CN105696338A - Finishing agent for preparing self-cleaning fabric - Google Patents
Finishing agent for preparing self-cleaning fabric Download PDFInfo
- Publication number
- CN105696338A CN105696338A CN201610153564.8A CN201610153564A CN105696338A CN 105696338 A CN105696338 A CN 105696338A CN 201610153564 A CN201610153564 A CN 201610153564A CN 105696338 A CN105696338 A CN 105696338A
- Authority
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- China
- Prior art keywords
- finishing agent
- fabric
- cleaning
- preparing self
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000004744 fabric Substances 0.000 title claims abstract description 38
- 238000004140 cleaning Methods 0.000 title claims abstract description 36
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 30
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003822 epoxy resin Substances 0.000 claims abstract description 5
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 5
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 5
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 5
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 8
- 238000005516 engineering process Methods 0.000 claims description 5
- 108090000371 Esterases Proteins 0.000 claims description 4
- 125000003368 amide group Chemical group 0.000 claims description 4
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 4
- 229920001400 block copolymer Polymers 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 4
- 230000007850 degeneration Effects 0.000 claims description 4
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 4
- 230000001804 emulsifying effect Effects 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- 239000003002 pH adjusting agent Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 239000000080 wetting agent Substances 0.000 claims description 4
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims description 3
- 238000002074 melt spinning Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 238000009987 spinning Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 229920001577 copolymer Polymers 0.000 abstract 1
- DGLRDKLJZLEJCY-UHFFFAOYSA-L disodium hydrogenphosphate dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].OP([O-])([O-])=O DGLRDKLJZLEJCY-UHFFFAOYSA-L 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000004816 latex Substances 0.000 abstract 1
- 229920000126 latex Polymers 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 abstract 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 abstract 1
- 229960002796 polystyrene sulfonate Drugs 0.000 abstract 1
- 239000011970 polystyrene sulfonate Substances 0.000 abstract 1
- 230000002940 repellent Effects 0.000 abstract 1
- 239000005871 repellent Substances 0.000 abstract 1
- 239000004753 textile Substances 0.000 description 7
- 230000003373 anti-fouling effect Effects 0.000 description 6
- 239000002689 soil Substances 0.000 description 6
- 239000000428 dust Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004531 microgranule Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000010415 tidying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/248—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing chlorine
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
- D06M11/71—Salts of phosphoric acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
- D06M11/82—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/07—Cellulose esters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/01—Stain or soil resistance
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to a finishing agent for preparing self-cleaning fabric. The finishing agent is prepared from, by weight, 70-85 parts of polyvinyl chloride latex, 20-33 parts of a polyoxyethylene-polyoxypropylene segmented copolymer, 11-16 parts of epoxy resin, 4-10 parts of nanometer titanium oxide, 3-5 parts of sodium phosphate dibasic dodecahydrate, 2-6 parts of polystyrene sulfonate ester and the like. The finishing agent has the advantages that a layer structure combining a micrometer structure and a nanometer structure is generated on the surface of the fabric by carrying out co-blending spinning or chemical treatment with the finishing agent, the roughness of the surface of the fabric is improved, and thus the self-cleaning performance and the water and oil repellent performance of the fabric are greatly improved.
Description
Technical field
The present invention relates to fibre self-cleaning finishing reagent, be specially a kind of finishing agent for preparing Self-cleaning fabric。
Background technology
Dirt on fabric includes water solublity dirt, oily pollutant and dust。Water solublity dirt, oily pollutant are due to dress ornament and human contact's absorption, or are caused contamination by external oils and fats (food oil or machine wet goods)；Dust produces mainly due to electrostatic interaction。Antifouling and easy decontamination is two different concepts, has again the contact of inherence between the two。Textile in use can stain gradually, antifouling refers to that clothing textile in use will not be caused contamination by water-based soils and the moistening of oily dirt institute, without because the dry dust of Electrostatic Absorption or microgranule are in fiber or fabric face。The arrangement that textile has antifouling property is made to be called soil resistant finish。
Easy decontamination refer to fabric once stain after, dirt is easily cleaned under normal wash conditions, and fabric will not adsorb the dirt in cleaning mixture in cleaning mixture and graying (namely wash the dirt got off from fabric, other positions of fabric are transferred to by cleaning mixture, this phenomenon is called wet recontamination, and in repeated washing, wet recontamination has summation)。The arrangement that textile has soil release performance energy is made to be called soil-releasing finiss。
The textile with antifouling and easy dirt-removing functions has self-cleaning function, had namely both had and has not easily stain, and had and for example been stained with greasy dirt without detergent, rinses with water。Corresponding finishing agent appellation self-cleaning finishing agent。For wearing fabric is come, particularly underwear, vest etc., often to wash, the appearance style of meeting heavy damage fabric, application Final finishing technology gives its self-cleaning function, it is possible to resolve this difficult problem, meets the requirement of consumer。But by antifouling and easy decontamination dual-use function unification to same finishing agent, and having good stability, degree-of-difficulty factor is bigger。
When nano inorganic self-cleaning finishing agent can make dress ornament run into dirt, only little a part of spot can be adsorbed onto on fabric, through certain photocatalytic self-cleaning effect, it is possible to this sub-fraction spot is thoroughly removed。It addition, the noxious bacteria for fabric can also decompose so that it is keep cleaning。But the inorganic finishing agent of highly concentrated nano disperses and is applied to technically have many difficulty, simultaneously soil resistance particularly dust tightness has relatively larger ageing, namely its self-cleaning function can reduce along with the lengthening model of Time of Administration, but adds organic finishing agent in cleaning system, it is possible to makes up this problem。Therefore, combine organic and inorganic composite self-cleaning finishing agent, there is important using value。
Summary of the invention
For the deficiencies in the prior art, what the present invention intended to solve technical problem is that a kind of finishing agent for preparing Self-cleaning fabric, and this combination cleaning and tidying agent has the effects such as better stability, function are strong, it is simple to meet the needs of the high-grade automatically cleaning textile of exploitation。By this finishing agent co-blended spinning or carry out chemical treatment and make its surface produce the hierarchical structure that combines with nanostructured of micrometer structure, the roughness of raising fabric face, the self-cleaning property of fabric and water and oil repellant performance is made to increase substantially。
The technical solution adopted in the present invention is: a kind of finishing agent for preparing Self-cleaning fabric, is made up of the raw material of following parts by weight:
Polyvinyl chloride emulsion 70-85,
Polyox-yethylene-polyoxypropylene block copolymer 20-33,
Epoxy resin 11-16,
Nano titanium oxide 4-10,
Disodium hydrogen phosphate 3-5,
PSS 2-6,
Cellulose esters 3-10,
Butyl benzyl phthalate 5-15,
Barium stearate 1-5,
Diboron trioxide 10-20,
Silicon dioxide 0.5-3,
Defoamer 0.2-0.5,
PH adjusting agent 0.8-1.5,
Coco betaine 1-2,
Emulsifying wetting agent 0.3-1,
Degeneration amido organosilicon 2-3,
Esterase 0.4-2。
Further, this finishing agent can also include erucyl amide 0.5-2 part。
Further, the particle diameter of described nano titanium oxide is all between 80-120nm。
Further, the described finishing agent for preparing Self-cleaning fabric can prepare functional fabric by melt-spinning technology。
Beneficial effects of the present invention:
(1) this finishing agent being used for preparing Self-cleaning fabric has good stability, repeatability；
(2) in fibre is applied, there is good waterproof, antifouling and soil release performance；
(3) needs developing various fiber top grade automatically cleaning rib-loop knitwear are met。
Detailed description of the invention
By the examples below, technical scheme is described in further detail。
Embodiment one:
A kind of finishing agent for preparing Self-cleaning fabric, is made up of the raw material of following parts by weight:
Polyvinyl chloride emulsion 70
Polyox-yethylene-polyoxypropylene block copolymer 20
Epoxy resin 11
Nano titanium oxide 4
Disodium hydrogen phosphate 3
PSS 2
Cellulose esters 3
Butyl benzyl phthalate 5
Barium stearate 1
Diboron trioxide 10
Silicon dioxide 0.5
Defoamer 0.2
PH adjusting agent 0.8
Coco betaine 1
Emulsifying wetting agent 0.3
Degeneration amido organosilicon 2
Esterase 0.4
Erucyl amide 0.5 part。
The particle diameter of described nano titanium oxide is all between 80-120nm。
The above-mentioned finishing agent for preparing Self-cleaning fabric prepares functional fabric by melt-spinning technology further。
Embodiment two:
A kind of finishing agent for preparing Self-cleaning fabric, is made up of the raw material of following parts by weight:
Polyvinyl chloride emulsion 85,
Polyox-yethylene-polyoxypropylene block copolymer 33,
Epoxy resin 16,
Nano titanium oxide 10,
Disodium hydrogen phosphate 5,
PSS 6,
Cellulose esters 10,
Butyl benzyl phthalate 15,
Barium stearate 5,
Diboron trioxide 20,
Silicon dioxide 3,
Defoamer 0.5,
PH adjusting agent 1.5,
Coco betaine 2,
Emulsifying wetting agent 1,
Degeneration amido organosilicon 3,
Esterase 0.4-2。
The particle diameter of described nano titanium oxide is all between 80-120nm。
The arrangement of automatically cleaning textile:
Fabric is being padded process, pressure 2.5kg/cm in the impregnation liquid containing the above-mentioned finishing agent for preparing Self-cleaning fabric2, liquid carrying rate 60%, by fabric constant temperature 1 hour between 130 DEG C after drying。
The above; it is only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope that disclosed herein; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention。Therefore, protection scope of the present invention should be as the criterion with claims protection defined。
Claims (4)
1. the finishing agent being used for preparing Self-cleaning fabric, it is characterised in that be made up of the raw material of following parts by weight:
Polyvinyl chloride emulsion 70-85,
Polyox-yethylene-polyoxypropylene block copolymer 20-33,
Epoxy resin 11-16,
Nano titanium oxide 4-10,
Disodium hydrogen phosphate 3-5,
PSS 2-6,
Cellulose esters 3-10,
Butyl benzyl phthalate 5-15,
Barium stearate 1-5,
Diboron trioxide 10-20,
Silicon dioxide 0.5-3,
Defoamer 0.2-0.5,
PH adjusting agent 0.8-1.5,
Coco betaine 1-2,
Emulsifying wetting agent 0.3-1,
Degeneration amido organosilicon 2-3,
Esterase 0.4-2。
2. a kind of finishing agent for preparing Self-cleaning fabric according to claim 1, it is characterised in that: this finishing agent can also include erucyl amide 0.5-2 part。
3. a kind of finishing agent for preparing Self-cleaning fabric according to claim 1 and 2, it is characterised in that: the particle diameter of described nano titanium oxide is all between 80-120nm。
4. the application in preparing functional fabric of a kind of finishing agent for preparing Self-cleaning fabric according to claim 1-3, it is characterised in that: the described finishing agent for preparing Self-cleaning fabric can prepare functional fabric by melt-spinning technology。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610153564.8A CN105696338A (en) | 2016-03-17 | 2016-03-17 | Finishing agent for preparing self-cleaning fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610153564.8A CN105696338A (en) | 2016-03-17 | 2016-03-17 | Finishing agent for preparing self-cleaning fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105696338A true CN105696338A (en) | 2016-06-22 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610153564.8A Pending CN105696338A (en) | 2016-03-17 | 2016-03-17 | Finishing agent for preparing self-cleaning fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105696338A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103397513A (en) * | 2013-07-04 | 2013-11-20 | 上海工程技术大学 | Nano-titanium dioxide sol finishing agent prepared at low temperature and application thereof |
| CN103952792A (en) * | 2014-04-18 | 2014-07-30 | 安徽省中日农业环保科技有限公司 | Anti-static moxa leaf fiber fabric with magnetic permeability and preparation method thereof |
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Application publication date: 20160622 |