus Bacterium acts on;
3rd, super water resistance is fixed on fibrous inside and protected by fiber, with durable antibacterial effect and excellent Washing fastness and drycleaning;
4th, excellent odor-resistant result, the stench as caused by microbial reproduction can be reduced, it is pure and fresh lasting;
5th, product safety, it is nontoxic, it is non-stimulated to skin;
6th, good compatibility, it is easily operated, can be with homo-ion softening agent processing with bath, to whiteness, coloured light, feel, Strength and moisture absorption, which are breathed freely, to have no adverse effects;
Above-mentioned wax point accounts for the 50%-90% of cloth area.
As shown in Figure 1 and Figure 2, it is in net on described pure-cotton fabric side fiber in one-way wet-guide pure-cotton fabric of the present invention Shape is laid with wax, and described wax point accounts for the 50%-90% of cloth area.In Fig. 1, Fig. 2, white portion is the wax being coated on fabric Point.Mixed with the Nano Silver of 5-20% parts by weight in described wax point.
Above-mentioned fabric produces as follows.
Embodiment 1
The pretreatment such as deoil is carried out to fabric;
Pretreated fabric is carried out into bath with Nano silver solution to wash, so that Nano Silver is penetrated into the fiber of cloth;It is right Fabric after bath is washed is dried;
Fabric after drying is placed on heating roller and is heated to 70 degree;
Netted wax layer will be coated with the cloth after heating with waxer, described wax layer area accounts for the 80% of cloth area.
Fabric after waxing is incubated 70 degree 5 minutes;
Wherein, described waxer by positioned at fabric upper surface surface temperature be 15 degree pressure roll and under fabric The waxing roller group that the surface temperature on surface is 70 degree is into the temperature difference between control pressure roller and waxing roller is advantageous to control coating The thickness of fabric is immersed in coating process, preferably to balance one side wet transmitting performance and permeability.In described waxing roller Lower section is provided with dewaxing groove, and the 1/4 of roller of waxing is located in the wax liquor of dewaxing groove;Waxing roller surface has the projection of net distribution, phase Formed with leading wax pan between adjacent two projections.
So, Nano Silver in fabric is immersed in bath process to be just fixed in fiber and be not easy to take off in washing process Fall.Simultaneously as scribble netted wax point in fabric bottom, and using fabric wax point formed the gap between wax point it is certain close Degree leads wet channel, by fabric ectonexine hydrophilic and hydrophobic difference, realizes that acquisition one-way wet-guide is strong, ventilative on pure cotton fabric Good, comfortable program height of property and other effects.
This programme can produce disposable or short-period used antibacterial, one side guide face material with fast and low-cost, can be extensive Fought flood and relieve victims, in the large-scale outdoor activities such as earthquake relief applied to various.
Embodiment 2,
The pretreatment such as decontaminated, deoiled to fabric;
Pretreated fabric is carried out into bath with Nano silver solution to wash, so that Nano Silver is penetrated into the fiber of cloth;It is right Fabric after bath is washed is dried;
Fabric after drying is placed on heating roller and is heated to 70 degree;
Netted wax liquor will be coated with the cloth after heating with waxer, the area of described wax liquor accounts for cloth area 50%-90%;Mixed with the Nano Silver of 15% parts by weight in described wax liquor.
Fabric after waxing is incubated 80 degree 3 minutes;
Wherein, described waxer is by the pressure roll that surface temperature is 20 degree and the waxing roller group that surface temperature is 60 degree Into, the temperature difference between control pressure roller and waxing roller is advantageous to the thickness for controlling coating to immerse fabric in coating process, with Preferably balance one side wet transmitting performance and permeability.Dewaxing groove is provided with below described waxing roller, the 1/4 of roller of waxing is located at In the wax liquor of dewaxing groove;Waxing roller surface has the projection of net distribution, formed with leading wax pan between adjacent two projection.
This programme in wax liquor by that mixed with a certain amount of Nano Silver, can make to be fixed on the amount of Nano Silver on fabric more Greatly, to strengthen the antibacterial effect of fabric.Meanwhile it can also obtain that one-way wet-guide is strong, good permeability, comfortable journey on pure cotton fabric Sequence height and other effects.
Embodiment 3
Decontamination is carried out to fabric the pretreatment such as to deoil;
Hydrophilic treated is done to fabric;
Netted wax coating will be coated with the cloth after heating with coating roll, the area of described wax coating accounts for fabric should The 50%-90% of face area.
Fabric after coating is incubated 70 degree 10 minutes, the length of soaking time immerses face with coating whole or more than 80% Expect that in fiber be best.
Wherein, described coating roll by the surface temperature on fabric upper surface be 10 degree pressure roll and positioned at fabric The waxing roller group that the temperature of lower surface is 70 degree is into the temperature difference between control pressure roller and waxing roller is advantageous to control coating to exist The thickness of fabric is immersed in coating process, preferably to balance one side wet transmitting performance and permeability.
Coatings tank is provided with below described waxing roller, the 1/4 of coating roll is located in the coating of coatings tank;The feed liquid temperature Spend for 75 degree;Waxing roller surface has the projection of net distribution, formed with deflector chute between adjacent two projection;
Described coating is made up of the raw material of following weight parts:20 parts of sodium hydroxyethyl cellulose HEC
6 parts of water repellent EX, 40 parts of wax, 5 parts of thickener, 25 parts of Nano Silver, 25 parts of water.
Adhesive, water repellent etc. are added in this programme so that the fabric accommodation produced is more extensive, Ke Yiying For the occasion such as short-term, medium-term and long-term.
In summary, the present invention is intended to provide a kind of cost is low, the simple antibiotic facing material of technique, at the same the fabric have it is single It is more notable to advantage, its economic benefits such as wet guilding strong, good permeability, comfortable program height.

Claims (4)

1. a kind of pure-cotton antimicrobial fabric plus material producing method, it is characterised in that described method comprises the steps:
Fabric is pre-processed;
Pretreated fabric is carried out into bath with Nano silver solution to wash;
Fabric after being washed to bath is dried;
Netted wax layer is coated with fabric with waxer, described wax layer area accounts for the 50%-90% of the cloth face area;
Fabric after waxing is incubated 50-80 degree 3-10 minutes;
Wherein, described waxer by positioned at fabric upper surface surface temperature for 8-20 degree pressure roll and positioned at fabric following table The surface temperature in face for 60-70 degree waxing roller group into being provided with dewaxing groove, the 1/4-1/ for roller of waxing below described waxing roller 6 in the wax liquor of dewaxing groove;The temperature of the wax liquor is 60-75 degree, and waxing roller surface has the projection of net distribution, adjacent Formed with leading wax pan between two projections.
2. production method as claimed in claim 1, it is characterised in that the receiving mixed with 5-20% parts by weight in described wax liquor Meter Yin.
3. production method as claimed in claim 1, it is characterised in that the fabric after drying is also placed on heating including one The step of 50-70 spends is heated on roller.
4. a kind of pure-cotton antimicrobial fabric plus material producing method, it is characterised in that described method comprises the steps:
Fabric is pre-processed;
Fabric is placed on heating roller and is heated to 50-70 degree;
Netted wax coating will be coated with the cloth after heating with coating roll, the area of described wax coating accounts for the fabric face face Long-pending 50%-90%;
Fabric after coating is incubated 50-80 degree 3-10 minutes;
Wherein, described coating roll by the surface temperature on fabric upper surface for 10-20 degree pressure roll and positioned at fabric The temperature of lower surface for 60-70 degree waxing roller group into being provided with coatings tank, the 1/4-1/ of coating roll below described waxing roller 6 in the coating of coatings tank;The feed temperature is 60-75 degree;Waxing roller surface has the projection of net distribution, and adjacent two Formed with deflector chute between projection;
Described coating is made up of the raw material of following weight parts:20 parts of sodium hydroxyethyl cellulose, 6 parts of water repellent EX, wax 20-50 Part, 5 parts of thickener, Nano Silver 10-50 parts, water 10-50 parts.
CN201610167925.4A 2014-12-22 2014-12-22 Pure-cotton antimicrobial fabric plus material producing method Active CN105734984B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610167925.4A CN105734984B (en) 2014-12-22 2014-12-22 Pure-cotton antimicrobial fabric plus material producing method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201410809036.4A CN104404773B (en) 2014-12-22 2014-12-22 Anti-bacterial fabric and production method thereof
CN201610167925.4A CN105734984B (en) 2014-12-22 2014-12-22 Pure-cotton antimicrobial fabric plus material producing method

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201410809036.4A Division CN104404773B (en) 2014-12-22 2014-12-22 Anti-bacterial fabric and production method thereof

Publications (2)

Publication Number Publication Date
CN105734984A CN105734984A (en) 2016-07-06
CN105734984B true CN105734984B (en) 2018-01-02

Family

ID=56251891

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610167925.4A Active CN105734984B (en) 2014-12-22 2014-12-22 Pure-cotton antimicrobial fabric plus material producing method

Country Status (1)

Country Link
CN (1) CN105734984B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107415390A (en) * 2017-06-21 2017-12-01 合肥远科服装设计有限公司 A kind of garment material
CN112227065A (en) * 2020-09-27 2021-01-15 安徽荣业纺织有限公司 Processing technology for prolonging antibacterial and mildew-proof performance of cotton and linen blended fabric

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103866460A (en) * 2012-12-18 2014-06-18 天津天纺投资控股有限公司 Nano-silver antibacterial fiber fabric and processing technology thereof
CN103911853A (en) * 2014-03-11 2014-07-09 何丽清 Nano-silver microsphere emulsion, and preparation method and applications thereof
CN203935964U (en) * 2014-06-24 2014-11-12 吴江市纺织科技中心有限公司 A kind of fabric Wax applyor

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10293A (en) * 1853-12-06 Arrangement of screw-cutting dies in the die-stock
CN1259480C (en) * 2004-05-21 2006-06-14 广东溢达纺织有限公司 Method for producing speical-finished pure cotton rapid-drying intelligent textile

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103866460A (en) * 2012-12-18 2014-06-18 天津天纺投资控股有限公司 Nano-silver antibacterial fiber fabric and processing technology thereof
CN103911853A (en) * 2014-03-11 2014-07-09 何丽清 Nano-silver microsphere emulsion, and preparation method and applications thereof
CN203935964U (en) * 2014-06-24 2014-11-12 吴江市纺织科技中心有限公司 A kind of fabric Wax applyor

Also Published As

Publication number Publication date
CN105734984A (en) 2016-07-06

Similar Documents

Publication Publication Date Title
CN103161071B (en) A kind of bacteriostatic non-woven cloth and preparation method thereof
CN104404773B (en) Anti-bacterial fabric and production method thereof
Nayak et al. Antimicrobial finishes for textiles
CN105040436A (en) Finishing method of antibacterial cotton fabric
CN101871167B (en) Preparation method of antibacterial cellulose fabric
KR100779746B1 (en) Anti-microbial fiber products
CN101967753B (en) Production method of nanometer antibiosis cashmere knit fabric
WO2011101857A2 (en) Multifunctional textile
CN105200773A (en) Preparation method of nano-silver coating of chitosan modified fabric
CN106939465A (en) A kind of weaving face fabric for baby
CN106592104B (en) A kind of tea polyphenols cellulose fibre spunlace non-woven cloth and its production method
CN106192395A (en) The method of modified cotton fabric surface enhanced nanometer silver antimicrobial bafta washing fastness
CN110791962A (en) Antibacterial spunlace non-woven fabric and preparation method thereof
CN110306340A (en) Antimicrobial natural textile material of surface modification borneol and the preparation method and application thereof
CN109295711A (en) A kind of preparation method and fibre of the antiviral anti-bacterial fibre of water-fastness type
Ibrahim et al. Eco-friendly modification and antibacterial functionalization of viscose fabric
CN105734984B (en) Pure-cotton antimicrobial fabric plus material producing method
WO2012001702A1 (en) Antimicrobial finish on fabrics
CN106948063A (en) A kind of antibacterial weaving face fabric for baby
CN106906558A (en) A kind of nano silver fibre antibacterial presses down the smelly knitting fabric of cool feeling
EP1612317A2 (en) Construction elements in a washing machine or wash-dryer or similiar either doped or layered with a bacteriozide
CN110524969A (en) Ventilative wind-proof man textile fabric
CN106149130A (en) A kind of controlled antibacterial towel of argentiferous chelating acrylic fiber and preparation method thereof
Dai et al. Reversible bacteria-killing and bacteria-releasing cotton fabric with anti-bacteria adhesion ability for potential sustainable protective clothing applications
CN104452471B (en) A kind of antimicrobial natural fiber wallpaper and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant