CN105694507A - 一种阻燃防静电木塑复合材料 - Google Patents

一种阻燃防静电木塑复合材料 Download PDF

Info

Publication number
CN105694507A
CN105694507A CN201610150769.0A CN201610150769A CN105694507A CN 105694507 A CN105694507 A CN 105694507A CN 201610150769 A CN201610150769 A CN 201610150769A CN 105694507 A CN105694507 A CN 105694507A
Authority
CN
China
Prior art keywords
parts
plastic composite
fire
wood plastic
composite material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610150769.0A
Other languages
English (en)
Inventor
杨玉发
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Chenxu Information Technology Co Ltd
Original Assignee
Hefei Chenxu Information Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Chenxu Information Technology Co Ltd filed Critical Hefei Chenxu Information Technology Co Ltd
Priority to CN201610150769.0A priority Critical patent/CN105694507A/zh
Publication of CN105694507A publication Critical patent/CN105694507A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/14—Applications used for foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种阻燃防静电木塑复合材料，主要由如下质量份数的组份制成：天然纤维粉55～70份、四针状氧化锌晶须12～18份、线性低密度聚乙烯30份、稳定剂10～15份、增强填料15～35份、发泡剂2～5份、固化剂5～7份及偶联剂3份；将填料通过干燥、改性、熔融共混、挤出完成。本发明有益效果是：有效地提升了填料与胶黏剂的表面的粘合力，具有较佳的防静电性能，在降低了脆性的同时有效地提高材料的耐热性、高韧性能等力学性能，并且大大节约了木材的使用量，实现了绿色环保，造福社会。

Description

一种阻燃防静电木塑复合材料
技术领域
本发明涉及复合材料领域，尤其涉及一种阻燃防静电木塑复合材料。
背景技术
近年来，由于塑木复合材料的快速发展，被广泛应用于建材、家具、物流包装甚至工业领域，其主要是利用热塑性树脂代替通常的树脂胶粘剂，与其它木质纤维混合在经过挤压、模压等工艺生产出板材或型材，其力学性能满足均能满足各方面要求；热塑性树脂具有加工成型简便、较高的机械能被广泛应用于各个领域，但缺点是耐热性较差，其制品在使用过程中易积聚大量静电导致火花放电而引发燃爆灾害事故，当遇到包括静电放电火花在内的各种明火时可被点燃，并迅速燃烧酿成火灾，这些都大大限制了它的应用领域。为此，开展对热塑性材料的防静电、阻燃改性并使二者兼容具有重要意义。因此，如何研究一种力学性能佳阻燃防静电木塑复合材料已成为目前需要解决的技术问题。
发明内容
本发明的目的在于克服现有技术存在的以上问题，为实现上述技术目的，达到上述技术效果，本发明通过以下技术方案实现：
一种阻燃防静电木塑复合材料，主要由如下质量份数的组份制成：天然纤维粉55～70份、四针状氧化锌晶须12～18份、线性低密度聚乙烯30份、稳定剂10～15份、增强填料15～35份、发泡剂2～5份、固化剂5～7份及偶联剂3份。
进一步地，所述天然纤维粉原料选自木屑、稻壳、花生壳或农作物秸秆中的一种或几种，且粉末粒径为30～60目。
进一步地，所述增强填料选自滑石粉、云母粉及石棉粉中的一种或多种，且颗粒粒径为170～200目。
进一步地，所述稳定剂为硬脂酸锌或硬脂酸钙。
本发明有益效果是：有效地提升了填料与胶黏剂的表面的粘合力，具有较佳的防静电性能，在降低了脆性的同时有效地提高材料的耐热性、高韧性能等力学性能，并且大大节约了木材的使用量，实现了绿色环保，造福社会。
具体实施方式
下面将结合实施例，来详细说明本发明。
一种阻燃防静电木塑复合材料，主要由如下质量份数的组份制成：天然纤维粉55份、四针状氧化锌晶须12份、线性低密度聚乙烯30份、稳定剂10份、增强填料15份、发泡剂3份、固化剂5份及偶联剂3份。
其中，天然纤维粉原料选自木屑、稻壳、花生壳或农作物秸秆中的一种或几种，且粉末粒径为30～60目。
其中，增强填料选自滑石粉、云母粉及石棉粉中的一种或多种，且颗粒粒径为170～200目。
其中，稳定剂为硬脂酸锌或硬脂酸钙。
一种阻燃防静电木塑复合材料，其制备步骤如下：
a）将天然纤维粉放入混合机中干燥至水含率的重量浓度小于3.5%，时间为2～5h，温度为150℃～220℃；
b）将干燥后的填料与各组份放入搅拌机中搅拌10～15mnin后，挤出造粒，挤出温度为180℃。
以上描述了本发明的举例，展示了主要特征和本发明的优点。应该了解，本发明不受上述实施例的限制，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。

Claims (5)

1.一种阻燃防静电木塑复合材料，其特征在于主要由如下质量份数的组份制成：天然纤维粉55～70份、四针状氧化锌晶须12～18份、线性低密度聚乙烯30份、稳定剂10～15份、增强填料15～35份、发泡剂2～5份、固化剂5～7份及偶联剂3份。
2.根据权利要求1所述的一种阻燃防静电木塑复合材料，其特征在于：所述天然纤维粉原料选自木屑、稻壳、花生壳或农作物秸秆中的一种或几种，且粉末粒径为30～60目。
3.根据权利要求1所述的一种阻燃防静电木塑复合材料，其特征在于：所述增强填料选自滑石粉、云母粉及石棉粉中的一种或多种，且颗粒粒径为170～200目。
4.根据权利要求1所述的一种阻燃防静电木塑复合材料，其特征在于：所述稳定剂为硬脂酸锌或硬脂酸钙。
5.根据权利要求1所述的一种阻燃防静电木塑复合材料，其特征在于：所述偶联剂为硅烷偶联剂或钛酸酯偶联剂。
CN201610150769.0A 2016-03-17 2016-03-17 一种阻燃防静电木塑复合材料 Pending CN105694507A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610150769.0A CN105694507A (zh) 2016-03-17 2016-03-17 一种阻燃防静电木塑复合材料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610150769.0A CN105694507A (zh) 2016-03-17 2016-03-17 一种阻燃防静电木塑复合材料

Publications (1)

Publication Number Publication Date
CN105694507A true CN105694507A (zh) 2016-06-22

Family

ID=56220681

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610150769.0A Pending CN105694507A (zh) 2016-03-17 2016-03-17 一种阻燃防静电木塑复合材料

Country Status (1)

Country Link
CN (1) CN105694507A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106496760A (zh) * 2016-11-11 2017-03-15 舒城安泰塑料制品有限公司 建筑外墙装饰板加工用木塑复合材料及其制备方法
CN112898796A (zh) * 2021-01-24 2021-06-04 湖北欧宅新材料科技有限公司 一种可回收再利用的阻燃型板材及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100999610A (zh) * 2006-01-12 2007-07-18 中国林业科学研究院木材工业研究所 木塑复合材料组合物及成型板以及它们的制备方法
US20110071237A1 (en) * 2006-09-25 2011-03-24 Chemtura Corporation Flame Resistance Natural Fiber-Filled Thermoplastics with Improved Properties
CN102924941A (zh) * 2011-08-08 2013-02-13 深圳市格林美高新技术股份有限公司 一种高强耐磨塑木复合材料及其制备方法
CN103360674A (zh) * 2013-07-26 2013-10-23 福州大学 一种木粉复合发泡材料及其制备方法
CN104861250A (zh) * 2014-12-23 2015-08-26 王玉燕 阻燃增强仿真木材及其制备方法
CN105038114A (zh) * 2015-08-04 2015-11-11 苏州博云塑业有限公司 一种通过纤维增强的复合材料

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100999610A (zh) * 2006-01-12 2007-07-18 中国林业科学研究院木材工业研究所 木塑复合材料组合物及成型板以及它们的制备方法
US20110071237A1 (en) * 2006-09-25 2011-03-24 Chemtura Corporation Flame Resistance Natural Fiber-Filled Thermoplastics with Improved Properties
CN102924941A (zh) * 2011-08-08 2013-02-13 深圳市格林美高新技术股份有限公司 一种高强耐磨塑木复合材料及其制备方法
CN103360674A (zh) * 2013-07-26 2013-10-23 福州大学 一种木粉复合发泡材料及其制备方法
CN104861250A (zh) * 2014-12-23 2015-08-26 王玉燕 阻燃增强仿真木材及其制备方法
CN105038114A (zh) * 2015-08-04 2015-11-11 苏州博云塑业有限公司 一种通过纤维增强的复合材料

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106496760A (zh) * 2016-11-11 2017-03-15 舒城安泰塑料制品有限公司 建筑外墙装饰板加工用木塑复合材料及其制备方法
CN112898796A (zh) * 2021-01-24 2021-06-04 湖北欧宅新材料科技有限公司 一种可回收再利用的阻燃型板材及其制备方法

Similar Documents

Publication Publication Date Title
CN101081540B (zh) 一种宽幅木塑发泡门和板材的制造方法
KR101153834B1 (ko) 난연성을 구비하는 친환경 합성목재 조성물로 이루어진 합성목재
JPH03217456A (ja) 難燃性及び高耐衝撃性ポリエチレン成形組成物
WO2007112104A3 (en) Polyurethane composite materials
CN109593297A (zh) 一种共挤无卤阻燃木塑材料及其制备方法
CN107266817A (zh) 一种轻质高强环保耐磨木塑复合材料及其制备方法
CN105906908A (zh) 可降解阻燃木塑复合材料及其制备方法
CN105713315A (zh) 一种高分子纤维复合新材料的合成配方
CN107501740A (zh) 一种编织袋
CN109593377A (zh) 一种高强度塑木材料及其制备方法
CN105694507A (zh) 一种阻燃防静电木塑复合材料
KR101218405B1 (ko) 삼층형 폴리염화 비닐관
CN110281616A (zh) 一种阻燃塑木复合材料板材及其制备方法
CN102153807B (zh) 一种硫酸钙晶须改性乙烯-乙烯醇共聚物及其制备工艺
KR101180906B1 (ko) 섬유질 플라스틱 복합재 및 이의 제조방법
US6114007A (en) Flame resistant reinforced composites
CN103642259A (zh) 一种阻燃型聚烯烃基木塑复合材料
CN110408223A (zh) 一种防潮防腐蚀木塑复合材料及其制备方法
KR101724670B1 (ko) 난연성 플라스틱 및 그 제조 방법
CN107141569A (zh) 一种高硬度pvc光面木塑板及其制备方法
CN106366686A (zh) 一种用于制作阻燃门板的塑木材料及其制备方法
CN105949568A (zh) 一种抗菌环保木塑复合材料
KR102393033B1 (ko) 내구성, 항균성 및 원적외선 방사능이 향상된 건축자재용 조성물, 건축자재용 복합재의 제조 방법 및 이로부터 제조된 건축자재용 복합재
KR101893077B1 (ko) 난연성 플라스틱 패널을 이용한 선박의 내화성 도어 및 그 제조방법
CN108314864A (zh) 一种阻燃抑烟型pvc木塑复合材料

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160622