CN105694549B - A kind of dura mater casting fire-resistant anticorrosion paint based on asbestos and preparation method thereof - Google Patents

A kind of dura mater casting fire-resistant anticorrosion paint based on asbestos and preparation method thereof Download PDF

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Publication number
CN105694549B
CN105694549B CN201610145749.4A CN201610145749A CN105694549B CN 105694549 B CN105694549 B CN 105694549B CN 201610145749 A CN201610145749 A CN 201610145749A CN 105694549 B CN105694549 B CN 105694549B
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Prior art keywords
asbestos
silica
anticorrosion paint
ludox
dura mater
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CN201610145749.4A
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CN105694549A (en
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张信卿
姚青奇
张永辉
张亚辉
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Henan Zhongshuai Metal Products Co Ltd
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Henan Zhongshuai Metal Products Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of dura mater casting fire-resistant anticorrosion paint based on asbestos and preparation method thereof, which consists of part by mass percentage with fire-resistant anticorrosion paint:Asbestos 1 3%, Ludox 2 6%, kaolin 1 2%, aluminium powder 0.1 0.3%, silica 0.1 0.3%, water 90 95%.Compared with prior art, coating produced by the present invention has the advantages that good high temperature resistant, alkali resistance, anticorrosive property and artificial ageing resistance, metal casting industry can be used in, die surface brushing uses, dope layer is intact for a long time, without blistering, peeling phenomenon, the problem of original serious corrosion of equipment, is well solved, and is greatly improved and extends the service life of metal grinding tool.The raw material of the present invention is easily purchased, and of low cost, easy to operate, technique is simple, is easy to industrialized production, has a vast market prospect and promotional value.

Description

A kind of dura mater casting fire-resistant anticorrosion paint based on asbestos and preparation method thereof
Technical field
The present invention relates to fire-resistant anticorrosion paint field, more particularly, to a kind of dura mater casting high temperature resistant based on asbestos Anticorrosive paint and preparation method thereof.
Background technology
With scientific and technological progress, high-temperature resistant coating more and more appears in every field, for example, jet chimney, high temperature furnace, Engine components and Metal surface anti-corrosion.Current market sales of high-temperature resistant coating substantially divides organosilicate coating and inorganic Two series of silicate paint, for the fire-resistant anticorrosion paint of organic series mostly using organosilicon as carrier, its maximum temperature is general No more than 400 degrees Celsius, it will be carbonized or soften more than this temperature, and inorganic serial high-temperature-resistant adhesive can be held Widely used by least 1000 degrees Celsius of high temperature, shallow layer can play good anti-oxidation corrosion-resistant effect, and thick coating is not But good anti-oxidation corrosion-resistant effect can be played, heat insulation and preservation effect can also be played.Ceramics, glass, gold can be used as The coating materials such as category, are widely used in metallurgical furnace, quartz heating-pipe plates white, coal-burning power plant's pulverized coal preparation system anti-impact corrosive wear coating Many industrial circles such as coating, automobile engine spark plug ceramic coating anti-carbon deposition, pyroceram ink, aerospace.Often Temperature spraying is in the body surfaces such as glass, ceramics, metal, low temperature drying or normal temperature self-drying, heavily fortified point very good with the adhesive force on surface Hard wear-resisting damage resistant, does not crack, function admirable.
Asbestos are also known as " asbestos ", refer to high-tensile, high flexible, chemically-resistant and thermal etching, electric insulation and with can The silicates mineral products for the property spun.It is the general name of natural fibrous silicates mineral matter, including chrysotile, Amphibole asbestos, actinolite asbestos, antophyllite, amosite, tremolite asbestos etc..Asbestos are by tow groups into and fiber Beam is formed by growing very much the very thin fiber that can be separated from each other again.Asbestos have extremely fireproof, electrical insulating property and thermal insulation, are weights Fire prevention, insulation and the thermal insulation material wanted.Be mainly used for machine driving, braking and insulation, fire prevention, heat-insulated, anti-corrosion, sound insulation, absolutely Edge etc., wherein more it is important that the manufacturing sector such as automobile, chemical industry, electrical equipment, construction industry.Asbestos fibre has good Heat resistance, heated generally below 300 DEG C 2 it is small when weight loss it is less, if being heated at a temperature of more than 1700 DEG C 2 small When, the weight loss of chrysotile asbestos fibre is more, other species asbestos fibre weight loss are less.It is easy how a kind of raw material is prepared , of low cost, preparation process is easy, and has notable high temperature resistant, and corrosion resistant coating is that high-temperature resistant coating industry needs to solve A problem certainly.
The content of the invention
In order to solve the technical problems such as conventional method, the present invention provides a kind of raw material and is easy to get, of low cost, preparation process letter Just, and there is notable high temperature resistant, the corrosion resistant dura mater casting fire-resistant anticorrosion paint based on asbestos and preparation method thereof.
The technical scheme is that:A kind of dura mater casting fire-resistant anticorrosion paint based on asbestos, by quality percentage Than consisting of part:Asbestos 1-3%, Ludox 2-6%, kaolin 1-2%, aluminium powder 0.1-0.3%, silica 0.1- 0.3%, water 90-95%.
Further optimization as a kind of dura mater casting fire-resistant anticorrosion paint based on asbestos of the present invention:The stone Cotton is selected from commercially available chrysotile or amphibole asbestos.
Further optimization as a kind of dura mater casting fire-resistant anticorrosion paint based on asbestos of the present invention:The silicon Colloidal sol is selected from the neutral Ludox that the neutral Ludox or dioxide-containing silica that commercially available dioxide-containing silica is 30% are 40%.
Further optimization as a kind of dura mater casting fire-resistant anticorrosion paint based on asbestos of the present invention:The height Ridge soil is selected from commercially available industrial kaolin.
Further optimization as a kind of dura mater casting fire-resistant anticorrosion paint based on asbestos of the present invention:The aluminium Powder is general industry aluminium powder.
Further optimization as a kind of dura mater casting fire-resistant anticorrosion paint based on asbestos of the present invention:Described two Silica is powdered industrial silica.
A kind of preparation method of the dura mater casting fire-resistant anticorrosion paint based on asbestos, this method comprise the following steps:
(1)Ludox is added to the water, is stirred by ultrasonic 30-60 minutes;
(2)Asbestos, kaolin, aluminium powder and silica are added in grinder by ormal weight, fineness is ground to and is less than 150 mesh;
(3)By step(1)And step(2)Stir 20-120 minutes after obtained material mixing, then ground in grinder Mill 20-120 minutes, filtering, obtains the dura mater casting fire-resistant anticorrosion paint based on asbestos, then closed, packaging.
Beneficial effect
Compared with prior art, the present invention Ludox is added to the water by the present invention, it is stirred by ultrasonic 30-60 minutes, and and The components such as asbestos, kaolin, aluminium powder and silica are ground 20-120 minutes in grinder, and asbestos powder is dissolved in Ludox, Asbestos powder can be mixed fully with other components, the excellent performance of asbestos is not fully exerted, simultaneously because asbestos The addition of powder, the high temperature resistant and corrosion resistance of Ludox lotion greatly enhance, and tolerable temperature can reach 1600 and take the photograph Family name's degree, the present invention have further the advantage that:
The axial tensile strength of chrysotile is 3000Mpa, has higher tensile strength;
(1)When the thermal conductivity factor of asbestos fibre is spent for 0.104-0.260 kilocalories/rice, there is good heat resistance;
(2)The surface specific resistance of asbestos is 8.2 × 107-1.2×1010Ω, volume resistivity 1.9108-4.79X109 Ω cm, are good insulating materials;
(3)The alkaline resistance properties of chrysotile is preferable, is hardly corroded by bases;
(4)Amphibole asbestos have higher acid resistance, alkali resistance and chemical stability, and rotproofness is also preferable.
(5)Coating produced by the present invention is excellent with splendid high temperature resistant, alkali resistance, anticorrosive property and artificial ageing resistance etc. Point;
(6)The present invention compared with the prior art, easily purchase, of low cost, easy to operate, and technique is simple by raw material, is easy to industry Metaplasia is produced.
Embodiment
With reference to specific embodiment, the present invention is described in further detail.
Embodiment 1
Each component is equipped with by following mass percent:Asbestos(Commercially available chrysotile)1%, Ludox(Commercially available dioxy SiClx content is 30% neutral Ludox)3%, kaolin(Commercially available industrial kaolin) 1%, aluminium powder (general industry aluminium powder End) 0.1%, silica (powdered industrial silica) 0.1%, water 94.8%.
The dura mater casting fire-resistant anticorrosion paint based on asbestos is made by following steps:
(1)Ludox is added to the water, is stirred by ultrasonic 30 minutes;
(2)Asbestos, kaolin, aluminium powder and silica are added in grinder by ormal weight, fineness is ground to and is less than 150 mesh;
(3)By step(1)And step(2)Stirred 30 minutes after obtained material mixing, 60 are then ground in grinder Minute, filtering, obtains the dura mater casting fire-resistant anticorrosion paint based on asbestos, then closed, packaging.
Embodiment 2
Each component is equipped with by following mass percent:Asbestos(Commercially available amphibole asbestos)2%, Ludox(Commercially available dioxy SiClx content is 40% neutral Ludox)4%, kaolin(Commercially available industrial kaolin) 2%, aluminium powder (general industry aluminium powder End) 0.2%, silica (powdered industrial silica) 0.2%, water 91.6%.
The dura mater casting fire-resistant anticorrosion paint based on asbestos is made by following steps:
(1)Ludox is added to the water, is stirred by ultrasonic 30 minutes;
(2)Asbestos, kaolin, aluminium powder and silica are added in grinder by ormal weight, fineness is ground to and is less than 150 mesh;
(3)By step(1)And step(2)Stirred 30 minutes after obtained material mixing, 60 are then ground in grinder Minute, filtering, obtains the dura mater casting fire-resistant anticorrosion paint based on asbestos, then closed, packaging.
Embodiment 3
Each component is equipped with by following mass percent:Asbestos(Commercially available chrysotile)3%, Ludox(Commercially available dioxy SiClx content is 40% neutral Ludox)4%, kaolin(Commercially available industrial kaolin) 1.5%, aluminium powder (general industry aluminium Powder) 0.3%, silica (powdered industrial silica) 0.3%, water 90.9%.
The dura mater casting fire-resistant anticorrosion paint based on asbestos is made by following steps:
(1)Ludox is added to the water, is stirred by ultrasonic 30 minutes;
(2)Asbestos, kaolin, aluminium powder and silica are added in grinder by ormal weight, fineness is ground to and is less than 150 mesh;
(3)By step(1)And step(2)Stirred 30 minutes after obtained material mixing, 60 are then ground in grinder Minute, filtering, obtains the dura mater casting fire-resistant anticorrosion paint based on asbestos, then closed, packaging.
Performance test to the dura mater casting fire-resistant anticorrosion paint based on asbestos obtained by embodiment 1-3 is according to state Mark carries out, and test result is shown in Table 1.
The performance of 1 fire-resistant anticorrosion paint of table
Embodiment 4
Each component is equipped with by following mass percent:Asbestos(Commercially available amphibole asbestos)2.5%, Ludox(Commercially available two Silica content is 30% neutral Ludox)5%, kaolin(Commercially available industrial kaolin) 1%, aluminium powder (general industry aluminium Powder) 0.3%, silica (powdered industrial silica) 0.3%, water 90.9%.
The dura mater casting fire-resistant anticorrosion paint based on asbestos is made by following steps:
(1)Ludox is added to the water, is stirred by ultrasonic 30 minutes;
(2)Asbestos, kaolin, aluminium powder and silica are added in grinder by ormal weight, fineness is ground to and is less than 150 mesh;
(3)By step(1)And step(2)Stirred 30 minutes after obtained material mixing, 60 are then ground in grinder Minute, filtering, obtains the dura mater casting fire-resistant anticorrosion paint based on asbestos, then closed, packaging.

Claims (1)

1. a kind of dura mater casting fire-resistant anticorrosion paint based on asbestos, it is characterised in that by mass percentage by with lower part It is grouped into:Asbestos 1-3%, Ludox 2-6%, kaolin 1-2%, aluminium powder 0.1-0.3%, silica 0.1-0.3%, water 90- 95%;The asbestos are selected from commercially available chrysotile or amphibole asbestos;The Ludox is selected from commercially available silica The neutral Ludox that the neutral Ludox or dioxide-containing silica that content is 30% are 40%;The kaolin is selected from commercially available work Industry kaolin;The aluminium powder is general industry aluminium powder;The silica is powdered industrial silica; The preparation method of the dura mater casting fire-resistant anticorrosion paint based on asbestos comprises the following steps:
(1)Ludox is added to the water, is stirred by ultrasonic 30-60 minutes;
(2)Asbestos, kaolin, aluminium powder and silica are added in grinder by ormal weight, are ground to fineness less than 150 Mesh;
(3)By step(1)And step(2)Stirred 20-120 minutes after obtained material mixing, 20- is then ground in grinder 120 minutes, filtering, obtained the dura mater casting fire-resistant anticorrosion paint based on asbestos, then closed, packaging.
CN201610145749.4A 2016-03-15 2016-03-15 A kind of dura mater casting fire-resistant anticorrosion paint based on asbestos and preparation method thereof Active CN105694549B (en)

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CN106362931A (en) * 2016-08-31 2017-02-01 无锡宏锐汽车零部件有限公司 Process for decorating stainless steel surface with nanometer ceramic aluminum coating

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1182655A (en) * 1997-10-08 1998-05-27 冶金工业部钢铁研究总院 Coating for casting thin foundry goods
CN101658899A (en) * 2009-09-17 2010-03-03 上海交通大学 Magnesium-alloy metal-type casting coating and preparation method thereof
CN102145372A (en) * 2011-03-15 2011-08-10 上海爱尔思轻合金制品有限公司 Coating for metal mold casting of aluminum alloy thin-walled piece and preparation method and coating method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1182655A (en) * 1997-10-08 1998-05-27 冶金工业部钢铁研究总院 Coating for casting thin foundry goods
CN101658899A (en) * 2009-09-17 2010-03-03 上海交通大学 Magnesium-alloy metal-type casting coating and preparation method thereof
CN102145372A (en) * 2011-03-15 2011-08-10 上海爱尔思轻合金制品有限公司 Coating for metal mold casting of aluminum alloy thin-walled piece and preparation method and coating method thereof

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