CN105713390A - PSF alloy and preparation method thereof - Google Patents

PSF alloy and preparation method thereof Download PDF

Info

Publication number
CN105713390A
CN105713390A CN201610125168.4A CN201610125168A CN105713390A CN 105713390 A CN105713390 A CN 105713390A CN 201610125168 A CN201610125168 A CN 201610125168A CN 105713390 A CN105713390 A CN 105713390A
Authority
CN
China
Prior art keywords
parts
alloy
psf
alkyl
heat stabilizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610125168.4A
Other languages
Chinese (zh)
Inventor
刘莉
王爽
邱晶
刘晓东
黄明明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Netshape Composite Materials Co Ltd
Original Assignee
Suzhou Netshape Composite Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Netshape Composite Materials Co Ltd filed Critical Suzhou Netshape Composite Materials Co Ltd
Priority to CN201610125168.4A priority Critical patent/CN105713390A/en
Publication of CN105713390A publication Critical patent/CN105713390A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/06—Polysulfones; Polyethersulfones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/9258—Velocity
    • B29C2948/9259—Angular velocity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses PSF alloy and a preparation method thereof. PSF, PET, PP, PTT, ABS, alkyl formamide diphenyl phosphate, paraffin, PPS, organic montmorilonite, PS and heat stabilizer are weighed according to the weight part ratio. The product has the tensile strength of 45-65 MPa and the elongation of 20-60%. The product is resistant to high temperature, and the vicat softening point is 170-190 DEG C. The product strength is high, the impact strength is 220-260 J/m. Viscosity is 1.1-1.5 Pa.s. Cost is low, and operation is easy.

Description

A kind of PSF alloy and preparation method thereof
Technical field
The application belongs to plastic alloy material field, particularly relates to a kind of PSF alloy and preparation method thereof.
Background technology
Plastic alloy be to utilize physical blending or the method for chemical graft and obtain high-performance, functionalization, a class new material of customizations.Plastic alloy product can be widely used for the fields such as automobile, electronics, precision instrument, office equipment, packaging material, construction material.It can improve or improve the performance of existing plastics and reduce cost, it has also become one of kind the most active in plastics industry, increases the rapidest.China's plastic industry to be got a clear understanding of the situation, and finds gap accurately, seizes the opportunity, and strengthens input in science and technology, accelerates development Plastics Industry, world development level of emulating.
General-purpose plastics alloy, if pvc (polrvinyl chloride), PE (polyethylene), PP (polypropylene), PS (polystyrene) are although alloy still has use value widely, but because its production technology is generally grasped, so abroad, mostly what each major company supplied specially is the engineering plastic alloy kind that added value is higher.Engineering plastic alloy refers to the blend of engineering plastics (resin), mainly include based on the co-mixing system of the engineering plastics such as PC, PBT, PA, POM (polyformaldehyde), PPO, PTFE (politef), and ABS resin is material modified.
PC/ABS resin, Merlon and acrylonitrile-butadiene-styrene copolymer and mixture, it is by Merlon (Polycarbonate) and the thermoplastic plastic rubber of polyacrylonitrile (ABS) alloy, combine the excellent specific property of bi-material, the mouldability of ABS material and the character such as the mechanicalness of PC, impact strength and heatproof, uvioresistant (UV), can be widely used on automotive interior parts, business machine, the communication apparatus, electrical home appliances and luminaire.
The maximum user of world's plastic alloy product is automobile component at present, next to that both mechanically and electrically components and parts.It can be seen that automotive plastic alloy accounts for 62% from Japan's major project plastic alloy demand structure, electric and business automation equipment accounts for 20%, and general precision optical machinery accounts for 6%, medical treatment, physical culture and other account for 12%.From the point of view of area, current North America is maximum plastic alloy consumption area, accounts for 45%；Next to that European, account for 34%；The Asia-pacific region accounts for 21%.In North America, PPO(polyphenylene oxide) alloy accounts for more than the 25% of plastic alloy total demand, the most especially with PPO/PA(polyamide), the having the call of PPO/PET (polyethylene terephthalate) and PPO/PBT (polybutylene terephthalate (PBT)) alloy；PC (Merlon) alloy accounts for more than the 12% of aggregate demand；ABS for automobile final use accounts for 99%.
China is to the research of plastic alloy from the sixties in 20th century, and development is very fast in recent years.According to statistics, total quantity consumed is about 1,200,000～1,400,000 tons to current China plastic alloy (containing modified resin), and domestic supply amount is less than 600,000 tons, and annual import volume is up to about 900,000 tons；And China's plastic alloy (mainly blending resin and modified resin) is mainly used in household electrical appliances, electronics, automobile and other industries, compared with developed countries, the plastic alloy application market of China also has the biggest expanding space.
Along with China's sustained and rapid development of economy, a few years from now on China plastic alloy market demand potential is huge, especially the rapid growth of telecommunications, automobile, building industry, pulls on China's engineering plastic alloy industry fast-developing.Expecting 2008, China five large-engineering plastics aggregate demand is up to 1,000,000 tons, and the demand of five big synthetic resin is up to 52,000,000 tons, will become one of maximum importer of whole world plastic alloy.
At present, China's plastic alloy research and production two aspects, all also in fragmentary scattered state, not yet form scale, and industry integral level is low, differs greatly with Foreign Advanced Lerel.In Plastics in China alloy production breed structure, the production of the special engineering plastics alloy of high added value is nearly at blank, is substantially the production of general-purpose plastics alloy and modified product.Existing 300 Duo Jia plastic alloy manufacturing enterprises of China in 2004, estimate that plastic alloy (containing modified pellet) production capacity is 700,000～800,000 tons/year, and yield is at about 600,000 tons/year.But larger enterprise only accounts for 15%, and this enterprise production of 15% accounts for more than the 70% of whole nation plastic alloy total output.Enterprise's major part is to be produced the Processing Firm of plastic alloy by plastic milling expressing technique.China's plastic alloy research and development and processing technique level have much room for improvement.And popularizing along with humanity concept, and the composition of novel harmonious society, a kind of intensity PSF alloy high, resistant to elevated temperatures of design and preparation method thereof is very important.
Summary of the invention
Solve the technical problem that:
The application is for above-mentioned technical problem, it is provided that a kind of PSF alloy and preparation method thereof, solves the technical problems such as existing plastic alloy material hot strength low, impact strength is low, non-refractory.
Technical scheme:
A kind of PSF alloy, the raw materials by weight portion proportioning of described PSF alloy is as follows: PSF100 part；PET25-45 part；PP5-25 part；PTT10-30 part；ABS15-35 part；Alkyl first diphenyl phosphite 0.2-0.6 part；Paraffin 5-25 part；PPS1-5 part；Organo montmorillonite 4-8 part；PS is 1.5-3.5 part；Heat stabilizer 5-25 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described PSF alloy is as follows: PSF100 part；PET30 part；PP10 part；PTT15 part；ABS20 part；Alkyl first diphenyl phosphite 0.3 part；10 parts of paraffin；PPS2 part；Organo montmorillonite 5 parts；PS is 2 parts；Heat stabilizer 10 parts.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described PSF alloy is as follows: PSF100 part；PET40 part；PP20 part；PTT20 part；ABS25 part；Alkyl first diphenyl phosphite 0.4 part；20 parts of paraffin；PPS4 part；Organo montmorillonite 7 parts；PS is 3 parts；Heat stabilizer 20 parts.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described PSF alloy is as follows: PSF100 part；PET35 part；PP15 part；PTT20 part；ABS25 part；Alkyl first diphenyl phosphite 0.4 part；15 parts of paraffin；PPS3 part；Organo montmorillonite 6 parts；PS is 2.5 parts；Heat stabilizer 15 parts.
As a preferred technical solution of the present invention: described heat stabilizer uses tribasic lead sulfate or dibasic lead phosphite.
As a preferred technical solution of the present invention: the preparation method of described PSF alloy, comprise the steps:
The first step: weigh PSF, PET, PP, PTT, ABS, alkyl first diphenyl phosphite, alkyl first diphenyl phosphite, PPS, organo montmorillonite, PS and heat stabilizer according to parts by weight proportioning；
Second step: raw material putting into blender mixing, is warming up to 50-70 DEG C, mixing velocity is 60-80r/min, mixes 1-3h；
3rd step: put into double screw extruder after mix homogeneously, barrel temperature 210-220 DEG C, 215-225 DEG C, 220-230 DEG C, 225-235 DEG C, 225-235 DEG C, extruder temperature 225-235 DEG C, head temperature 230-240 DEG C, 245-255 DEG C, 245-255 DEG C, 260-265 DEG C, 260-270 DEG C, screw speed 12-16r/min, feed intake rotating speed 20-40 r/min。
Beneficial effect:
A kind of PSF alloy of the present invention and preparation method thereof uses above technical scheme compared with prior art, has following technical effect that 1, product hot strength 45-65MPa, percentage elongation 20-60%；2, product is high temperature resistant, Vicat softening point 170-190 DEG C；3, product strength is high, impact strength 220-260J/m；4, viscosity 1.1-1.5Pa s, with low cost, simple to operate, can be with the widespread production not division of history into periods for current material.
Detailed description of the invention
Embodiment 1:
PSF100 part is weighed according to parts by weight proportioning；PET25 part；PP5 part；PTT10 part；ABS15 part；Alkyl first diphenyl phosphite 0.2 part；5 parts of paraffin；PPS1 part；Organo montmorillonite 4 parts；PS is 1.5 parts；Dibasic lead phosphite 5 parts.
Raw material putting into blender mixing, is warming up to 50 DEG C, mixing velocity is 60r/min, mixes 1h.
Putting into double screw extruder after mix homogeneously, barrel temperature 210 DEG C, 215 DEG C, 220 DEG C, 225 DEG C, 225 DEG C, extruder temperature 225 DEG C, head temperature 230 DEG C, 245 DEG C, 245 DEG C, 260 DEG C, 260 DEG C, screw speed 12r/min, feed intake rotating speed 20 r/min.
Product hot strength 45MPa, percentage elongation 20%；Product is high temperature resistant, Vicat softening point 170 DEG C；Product strength is high, impact strength 220J/m；Viscosity 1.1Pa s, with low cost, simple to operate.
Embodiment 2:
PSF100 part is weighed according to parts by weight proportioning；PET45 part；PP25 part；PTT30 part；ABS35 part；Alkyl first diphenyl phosphite 0.6 part；25 parts of paraffin；PPS5 part；Organo montmorillonite 8 parts；PS is 3.5 parts；Dibasic lead phosphite 25 parts.
Raw material putting into blender mixing, is warming up to 70 DEG C, mixing velocity is 80r/min, mixes 3h.
Putting into double screw extruder after mix homogeneously, barrel temperature 220 DEG C, 225 DEG C, 230 DEG C, 235 DEG C, 235 DEG C, extruder temperature 235 DEG C, head temperature 240 DEG C, 255 DEG C, 255 DEG C, 265 DEG C, 270 DEG C, screw speed 16r/min, feed intake rotating speed 40 r/min.
Product hot strength 50MPa, percentage elongation 30%；Product is high temperature resistant, Vicat softening point 175 DEG C；Product strength is high, impact strength 230J/m；Viscosity 1.2Pa s, with low cost, simple to operate.
Embodiment 3:
PSF100 part is weighed according to parts by weight proportioning；PET30 part；PP10 part；PTT15 part；ABS20 part；Alkyl first diphenyl phosphite 0.3 part；10 parts of paraffin；PPS2 part；Organo montmorillonite 5 parts；PS is 2 parts；Dibasic lead phosphite 10 parts.
Raw material putting into blender mixing, is warming up to 60 DEG C, mixing velocity is 70r/min, mixes 2h.
Putting into double screw extruder after mix homogeneously, barrel temperature 210 DEG C, 215 DEG C, 220 DEG C, 225 DEG C, 225 DEG C, extruder temperature 225 DEG C, head temperature 230 DEG C, 245 DEG C, 245 DEG C, 260 DEG C, 260 DEG C, screw speed 12r/min, feed intake rotating speed 20 r/min.
Product hot strength 55MPa, percentage elongation 40%；Product is high temperature resistant, Vicat softening point 180 DEG C；Product strength is high, impact strength 240J/m；Viscosity 1.3Pa s, with low cost, simple to operate.
Embodiment 4:
PSF100 part is weighed according to parts by weight proportioning；PET40 part；PP20 part；PTT20 part；ABS25 part；Alkyl first diphenyl phosphite 0.4 part；20 parts of paraffin；PPS4 part；Organo montmorillonite 7 parts；PS is 3 parts；Tribasic lead sulfate 20 parts.
Raw material putting into blender mixing, is warming up to 70 DEG C, mixing velocity is 80r/min, mixes 3h.
Putting into double screw extruder after mix homogeneously, barrel temperature 220 DEG C, 225 DEG C, 230 DEG C, 235 DEG C, 235 DEG C, extruder temperature 235 DEG C, head temperature 240 DEG C, 255 DEG C, 255 DEG C, 265 DEG C, 270 DEG C, screw speed 16r/min, feed intake rotating speed 40 r/min.
Product hot strength 60MPa, percentage elongation 50%；Product is high temperature resistant, Vicat softening point 185 DEG C；Product strength is high, impact strength 250J/m；Viscosity 1.4Pa s, with low cost, simple to operate.
Embodiment 5:
PSF100 part is weighed according to parts by weight proportioning；PET35 part；PP15 part；PTT20 part；ABS25 part；Alkyl first diphenyl phosphite 0.4 part；15 parts of paraffin；PPS3 part；Organo montmorillonite 6 parts；PS is 2.5 parts；Tribasic lead sulfate 15 parts.
Raw material putting into blender mixing, is warming up to 60 DEG C, mixing velocity is 70r/min, mixes 2h.
Putting into double screw extruder after mix homogeneously, barrel temperature 215 DEG C, 220 DEG C, 225 DEG C, 230 DEG C, 230 DEG C, extruder temperature 230 DEG C, head temperature 235 DEG C, 250 DEG C, 250 DEG C, 260 DEG C, 265 DEG C, screw speed 14r/min, feed intake rotating speed 30 r/min.
Product hot strength 65MPa, percentage elongation 60%；Product is high temperature resistant, Vicat softening point 190 DEG C；Product strength is high, impact strength 260J/m；Viscosity 1.5Pa s, with low cost, simple to operate.
Compositions all components in above example all can be commercially available.
Above-described embodiment is only intended to be illustrated present disclosure rather than limit, therefore any change in the implication suitable with claims of the present invention and scope, is all considered as being included within the scope of the claims.

Claims (6)

1. a PSF alloy, it is characterised in that the raw materials by weight portion proportioning of described PSF alloy is as follows: PSF100 part；PET25-45 part；PP5-25 part；PTT10-30 part；ABS15-35 part；Alkyl first diphenyl phosphite 0.2-0.6 part；Paraffin 5-25 part；PPS1-5 part；Organo montmorillonite 4-8 part；PS is 1.5-3.5 part；Heat stabilizer 5-25 part.
A kind of PSF alloy the most according to claim 1, it is characterised in that described PSF alloy raw material proportioning by weight is as follows: PSF100 part；PET30 part；PP10 part；PTT15 part；ABS20 part；Alkyl first diphenyl phosphite 0.3 part；10 parts of paraffin；PPS2 part；Organo montmorillonite 5 parts；PS is 2 parts；Heat stabilizer 10 parts.
A kind of PSF alloy the most according to claim 1, it is characterised in that the raw materials by weight portion proportioning of described PSF alloy is as follows: PSF100 part；PET40 part；PP20 part；PTT20 part；ABS25 part；Alkyl first diphenyl phosphite 0.4 part；20 parts of paraffin；PPS4 part；Organo montmorillonite 7 parts；PS is 3 parts；Heat stabilizer 20 parts.
A kind of PSF alloy the most according to claim 1, it is characterised in that the raw materials by weight portion proportioning of described PSF alloy is as follows: PSF100 part；PET35 part；PP15 part；PTT20 part；ABS25 part；Alkyl first diphenyl phosphite 0.4 part；15 parts of paraffin；PPS3 part；Organo montmorillonite 6 parts；PS is 2.5 parts；Heat stabilizer 15 parts.
A kind of PSF alloy the most according to claim 1, it is characterised in that: described heat stabilizer uses tribasic lead sulfate or dibasic lead phosphite.
6. the preparation method of PSF alloy described in a claim 1, it is characterised in that comprise the steps:
The first step: weigh PSF, PET, PP, PTT, ABS, alkyl first diphenyl phosphite, alkyl first diphenyl phosphite, PPS, organo montmorillonite, PS and heat stabilizer according to parts by weight proportioning；
Second step: raw material putting into blender mixing, is warming up to 50-70 DEG C, mixing velocity is 60-80r/min, mixes 1-3h；
3rd step: put into double screw extruder after mix homogeneously, barrel temperature 210-220 DEG C, 215-225 DEG C, 220-230 DEG C, 225-235 DEG C, 225-235 DEG C, extruder temperature 225-235 DEG C, head temperature 230-240 DEG C, 245-255 DEG C, 245-255 DEG C, 260-265 DEG C, 260-270 DEG C, screw speed 12-16r/min, feed intake rotating speed 20-40 r/min.
CN201610125168.4A 2016-03-07 2016-03-07 PSF alloy and preparation method thereof Pending CN105713390A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610125168.4A CN105713390A (en) 2016-03-07 2016-03-07 PSF alloy and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610125168.4A CN105713390A (en) 2016-03-07 2016-03-07 PSF alloy and preparation method thereof

Publications (1)

Publication Number Publication Date
CN105713390A true CN105713390A (en) 2016-06-29

Family

ID=56156307

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610125168.4A Pending CN105713390A (en) 2016-03-07 2016-03-07 PSF alloy and preparation method thereof

Country Status (1)

Country Link
CN (1) CN105713390A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1432048A (en) * 2001-04-03 2003-07-23 Ge聚合物株式会社 Polymer resin for ion beam or ion injection treatment to give surface conductiveness
CN1986639A (en) * 2005-12-23 2007-06-27 中国科学院化学研究所 Thermosetting resin-base composite material and its preparing
CN101595162A (en) * 2006-11-22 2009-12-02 沙伯基础创新塑料知识产权有限公司 Make the method for polymer blend composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1432048A (en) * 2001-04-03 2003-07-23 Ge聚合物株式会社 Polymer resin for ion beam or ion injection treatment to give surface conductiveness
CN1986639A (en) * 2005-12-23 2007-06-27 中国科学院化学研究所 Thermosetting resin-base composite material and its preparing
CN101595162A (en) * 2006-11-22 2009-12-02 沙伯基础创新塑料知识产权有限公司 Make the method for polymer blend composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
黄锐等: "《塑料工程手册 上册》", 30 April 2000, 机械工业出版社 *

Similar Documents

Publication Publication Date Title
CN102532874B (en) Thermo-oxidative ageing-resistant nylon/acrylonitrile-butadiene-styrene resin mixed material
CN102775720A (en) High-impact and high-heat-resistance ABS alloy and its preparation technology
CN103387710A (en) Polypropylene/polyester alloy material, and preparation method and application thereof
CN104419106A (en) High-gloss paint spray-free scratch resistant alloy material and preparation method thereof
CN105754319A (en) Vehicle polyphenyl ether alloy material and preparation method thereof
CN103087500A (en) PA66 (polyamide 66) plastic
CN102911492B (en) Excellent-performance plastic alloy
CN105647062A (en) PVC alloy and preparation method thereof
CN105713390A (en) PSF alloy and preparation method thereof
CN102181121A (en) High-fatigue-resistance ABS (Acrylonitrile Butadiene Styrene) resin composition and preparation method thereof
CN104292802A (en) Synthetic plastic
CN105647156A (en) PPO alloy and preparation method thereof
CN104629325A (en) Low-gloss impact-resistant flame-resistant modified PC/ABS blending alloy
CN102775732A (en) Formula of composite high-performance nonmetal material
CN105273239A (en) Cellulose diacetate composite material and preparation method thereof
CN102827451B (en) High-gloss ABS master batch and preparation method thereof
CN105733073A (en) HDPE (high density polyethylene) and PET (polyethylene terephthalate) alloy and preparation method thereof
CN105566911A (en) Automobile PSF plastic alloy material and preparation method thereof
CN105542467A (en) PPS (polyphenylene sulfide) plastic alloy material for automobiles and preparation method of material
CN104327482A (en) Plastics
CN105647149A (en) PC alloy and preparation method thereof
CN105647184A (en) PPS alloy and preparation method thereof
CN105754281A (en) ABS (acrylonitrile butadiene styrene) and PVC (polyvinyl chloride) alloy and preparation method thereof
CN105733203A (en) PET alloy and preparation method thereof
CN103467933B (en) A kind of preparation method of modification polybutylene terephthalate particulate material

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20160629