CN105694673A - High-toughness high-strength antirust powder paint - Google Patents
High-toughness high-strength antirust powder paint Download PDFInfo
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- CN105694673A CN105694673A CN201610183837.3A CN201610183837A CN105694673A CN 105694673 A CN105694673 A CN 105694673A CN 201610183837 A CN201610183837 A CN 201610183837A CN 105694673 A CN105694673 A CN 105694673A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/103—Anti-corrosive paints containing metal dust containing Al
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-toughness high-strength antirust powder paint which is prepared from the following raw materials in parts by weight: 35-45 parts of bisphenol A epoxy resin, 17-20 parts of polyester resin, 18-22 parts of fluorine-containing hydrophobic material, 8-10 parts of novolac epoxy resin, 7-10 parts of nano silicon dioxide, 5-7 parts of talcum powder, 2-4 parts of carbon black, 3-5 parts of polyvinyl alcohol, 2-8 parts of titanium white, 3-6 parts of aluminum powder, 2-5 parts of calcium carbonate, 2-4 parts of leveling agent, 1-3 parts of curing agent, 1-2 parts of matting agent and 5-8 parts of antirust mixed pigment. The high-toughness high-strength antirust powder paint disclosed by the invention has the advantages of favorable toughness, high strength and excellent rust resistance.
Description
Technical field
The present invention relates to powder coating technology field, particularly relate to a kind of antirust powdery paints of high-toughness high-strength。
Background technology
Along with socioeconomic development, the hardwares such as various scaffolds, means of transportation, guardrail are widely used, and the anti-corrosion measure of these hardwares is essentially relying on its surface coating coating, powdery paints be exactly a kind of easy and simple to handle, pollute little high-quality coating。The coating of hardware often faces outdoor exposure, drench with rain and the effect of external force, makes coating occur bubbling, breaks, the phenomenon such as stripping, thus causing that hardware gets rusty, therefore, the toughness of paint coatings, intensity and hydrophobic antirust ability is greatly improved particularly significant。
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of antirust powdery paints of high-toughness high-strength, and good toughness, intensity are high, and possesses the rustproof property of excellence。
The antirust powdery paints of a kind of high-toughness high-strength that the present invention proposes, its raw material includes by weight: bisphenol A type epoxy resin 35-45 part, polyester resin 17-20 part, fluorine-containing hydrophobic material 18-22 part, novolac epoxy resin 8-10 part, nano silicon 7-10 part, Pulvis Talci 5-7 part, white carbon black 2-4 part, polyvinyl alcohol 3-5 part, titanium dioxide 2-8 part, aluminium powder 3-6 part, calcium carbonate 2-5 part, levelling agent 2-4 part, firming agent 1-3 part, delustering agent 1-2 part, antirust hybrid pigment 5-8 part。
Preferably, bisphenol A type epoxy resin, polyester resin, fluorine-containing hydrophobic material, novolac epoxy resin weight ratio be 38-42:18-19:19-21:8.5-9。
Preferably, its raw material includes by weight: bisphenol A type epoxy resin 38-42 part, polyester resin 18-19 part, fluorine-containing hydrophobic material 19-21 part, novolac epoxy resin 8.5-9 part, nano silicon 8-9 part, Pulvis Talci 5.5-6 part, white carbon black 3-3.5 part, polyvinyl alcohol 3.5-4.5 part, titanium dioxide 2.5-3.5 part, aluminium powder 3.5-4 part, calcium carbonate 3-4 part, levelling agent 3-3.5 part, firming agent 2-2.5 part, delustering agent 1.4-1.8 part, antirust hybrid pigment 6-7 part。
Preferably, the preparation technology of fluorine-containing hydrophobic material is as follows: put into the first process equipment after methacrylic acid 12 heptyl ester, vinyl acetate, polydimethylsiloxane, azodiisobutyronitrile mix homogeneously, is filled with carbon dioxide and carries out gas displacement in the first process equipment；Then the first process equipment is placed in water-bath, continues to be filled with carbon dioxide to the first process equipment, discharge carbon dioxide after keeping certain time and obtain material A；Material A is put in the second process equipment containing toluene, raises the second process equipment temperature, insulation, cooling, take out and obtain material B, then successively clean with methanol, deionized water, dry and obtain fluorine-containing hydrophobic material。
Preferably, the preparation technology of fluorine-containing hydrophobic material is as follows: put into the first process equipment after methacrylic acid 12 heptyl ester, vinyl acetate, polydimethylsiloxane, azodiisobutyronitrile mix homogeneously, is filled with carbon dioxide and carries out gas displacement in the first process equipment；Then being placed in 55-60 DEG C of water-bath by the first process equipment, continuing to be filled with carbon dioxide to the first process equipment internal pressure is 15.5-16.0MPa, discharges carbon dioxide and obtain material A after keeping 40-45h；Material A is put in the second process equipment containing toluene, raises the second process equipment temperature to 40-45 DEG C, be incubated 10-15min, cooling, take out and obtain material B, then successively clean with methanol, deionized water, dry and obtain fluorine-containing hydrophobic material。
Preferably, the preparation technology of fluorine-containing hydrophobic material is as follows: puts into the first process equipment after 10-12 part methacrylic acid 12 heptyl ester, 6-8 part vinyl acetate, 3.8-4.5 part polydimethylsiloxane, 0.06-0.09 part azodiisobutyronitrile mix homogeneously by weight, is filled with carbon dioxide and carries out gas displacement in the first process equipment；Then being placed in 55-60 DEG C of water-bath by the first process equipment, continuing to be filled with carbon dioxide to the first process equipment internal pressure is 15.5-16.0MPa, discharges carbon dioxide and obtain material A after keeping 40-45h；Material A is put in the second process equipment containing toluene, raises the second process equipment temperature to 40-45 DEG C, be incubated 10-15min, cooling, take out and obtain material B, then successively clean with methanol, deionized water, dry and obtain fluorine-containing hydrophobic material。
Preferably, in the preparation technology of fluorine-containing hydrophobic material, the temperature of drying is 50-55 DEG C, and the time of drying is 40-45min。
The present invention adopts bisphenol A type epoxy resin, polyester resin, fluorine-containing hydrophobic material, novolac epoxy resin to coordinate as film forming matter, substantially increases rustless property and toughness, the intensity of the present invention, has splendid film forming characteristics；The fluorine-containing hydrophobic material that auxiliary is added is with dodecafluoroheptyl methacrylate, vinyl acetate, three kinds of monomers of polydimethylsiloxane for major ingredient, it is possible to while the hydrophobic performance of the present invention is greatly improved, and improves the strength and stability of the present invention；Three kinds of monomers, under the effect of initiator azodiisobutyronitrile, cross-link rapidly, and polymerization formation has low free energy high molecular polymer, and the C-F bond energy that it has enough fitly is arranged in film forming layer surface, make the present invention have hydrophobic, the anti-wear performance of excellence；And the supercritical carbon dioxide environment that the first process equipment of specified pressure and temperature is internally formed, it is possible to strengthen plasticization, improve the diffusion of monomer, improve the conversion ratio of polymerization rate, product purity and monomer；Material A is put in toluene, heat up and after held for some time, clean then through methanol, deionized water, it is possible to remove the overwhelming majority and have neither part nor lot in the monomer of reaction, substantially increase the yield rate of the present invention, reduce cost；Nano silicon, Pulvis Talci, white carbon black, titanium dioxide, aluminium powder, calcium carbonate interpolation, improve the volume of the present invention, reduce cost；Polyvinyl alcohol then improves the bonding force between adhesive force and each raw material of the present invention。
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail。
Embodiment 1
The antirust powdery paints of a kind of high-toughness high-strength that the present invention proposes, its raw material includes by weight: bisphenol A type epoxy resin 45 parts, 17 parts of polyester resin, fluorine-containing hydrophobic material 22 parts, novolac epoxy resin 8 parts, nano silicon 10 parts, Pulvis Talci 5 parts, white carbon black 4 parts, polyvinyl alcohol 3 parts, titanium dioxide 8 parts, aluminium powder 3 parts, calcium carbonate 5 parts, levelling agent 2 parts, 3 parts of firming agent, delustering agent 1 part, antirust hybrid pigment 8 parts。
The preparation technology of fluorine-containing hydrophobic material is as follows: puts into the first process equipment after 10 parts of methacrylic acid 12 heptyl esters, 8 parts of vinyl acetates, 3.8 parts of polydimethylsiloxane, 0.09 part of azodiisobutyronitrile mix homogeneously by weight, is filled with carbon dioxide and carries out gas displacement in the first process equipment；Then being placed in 55 DEG C of water-baths by the first process equipment, continuing to be filled with carbon dioxide to the first process equipment internal pressure is 16.0MPa, discharges carbon dioxide and obtain material A after keeping 40h；Material A is put in the second process equipment containing toluene, raises the second process equipment temperature to 45 DEG C, be incubated 10min, cooling, takes out and obtains material B, then successively cleans with methanol, deionized water, drying obtains fluorine-containing hydrophobic material, and the temperature of drying is 55 DEG C, and the time of drying is 40min。
Embodiment 2
The antirust powdery paints of a kind of high-toughness high-strength that the present invention proposes, its raw material includes by weight: bisphenol A type epoxy resin 35 parts, 20 parts of polyester resin, fluorine-containing hydrophobic material 18 parts, novolac epoxy resin 10 parts, nano silicon 7 parts, Pulvis Talci 7 parts, white carbon black 2 parts, polyvinyl alcohol 5 parts, titanium dioxide 2 parts, aluminium powder 6 parts, calcium carbonate 2 parts, levelling agent 4 parts, 1 part of firming agent, delustering agent 2 parts, antirust hybrid pigment 5 parts。
The preparation technology of fluorine-containing hydrophobic material is as follows: puts into the first process equipment after 12 parts of methacrylic acid 12 heptyl esters, 6 parts of vinyl acetates, 4.5 parts of polydimethylsiloxane, 0.06 part of azodiisobutyronitrile mix homogeneously by weight, is filled with carbon dioxide and carries out gas displacement in the first process equipment；Then being placed in 60 DEG C of water-baths by the first process equipment, continuing to be filled with carbon dioxide to the first process equipment internal pressure is 15.5MPa, discharges carbon dioxide and obtain material A after keeping 45h；Material A is put in the second process equipment containing toluene, raises the second process equipment temperature to 40 DEG C, be incubated 15min, cooling, takes out and obtains material B, then successively cleans with methanol, deionized water, drying obtains fluorine-containing hydrophobic material, and the temperature of drying is 50 DEG C, and the time of drying is 45min。
Embodiment 3
The antirust powdery paints of a kind of high-toughness high-strength that the present invention proposes, its raw material includes by weight: bisphenol A type epoxy resin 42 parts, 18 parts of polyester resin, fluorine-containing hydrophobic material 21 parts, novolac epoxy resin 8.5 parts, nano silicon 9 parts, Pulvis Talci 5.5 parts, white carbon black 3.5 parts, polyvinyl alcohol 3.5 parts, titanium dioxide 3.5 parts, aluminium powder 3.5 parts, calcium carbonate 4 parts, levelling agent 3 parts, 2.5 parts of firming agent, delustering agent 1.4 parts, antirust hybrid pigment 7 parts。
The preparation technology of fluorine-containing hydrophobic material is as follows: puts into the first process equipment after 10.5 parts of methacrylic acid 12 heptyl esters, 7 parts of vinyl acetates, 4.1 parts of polydimethylsiloxane, 0.08 part of azodiisobutyronitrile mix homogeneously by weight, is filled with carbon dioxide and carries out gas displacement in the first process equipment；Then being placed in 56 DEG C of water-baths by the first process equipment, continuing to be filled with carbon dioxide to the first process equipment internal pressure is 15.8MPa, discharges carbon dioxide and obtain material A after keeping 42h；Material A is put in the second process equipment containing toluene, raises the second process equipment temperature to 44 DEG C, be incubated 11min, cooling, takes out and obtains material B, then successively cleans with methanol, deionized water, drying obtains fluorine-containing hydrophobic material, and the temperature of drying is 53 DEG C, and the time of drying is 42min。
Embodiment 4
The antirust powdery paints of a kind of high-toughness high-strength that the present invention proposes, its raw material includes by weight: bisphenol A type epoxy resin 38 parts, 19 parts of polyester resin, fluorine-containing hydrophobic material 19 parts, novolac epoxy resin 9 parts, nano silicon 8 parts, Pulvis Talci 6 parts, white carbon black 3 parts, polyvinyl alcohol 4.5 parts, titanium dioxide 2.5 parts, aluminium powder 4 parts, calcium carbonate 3 parts, levelling agent 3.5 parts, 2 parts of firming agent, delustering agent 1.8 parts, antirust hybrid pigment 6 parts。
The preparation technology of fluorine-containing hydrophobic material is as follows: puts into the first process equipment after 11 parts of methacrylic acid 12 heptyl esters, 6.5 parts of vinyl acetates, 4.3 parts of polydimethylsiloxane, 0.07 part of azodiisobutyronitrile mix homogeneously by weight, is filled with carbon dioxide and carries out gas displacement in the first process equipment；Then being placed in 58 DEG C of water-baths by the first process equipment, continuing to be filled with carbon dioxide to the first process equipment internal pressure is 15.6MPa, discharges carbon dioxide and obtain material A after keeping 43h；Material A is put in the second process equipment containing toluene, raises the second process equipment temperature to 43 DEG C, be incubated 13min, cooling, takes out and obtains material B, then successively cleans with methanol, deionized water, drying obtains fluorine-containing hydrophobic material, and the temperature of drying is 52 DEG C, and the time of drying is 43min。
The above; it is only the present invention preferably detailed description of the invention; but protection scope of the present invention is not limited thereto; any those familiar with the art is in the technical scope that the invention discloses; it is equal to replacement according to technical scheme and inventive concept thereof or is changed, all should be encompassed within protection scope of the present invention。
Claims (7)
1. the antirust powdery paints of high-toughness high-strength, it is characterised in that its raw material includes by weight: bisphenol A type epoxy resin 35-45 part, polyester resin 17-20 part, fluorine-containing hydrophobic material 18-22 part, novolac epoxy resin 8-10 part, nano silicon 7-10 part, Pulvis Talci 5-7 part, white carbon black 2-4 part, polyvinyl alcohol 3-5 part, titanium dioxide 2-4 part, aluminium powder 3-4.5 part, calcium carbonate 2-5 part, levelling agent 2-4 part, firming agent 1-3 part, delustering agent 1-2 part, antirust hybrid pigment 5-8 part。
2. the antirust powdery paints of high-toughness high-strength according to claim 1, it is characterised in that bisphenol A type epoxy resin, polyester resin, fluorine-containing hydrophobic material, novolac epoxy resin weight ratio be 38-42:18-19:19-21:8.5-9。
3. the antirust powdery paints of high-toughness high-strength according to claim 1 or claim 2, it is characterized in that, its raw material includes by weight: bisphenol A type epoxy resin 38-42 part, polyester resin 18-19 part, fluorine-containing hydrophobic material 19-21 part, novolac epoxy resin 8.5-9 part, nano silicon 8-9 part, Pulvis Talci 5.5-6 part, white carbon black 3-3.5 part, polyvinyl alcohol 3.5-4.5 part, titanium dioxide 2.5-3.5 part, aluminium powder 3.5-4 part, calcium carbonate 3-4 part, levelling agent 3-3.5 part, firming agent 2-2.5 part, delustering agent 1.4-1.8 part, antirust hybrid pigment 6-7 part。
4. the antirust powdery paints of high-toughness high-strength according to any one of claim 1-3, it is characterized in that, the preparation technology of fluorine-containing hydrophobic material is as follows: put into the first process equipment after methacrylic acid 12 heptyl ester, vinyl acetate, polydimethylsiloxane, azodiisobutyronitrile mix homogeneously, is filled with carbon dioxide and carries out gas displacement in the first process equipment；Then the first process equipment is placed in water-bath, continues to be filled with carbon dioxide to the first process equipment, discharge carbon dioxide after keeping certain time and obtain material A；Material A is put in the second process equipment containing toluene, raises the second process equipment temperature, insulation, cooling, take out and obtain material B, then successively clean with methanol, deionized water, dry and obtain fluorine-containing hydrophobic material。
5. the antirust powdery paints of high-toughness high-strength according to any one of claim 1-4, it is characterized in that, the preparation technology of fluorine-containing hydrophobic material is as follows: put into the first process equipment after methacrylic acid 12 heptyl ester, vinyl acetate, polydimethylsiloxane, azodiisobutyronitrile mix homogeneously, is filled with carbon dioxide and carries out gas displacement in the first process equipment；Then being placed in 55-60 DEG C of water-bath by the first process equipment, continuing to be filled with carbon dioxide to the first process equipment internal pressure is 15.5-16.0MPa, discharges carbon dioxide and obtain material A after keeping 40-45h；Material A is put in the second process equipment containing toluene, raises the second process equipment temperature to 40-45 DEG C, be incubated 10-15min, cooling, take out and obtain material B, then successively clean with methanol, deionized water, dry and obtain fluorine-containing hydrophobic material。
6. the antirust powdery paints of high-toughness high-strength according to any one of claim 1-5, it is characterized in that, the preparation technology of fluorine-containing hydrophobic material is as follows: puts into the first process equipment after 10-12 part methacrylic acid 12 heptyl ester, 6-8 part vinyl acetate, 3.8-4.5 part polydimethylsiloxane, 0.06-0.09 part azodiisobutyronitrile mix homogeneously by weight, is filled with carbon dioxide and carries out gas displacement in the first process equipment；Then being placed in 55-60 DEG C of water-bath by the first process equipment, continuing to be filled with carbon dioxide to the first process equipment internal pressure is 15.5-16.0MPa, discharges carbon dioxide and obtain material A after keeping 40-45h；Material A is put in the second process equipment containing toluene, raises the second process equipment temperature to 40-45 DEG C, be incubated 10-15min, cooling, take out and obtain material B, then successively clean with methanol, deionized water, dry and obtain fluorine-containing hydrophobic material。
7. the antirust powdery paints of high-toughness high-strength according to any one of claim 1-6, it is characterised in that in the preparation technology of fluorine-containing hydrophobic material, the temperature of drying is 50-55 DEG C, and the time of drying is 40-45min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610183837.3A CN105694673A (en) | 2016-03-24 | 2016-03-24 | High-toughness high-strength antirust powder paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610183837.3A CN105694673A (en) | 2016-03-24 | 2016-03-24 | High-toughness high-strength antirust powder paint |
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| CN105694673A true CN105694673A (en) | 2016-06-22 |
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| CN201610183837.3A Pending CN105694673A (en) | 2016-03-24 | 2016-03-24 | High-toughness high-strength antirust powder paint |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106010117A (en) * | 2016-06-29 | 2016-10-12 | 芜湖市佳谷豆工贸有限公司 | Thermosetting powder paint |
| CN106634431A (en) * | 2016-12-20 | 2017-05-10 | 山东东方新材料有限公司 | Superhydrophobic-structure fusion-bonded epoxy powder paint and preparation method thereof |
| CN117264506A (en) * | 2023-11-23 | 2023-12-22 | 赛高新材料科技有限公司 | Antibacterial powder coating and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805556A (en) * | 2010-04-12 | 2010-08-18 | 安徽华辉塑业科技有限公司 | Thermosetting powder coating with high tenacity |
| CN103382353A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Heavy-duty anticorrosion environmental-friendly enhanced powder coating |
-
2016
- 2016-03-24 CN CN201610183837.3A patent/CN105694673A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805556A (en) * | 2010-04-12 | 2010-08-18 | 安徽华辉塑业科技有限公司 | Thermosetting powder coating with high tenacity |
| CN103382353A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Heavy-duty anticorrosion environmental-friendly enhanced powder coating |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106010117A (en) * | 2016-06-29 | 2016-10-12 | 芜湖市佳谷豆工贸有限公司 | Thermosetting powder paint |
| CN106634431A (en) * | 2016-12-20 | 2017-05-10 | 山东东方新材料有限公司 | Superhydrophobic-structure fusion-bonded epoxy powder paint and preparation method thereof |
| CN106634431B (en) * | 2016-12-20 | 2019-06-25 | 山东东宏管业股份有限公司 | A kind of clinkery epoxy powder coating and preparation method thereof with super-drainage structure |
| CN117264506A (en) * | 2023-11-23 | 2023-12-22 | 赛高新材料科技有限公司 | Antibacterial powder coating and preparation method thereof |
| CN117264506B (en) * | 2023-11-23 | 2024-01-26 | 赛高新材料科技有限公司 | Antibacterial powder coating and preparation method thereof |
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Application publication date: 20160622 |