CN105733554A - Reversible thermochromic composite material and preparation method thereof - Google Patents
Reversible thermochromic composite material and preparation method thereof Download PDFInfo
- Publication number
- CN105733554A CN105733554A CN201610128103.5A CN201610128103A CN105733554A CN 105733554 A CN105733554 A CN 105733554A CN 201610128103 A CN201610128103 A CN 201610128103A CN 105733554 A CN105733554 A CN 105733554A
- Authority
- CN
- China
- Prior art keywords
- reversible thermochromic
- color
- fatty alcohol
- organic amine
- thermochromic composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000002441 reversible effect Effects 0.000 title claims abstract description 27
- 239000002131 composite material Substances 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000007787 solid Substances 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 27
- 150000001412 amines Chemical class 0.000 claims abstract description 15
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 238000010438 heat treatment Methods 0.000 claims description 14
- 239000000975 dye Substances 0.000 claims description 11
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 claims description 10
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 10
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 9
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 6
- 230000001476 alcoholic effect Effects 0.000 claims description 5
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 5
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 210000000577 adipose tissue Anatomy 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 230000007423 decrease Effects 0.000 abstract 1
- 230000035945 sensitivity Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 244000061458 Solanum melongena Species 0.000 description 6
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 230000004075 alteration Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 125000005997 bromomethyl group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000123069 Ocyurus chrysurus Species 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- UDSAIICHUKSCKT-UHFFFAOYSA-N bromophenol blue Chemical compound C1=C(Br)C(O)=C(Br)C=C1C1(C=2C=C(Br)C(O)=C(Br)C=2)C2=CC=CC=C2S(=O)(=O)O1 UDSAIICHUKSCKT-UHFFFAOYSA-N 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- OBRMNDMBJQTZHV-UHFFFAOYSA-N cresol red Chemical compound C1=C(O)C(C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C=C(C)C(O)=CC=2)=C1 OBRMNDMBJQTZHV-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- -1 inorganic matter Chemical class 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000004861 thermometry Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
- C09K9/02—Organic tenebrescent materials
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K11/00—Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00
- G01K11/12—Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00 using changes in colour, translucency or reflectance
- G01K11/16—Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00 using changes in colour, translucency or reflectance of organic materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/10—Non-macromolecular compounds
- C09K2211/1003—Carbocyclic compounds
- C09K2211/1011—Condensed systems
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Abstract
The invention discloses a reversible thermochromic composite material and a preparation method thereof. The composite material comprises a dye, organic amine and solid fatty alcohol, wherein the dye is a chromophoric reagent; the organic amine is a color developing agent; the solid fatty alcohol is a solvent; the ratio of the dye to the organic amine to the solid fatty alcohol is 1:(20-50):(200-400). The reversible thermochromic composite material disclosed by the invention is relatively simple in preparation, environmentally friendly, stable, reliable, bright in color change, and easy to obtain and implement. The material is high in reversible thermochromic sensitivity and durable in reversible color-changing, and the color-changing temperature range mainly concentrates in 40-65 DEG C; when the temperature reaches a certain specific value or a narrow specific range, a material system is changed from purple to yellow; when the temperature decreases to restore to the specific value or below, the reversible change in color occurs.
Description
Technical field
The present invention relates to the technical field of thermally indicating material, refer in particular to a kind of reversible thermochromic composite and
Preparation method.
Background technology
The demand for development thermometry of industry and science and technology is simple, fast and easy accurately now, novel
Thermally indicating material just arises at the historic moment, and they can be used in reluctant dangerous area or the most maccessiable
Side.Thermally indicating material is the one utilizing camouflage paint thermochromism to come Measuring Object surface temperature and Temperature Distribution
Specific functionality material, also referred to as off-color material or thermo-sensitive material.The color when material is heated to uniform temperature
Change, show a kind of new color, and when cooling down again, return to the most again original color, this
Material is reversible thermally indicating material;If color can not be recovered during cooling, then it it is irreversible thermally indicating material.
At present, scientists has found big in the classes of compounds such as inorganic matter, Organic substance, polymer and liquid crystal
Measurer has the material of thermochromic properties, and their color change people i.e. be can be observed by naked eyes, thermocolour
Property material is mainly used in color changeable pigment or the thermo-color of synthesizing new.Develop thermally indicating material for many years both at home and abroad,
And achieved with quite achievement, develop what many generations of the color when variations in temperature for temperature indicating substantially changed
Thermochromism.At present, low-temp reversible thermochromatic material is mainly thermally altered coals capsule, core on the market
Material composition includes colour former, developer, solid solvent.Such as, temperature-sensitive red with crystal violet lactone, temperature-sensitive
Black TF-BL etc. are colour former, form thermo-color with developer bisphenol-A and dissolved solids fatty alcohol respectively and compound
Thing;With bromophenol blue, bromomethyl is green, bromomethyl is purple, cresol red as colour former, respectively with developer alkaline earth gold
Belong to salt and dissolved solids fatty alcohol forms thermally altered coals.And right, the developer the most delivered
Kind is substantially organic acid and alkali salt two class, and the present invention, with organic amine as developer, discloses one
Plant novel thermo-color composite.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art and shortcoming, it is provided that a kind of reversible thermochromic is combined
Material and preparation method thereof, this reversible thermochromic composite prepare simple and fast, environmental protection, surely
Fixed reliable, color change distinctness, material is easy to get, and has widened the choosing of low-temp reversible thermo-color thermally altered coals
Select scope.
For achieving the above object, technical scheme provided by the present invention is as follows:
A kind of reversible thermochromic composite, including dyestuff, for colour former;Organic amine, for developer;Gu
Body fat alcohol, for solvent;Wherein, described dyestuff, organic amine, solid fatty alcohol ratio are 1:(20-50):
(200-400)。
Described dyestuff is alizarin red agent.
Described organic amine is tripolycyanamide or hexamethylenetetramine.
Described solid fatty alcohol is the one in tetradecyl alchohol, hexadecanol, octadecanol.
Described dyestuff, organic amine, solid fatty alcohol are analytical pure level.
The preparation method of above-mentioned reversible thermochromic composite is as follows:
Weigh dyestuff, organic amine, solid fatty alcohol according to the ratio described in claim 1 and mix, then
Heating and melting alcoholic solvent also cools down after being sufficiently stirred for, i.e. available required reversible thermochromic composite, its
Discoloring temperature is 40-65 DEG C, when temperature arrive particular value or specific interval time, its material system by purple to
Yellow changes, and when temperature reduction recovers to particular value, its color generation Back Up.
The present invention compared with prior art, has the advantage that and beneficial effect:
1, the reversible thermochromic material of the present invention is prepared fairly simple, and environmental protection is reliable and stable, and color becomes
Changing distinctness, material is easy to get, and implements easily.
2, the reversible thermochromic of material of the present invention is highly sensitive, and reversible color is lasting, discoloring temperature interval master
40-65 DEG C to be concentrated on;When temperature arrives certain particular value or the narrowest specific interval, its material
System is changed to yellow by purple;When temperature reduction recovers to particular value, there is reverse change in its color
Change.
Accompanying drawing explanation
Fig. 1 is the thermo-color complex chromatic aberration figure with temperature of gained in embodiment 1.
Fig. 2 is the thermo-color complex chromatic aberration figure with temperature of gained in embodiment 4.
Detailed description of the invention
Below in conjunction with multiple specific embodiments, the invention will be further described.
Embodiment 1
Raw material is as follows:
Dyestuff (specially alizarin red agent), for colour former;Organic amine (specially tripolycyanamide), for developer;
Solid fatty alcohol (specially hexadecanol), for solvent.Wherein, alizarin red agent: tripolycyanamide: the matter of hexadecanol
Amount ratio is 1:50:200.
Preparation method is as follows:
Weighing the hexadecanol mixing of the alizarin red agent of 0.1g, 5g tripolycyanamide and 20g, then heating and melting alcohol is molten
Agent cools down after being sufficiently stirred for 5min, i.e. obtains purple wax after cooling, when heating this wax to 50 DEG C,
Solid color from purple becomes yellow, continues heating, becomes yellow liquid, cool down the most at normal temperatures and pressures,
Color has yellow liquid to become yellow solid to become violet solid again, and chromatic aberration is as shown in Figure 1.
Embodiment 2
According to alizarin red agent: hexamethylenetetramine: the mass ratio of hexadecanol is 1:20:200, weighs 0.1g
Alizarin red agent, 2g hexamethylenetetramine and the hexadecanol of 20g, mixing, then heating and melting alcoholic solvent is abundant
Cool down after stirring 5min, after cooling, i.e. obtain aubergine wax, when heating this wax to 50 DEG C, solid
Color is become orange-yellow from aubergine, continues heating, becomes orange-yellow liquid, the coldest
But, color has yellow liquid to become orange/yellow solid to become aubergine solid again.
Embodiment 3
According to alizarin red agent: hexamethylenetetramine: the mass ratio of octadecanol is 1:50:400, weighs 0.1g
Alizarin red agent, 5g tripolycyanamide and the hexadecanol of 40g, mixing, then heating and melting alcoholic solvent is sufficiently stirred for
Cool down after 5min, after cooling, i.e. obtain aubergine wax, when heating this wax to 60 DEG C, solid color
Being become yellow from purple, continue heating, become yellow liquid, cool down the most at normal temperatures and pressures, color has
Yellow liquid becomes yellow solid and becomes aubergine solid again.
Embodiment 4
According to alizarin red agent: tripolycyanamide: the mass ratio of tetradecyl alchohol is 1:20:200, weigh the madder of 0.1g
Red pigment, 2g tripolycyanamide and the hexadecanol of 20g, mixing, then heating and melting alcoholic solvent is sufficiently stirred for 5min
Rear cooling, i.e. obtains aubergine wax after cooling, when heating this wax to 39 DEG C, solid color is by purple
Complexion changed is yellow, continues heating, becomes yellow liquid, cool down the most at normal temperatures and pressures, and color has yellow
Liquid becomes yellow solid and becomes violet solid again, and chromatic aberration is as shown in Figure 2.
The examples of implementation of the above are only the preferred embodiments of the invention, not limit the reality of the present invention with this
Execute scope, therefore the change that all shapes according to the present invention, principle are made, the protection model in the present invention all should be contained
In enclosing.
Claims (6)
1. a reversible thermochromic composite, it is characterised in that: include dyestuff, for colour former;Organic amine,
For developer;Solid fatty alcohol, for solvent;Wherein, described dyestuff, organic amine, solid fatty alcohol ratio
For 1:(20-50): (200-400).
A kind of reversible thermochromic composite the most according to claim 1, it is characterised in that: described dye
Material is alizarin red agent.
A kind of reversible thermochromic composite the most according to claim 1, it is characterised in that have described in:
Machine amine is tripolycyanamide or hexamethylenetetramine.
A kind of reversible thermochromic composite the most according to claim 1, it is characterised in that: described solid
Body fat alcohol is the one in tetradecyl alchohol, hexadecanol, octadecanol.
A kind of reversible thermochromic composite the most according to claim 1, it is characterised in that: described dye
Material, organic amine, solid fatty alcohol are analytical pure level.
6. the preparation method of reversible thermochromic composite described in a claim 1, it is characterised in that: press
Weighing dyestuff, organic amine, solid fatty alcohol according to the ratio described in claim 1 and mix, then heating is melted
Cool down after changing alcoholic solvent and being sufficiently stirred for, i.e. available required reversible thermochromic composite, its color temperature
Degree is 40-65 DEG C, and when temperature arrives particular value or specific interval, its material system is turned to yellow by purple
Become, and when temperature reduction recovers to particular value, its color generation Back Up.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610128103.5A CN105733554B (en) | 2016-03-07 | 2016-03-07 | A kind of reversible thermochromic composite and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610128103.5A CN105733554B (en) | 2016-03-07 | 2016-03-07 | A kind of reversible thermochromic composite and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105733554A true CN105733554A (en) | 2016-07-06 |
CN105733554B CN105733554B (en) | 2017-12-26 |
Family
ID=56249970
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610128103.5A Expired - Fee Related CN105733554B (en) | 2016-03-07 | 2016-03-07 | A kind of reversible thermochromic composite and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105733554B (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106810927A (en) * | 2016-12-28 | 2017-06-09 | 张学健 | It is a kind of to be applied to temperature induced color changing coating of fabric and preparation method thereof |
CN107041749A (en) * | 2017-01-26 | 2017-08-15 | 杨鹏 | A kind of skin temperature allochroic paint for backbone reduction system |
CN108103582A (en) * | 2017-12-13 | 2018-06-01 | 江南大学 | A kind of low-temp reversible thermochromic crystals material, preparation method and the usage |
CN111602041A (en) * | 2018-01-22 | 2020-08-28 | 株式会社日立产机系统 | Temperature detection ink, method for initializing temperature detection ink, temperature indicator, and article management system |
CN111998967A (en) * | 2020-08-29 | 2020-11-27 | 重庆地格科技有限责任公司 | Temperature-indicating paster for electrical equipment and preparation method thereof |
CN113234432A (en) * | 2021-05-25 | 2021-08-10 | 台州学院 | Attapulgite-dye reversible thermochromic composite pigment and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101724392A (en) * | 2009-11-24 | 2010-06-09 | 张世智 | Multiple reversible color change microcapsule anti-counterfeiting material and preparation method and application thereof |
CN101755029A (en) * | 2007-04-16 | 2010-06-23 | 弗劳恩霍弗实用研究促进协会 | Have the mixture of inverse thermochromic properties, the matrix material that contains it and purposes |
CN102191032A (en) * | 2010-03-19 | 2011-09-21 | 陈铨荣 | Reversible thermochromic organic material microcapsule |
CN104830309A (en) * | 2015-04-29 | 2015-08-12 | 中山大学 | Preparation of reversible thermo-color material, and preparation and applications of thermo-color solution system thereof |
-
2016
- 2016-03-07 CN CN201610128103.5A patent/CN105733554B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101755029A (en) * | 2007-04-16 | 2010-06-23 | 弗劳恩霍弗实用研究促进协会 | Have the mixture of inverse thermochromic properties, the matrix material that contains it and purposes |
CN101724392A (en) * | 2009-11-24 | 2010-06-09 | 张世智 | Multiple reversible color change microcapsule anti-counterfeiting material and preparation method and application thereof |
CN102191032A (en) * | 2010-03-19 | 2011-09-21 | 陈铨荣 | Reversible thermochromic organic material microcapsule |
CN104830309A (en) * | 2015-04-29 | 2015-08-12 | 中山大学 | Preparation of reversible thermo-color material, and preparation and applications of thermo-color solution system thereof |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106810927A (en) * | 2016-12-28 | 2017-06-09 | 张学健 | It is a kind of to be applied to temperature induced color changing coating of fabric and preparation method thereof |
CN107041749A (en) * | 2017-01-26 | 2017-08-15 | 杨鹏 | A kind of skin temperature allochroic paint for backbone reduction system |
CN107041749B (en) * | 2017-01-26 | 2018-11-09 | 杨鹏 | A kind of skin temperature allochroic paint for backbone reduction system |
CN108103582A (en) * | 2017-12-13 | 2018-06-01 | 江南大学 | A kind of low-temp reversible thermochromic crystals material, preparation method and the usage |
CN111602041A (en) * | 2018-01-22 | 2020-08-28 | 株式会社日立产机系统 | Temperature detection ink, method for initializing temperature detection ink, temperature indicator, and article management system |
CN111998967A (en) * | 2020-08-29 | 2020-11-27 | 重庆地格科技有限责任公司 | Temperature-indicating paster for electrical equipment and preparation method thereof |
CN113234432A (en) * | 2021-05-25 | 2021-08-10 | 台州学院 | Attapulgite-dye reversible thermochromic composite pigment and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN105733554B (en) | 2017-12-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105733554A (en) | Reversible thermochromic composite material and preparation method thereof | |
CN102807853B (en) | Reversible thermochromic microcapsule and preparation method thereof | |
Zhang et al. | Fabrication of visual textile temperature indicators based on reversible thermochromic fibers | |
CN102191032A (en) | Reversible thermochromic organic material microcapsule | |
CN105170041A (en) | Reversible thermochromic microcapsule pigment preparation method | |
CN101665677B (en) | Thermosensitive chromotropic material and manufacturing method and application thereof | |
CN102827597A (en) | Thermosensitive discoloring energy-storage material and preparation method thereof | |
CN104877065B (en) | The big organic reversible thermochromic microcapsules of long lifespan aberration and preparation method | |
BR112018004364B1 (en) | COMPOUND FOR USE IN COLOR CHANGE COMPOSITIONS, COLOR CHANGE COMPOSITION COMPRISING SAID COMPOUND, MICROENCAPSULATED PIGMENT COMPOSITION, INK COMPOSITION, WRITING IMPLEMENT, INDICATOR, PROCESS FOR PRODUCING SAID INDICATOR AND FURTHER USE OF THE COMPOUND, COMPOSITION AND SURFACTANT | |
CN109575664B (en) | Long-term stable color-changing oil painting stick and preparation method thereof | |
CN109627853A (en) | Reversible thermochromic color pencil lead and preparation method thereof and pencil | |
CN104497709A (en) | Preparation method of novel thermochromic printing ink | |
CN106366704B (en) | With soda acid/solvent discoloration behavior attapulgite hybrid pigment and preparation method thereof | |
US11524515B2 (en) | Thermochromic dye compositions and method for preparing same | |
Salom et al. | Temperature sensitive colour changing leathers with thermochromic pigments | |
CN104844999A (en) | Thermochromic silicone cup | |
CN109135409B (en) | Formaldehyde-free fluorescent pigment for water-based ink | |
CN107690460A (en) | A kind of decentralized waterborne general color chips | |
CN104844998A (en) | Color-changing silicone cup | |
CN104893421A (en) | Reversible temperature-sensitive color-changeable solid ink composition | |
CN103834220A (en) | Chromotropic paint | |
CN108559452A (en) | A kind of preparation method of phase-change thermal storage off-color material | |
JPH0219155B2 (en) | ||
CN104893427A (en) | Reversible temperature-sensitive color-changeable gel ink | |
CN102140260B (en) | Low-cost black cationic dye combination |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20171226 Termination date: 20200307 |
|
CF01 | Termination of patent right due to non-payment of annual fee |