CN105724406A - Herbicidal composition containing trifloxysulfuron and diuron and application thereof - Google Patents
Herbicidal composition containing trifloxysulfuron and diuron and application thereof Download PDFInfo
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- CN105724406A CN105724406A CN201610143594.0A CN201610143594A CN105724406A CN 105724406 A CN105724406 A CN 105724406A CN 201610143594 A CN201610143594 A CN 201610143594A CN 105724406 A CN105724406 A CN 105724406A
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- diuron
- trifloxysulfuron
- herbicidal combinations
- herbicidal
- mass ratio
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a herbicidal composition containing trifloxysulfuron and diuron and application thereof. The herbicidal composition uses trifloxysulfuron and diuron as effective ingredients having a mass ratio of 1-60:1-60. The herbicidal composition is useful in post-seedling weeding of cotton fields, particularly significant in preventing and removing broad-leaved weeds in cotton fields. Compared with a single agent, the herbicidal composition is higher in efficiency, can delay resistance of weeds, has wide herbicidal spectrum and long acting period, and is safe to both cotton and afterculture crops.
Description
Technical field
The invention belongs to technical field of pesticide, especially herbicide field, be specifically related to a kind of Herbicidal combinations containing trifloxysulfuron with diuron and application thereof.
Background technology
Trifloxysulfuron, has another name called Ying Feite.Chemical name: 1-(4,6-dimethoxypyridin-2-base)-3-[3-(2,2,2-trifluoro ethoxy)-2-pyridine sulfonyl sulfonyl] urea, structural formula is:
Trifloxysulfuron belongs to sulfonylurea herbicide, can be absorbed by the root of weeds, stem, leaf after dispenser, downwardly and upwardly can conduct in plant, by suppressing the activity of acetolactate synthestase (ALS), thus affecting the biosynthesis of branched-chain amino acid (such as leucine, isoleucine, valine etc.).Showing as growing point necrosis, vein chlorosis after hazard of plant, plant growing is heavily suppressed, dwarfing, and final Herb is withered.Trifloxysulfuron is to difference mainly due to katabolism of the selectivity of weeds and crop.It can be inactive material by rapid metabolization in Cotton Gossypii and Caulis Sacchari sinensis body, so that crop plant escapes injury.
Diuron, has another name called that DICAO is clean, reaches and have dragon, and chemical name: N-(3,4-Dichlorobenzene base)-N', N'-dimethyl urea belongs to carbamide herbicides, structural formula:
Diuron is inner sucting conduction type spectrum herbicide, can be absorbed by the root of plant, leaf, it is suppressed that the Hill reaction in photosynthesis.Medicament absorbed by root system of plant or blade after inhibited photosynthesis, cause leaf chlorosis, blade tip and edge to fade, cause plant for want of nutrition and dead.Diuron can pass through potential difference under low dosage and the time difference selects to carry out weeding, becomes steriland herbicide during high dose.Most of annual and perennial weeds is effective, sustainable more than the 60d of drug effect.
Current weeding in cotton field agent is limit by crop safety, herbicide spectrum is also limited, it is used alone a kind of herbicide single dose and can not control the generation of Cotton Fields weeds completely effectively, furthermore some herbicide is owing to water solublity is big or the field lasting period is oversize, consumption is excessive or the uneven residual hazard all easily caused this season crop or succession crop of dispenser.Therefore, the present invention selects herbicide to compose difference, it is made into mixture use after the trifloxysulfuron of pluses and minuses complementation and two kinds of suitable decrements of herbicide of diuron, so both expand herbicide spectrum, significantly improve herbicidal effect, it also avoid and this season crop is produced poisoning and succession crop is produced the probability of residual hazard.
Summary of the invention
It is an object of the invention to provide a kind of Herbicidal combinations containing trifloxysulfuron Yu diuron.
It is a further object of the present invention to provide the application in weeding in cotton field of this Herbicidal combinations.
A kind of Herbicidal combinations containing trifloxysulfuron Yu diuron, it is characterized in that this Herbicidal combinations is with trifloxysulfuron and diuron for effective ingredient, the mass ratio of trifloxysulfuron and diuron is 1～60:1～60, the mass ratio of preferred trifloxysulfuron and diuron is 1～40:1～30, it is preferred that the mass ratio of trifloxysulfuron and diuron is 1:9～59:1, it is most preferred that the mass ratio of trifloxysulfuron and diuron is 12～59:1.
In a preferred embodiment of the invention, trifloxysulfuron is composite with the mass ratio of 34:1,29:1,59:1,12:1 with diuron, it is possible to produce Synergistic herbicidal effect.
In a preferred embodiment of the invention, trifloxysulfuron is composite with the mass ratio of 1:4,1:9,1:5,2:3.1,19:60,1:1 with diuron, it is possible to produce considerable Synergistic herbicidal effect.
In Herbicidal combinations, trifloxysulfuron and both diuron weight/mass percentage composition in Herbicidal combinations are 1～80%, it is preferable that weight/mass percentage composition is 30～65%.
In the binary built compositions of the trifloxysulfuron of the present invention and diuron, except the effective ingredient such as trifloxysulfuron and diuron, it is also possible to add any one dosage form that the auxiliary agents such as the conventional surfactants, thickening agent, solvent or the solid packing that allow on pesticidal preparations are configured on pesticide to allow.Preferably it is processed into cream, suspending agent, aqueous emulsion, microemulsion, water dispersion granule, wettable powder etc..
Herbicidal combinations of the present invention can be applied in Cotton Fields postemergence weed control, and particularly in preventing and kill off Cotton Fields, in grass family and broad leaved weed, application has remarkable result.
" % " that do not make specified otherwise in the present invention all represents mass percent.
The Herbicidal combinations of the present invention has the advantage that
1, activity of weeding is high.The Herbicidal combinations of the present invention can kill weeds by two kinds of different mechanism so that Weed Resistance produces speed and reduces, and is greatly enhanced the removing activity of herbicide.
2, herbicidal spectrum is wide, and the lasting period is long.Most of annual and perennial weeds are had good preventive effect by diuron, and trifloxysulfuron can prevent and treat most of broad leaved weed and part arbor section weeds.After both mixing, it is possible to increase the preventing and treating to multiple broad leaved weed.
3, Weed Resistance is delayed.Herbicidal combinations of the present invention passes through binary built, the reduction weeds resistance to medicament, and improves the preventive effect of antagonism weeds, thus extending the service life of medicament.
4, safety is high.Owing to its using dosage is under control, making medicament under the premise that improve drug effect, the safety of Cotton Gossypii and succession crop be have also been obtained raising by it.
The Herbicidal combinations of the present invention, is applied to Cotton Fields postemergence weed control, and it can prevent and kill off various broad leaved weeds in Cotton Fields, under the premise that improve drug effect, Cotton Gossypii and succession crop is all had safety.
Therefore, Herbicidal combinations of the present invention can be applied in the preparation herbicide for Cotton Fields postemergence weed control, particularly applies in the herbicide of broad leaved weed for preventing and kill off in Cotton Fields in preparation.
Detailed description of the invention
Embodiment 1
Trifloxysulfuron 34%, diuron 1%, alkylphenol polyoxyethylene 4%, phenethyl phenol polyethenoxy ether 15%, dimethylbenzene is to 100%, and formulation method conventionally is configured to the cream that weight/mass percentage composition is 35%.
Embodiment 2
Trifloxysulfuron 29%, diuron 1%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE 3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus is water, and total percentage composition of all the components is 100%.Formulation method conventionally is configured to the suspending agent that weight/mass percentage composition is 30%.
Embodiment 3
Trifloxysulfuron 59%, diuron 1%, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol 2%, Kaolin is to 100%, and formulation method conventionally is configured to the water dispersion granule that weight/mass percentage composition is 60%.
Embodiment 4
Trifloxysulfuron 60%, diuron 5%, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 6%, wooden sodium iodate 4%, Kaolin is to 100%, and formulation method conventionally is configured to the wettable powder that weight/mass percentage composition is 65%.
Embodiment 5
Trifloxysulfuron 3%, diuron 12%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE 3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, solvent naphtha 20%, water is to 100%, and formulation method conventionally is configured to the aqueous emulsion that weight/mass percentage composition is 15%.
Embodiment 6
Trifloxysulfuron 1%, diuron 9%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE 3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, water is to 100%, and formulation method conventionally is configured to the microemulsion that weight/mass percentage composition is 10%.
Embodiment 7
Trifloxysulfuron 10%, diuron 50%, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 6%, wooden sodium iodate 4%, Kaolin is to 100%, and formulation method conventionally is configured to the wettable powder that weight/mass percentage composition is 60%.
Embodiment 8
Trifloxysulfuron 20%, diuron 31%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE 3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus is water, and total percentage composition of all the components is 100%.Formulation method conventionally is configured to the suspending agent that weight/mass percentage composition is 51%.
Embodiment 9
Trifloxysulfuron 19%, diuron 60%, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol 2%, Kaolin is to 100%, and formulation method conventionally is configured to the water dispersion granule that weight/mass percentage composition is 79%.
Embodiment 10
Trifloxysulfuron 5%, diuron 5%, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 6%, wooden sodium iodate 4%, Kaolin is to 100%, and formulation method conventionally is configured to the wettable powder that weight/mass percentage composition is 10%.
Embodiment 11
1), toxicity determination test
Utilize the preparation in embodiment 1～4, measure its co-toxicity coefficient to Cotton Fields common weed Herba Commelinae.
Test method: be seeded in respectively in the Disposable paper cup of 9cm by the seed of quantitative Herba Commelinae, sows 10～15 seeds, cultivates, when Herba Commelinae 3～6 leaf phase, make to carry out on composition spray spraying process in crawler type in illumination box in every glass.Continuing in greenhouse after process to cultivate, routine observation respectively processes the preventive effect to weeds, weighs the weeds fresh weight after each process after 30d, calculates its toxicity regression curve and co-toxicity coefficient.Co-toxicity coefficient is more than 100, it was shown that two kinds of active substance have potentiation, and co-toxicity coefficient is less than 100, it was shown that two kinds of active substance have antagonism.Measurement result is as shown in table 1.
Table 1 toxicity measurement result
As can be seen from the above table, the co-toxicity coefficient after two kinds of active substance are composite both is greater than 100, illustrates that the present invention has obvious potentiation.
2), field control effectiveness test.
Reagent agent:
4 kinds of re-compounded binary herbicides in embodiment 1～4.
Comparison medicament:
10% trifloxysulfuron can wet-milling (commercially available), 250g/L diuron can wet-milling (self-control).
For studying thing: Cotton Gossypii
Cotton seedling grows fine, robust plant, without other pest and disease damages.
Prevent and kill off object:
The weeds such as barnyard grass, Herba Digitariae, Semen Euphorbiae, Herba chenopodii, Herba Amaranthi tricoloris, smartweed.
Test method:
According to the area of experimental plot, the good various medicament of precise, and after being watered dilution, utilize knapsack sprayer, carry out even spraying, the Fan spray head that sprinkler selection herbicide is special.During spraying, it should be noted that uniformly sprayed application in experimental plot by medicinal liquid, accomplish the phenomenon not having drain spray, many sprays.
After test, after medicine, 20d, 40d observe weeds death condition respectively, and compare the activity of weeding of various medicaments.Additionally, also to observe the condition of production (consumption of consumption with being every mu effective ingredient) of crop after medicine in 1～15d, to investigate medicament to whether crop has poisoning.
Embodiments of the invention preparation Herbicidal Testing Trials effect is shown in table 2 below (after medicine 20d) and table 3 (after medicine 40d)
Table 2 field control effectiveness test result (after medicine 20d)
Table 3 field control effectiveness test result (after medicine 40d)
As can be seen from the above table, Herbicidal combinations of the present invention has expansion herbicidal spectrum, improves the effect of activity of weeding, and extends the lasting period of medicament.
Table 4 medicament security survey result to crop
Each Cotton growth processed in community is good, has no any medicine speckle, illustrates that various medicament is all safe to Cotton Gossypii.
Claims (10)
1. the Herbicidal combinations containing trifloxysulfuron Yu diuron, it is characterised in that this Herbicidal combinations is with trifloxysulfuron and diuron for effective ingredient, wherein, the mass ratio of trifloxysulfuron and diuron is 1～60:1～60.
2. the Herbicidal combinations containing trifloxysulfuron Yu diuron according to claim 1, it is characterised in that in this Herbicidal combinations, trifloxysulfuron is 1～40:1～30 with the mass ratio of diuron.
3. the Herbicidal combinations containing trifloxysulfuron Yu diuron according to claim 1, it is characterised in that in this Herbicidal combinations, trifloxysulfuron is 1:9～59:1 with the mass ratio of diuron.
4. the Herbicidal combinations containing trifloxysulfuron Yu diuron according to claim 3, it is characterised in that in this Herbicidal combinations, trifloxysulfuron is 12～59:1 with the mass ratio of diuron.
5. the Herbicidal combinations according to any one of Claims 1 to 4, it is characterised in that trifloxysulfuron and both diuron weight/mass percentage composition in Herbicidal combinations are 1～80%.
6. Herbicidal combinations according to claim 5, it is characterised in that trifloxysulfuron and both diuron weight/mass percentage composition in Herbicidal combinations are 30～65%.
7. Herbicidal combinations according to claim 1, it is characterised in that it is with trifloxysulfuron and diuron for effective ingredient, and the auxiliary agent allowed on pesticide is configured to any one dosage form.
8. Herbicidal combinations according to claim 7, it is characterised in that described dosage form is cream, suspending agent, aqueous emulsion, microemulsion, water dispersion granule or wettable powder.
9. the application in the herbicide preparing Cotton Fields postemergence weed control of the Herbicidal combinations described in claim 1.
10. the application that the Herbicidal combinations described in claim 1 is prevented and kill off in Cotton Fields in the herbicide of broad leaved weed and/or grassy weed in preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610143594.0A CN105724406A (en) | 2016-03-14 | 2016-03-14 | Herbicidal composition containing trifloxysulfuron and diuron and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610143594.0A CN105724406A (en) | 2016-03-14 | 2016-03-14 | Herbicidal composition containing trifloxysulfuron and diuron and application thereof |
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| CN105724406A true CN105724406A (en) | 2016-07-06 |
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| CN201610143594.0A Pending CN105724406A (en) | 2016-03-14 | 2016-03-14 | Herbicidal composition containing trifloxysulfuron and diuron and application thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0540697B1 (en) * | 1991-03-25 | 1998-06-03 | Novartis AG | Sulfonylureas |
| JP2006131602A (en) * | 2004-11-04 | 2006-05-25 | Maruwa Biochemical Co Ltd | Fine granule agent containing acetolactate synthesis inhibitor |
| CN101827524A (en) * | 2007-10-23 | 2010-09-08 | 杜邦公司 | Herbicide mixture, method for controlling undesirable vegetation and use of herbicides |
-
2016
- 2016-03-14 CN CN201610143594.0A patent/CN105724406A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0540697B1 (en) * | 1991-03-25 | 1998-06-03 | Novartis AG | Sulfonylureas |
| JP2006131602A (en) * | 2004-11-04 | 2006-05-25 | Maruwa Biochemical Co Ltd | Fine granule agent containing acetolactate synthesis inhibitor |
| CN101827524A (en) * | 2007-10-23 | 2010-09-08 | 杜邦公司 | Herbicide mixture, method for controlling undesirable vegetation and use of herbicides |
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