CN105731625B - Ozone anion generation device and method - Google Patents
Ozone anion generation device and method Download PDFInfo
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- CN105731625B CN105731625B CN201610096393.XA CN201610096393A CN105731625B CN 105731625 B CN105731625 B CN 105731625B CN 201610096393 A CN201610096393 A CN 201610096393A CN 105731625 B CN105731625 B CN 105731625B
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- cylinder
- electric discharge
- discharge
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- ozone
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/02—Specific form of oxidant
- C02F2305/023—Reactive oxygen species, singlet oxygen, OH radical
Abstract
The invention discloses a kind of ozone anion generation device, the electromagnetic excitation cylinder being connected including electric discharge cylinder and with electric discharge cylinder, blower fan is provided with front of electric discharge cylinder, embedded be provided with is respectively used to connect the positive pole of discharge excitation power supply and the electric discharge positive terminal of negative pole and electric discharge negative terminal on electric discharge cylinder, the anode electrode being connected with electric discharge positive terminal and the negative discharge electrode being connected with electric discharge negative terminal are provided with electric discharge cylinder, the both sides external of electromagnetic excitation cylinder is respectively arranged with the first side plate and the second side plate, the magnet coil being fixedly connected between the first side plate and the second side plate is wound with electromagnetic excitation cylinder, the coil electrode binding post and coil negative terminal for being respectively used to the positive pole and negative pole for connecting electromagnetic excitation power supply are provided with magnet coil；The invention also discloses a kind of ozone anion production method.It is of the invention novel in design reasonable, realize that convenient and cost is low, it is practical, have a wide range of application, application value is high.
Description
Technical field
The invention belongs to ozone anion generation technology field, and in particular to a kind of ozone anion generation device and side
Method.
Background technology
Oxygen molecule in air is the paramagnetism molecule with three kinds of excitation state, because ground state oxygen molecule has two spins
The parallel lone electron in direction, therefore, the reactivity of oxygen molecule and organic compound etc. be not high.But in ultraviolet, laser, band
Ground state oxygen molecule can be excited under charged particle, electromagnetic excitation, high-tension electricity, illumination equal excitation as the high active oxygen of activity.It is living
Property oxygen (also known as free radical, free radical or oxygen radical) be directly or indirectly to be transformed by oxygen molecule, there is unpaired electricity
Son.Its chemical reactivity is more more active than ground state oxygen molecule, has strong oxidability, can carry out chain reaction, unstable
And the life-span is extremely short.For example, ozone (O3)、1O2(singlet oxygen), O2 -(superoxide anion/superoxide radical), HO2(hydrogen
Peroxy radical), OH (hydroxyl radical free radical), H2O2(hydrogen peroxide), RO (alkoxy), ROO (alkane peroxy) and ROOH
(hydroperoxides) etc..Most strikingly have among these with organic matter high respond hydroxyl radical free radical (
OH).Hydroxyl radical free radical (OH) is the most extensive chemical oxygen that can complete organic matter dehydrogenation reaction and hydrolyzable on the earth with moment
Compound, the dehydrogenation of organic matter can be carried out rapidly or add water reaction, oxidation, deodorization, decolourize, the decomposition of water pollutant, sterilization and
Sterilizing etc..Our known hydroxyl radical free radicals (OH) in sewage disposal are by hydrogen peroxide (H2O2) and copper or iron etc.
Heavy metal ion occurs what Fenton reactions were obtained.
H2O2+Fe2+→·OH+Fe3+Fenton reacts
But due to hydrogen peroxide (H2O2) it is chemical agent, price is high and has certain danger, therefore except making
It is outer that paper plant etc. is used as bleaching agent to use, and is not used generally in sewage disposal also.
Another produces the method for hydroxyl radical free radical (OH), is by ozone (O3) and superoxide anion (O2 -) anti-
Ozone anion (O should be generated3 -), then with water (H2O) react acquisition.
O3+·O2 -→O3 -+O2The generation of ozone anion
O3 -+H2O→·OH+O2+OH-The generation of hydroxyl radical free radical
Ozone (O3) and superoxide anion (O2 -) itself do not exist in the Nature and chemical agent, these are all due to
Material caused by ability below atmospherical discharges or electromagnetic action.Ozone anion (O can be produced by also lacking in the prior art3 -)
Apparatus and method, therefore also limit the industrial applications of hydroxyl radical free radical.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, the technical problem to be solved by the present invention is that provide a kind of structure letter
List, meter are new reasonable, realize that convenient and cost is low, practical, have a wide range of application, the high ozone anion of application value
Generation device.
In order to solve the above technical problems, the technical solution adopted by the present invention is：A kind of ozone anion generation device, it is special
Sign is：The electromagnetic excitation cylinder being connected including electric discharge cylinder and with electric discharge cylinder, the electric discharge cylinder front are provided with blower fan, the electric discharge
Embedded be provided with is respectively used to connect the positive pole of discharge excitation power supply and the electric discharge positive terminal of negative pole and discharged negative on cylinder
Pole binding post, be provided with the electric discharge cylinder with the anode electrode that is connected of electric discharge positive terminal and with electric discharge negative terminal
The negative discharge electrode of terminal connection, the both sides external of the electromagnetic excitation cylinder are respectively arranged with the first side plate and the second side plate,
The magnet coil being fixedly connected between the first side plate and the second side plate, the magnet coil are wound with the electromagnetic excitation cylinder
On be provided be respectively used to connect electromagnetic excitation power supply positive pole and negative pole coil electrode binding post and coil negative terminal
Terminal.
Above-mentioned ozone anion generation device, it is characterised in that：The negative discharge electrode be spray point, discharge electrode or
Discharge tube.
Above-mentioned ozone anion generation device, it is characterised in that：The electric discharge cylinder and the shape of electromagnetic excitation cylinder are
Cylindric or square tube shape.
Above-mentioned ozone anion generation device, it is characterised in that：The material of the electric discharge cylinder is ABS, polyvinyl chloride, glue
Wood, glass or ceramics.
Above-mentioned ozone anion generation device, it is characterised in that：The material of the electromagnetic excitation cylinder is copper, aluminium, tin, Huang
Copper, zinc or titanium.
Above-mentioned ozone anion generation device, it is characterised in that：The anode electrode is shaped as tabular or annulus
Shape.
Above-mentioned ozone anion generation device, it is characterised in that：The material of the negative discharge electrode and anode electrode
It is molybdenum or tungsten.
Above-mentioned ozone anion generation device, it is characterised in that：The discharge excitation power supply is that output voltage is 3000V
~5000V voltage source.
Above-mentioned ozone anion generation device, it is characterised in that：The electromagnetic excitation power supply be output current be 3A~
5A current source.
Present invention also offers a kind of method and step it is simple, realize convenient ozone anion production method, its feature exists
Comprise the following steps in this method：
Step 1: will discharge positive terminal and electric discharge negative terminal respectively with the positive pole of discharge excitation power supply and
Negative pole connects, and by coil electrode binding post and coil the negative terminal positive pole and negative pole with electromagnetic excitation power supply respectively
Connection；
Step 2: star t-up discharge excitation power supply, electromagnetic excitation power supply and blower fan；
Step 3: the negative discharge electrode discharge, produces free electron e-, the partial oxidation in air is decomposed polymerization
For ozone O3, and ozone O3With free electron e-Air stream with blower fan blowout enters in electromagnetic excitation cylinder；
Step 4: air stream in electromagnetic excitation cylinder by strong magnetic field action caused by magnet coil, in electromagnetically induced
In the presence of produce strong rotation, make the oxygen molecule O in air stream2Be activated and with free electron e-Reaction generation super oxygen is cloudy
Ion O2 -, then with ozone O3Reaction generation ozone anion O3 -。
The present invention has advantages below compared with prior art：
1st, the structure of ozone anion generation device of the present invention is simple, novel in design reasonable, realizes that convenient and cost is low.
2nd, the use simple operation of ozone anion generation device of the present invention, the oxygen molecule in air can be subjected to electromagnetism
Excitation activation, produces ozone O3, superoxide anion O2 -, finally discharge ozone anion O3 -。
3rd, the method and step of ozone anion production method of the present invention is simple, and it is convenient to realize.
4th, ozone anion O caused by the present invention3 -With hydrone H2O reacts, you can obtains hydroxyl radical free radical OH-, hydroxyl
Base free radical OH-Although the only extremely short life-span of microsecond, it is can to complete organic matter with moment on the earth to take off
Hydrogen reaction and the most extensive chemical oxide of hydrolyzable, the dehydrogenation of organic matter can be carried out rapidly or add water to react, aoxidize, being deodorized,
Decolouring, the decomposition of water pollutant, sterilization and sterilizing etc..
5th, the present invention enables to the industrial applications of hydroxyl radical free radical to be possibly realized, and can be widely applied to the oxygen of organic matter
Change the various aspects such as reduction, hydrolyzable, degraded, gasification, deodorization, sterilization, decolouring, practical, application value
It is high.
In summary, modern design of the invention rationally, realizes that convenient and cost is low, practical, has a wide range of application, pushes away
Wide application value is high.
Below by drawings and examples, technical scheme is described in further detail.
Brief description of the drawings
Fig. 1 is the structural representation of ozone anion generation device in the embodiment of the present invention 1.
Fig. 2 is the structural representation of ozone anion generation device in the embodiment of the present invention 2.
Fig. 3 is the structural representation of ozone anion generation device in the embodiment of the present invention 3.
Description of reference numerals:
1-electric discharge cylinder；2-1-spray point；2-2-discharge electrode；
2-3-discharge tube；3-anode electrode；4-electric discharge positive terminal；
5-electric discharge negative terminal；6-electromagnetic excitation cylinder；7-magnet coil；
8-coil electrode binding post；9-coil negative terminal；10-the first side plate；
11-the second side plate；12-blower fan；13-discharge excitation power supply；
14-electromagnetic excitation power supply.
Embodiment
Embodiment 1
Ozone anion generation device as shown in Figure 1, including electric discharge cylinder 1 and with the electromagnetic excitation cylinder that is connected of electric discharge cylinder 1
6, the front of electric discharge cylinder 1 is provided with blower fan 12, and embedded be provided with is respectively used to connect discharge excitation power supply on the electric discharge cylinder 1
13 positive pole and the electric discharge positive terminal 4 of negative pole and electric discharge negative terminal 5, it is provided with and puts in the electric discharge cylinder 1
The anode electrode 3 of the electric connection of positive terminal 4 and the negative discharge electrode being connected with electric discharge negative terminal 5, the electricity
The both sides external of magnetic pumping cylinder 6 is respectively arranged with the first side plate 10 and the second side plate 11, is wound with the electromagnetic excitation cylinder 6 solid
Surely the magnet coil 7 being connected between the first side plate 10 and the second side plate 11, the company of being respectively used to is provided with the magnet coil 7
Connect the positive pole of electromagnetic excitation power supply 14 and the coil electrode binding post 8 of negative pole and coil negative terminal 9.
In the present embodiment, the negative discharge electrode is spray point 2-1.
In the present embodiment, the shape of the electric discharge cylinder 1 and electromagnetic excitation cylinder 6 is cylindric or square tube shape.
In the present embodiment, the material of the electric discharge cylinder 1 is ABS, polyvinyl chloride, bakelite, glass or ceramics.Specific implementation
When, the material of the electric discharge cylinder 1 can also be other non-conducting materials such as non-conductive resin.
In the present embodiment, the material of the electromagnetic excitation cylinder 6 is copper, aluminium, one-tin brass, zinc or titanium.When it is implemented, institute
The nonmagnetic metal of good heat-conductive characteristic can also be had for other by stating the material of electromagnetic excitation cylinder 6, can either so be protected
The card magnetic line of force penetrates, additionally it is possible to avoids magnet coil 7 because of heating open circuit.In addition, heat can also pass through caused by magnet coil 7
Air stream in electromagnetic excitation cylinder 6 is cooled down.
In the present embodiment, the anode electrode 3 is shaped as tabular or annular shape.
In the present embodiment, the material of the negative discharge electrode and anode electrode 3 is molybdenum or tungsten.When it is implemented, institute
The material for stating negative discharge electrode and anode electrode 3 can also be other corrosion-resistant, good conductivity metal materials.
In the present embodiment, the discharge excitation power supply 13 is the voltage source that output voltage is 3000V~5000V.
In the present embodiment, the electromagnetic excitation power supply 14 is the current source that output current is 3A~5A.
The ozone anion production method of the present embodiment, comprises the following steps：
Step 1: will electric discharge positive terminal 4 and discharge negative terminal 5 respectively with discharge excitation power supply 13 just
Pole connects with negative pole, and by coil electrode binding post 8 and coil negative terminal 9 respectively with electromagnetic excitation power supply 14 just
Pole connects with negative pole；
Step 2: star t-up discharge excitation power supply 13, electromagnetic excitation power supply 14 and blower fan 12；
Step 3: the negative discharge electrode discharge, produces free electron e-, the partial oxidation in air is decomposed polymerization
For ozone O3, and ozone O3With free electron e-The air stream blown out with blower fan 12 enters in electromagnetic excitation cylinder 6；
Step 4: air stream is interior by strong magnetic field action caused by magnet coil 7 in electromagnetic excitation cylinder 6, lured in electromagnetism
Strong rotation is produced in the presence of leading, makes the oxygen molecule O in air stream2Be activated and with free electron e-Reaction generation super oxygen
Anion O2 -, then with ozone O3Reaction generation ozone anion O3 -.Wherein, superoxide anion O2 -With ozone O3Reaction generation
Ozone anion O3 -Reaction equation be：O3+·O2 -→O3 -+O2。
Embodiment 2
The present embodiment is as different from Example 1：The ozone anion generation device of the present embodiment, the negative discharge electricity
Extremely discharge electrode 2-2, remaining structure are same as Example 1.The ozone anion production method of the present embodiment and the phase of embodiment 1
Together.
Embodiment 3
The present embodiment is as different from Example 1：The ozone anion generation device of the present embodiment, the negative discharge electricity
Extremely discharge tube 2-3, remaining structure are same as Example 1.The ozone anion production method of the present embodiment and the phase of embodiment 1
Together.
In the present invention, in order to produce ozone anion O3 -, blower fan 12 is employed to air stream is provided in electric discharge cylinder 1, specifically
During implementation, ozone anion can also be extracted by the way of air-introduced machine.
It is to use magnet coil 7 as containing ozone O in the present invention3With free electron e-Air stream provide magnetic field, specifically
During implementation, the permanent magnets such as other forms such as ferrite or neodium magnet can also be used to provide magnetic field.
In summary, the present invention is that the oxygen molecule in air is carried out into electromagnetic excitation activation, produces ozone O3, super oxygen the moon from
Sub- O2 -, finally discharge ozone anion O3 -Device, utilize superoxide anion O caused by the present invention2 -Though life-span
So only short life of only several seconds, but with ozone O3Reaction generation ozone anion O3 -It is not only active extremely strong, and the life-span
Up to several minutes, the chemical oxidation operations such as this decomposes to organic matter, is deodorized and decolourized are extremely advantageous, and ozone anion O3 -With water
Molecule H2O reacts, you can obtains hydroxyl radical free radical OH-, hydroxyl radical free radical OH-Although only microsecond is extremely short
Life-span, but it is the most extensive chemical oxide that can complete organic matter dehydrogenation reaction and hydrolyzable on the earth with moment, can be rapid
Carry out the dehydrogenation of organic matter or add water reaction, oxidation, deodorization, decolouring, the decomposition of water pollutant, sterilization and sterilizing etc..This hair
The bright industrial applications for enabling to hydroxyl radical free radical are possibly realized, and can be widely applied to redox plus the moisture of organic matter
The various aspects such as solution, degraded, gasification, deodorization, sterilization, decolouring.
It is described above, only it is presently preferred embodiments of the present invention, not the present invention is imposed any restrictions, it is every according to the present invention
Any simple modification, change and the equivalent structure change that technical spirit is made to above example, still fall within skill of the present invention
In the protection domain of art scheme.
Claims (10)
- A kind of 1. ozone anion generation device, it is characterised in that：Including electric discharge cylinder (1) and the electromagnetism being connected with electric discharge cylinder (1) Encourage cylinder (6), blower fan (12) be provided with front of electric discharge cylinder (1), on the electric discharge cylinder (1) insertion the company of being respectively used to is installed The positive pole of discharge excitation power supply (13) and the electric discharge positive terminal (4) of negative pole and electric discharge negative terminal (5) are connect, it is described Be provided with electric discharge cylinder (1) anode electrode (3) that is connected with electric discharge positive terminal (4) and with electric discharge negative terminal (5) the negative discharge electrode of connection, the both sides external of the electromagnetic excitation cylinder (6) are respectively arranged with the first side plate (10) and second Side plate (11), it is wound with the electromagnetic excitation cylinder (6) and is fixedly connected between the first side plate (10) and the second side plate (11) Magnet coil (7), the positive pole for being respectively used to connect electromagnetic excitation power supply (14) and negative pole are provided with the magnet coil (7) Coil electrode binding post (8) and coil negative terminal (9).
- 2. according to the ozone anion generation device described in claim 1, it is characterised in that：The negative discharge electrode is electric discharge Pin (2-1), discharge electrode (2-2) or discharge tube (2-3).
- 3. according to the ozone anion generation device described in claim 1, it is characterised in that：The electric discharge cylinder (1) and electromagnetism swash The shape for encouraging cylinder (6) is cylindric or square tube shape.
- 4. according to the ozone anion generation device described in claim 1, it is characterised in that：It is described electric discharge cylinder (1) material be ABS, polyvinyl chloride, bakelite, glass or ceramics.
- 5. according to the ozone anion generation device described in claim 1, it is characterised in that：The material of the electromagnetic excitation cylinder (6) Matter is copper, aluminium, one-tin brass, zinc or titanium.
- 6. according to the ozone anion generation device described in claim 1, it is characterised in that：The shape of the anode electrode (3) For tabular or annular shape.
- 7. according to the ozone anion generation device described in claim 1, it is characterised in that：The negative discharge electrode and positive pole The material of electrode (3) is molybdenum or tungsten.
- 8. according to the ozone anion generation device described in claim 1, it is characterised in that：The discharge excitation power supply (13) is Output voltage is 3000V~5000V voltage source.
- 9. according to the ozone anion generation device described in claim 1, it is characterised in that：The electromagnetic excitation power supply (14) is Output current is 3A~5A current source.
- A kind of 10. method that ozone anion is produced using device as claimed in claim 1, it is characterised in that this method bag Include following steps：Step 1: will electric discharge positive terminal (4) and discharge negative terminal (5) respectively with discharge excitation power supply (13) Positive pole connects with negative pole, and by coil electrode binding post (8) and coil negative terminal (9) respectively with electromagnetic excitation power supply (14) positive pole connects with negative pole；Step 2: star t-up discharge excitation power supply (13), electromagnetic excitation power supply (14) and blower fan (12)；Step 3: the negative discharge electrode discharge, produces free electron e-, it is polymerized to the decomposition of the partial oxidation in air smelly Oxygen O3, and ozone O3With free electron e-Air stream with blower fan (12) blowout enters in electromagnetic excitation cylinder (6)；Step 4: air stream is interior by strong magnetic field action caused by magnet coil (7) in electromagnetic excitation cylinder (6), lured in electromagnetism Strong rotation is produced in the presence of leading, makes the oxygen molecule O in air stream2Be activated and with free electron e-Reaction generation super oxygen Anion O2 -, then with ozone O3Reaction generation ozone anion O3 -。
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| CN201610096393.XA CN105731625B (en) | 2016-02-22 | 2016-02-22 | Ozone anion generation device and method |
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|---|---|---|---|
| CN201610096393.XA CN105731625B (en) | 2016-02-22 | 2016-02-22 | Ozone anion generation device and method |
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| CN105731625B true CN105731625B (en) | 2018-04-10 |
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| CN108321679A (en) * | 2017-01-16 | 2018-07-24 | 巽晨国际股份有限公司 | The device for generating super oxygen state anion can be concentrated |
| CN113754033A (en) * | 2020-07-28 | 2021-12-07 | 平流层复合水离子(深圳)有限公司 | Magnetic rotary water ion generator |
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| US4780277A (en) * | 1985-05-10 | 1988-10-25 | Shinryo Corporation | Method and apparatus for subjecting gases to discharge treatment |
| CN1727277A (en) * | 2004-07-29 | 2006-02-01 | 倪嘉仁 | Oxyanion generation tube |
| CN103985937A (en) * | 2014-03-26 | 2014-08-13 | 南京航空航天大学 | Plasma microwave isolation device, microwave isolation method and device applications |
| CN104084309A (en) * | 2014-07-03 | 2014-10-08 | 王健 | Semiconductor electrostatic adsorption device |
| CN205398112U (en) * | 2016-02-22 | 2016-07-27 | 孟昭 | Ozone anion generating device |
-
2016
- 2016-02-22 CN CN201610096393.XA patent/CN105731625B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4780277A (en) * | 1985-05-10 | 1988-10-25 | Shinryo Corporation | Method and apparatus for subjecting gases to discharge treatment |
| CN1727277A (en) * | 2004-07-29 | 2006-02-01 | 倪嘉仁 | Oxyanion generation tube |
| CN103985937A (en) * | 2014-03-26 | 2014-08-13 | 南京航空航天大学 | Plasma microwave isolation device, microwave isolation method and device applications |
| CN104084309A (en) * | 2014-07-03 | 2014-10-08 | 王健 | Semiconductor electrostatic adsorption device |
| CN205398112U (en) * | 2016-02-22 | 2016-07-27 | 孟昭 | Ozone anion generating device |
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