CN105712793A - Special organic-inorganic blue-green alga compound fertilizer for corn and preparation method thereof - Google Patents

Special organic-inorganic blue-green alga compound fertilizer for corn and preparation method thereof Download PDF

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Publication number
CN105712793A
CN105712793A CN201610283668.0A CN201610283668A CN105712793A CN 105712793 A CN105712793 A CN 105712793A CN 201610283668 A CN201610283668 A CN 201610283668A CN 105712793 A CN105712793 A CN 105712793A
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parts
cyanophyceae
corn
blue
compound fertilizer
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李云利
毕相东
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TIANJIN LUYANG CHEMICAL FERTILIZER CO Ltd
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TIANJIN LUYANG CHEMICAL FERTILIZER CO Ltd
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Priority to CN201610283668.0A priority Critical patent/CN105712793A/en
Publication of CN105712793A publication Critical patent/CN105712793A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Fertilizers (AREA)

Abstract

The invention provides a special organic-inorganic blue-green alga compound fertilizer for corn and a preparation method thereof. The compound fertilizer comprises the following raw materials in parts by weight: 20-28 parts of blue-green alga powder, 35-46 parts of urea, 15-23 parts of monoammonium phosphate, 6-12 parts of potassium chloride, 0.5-3 parts of zinc sulfate, 0.5-1.5 parts of borax and 2-9 parts of sepiolite powder. The compound fertilizer has the advantages that the sepiolite powder is utilized as an adhesive due to adhesiveness to gain better granulation effects; the material granulation rate is high; the moisture content of the product is low, thus solving the problems that organic fertilizer products have high moisture contents and are powdered after being stored for a long time, thus being not suitable to sow by machine; the nutrient ratio of the product and abundant trace elements in the product are more suitable for the growth requirements of corn; and the product also has the effects of promoting fertilizer synergy, improving soil and improving the crop yield and quality.

Description

A kind of cyanophyceae organic and inorganic Special compound fertilizer for corn and preparation method thereof
Technical field
The invention belongs to organic-inorganic compound fertilizer technical field, especially relate to a kind of cyanophyceae organic-nothing Machine Special compound fertilizer for corn and preparation method thereof.
Background technology
Along with increasing the weight of of water body eutrophication degree, based on the cyanophyceae of Microcystis aeruginosa (Microcystis sp.) View and admire recreational lake and water supplying capability reservoir etc. frequently break out, to me in Chinese large-sized shallow lake, city State's water ecological environment causes significant damage.It is to reduce blue algae water pollution ecology disaster and reduce that salvaging processes Secondary break out the most direct effective measures of intensity.But salvage cyanophyceae landfill out or be deposited in bank for a long time Do not simply fail to effectively utilize abundant cyanophyceae organic, and the toxicity such as Algae toxins, polycyclic aromatic hydrocarbon can be produced Material, and along with the release of the harmful gass such as tool hydrogen sulfide frowzy, ammonia.At present, due to behaviour Make easy, low cost, prepare compost and efficient organic fertilizer has become the blue algae resource being most widely used Change Land use systems.
Owing in natural water, the accumulation ability of the glue sheath heavy metal ion of Cells of Blue-green Algae is very strong, preparation The blue alga organic fertilizer gone out usually causes the secondary pollution in farmland because content of beary metal exceeds standard after using, and then resistance Hinder the process efficiently utilizing cyanophyceae to prepare fertilizer.At present, the preparation process such as Blue alga compost and fertilizer In basic employing simply bank up, soak the extensive modes such as pouring and be removed, the heavy metal amount of removal is few, Organic fertilizer by this raw material production is heavily contaminated, when after incorporation of fertilizerin the soil, and noxious substance quilt Crop, accumulates in vivo, and the product of its results must produce chronic poisoning after being eaten, and seriously damages Evil human health.
Summary of the invention
In view of this, it is contemplated that propose a kind of cyanophyceae organic and inorganic Special compound fertilizer for corn and Preparation method, to meet the demand of corn growth, the problem such as pollution simultaneously solving cyanophyceae..
For reaching above-mentioned purpose, the technical scheme is that and be achieved in that:
A kind of cyanophyceae organic and inorganic Special compound fertilizer for corn, including the raw material of following parts by weight, blue Algae powder 20~28 parts;Carbamide 35~46 parts;MAP 15~23 parts;Potassium chloride 6~12 parts;Sulphuric acid Zinc 0.5~3 parts;Borax 0.5~1.5 parts;Sepiolite powder 2~9 parts.Meerschaum is a kind of natural mineral matter, Its silicone content between 50~60%, content of magnesium between 20~25%, the sepiolite powder mesh number of processing and fabricating More than 200 mesh.
Preferably, including the raw material of following parts by weight, blue algae powder 23~25 parts;Carbamide 38~43 parts; MAP 18~20 parts;Potassium chloride 8~10 parts;Zinc sulfate 1~2 parts;Borax 1 part;Sepiolite powder 4~7 parts.
Preferably, including the raw material of following parts by weight, blue algae powder 25 parts;38.5 parts of carbamide;Phosphoric acid One ammonium 19 parts;8.5 parts of potassium chloride;2 parts of zinc sulfate;Borax 1 part;Sepiolite powder 6 parts.
Preferably, including the raw material of following parts by weight, blue algae powder 23.5 parts;42.8 parts of carbamide;Phosphorus Acid one ammonium 19 parts;8.5 parts of potassium chloride;1 part of zinc sulfate;Borax 1 part;Sepiolite powder 4.2 parts.
Preferably, final products quality of organic matter content 15%, product N P and K total nutrient mass content 35%, biodiversity content 2%, and containing in the sulfur needed for corn growth, zinc, silicon, boron, magnesium Trace element.
Present invention also offers one and prepare cyanophyceae organic and inorganic Special compound fertilizer for corn as above Method, comprise the following steps:
(1) preparation of blue algae powder, comprises the steps, chelating Cells of Blue-green Algae glue sheath in heavy metal from Son, be dehydrated, ferment, dry and be dried;
(2) in granulating method compound fertilizer producing equipment, by carbamide, potassium chloride, MAP, Hai Pao Blue algae powder prepared by stone powder, zinc sulfate, Borax and step (1) enters rotary drum granulator after metering, Steam is led in the bed of material of rotary drum granulator, utilize sepiolite powder to complete material granulation mistake as binding agent Journey, in rotary drum granulator, temperature of charge controls at 60~70 DEG C, granulation time 5~7min;
(3) after pelletize, material enters drying machine, and dryer temperature controls at 110~120 DEG C, when being dried Between 30-40min;
(4) dried material enters cooling system cooling, cool time 20~30min;
(5) respectively through the screening of sieve diameter 2.0~3.0mm dusting cover and sieve diameter after material cooling 4.0~4.5mm scalping screenings, the granular material after dusting cover returns together with broken with the bulky grain after scalping Rotary drum granulator, sieves qualified certified products and enters packing machine;
(6) certified products carry out anti-caking process by packing machine, pack after feed bin stores.
Preferably, in described step (1), the preparation of blue algae powder comprises the steps,
A, in cyanophyceae, add ethylenediaminetetraacetic acid in proportion, utilize ethylenediaminetetraacetic acid chelating cyanophyceae thin Heavy metal ion in born of the same parents' glue sheath;
B, by sludge dewatering equipment by the blue algae dewatering after chelating, remove in cyanophyceae the heavy metal that contains from Sub-waste water, obtains blue-green algae residue;
C, blue-green algae residue step B prepared are put in biochemical fermentation tank, add Multifunctional fermentation strain, Complete fermentation;Preferably, described Multifunctional fermentation strain includes high yield albumen bacillus subtilis, root nodule bacteria And phosphobacteria;
D, the blue-green algae residue after fermentation is dried, dry temperature 60~80 DEG C, drying time 25~30 points Clock, makes moisture be less than 10%, obtains the blue-green algae residue being dried;
E, dried blue-green algae residue is pulverized, obtain blue algae powder.
Preferably, in described step A, cyanophyceae is 5000:1 with the mass ratio of ethylenediaminetetraacetic acid.
The present invention also provides for a kind of cyanophyceae organic and inorganic Special compound fertilizer for corn as above at Semen Maydis Application in plantation.
Present invention simultaneously provides the system of a kind of cyanophyceae organic and inorganic Special compound fertilizer for corn as above Fertilizer prepared by the Preparation Method application in corn planting.
Relative to prior art, cyanophyceae organic and inorganic Special compound fertilizer for corn of the present invention and Preparation method, has the advantage that
(1) present invention is by carrying out heavy metals removal to cyanophyceae, utilize its rich in organic production have Machine-inorganic fertilizer, makes cyanophyceae turn waste into wealth, and decreases the dye of the dye to environment.With use feces of livestock and poultry, The material production organic fertilizers such as slaughterhouse garbage are compared, and do not contain the noxious substances such as heavy metal and live body Guo Worm's ovum and escherichia coli, do not result in environmental pollution and propagate the public hazards such as human body diseases.
(2) the product moisture content 2% of the present invention, far below the national standard of moisture 12%, Therefore, product strength is high, prevented from caking, and the long time stored granule that also do not haves becomes mildewed and the asking of efflorescence Topic, it is adaptable to machinery is used.
(3) product N P and K total nutrient content 35%, machine matter content 15%, and containing corn growth Trace element in required sulfur, zinc, silicon, boron, magnesium, reaches to improve soil, improves fertilizer efficiency, make crop Volume increase, improves the effect of crop quality.Compared with other organic fertilizer, need not during use add other Inorganic fertilizer, saving of work and time, social benefit is notable.
Accompanying drawing explanation
The accompanying drawing of the part constituting the present invention is used for providing a further understanding of the present invention, the present invention's Schematic description and description is used for explaining the present invention, is not intended that inappropriate limitation of the present invention.? In accompanying drawing:
Fig. 1 is the preparation side of the cyanophyceae organic and inorganic Special compound fertilizer for corn described in the embodiment of the present invention The flow chart of method.
Detailed description of the invention
Describe the present invention below with reference to the accompanying drawings and in conjunction with the embodiments in detail.
Embodiment 1
A kind of cyanophyceae organic and inorganic Special compound fertilizer for corn, including the raw material of following parts by weight, cyanophyceae 25 parts of powder;38.5 parts of carbamide;MAP 19 parts;8.5 parts of potassium chloride;2 parts of zinc sulfate;Borax 1 part;Sepiolite powder 6 parts.
As it is shown in figure 1, concrete preparation flow:
1) adding ethylenediaminetetraacetic acid in cyanophyceae in proportion, interpolation mass ratio is 5000:1, then Blue algae dewatering after being chelated by sludge dewatering equipment, removes the effluent containing heavy metal ions contained in cyanophyceae, To blue-green algae residue, blue-green algae residue is put in biochemical fermentation tank, add Multifunctional fermentation strain, complete to send out Ferment.Blue-green algae residue after fermentation is dried, dries temperature 70 C, drying time 25 minutes, obtain water Divide the content cyanophyceae slag less than 7%, dried blue-green algae residue is pulverized, obtains blue algae powder.Described many Function fermented bacterium includes high yield albumen bacillus subtilis, root nodule bacteria and phosphobacteria.
2) 385 kilograms of carbamide (mass percent, lower same, containing N 46.2%) is added through computer metering, Powdery monoammonium phosphate is (containing N 12%, P2O553%) 190 kilograms, potassium chloride is (containing K2O 60%) 85 Kilogram, blue algae powder (containing organic 65%) 250 kilograms, sepiolite powder (containing Si, Mg element) 60 Kilogram, 20 kilograms of zinc sulfate (containing S, Zn element), Borax (containing B element) 10 kilograms, on State material to mix in rotary drum granulator, become feed liquid phasor by adding steam increase, and utilize meerschaum The peculiar tough feature of powder is as binding agent, after 6min pelletize, enters drying machine.
3) drying machine (i.e. drying system) gas inlet temperature is 110 DEG C, is dried 35min minute, Cool down after drying, straight through the screening of sieve diameter 2.5mm dusting cover and sieve aperture respectively after cooling 25min Footpath 4.5mm scalping screening, the granular material after dusting cover returns together with broken with the bulky grain after scalping Rotary drum granulator.
4) certified products enter packing machine, carry out anti-caking process, parcel, and packaging, obtaining granularity is The compound fertilizer of 2~4.5mm.
Product P Han N2O5—K2O nutrient mass-content is 20.10% 10.10% 5.10%, organic Matter mass content 16.25%, sulfur-bearing (S) zinc (Zn) magnesium (Mg) silicon (Si) boron (B) Middle trace element, biodiversity content 1.8%.
Embodiment 2
A kind of cyanophyceae organic and inorganic Special compound fertilizer for corn, including the raw material of following parts by weight, cyanophyceae 23.5 parts of powder;42.8 parts of carbamide;MAP 19 parts;8.5 parts of potassium chloride;1 part of zinc sulfate;Boron 1 part of sand;Sepiolite powder 4.2 parts.
As it is shown in figure 1, concrete preparation flow:
1) adding ethylenediaminetetraacetic acid in cyanophyceae in proportion, interpolation mass ratio is 5000:1, then Blue algae dewatering after being chelated by sludge dewatering equipment, removes the effluent containing heavy metal ions contained in cyanophyceae, To blue-green algae residue, blue-green algae residue is put in biochemical fermentation tank, add Multifunctional fermentation strain, complete to send out Ferment.Blue-green algae residue after fermentation is dried, dries temperature 70 C, drying time 25 minutes, obtain moisture The content cyanophyceae slag less than 7%, pulverizes dried blue-green algae residue, obtains blue algae powder.Described many merits High yield albumen bacillus subtilis, root nodule bacteria and phosphobacteria can be included by fermented bacterium.
2) 428 kilograms of carbamide (mass percent, lower same, containing N 46.2%) is added through computer metering, Powdery monoammonium phosphate is (containing N 12%, P2O553%) 190 kilograms, potassium chloride is (containing K2O 60%) 85 Kilogram, blue algae powder (containing organic 65%) 235 kilograms, sepiolite powder (containing Si, Mg element) 42 Kilogram, 10 kilograms of zinc sulfate (containing S, Zn element), Borax (containing B element) 10 kilograms, on State material to mix in rotary drum granulator, become feed liquid phasor by adding steam increase, and utilize meerschaum The peculiar tough feature of powder is as binding agent, after 5min pelletize, enters drying machine.
3) drying machine (i.e. drying system) gas inlet temperature is 115 DEG C, is dried 35min minute, Cool down after drying, straight through the screening of sieve diameter 2.5mm dusting cover and sieve aperture respectively after cooling 25min Footpath 4.5mm scalping screening, the granular material after dusting cover returns together with broken with the bulky grain after scalping Rotary drum granulator.
4) certified products enter packing machine, carry out anti-caking process, parcel, and packaging, obtaining granularity is 2 The compound fertilizer of 4.5mm.
Product P Han N2O5—K2O nutrient mass-content is 22.10% 10.10% 5.10%, organic Matter mass content 15.27%, sulfur-bearing (S) zinc (Zn) magnesium (Mg) silicon (Si) boron (B) Middle trace element, biodiversity content 1.9%.
The foregoing is only the preferred embodiment of the invention, not in order to limit the invention, Within all spirit in the invention and principle, any modification, equivalent substitution and improvement etc. made, Within should be included in the protection domain of the invention.

Claims (10)

1. a cyanophyceae organic and inorganic Special compound fertilizer for corn, it is characterised in that: include following weight The raw material of amount number, blue algae powder 20~28 parts;Carbamide 35~46 parts;MAP 15~23 parts;Chlorination Potassium 6~12 parts;Zinc sulfate 0.5~3 parts;Borax 0.5~1.5 parts;Sepiolite powder 2~9 parts.
Cyanophyceae organic and inorganic Special compound fertilizer for corn the most according to claim 1, its feature exists In: include the raw material of following parts by weight, blue algae powder 23~25 parts;Carbamide 38~43 parts;MAP 18~20 parts;Potassium chloride 8~10 parts;Zinc sulfate 1~2 parts;Borax 1 part;Sepiolite powder 4~7 parts.
Cyanophyceae organic and inorganic Special compound fertilizer for corn the most according to claim 1, its feature exists In: include the raw material of following parts by weight, blue algae powder 25 parts;38.5 parts of carbamide;MAP 19 Part;8.5 parts of potassium chloride;2 parts of zinc sulfate;Borax 1 part;Sepiolite powder 6 parts.
Cyanophyceae organic and inorganic Special compound fertilizer for corn the most according to claim 1, its feature exists In: include the raw material of following parts by weight, blue algae powder 23.5 parts;42.8 parts of carbamide;MAP 19 Part;8.5 parts of potassium chloride;1 part of zinc sulfate;Borax 1 part;Sepiolite powder 4.2 parts.
5. according to the cyanophyceae organic and inorganic Special compound fertilizer for corn described in any one of Claims 1 to 4, It is characterized in that: final products quality of organic matter content 15%, product N P and K total nutrient mass content 35%, biodiversity content 2%, and containing in the sulfur needed for corn growth, zinc, silicon, boron, magnesium Trace element.
6. prepare special according to the cyanophyceae organic and inorganic Semen Maydis as described in any one of Claims 1 to 5 for one kind The method of compound fertilizer, it is characterised in that comprise the following steps:
(1) preparation of blue algae powder, comprises the steps, chelating Cells of Blue-green Algae glue sheath in heavy metal from Son, be dehydrated, ferment, dry and be dried;
(2) in granulating method compound fertilizer producing equipment, by carbamide, potassium chloride, MAP, Hai Pao Blue algae powder prepared by stone powder, zinc sulfate, Borax and step (1) enters rotary drum granulator after metering, Steam is led in the bed of material of rotary drum granulator, utilize sepiolite powder to complete material granulation mistake as binding agent Journey, in rotary drum granulator, temperature of charge controls at 60~70 DEG C, granulation time 5~7min;
(3) after pelletize, material enters drying machine, and dryer temperature controls at 110~120 DEG C, when being dried Between 30-40min;
(4) dried material enters cooling system cooling, cool time 20~30min;
(5) respectively through the screening of sieve diameter 2.0~3.0mm dusting cover and sieve diameter after material cooling 4.0~4.5mm scalping screenings, the granular material after dusting cover returns together with broken with the bulky grain after scalping Rotary drum granulator, sieves qualified certified products and enters packing machine;
(6) certified products carry out anti-caking process by packing machine, pack after feed bin stores.
The preparation method of cyanophyceae organic and inorganic Special compound fertilizer for corn the most according to claim 6, It is characterized in that: in described step (1), the preparation of blue algae powder comprises the steps,
A, in cyanophyceae, add ethylenediaminetetraacetic acid in proportion, utilize ethylenediaminetetraacetic acid chelating cyanophyceae thin Heavy metal ion in born of the same parents' glue sheath;
B, by sludge dewatering equipment by the blue algae dewatering after chelating, remove in cyanophyceae the heavy metal that contains from Sub-waste water, obtains blue-green algae residue;
C, blue-green algae residue step B prepared are put in biochemical fermentation tank, add Multifunctional fermentation strain, Complete fermentation;Described Multifunctional fermentation strain includes that high yield albumen bacillus subtilis, root nodule bacteria and phosphorus are thin Bacterium;
D, the blue-green algae residue after fermentation is dried, dry temperature 60~80 DEG C, drying time 25~30 points Clock, makes moisture be less than 10%, obtains the blue-green algae residue being dried;
E, dried blue-green algae residue is pulverized, obtain blue algae powder.
The preparation method of cyanophyceae organic and inorganic Special compound fertilizer for corn the most according to claim 7, It is characterized in that: in described step A, cyanophyceae is 5000:1 with the mass ratio of ethylenediaminetetraacetic acid.
9. exist according to the cyanophyceae organic and inorganic Special compound fertilizer for corn described in any one of Claims 1 to 5 Application in corn planting.
10. according to the cyanophyceae organic and inorganic Special compound fertilizer for corn described in any one of claim 6~8 The application in corn planting of the fertilizer prepared of preparation method.
CN201610283668.0A 2016-04-28 2016-04-28 Special organic-inorganic blue-green alga compound fertilizer for corn and preparation method thereof Pending CN105712793A (en)

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