CN105733289A - Anti-corrosion environment-friendly material and preparation method thereof - Google Patents
Anti-corrosion environment-friendly material and preparation method thereof Download PDFInfo
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- CN105733289A CN105733289A CN201610269388.4A CN201610269388A CN105733289A CN 105733289 A CN105733289 A CN 105733289A CN 201610269388 A CN201610269388 A CN 201610269388A CN 105733289 A CN105733289 A CN 105733289A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses an anti-corrosion environment-friendly material.The anti-corrosion environment-friendly material is prepared from, by weight, 5-10 parts of sepiolite, 3-8 parts of graphene, 25-35 parts of waste rubber, 30-40 parts of plastic scraps, 15-20 parts of phenolic resin, 12-18 parts of phytantriol, 16-22 parts of L-carveol, 6-12 parts of aluminum dihydrogen phosphate, 4-8 parts of 3-butenyl trimethyl silane and 15-25 parts of glycerol diacetate.The waste rubber and the plastic scraps serve as main raw materials to prepare the universal environment-friendly material, and the material has good corrosion resistance and can properly adsorb formaldehyde and purify air.
Description
Technical field
The invention belongs to environment-friendly materials field, be specifically related to a kind of corrosion-resistant environment-friendly materials and preparation method thereof.
Background technology
At present, the use of environment-friendly materials has penetrated in all trades and professions.And due to the requirement of operation, many occasions and neck
Territory all more or less can touch Korrosionsmedium, and this directly influences the service life of parts, such as various laboratorys,
Workshop etc..Current existing anticorrosive is to pray etch-proof effect by the intrinsic parts of change equipment mostly,
Not yet find that using the forms such as spraying or bonding to combine anticorrosion environment-friendly materials by not changing original parts plays anticorrosion
The report of erosion effect.
Summary of the invention
For above technical problem present in prior art, the present invention provides a kind of corrosion-resistant environment-friendly materials and preparation thereof
Method, makes full use of garbage scrap rubber and plastic scrap prepares universal corrosion-resistant environment-friendly materials, and it can be with existing
Equipment or product combine, and reach corrosion resistant purpose on the premise of change technique minimum.
Technical scheme: a kind of corrosion-resistant environment-friendly materials, including the composition of following parts by weight: meerschaum 5-10 part, graphite
Alkene 3-8 part, scrap rubber 25-35 part, plastic scrap 30-40 part, phenolic resin 15-20 part, plant triol 12-18 part, L-carveol
16-22 part, aluminium dihydrogen phosphate 6-12 part, 3-cyclobutenyl trimethyl silane 4-8 part, diacetine 15-25 part.Further
, described meerschaum 6-8 part, Graphene 4-7 part, scrap rubber 28-32 part, plastic scrap 35-38 part, phenolic resin 17-19 part,
Plant triol 14-17 part, L-carveol 18-21 part, aluminium dihydrogen phosphate 8-11 part, 3-cyclobutenyl trimethyl silane 5-7 part, oxalic acid
Glyceride 18-22 part.
Further, described meerschaum 7 parts, Graphene 6 parts, scrap rubber 30 parts, plastic scrap 37 parts, phenolic resin 18
Part, plant triol 16 parts, L-carveol 19 parts, aluminium dihydrogen phosphate 10 parts, 3-cyclobutenyl trimethyl silane 6 parts, diacetine
20 parts.
The preparation method of a kind of corrosion-resistant environment-friendly materials, comprises the steps:
S1: scrap rubber 25-35 part and plastic scrap 30-40 part are ground into chip, are added thereto to phenolic resin 15-20
Part and plant triol 12-18 part, first stir 10-20min at normal temperatures；It is subsequently added the meerschaum 5-10 part after grinding and 3-butylene
Base trimethyl silane 4-8 part, rise high-temperature to 80-100 DEG C, impregnation 30-50min, obtain liquid A；
S2: Graphene 3-8 part, L-carveol 16-22 part and diacetine 15-25 part are mixed, in temperature 30-40
Stir 20-40min at DEG C, obtain liquid B；
S3: by liquid A in addition step S1 of liquid B described in step S2, be simultaneously introduced aluminium dihydrogen phosphate 6-12 part, isolation sky
While gas, temperature is adjusted to 60-80 DEG C, reacts 1-3h；Question response cools down after terminating, filters, is dried, extruded after
Obtain described corrosion-resistant environment-friendly materials.
Further, described in step S1, the time of stirring is 18min；The temperature of dipping is 88-90 DEG C, impregnation
42min。
Further, temperature described in step S2 is 36 DEG C, stirs 28min.
Further, temperature described in step S3 is 75 DEG C, reacts 2.5h.
Further, the temperature being dried described in step S3 is 120 DEG C.
Beneficial effect: the preparation method of a kind of corrosion-resistant environment-friendly materials of the present invention, with scrap rubber and plastic scrap be
Primary raw material, prepares universal corrosion-resistant environment-friendly materials in conjunction with multi-chemical, Graphene etc.；These environment-friendly materials are
Little degree is capable of corrosion resistant purpose on the premise of changing existing product, and this material can also adsorb being harmful in air
Material, it is achieved purify the purpose of air.
Detailed description of the invention
Embodiment 1
S1: scrap rubber 25 parts and plastic scrap 30 parts are ground into chip, is added thereto to 15 parts of phenolic resin and plants three
Alcohol 12 parts, first stirs 10min at normal temperatures；It is subsequently added the meerschaum after grinding 5 parts and 3-cyclobutenyl trimethyl silane 4 parts,
Rise high-temperature to 80 DEG C, impregnation 30min, obtain liquid A；
S2: by Graphene 3 parts, L-carveol 16 parts and diacetine 15 parts mixing, stirs at temperature 30 DEG C
20min, obtains liquid B；
S3: by liquid A in addition step S1 of liquid B described in step S2, be simultaneously introduced aluminium dihydrogen phosphate 6 parts, completely cut off air
While temperature is adjusted to 60 DEG C, react 1h；Question response cools down after terminating, filters, be dried at 120 DEG C, extruded after
Obtain described corrosion-resistant environment-friendly materials.
Comparative example 1
S1: scrap rubber 25 parts and plastic scrap 30 parts are ground into chip, is added thereto to 15 parts of phenolic resin, first often
Stir 10min under temperature, obtain liquid A；
S2: by L-carveol 16 parts and diacetine 15 parts mixing, stirs 20min at temperature 30 DEG C, obtains liquid B；
S3: added by liquid B described in step S2 in step S1 in liquid A, is adjusted to 60 DEG C by temperature, instead while isolation air
Answer 1h；Question response cools down after terminating, filters, be dried at 120 DEG C, extruded after i.e. can get material.
Embodiment 2
S1: scrap rubber 35 parts and plastic scrap 40 parts are ground into chip, is added thereto to 20 parts of phenolic resin and plants three
Alcohol 18 parts, first stirs 20min at normal temperatures；It is subsequently added the meerschaum after grinding 10 parts and 3-cyclobutenyl trimethyl silane 8 parts,
Rise high-temperature to 100 DEG C, impregnation 50min, obtain liquid A；
S2: by Graphene 8 parts, L-carveol 22 parts and diacetine 25 parts mixing, stirs at temperature 40 DEG C
40min, obtains liquid B；
S3: by liquid A in addition step S1 of liquid B described in step S2, be simultaneously introduced aluminium dihydrogen phosphate 12 parts, completely cut off air
While temperature is adjusted to 80 DEG C, react 3h；Question response cools down after terminating, filters, be dried at 120 DEG C, extruded after
Obtain described corrosion-resistant environment-friendly materials.
Comparative example 2
S1: scrap rubber 35 parts and plastic scrap 40 parts are ground into chip, is added thereto to 20 parts of phenolic resin, first often
Stir 20min under temperature, obtain liquid A；
S2: by L-carveol 22 parts and diacetine 25 parts mixing, stirs 40min at temperature 40 DEG C, obtains liquid B；
S3: added by liquid B described in step S2 in step S1 in liquid A, is adjusted to 80 DEG C by temperature, instead while isolation air
Answer 3h；Question response cools down after terminating, filters, be dried at 120 DEG C, extruded after i.e. can get described corrosion-resistant environment-friendly materials.
Embodiment 3
S1: scrap rubber 28 parts and plastic scrap 35 parts are ground into chip, is added thereto to 17 parts of phenolic resin and plants three
Alcohol 14 parts, first stirs 10min at normal temperatures；It is subsequently added the meerschaum after grinding 6 parts and 3-cyclobutenyl trimethyl silane 5 parts,
Rise high-temperature to 88 DEG C, impregnation 40min, obtain liquid A；
S2: by Graphene 4 parts, L-carveol 18 parts and diacetine 18 parts mixing, stirs at temperature 40 DEG C
40min, obtains liquid B；
S3: by liquid A in addition step S1 of liquid B described in step S2, be simultaneously introduced aluminium dihydrogen phosphate 11 parts, completely cut off air
While temperature is adjusted to 80 DEG C, react 3h；Question response cools down after terminating, filters, be dried at 120 DEG C, extruded after
Obtain described corrosion-resistant environment-friendly materials.
Embodiment 4
S1: scrap rubber 32 parts and plastic scrap 38 parts are ground into chip, is added thereto to 19 parts of phenolic resin and plants three
Alcohol 17 parts, first stirs 20min at normal temperatures；It is subsequently added the meerschaum after grinding 8 parts and 3-cyclobutenyl trimethyl silane 7 parts,
Rise high-temperature to 90 DEG C, impregnation 50min, obtain liquid A；
S2: by Graphene 7 parts, L-carveol 21 parts and diacetine 22 parts mixing, stirs at temperature 30 DEG C
30min, obtains liquid B；
S3: by liquid A in addition step S1 of liquid B described in step S2, be simultaneously introduced aluminium dihydrogen phosphate 8 parts, completely cut off air
While temperature is adjusted to 70 DEG C, react 2h；Question response cools down after terminating, filters, be dried at 120 DEG C, extruded after
Obtain described corrosion-resistant environment-friendly materials.
Embodiment 5
S1: scrap rubber 30 parts and plastic scrap 37 parts are ground into chip, is added thereto to 18 parts of phenolic resin and plants three
Alcohol 16 parts, first stirs 18min at normal temperatures；It is subsequently added the meerschaum after grinding 7 parts and 3-cyclobutenyl trimethyl silane 6 parts,
Rise high-temperature to 88 DEG C, impregnation 42min, obtain liquid A；
S2: by Graphene 6 parts, L-carveol 19 parts and diacetine 20 parts mixing, stirs at temperature 36 DEG C
28min, obtains liquid B；
S3: by liquid A in addition step S1 of liquid B described in step S2, be simultaneously introduced aluminium dihydrogen phosphate 10 parts, completely cut off air
While temperature is adjusted to 75 DEG C, react 2.5h；Question response cools down after terminating, filters, be dried at 120 DEG C, extruded after i.e.
Available described corrosion-resistant environment-friendly materials.
To each embodiment above and comparative example resulting materials, utilize 50%H2SO4It is 25% naoh treatment with concentration
After carry out acid and alkali-resistance test, and carry out formaldehyde adsorption test, result is as follows:
| Experiment | Acid-swellable rate (%) | Alkali swelling ratio (%) | Formaldehyde absorbing rate (%) |
| Comparative example 1 | 30.5 | 26.8 | 0 |
| Embodiment 1 | 1.3 | 1.1 | 50% |
| Comparative example 2 | 31.8 | 29.7 | 0 |
| Embodiment 2 | 1.1 | 1.3 | 53% |
| Embodiment 3 | 0.85 | 1.1 | 58% |
| Embodiment 4 | 0.7 | 0.91 | 60% |
| Embodiment 5 | 0.65 | 0.85 | 62% |
。
Claims (8)
1. corrosion-resistant environment-friendly materials, it is characterised in that include the composition of following parts by weight: meerschaum 5-10 part, graphite
Alkene 3-8 part, scrap rubber 25-35 part, plastic scrap 30-40 part, phenolic resin 15-20 part, plant triol 12-18 part, L-carveol
16-22 part, aluminium dihydrogen phosphate 6-12 part, 3-cyclobutenyl trimethyl silane 4-8 part, diacetine 15-25 part.
The corrosion-resistant environment-friendly materials of one the most according to claim 1, it is characterised in that described meerschaum 6-8 part, Graphene
4-7 part, scrap rubber 28-32 part, plastic scrap 35-38 part, phenolic resin 17-19 part, plant triol 14-17 part, L-carveol 18-
21 parts, aluminium dihydrogen phosphate 8-11 part, 3-cyclobutenyl trimethyl silane 5-7 part, diacetine 18-22 part.
The corrosion-resistant environment-friendly materials of one the most according to claim 2, it is characterised in that described meerschaum 7 parts, Graphene 6
Part, scrap rubber 30 parts, plastic scrap 37 parts, 18 parts of phenolic resin, plant triol 16 parts, L-carveol 19 parts, aluminium dihydrogen phosphate 10
Part, 3-cyclobutenyl trimethyl silane 6 parts, diacetine 20 parts.
4. the preparation method of corrosion-resistant environment-friendly materials, it is characterised in that comprise the steps:
S1: scrap rubber 25-35 part and plastic scrap 30-40 part are ground into chip, be added thereto to phenolic resin 15-20 part and
Plant triol 12-18 part, first stir 10-20min at normal temperatures；It is subsequently added the meerschaum 5-10 part after grinding and 3-cyclobutenyl three
Methyl-monosilane 4-8 part, rise high-temperature to 80-100 DEG C, impregnation 30-50min, obtain liquid A；
S2: Graphene 3-8 part, L-carveol 16-22 part and diacetine 15-25 part are mixed, at temperature 30-40 DEG C
Stirring 20-40min, obtains liquid B；
S3: by liquid A in addition step S1 of liquid B described in step S2, be simultaneously introduced aluminium dihydrogen phosphate 6-12 part, isolation air
Temperature is adjusted to 60-80 DEG C simultaneously, reacts 1-3h；Question response cools down after terminating, filters, is dried, extruded after the most available
Described corrosion-resistant environment-friendly materials.
The preparation method of a kind of corrosion-resistant environment-friendly materials the most according to claim 4, it is characterised in that described in step S1
The time of stirring is 18min；The temperature of dipping is 88-90 DEG C, impregnation 42min.
The preparation method of a kind of corrosion-resistant environment-friendly materials the most according to claim 4, it is characterised in that described in step S2
Temperature is 36 DEG C, stirs 28min.
The preparation method of a kind of corrosion-resistant environment-friendly materials the most according to claim 4, it is characterised in that described in step S3
Temperature is 75 DEG C, reacts 2.5h.
The preparation method of a kind of corrosion-resistant environment-friendly materials the most according to claim 4, it is characterised in that described in step S3
The temperature being dried is 120 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610269388.4A CN105733289A (en) | 2016-04-27 | 2016-04-27 | Anti-corrosion environment-friendly material and preparation method thereof |
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| CN201610269388.4A CN105733289A (en) | 2016-04-27 | 2016-04-27 | Anti-corrosion environment-friendly material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107337933A (en) * | 2017-07-18 | 2017-11-10 | 合肥峰腾节能科技有限公司 | A kind of environment-friendly materials capable of purifying air and preparation method thereof |
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| CN102079835A (en) * | 2010-10-21 | 2011-06-01 | 曾广胜 | Waste rubber powder/polystyrene thermoplastic elastomer material and preparation process thereof |
| CN103052676A (en) * | 2010-08-03 | 2013-04-17 | 费罗公司 | Polymer composite foams |
| CN105062113A (en) * | 2015-08-13 | 2015-11-18 | 许超群 | High-temperature-resistant wood-plastic composite material and preparation method thereof |
| CN105175841A (en) * | 2014-08-19 | 2015-12-23 | 南京林业大学 | Sound absorbing material based on waste rubber powder and manufacturing method thereof |
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2016
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Patent Citations (5)
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| CN101279237A (en) * | 2008-05-23 | 2008-10-08 | 张宏 | Purificant for adsorbing formaldehyde and method of preparing the same |
| CN103052676A (en) * | 2010-08-03 | 2013-04-17 | 费罗公司 | Polymer composite foams |
| CN102079835A (en) * | 2010-10-21 | 2011-06-01 | 曾广胜 | Waste rubber powder/polystyrene thermoplastic elastomer material and preparation process thereof |
| CN105175841A (en) * | 2014-08-19 | 2015-12-23 | 南京林业大学 | Sound absorbing material based on waste rubber powder and manufacturing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107337933A (en) * | 2017-07-18 | 2017-11-10 | 合肥峰腾节能科技有限公司 | A kind of environment-friendly materials capable of purifying air and preparation method thereof |
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Application publication date: 20160706 |