CN105714614A - Seamless aqueous foamed wallpaper and manufacturing method thereof - Google Patents
Seamless aqueous foamed wallpaper and manufacturing method thereof Download PDFInfo
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- CN105714614A CN105714614A CN201610115731.XA CN201610115731A CN105714614A CN 105714614 A CN105714614 A CN 105714614A CN 201610115731 A CN201610115731 A CN 201610115731A CN 105714614 A CN105714614 A CN 105714614A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/104—Hydrazines; Hydrazides; Semicarbazides; Semicarbazones; Hydrazones; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
- D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
- D21H27/28—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures treated to obtain specific resistance properties, e.g. against wear or weather
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention discloses seamless aqueous foamed wallpaper and a manufacturing method thereof. The manufacturing method comprises the steps that 1, polyacrylic acid and a pigment agent are mixed, and the mixture is printed on the surface of a basic layer and dried to form a printed layer; 2, aqueous foamex, a foaming agent, a leveling agent and a stabilizing agent are mixed and foamed, and then the mixture is transferred to the surface of the printed layer to be cured and dried to form a process layer, wherein the basic layer is a non-woven basic layer or a cloth basic layer or a paper basic layer, and the aqueous foamex is selected from polyacrylic acid and/or polyurethane. The wallpaper manufactured through the method has the advantages of resisting tarnishing, resisting scrubbing and preventing dampness and mildew.
Description
Technical field
The present invention relates to wallpaper, in particular it relates to seamless aqueous foaming wallpaper and preparation method thereof.
Background technology
Material very common in the existing interior decoration of wallpaper, the mode mainly by gluing and splicing is arranged on wall, although the quality of existing wallpaper is comparatively excellent, but the weak point of having still suffered from: more easy to change, not scrubbing resistance, the easy moisture absorption and go mouldy.Due to above-mentioned defect, significantly limit decoration popularization in decoration, in order to wallpaper industry brings great industry obstacle.
Summary of the invention
It is an object of the invention to provide a kind of seamless aqueous foaming wallpaper and preparation method thereof, the wallpaper prepared by the method has fastness, scrubbing resistance, moistureproof and anti-mildew characteristic.
To achieve these goals, the preparation method that the invention provides a kind of seamless aqueous foaming wallpaper, including:
1) polyacrylic acid is mixed with pigment agent, be then printed in the surface of basic unit and dry formation prints layer;
2) aqueous foaming resin, foaming agent, levelling agent and stabilizer hybrid concurrency being steeped, the surface being then transferred to printing layer carries out solidifying, drying with formation process layer;
Wherein, basic unit is non-woven substrate, Bu Zhi basic unit or papery basic unit, and aqueous foaming resin is selected from polyacrylic acid and/or polyurethane.
Present invention also offers a kind of seamless aqueous foaming wallpaper, this is seamless, and aqueous foaming wallpaper is prepared from by above-mentioned method.
By technique scheme, seamless aqueous foaming wallpaper provided by the invention includes basic unit, printing layer and process layer, makes the wallpaper prepared have the fastness of excellence, scrubbing resistance, moistureproof and anti-mildew characteristic by the synergism between each layer.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the specific embodiment of the present invention is described in detail.It should be appreciated that detailed description of the invention described herein is merely to illustrate and explains the present invention, it is not limited to the present invention.
The preparation method that the invention provides a kind of seamless aqueous foaming wallpaper, including:
1) polyacrylic acid is mixed with pigment agent, be then printed in the surface of basic unit and dry formation prints layer;
2) aqueous foaming resin, foaming agent, levelling agent and stabilizer hybrid concurrency being steeped, the surface being then transferred to printing layer carries out solidifying, drying with formation process layer;
Wherein, basic unit is non-woven substrate, Bu Zhi basic unit or papery basic unit, and aqueous foaming resin is selected from polyacrylic acid and/or polyurethane.
Step 1 in the present invention) in, the consumption of raw material in printing layer can select in wide scope, but so that prepared wallpaper has more excellent fastness, scrubbing resistance, moistureproof and anti-mildew characteristic;Preferably, with print layer gross weight for benchmark, polyacrylic content is 90-95 weight %, and the content of pigment agent is 5-10 weight %.
Step 1 in the present invention) in, polyacrylic weight average molecular weight can select in wide scope, but so that the wallpaper prepared has more excellent fastness, scrubbing resistance, moistureproof and anti-mildew characteristic;Preferably, polyacrylic weight average molecular weight is 500-1500.
Step 1 in the present invention) in, mixing and drying condition can select in wide scope, but so that prepared wallpaper has more excellent fastness, scrubbing resistance, moistureproof and anti-mildew characteristic;Preferably, in step 1) in, mixing at least meets the following conditions: mixing temperature is 15-35 DEG C, and incorporation time is 5-30min;Dry and at least meet the following conditions: baking temperature is 120-200 DEG C, and drying time is 0.5-2min.
Step 1 in the present invention) in, the thickness of basic unit and printing layer can select in wide scope, but so that prepared wallpaper has more excellent fastness, scrubbing resistance, moistureproof and anti-mildew characteristic;Preferably, the thickness of basic unit is 20-30 silk, and the thickness of printing layer is 1-5 silk.
Step 2 in the present invention) in, the consumption of the raw material of process layer can select in wide scope, but so that the wallpaper prepared has more excellent fastness, scrubbing resistance, moistureproof and anti-mildew characteristic;Preferably, relative to the aqueous foaming resin of 100 weight portions, the consumption of foaming agent is 5-15 weight portion, and levelling agent consumption is 0.5-1.5 weight portion, and stabilizing agent dosage is 1-2 weight portion.
Step 2 in the present invention) in, the weight average molecular weight of aqueous foaming resin can select in wide scope, but so that the wallpaper prepared has more excellent fastness, scrubbing resistance, moistureproof and anti-mildew characteristic;Preferably, the weight average molecular weight of aqueous foaming resin is 1000-3500.
Step 2 in the present invention) in, the kind of foaming agent, levelling agent and stabilizer can select in wide scope, but so that the wallpaper prepared has more excellent fastness, scrubbing resistance, moistureproof and anti-mildew characteristic;Preferably, foaming agent selected from 1-benzoyl-2-to Methyl benzenesulfonyl hydrazine, 1-to toluyl-2-benzene sulfonyl hydrazide, 1-chlorobenzoyl-2-to one or more in Methyl benzenesulfonyl hydrazine and 1-chlorobenzoyl-2-benzene sulfonyl hydrazide;Levelling agent is selected from one or more in silicone oil, polydimethylsiloxane, Lauxite and melamine resin;Stabilizer is selected from one or more in methyl phosphite, phosphorous acid ethyl ester, epoxy soybean oil, tetramethylolmethane, xylitol and mannitol.
Step 2 in the present invention) in, mixing, foaming, solidify and dry kind can select in wide scope, but so that prepared wallpaper has more excellent fastness, scrubbing resistance, moistureproof and anti-mildew characteristic;Preferably, mixing at least meets the following conditions: mixing temperature is 15-35 DEG C, and incorporation time is 0.5-1h;Foaming at least meets the following conditions: blowing temperature is 170-190 DEG C, and foamed time is 0.5-1h;Solidify and at least meet the following conditions: solidification temperature is 120-150 DEG C, and hardening time is 5-10min;Dry and at least meet the following conditions: baking temperature is 120-180 DEG C, and drying time is 5-10min.
Step 2 in the present invention) in, the thickness of process layer can select in wide scope, but so that the wallpaper prepared has more excellent fastness, scrubbing resistance, moistureproof and anti-mildew characteristic;Preferably, the thickness of process layer is 25-45 silk.
In order to improve the performance attractive in appearance of this wallpaper further, it is preferable that this preparation method also includes: in step 2) after, implant decorative layer at process layer, decorative layer is selected from one or more in embroidery layer, embossed layers and flannelette layer.
In the above-described embodiment, the thickness of decorative layer can select in wide scope, but so that the wallpaper prepared has more excellent fastness, scrubbing resistance, moistureproof and anti-mildew characteristic;Preferably, the thickness of decorative layer is 20-50 silk.
Present invention also offers a kind of seamless aqueous foaming wallpaper, this is seamless, and aqueous foaming wallpaper is prepared from by above-mentioned method.
In seamless aqueous foaming wallpaper provided by the invention, the width of wallpaper can select in wide scope, but in order to realize the seamless setting of wallpaper;Preferably, the width of seamless aqueous foaming wallpaper is 2-3.5m.
Hereinafter will be described the present invention by embodiment.
Embodiment 1
1) polyacrylic acid (weight average molecular weight is 1000) is mixed 15min according to 92:8 weight ratio with pigment agent at 25 DEG C, then (thickness is 25 to be printed in basic unit, width is 3m, non-woven substrate) surface and at 170 DEG C dry 1min form printing layer (thickness is 3);
2) by aqueous foaming resin, (weight average molecular weight is 2500, polyacrylic acid), foaming agent (1-benzoyl-2-is to Methyl benzenesulfonyl hydrazine), levelling agent (silicone oil) and stabilizer (methyl phosphite) at 25 DEG C, mix 0.8h according to the weight ratio of 100:10:1:1.5, and the 0.7h that foams at 180 DEG C, be then transferred to the surface of printing layer and at 130 DEG C, solidify 8min, at 160 DEG C dry 8min formation process layer (thickness is 35) with prepared wallpaper A1.
Embodiment 2
1) polyacrylic acid (weight average molecular weight is 500) is mixed 5min according to 90:10 weight ratio with pigment agent at 15 DEG C, then (thickness is 20 to be printed in basic unit, width is 2m, Bu Zhi basic unit) surface and at 120 DEG C dry 0.5min form printing layer (thickness is 1);
2) by aqueous foaming resin, (weight average molecular weight is 1000, polyurethane), foaming agent (1-is to toluyl-2-benzene sulfonyl hydrazide), levelling agent (Lauxite) and stabilizer (epoxy soybean oil) at 15 DEG C, mix 0.5h according to the weight ratio of 100:5:0.5:1, and the 0.5h that foams at 170 DEG C, be then transferred to the surface of printing layer and at 120 DEG C, solidify 5min, at 120 DEG C dry 5min formation process layer (thickness is 25) with prepared wallpaper A2.
Embodiment 3
1) polyacrylic acid (weight average molecular weight is 1500) is mixed 30min according to 95:5 weight ratio with pigment agent at 35 DEG C, then (thickness is 30 to be printed in basic unit, width is 3.5m, papery basic unit) surface and at 200 DEG C dry 2min form printing layer (thickness is 5);
2) by aqueous foaming resin, (weight average molecular weight is 3500, polyacrylic acid), foaming agent (1-chlorobenzoyl-2-benzene sulfonyl hydrazide), levelling agent (melamine resin) and stabilizer (mannitol) at 35 DEG C, mix 1h according to the weight ratio of 100:15:1.5:2, and the 1h that foams at 190 DEG C, be then transferred to the surface of printing layer and at 150 DEG C, solidify 10min, at 180 DEG C dry 10min formation process layer (thickness is 45) with prepared wallpaper A3.
Embodiment 4
Carry out preparing wallpaper A4 according to the method for embodiment 1, institute the difference is that on process layer implantation thickness be the embroidery layer of 40.
Detection example 1
1, scrubbing resistance detection: above-mentioned wallpaper is carried out friction 10000 times by above-mentioned burlap, then observes wallpaper whether variable color.Result is that wallpaper A1-A4 does not all fade.
2, fastness detection: be placed in by above-mentioned wallpaper under the uviol lamp of 100W and irradiate 30 days, then observes wallpaper whether variable color.Result is all non-variable color of wallpaper A1-A4.
3, anti-mildew becomes detection: when above-mentioned wallpaper is placed in air humidity into 60% 30 days, then passes through microscope and observes whether wallpaper produces to go mouldy.Result is that wallpaper A1-A4 all goes mouldy.
The preferred embodiment of the present invention described in detail above; but, the present invention is not limited to the detail in above-mentioned embodiment, in the technology concept of the present invention; technical scheme can being carried out multiple simple variant, these simple variant belong to protection scope of the present invention.
It is further to note that, each concrete technical characteristic described in above-mentioned detailed description of the invention, in reconcilable situation, it is possible to be combined by any suitable mode, in order to avoid unnecessary repetition, various possible compound modes are no longer illustrated by the present invention separately.
Additionally, can also carry out combination in any between the various different embodiment of the present invention, as long as it is without prejudice to the thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (10)
1. the preparation method of a seamless aqueous foaming wallpaper, it is characterised in that including:
1) polyacrylic acid is mixed with pigment agent, be then printed in the surface of basic unit and dry formation prints layer;
2) aqueous foaming resin, foaming agent, levelling agent and stabilizer hybrid concurrency being steeped, the surface being then transferred to described printing layer carries out solidifying, drying with formation process layer;
Wherein, described basic unit is non-woven substrate, Bu Zhi basic unit or papery basic unit, and described aqueous foaming resin is selected from polyacrylic acid and/or polyurethane.
2. preparation method according to claim 1, wherein, in step 1) in, with the gross weight of described printing layer for benchmark, described polyacrylic content is 90-95 weight %, and the content of described pigment agent is 5-10 weight %;
Preferably, described polyacrylic weight average molecular weight is 500-1500.
3. preparation method according to claim 2, wherein, in step 1) in, described mixing at least meets the following conditions: mixing temperature is 15-35 DEG C, and incorporation time is 5-30min;
Described drying at least meets the following conditions: baking temperature is 120-200 DEG C, and drying time is 0.5-2min.
4. preparation method according to claim 2, wherein, in step 1) in, the thickness of described basic unit is 20-30 silk, and the thickness of described printing layer is 1-5 silk.
5. the preparation method according to any one in claim 1-4, wherein, in step 2) in, described aqueous foaming resin relative to 100 weight portions, the consumption of described foaming agent is 5-15 weight portion, described levelling agent consumption is 0.5-1.5 weight portion, and described stabilizing agent dosage is 1-2 weight portion;
Preferably, the weight average molecular weight of described aqueous foaming resin is 1000-3500.
6. preparation method according to claim 5, wherein, described foaming agent selected from 1-benzoyl-2-to Methyl benzenesulfonyl hydrazine, 1-to toluyl-2-benzene sulfonyl hydrazide, 1-chlorobenzoyl-2-to one or more in Methyl benzenesulfonyl hydrazine and 1-chlorobenzoyl-2-benzene sulfonyl hydrazide;
Described levelling agent is selected from one or more in silicone oil, polydimethylsiloxane, Lauxite and melamine resin;
Described stabilizer is selected from one or more in methyl phosphite, phosphorous acid ethyl ester, epoxy soybean oil, tetramethylolmethane, xylitol and mannitol.
7. the preparation method according to claim 5 or 6, wherein, in step 2) in, described mixing at least meets the following conditions: mixing temperature is 15-35 DEG C, and incorporation time is 0.5-1h;
Described foaming at least meets the following conditions: blowing temperature is 170-190 DEG C, and foamed time is 0.5-1h;
Described solidification at least meets the following conditions: solidification temperature is 120-150 DEG C, and hardening time is 5-10min;
Described drying at least meets the following conditions: baking temperature is 120-180 DEG C, and drying time is 5-10min.
8. preparation method according to claim 7, wherein, in step 2) in, the thickness of described process layer is 25-45 silk.
9. the preparation method according to claim 5 or 6, wherein, described preparation method also includes: in step 2) after, implant decorative layer at described process layer, described decorative layer is selected from one or more in embroidery layer, embossed layers and flannelette layer;
Preferably, the thickness of described decorative layer is 20-50 silk.
10. a seamless aqueous foaming wallpaper, it is characterised in that described seamless aqueous foaming wallpaper is prepared from by the method described in any one in claim 1-9;
Preferably, the width of described seamless aqueous foaming wallpaper is 2-3.5m.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108729298A (en) * | 2018-06-06 | 2018-11-02 | 苏州华尔美特装饰材料股份有限公司 | A kind of seamless hard wallpaper recruitment skill slurry |
CN110396870A (en) * | 2018-04-24 | 2019-11-01 | 苏州华尔美特装饰材料股份有限公司 | A kind of wallpaper aqueous slurry |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101942767A (en) * | 2010-07-28 | 2011-01-12 | 丽水市优耐克水性树脂科技有限公司 | Interior wall adornment leather and preparation method |
CN103562283A (en) * | 2011-06-01 | 2014-02-05 | 汉高股份有限及两合公司 | Process for producing foamed wallpapers |
CN103897257A (en) * | 2014-03-29 | 2014-07-02 | 浙江科翔壁纸制造有限公司 | Novel non-woven cloth wallpaper, printing sizing agent and preparation methods of non-woven cloth wallpaper and printing sizing agent |
CN204825507U (en) * | 2015-06-15 | 2015-12-02 | 浙江宏健纺织有限公司 | Seamless wall paper |
-
2016
- 2016-03-01 CN CN201610115731.XA patent/CN105714614B/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101942767A (en) * | 2010-07-28 | 2011-01-12 | 丽水市优耐克水性树脂科技有限公司 | Interior wall adornment leather and preparation method |
CN103562283A (en) * | 2011-06-01 | 2014-02-05 | 汉高股份有限及两合公司 | Process for producing foamed wallpapers |
US20140087088A1 (en) * | 2011-06-01 | 2014-03-27 | Henkel Ag & Co. Kgaa | Process for producing foamed wallpapers |
CN103897257A (en) * | 2014-03-29 | 2014-07-02 | 浙江科翔壁纸制造有限公司 | Novel non-woven cloth wallpaper, printing sizing agent and preparation methods of non-woven cloth wallpaper and printing sizing agent |
CN204825507U (en) * | 2015-06-15 | 2015-12-02 | 浙江宏健纺织有限公司 | Seamless wall paper |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110396870A (en) * | 2018-04-24 | 2019-11-01 | 苏州华尔美特装饰材料股份有限公司 | A kind of wallpaper aqueous slurry |
CN108729298A (en) * | 2018-06-06 | 2018-11-02 | 苏州华尔美特装饰材料股份有限公司 | A kind of seamless hard wallpaper recruitment skill slurry |
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