CN105694413A - High-thermal-conductivity graphene-based polycarbonate composite material and preparation method thereof - Google Patents
High-thermal-conductivity graphene-based polycarbonate composite material and preparation method thereof Download PDFInfo
- Publication number
- CN105694413A CN105694413A CN201610168561.1A CN201610168561A CN105694413A CN 105694413 A CN105694413 A CN 105694413A CN 201610168561 A CN201610168561 A CN 201610168561A CN 105694413 A CN105694413 A CN 105694413A
- Authority
- CN
- China
- Prior art keywords
- composite material
- graphene
- thermal conductivity
- high thermal
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention relates to the field of polymer materials, and particularly discloses a high-thermal-conductivity graphene-base polycarbonate composite material. The graphene-base polycarbonate composite material is prepared from the following components in parts by mass: 50-100 parts of polycarbonate masterbatch, 1-5 parts of carbon material, 2-5 parts of maleic anhydride-grafted polypropylene, 1-5 parts of antioxidant, 1-5 parts of plasticizer and 0.1-1 part of coupling agent. A preparation method of the graphene-base polycarbonate composite material comprises the following steps: uniformly mixing the carbon material and the maleic anhydride-grafted polypropylene, uniformly mixing with the polycarbonate masterbatch, and finally adding an aid; drying at the temperature of 120-150 DEG C for 6-10 hours, feeding the dried material into a twin-screw extruder for extruding, and pelletizing with a pelletizer. The obtained composite material is low in cost, has high thermal conductivity, and can be applied to the fields of sealing cabinets, LED (Light-Emitting Diode) heat dissipation shells, motor coils, electronic component heat dissipation shells, and the like.
Description
Technical field
The present invention relates to polymeric material field, be related specifically to a kind of high thermal conductivity graphene-based polycarbonate composite material and preparation method thereof。
Background technology
Merlon is the engineering plastics using growth rate the fastest in recent years, there is the features such as high elastic coefficient, high impact, high transparent, weatherability and avirulence, be widely used in the fields such as CD, automobile, office equipment, casing, packaging, medicine, illumination, thin film。But the heat conductivity of Merlon is not high, only 0.17W/m k, being far not by far up to the mark in industries such as automobile, LED, electronic packagings, this needs us by Heat Conduction Material, Merlon to be modified。
All adopting metal packing for the heat conductivility of polycarbonate plastic is modified in prior art, such as argentum powder, copper powder, aluminium powder etc., but these fillers are expensive and it cannot be guaranteed that material has higher insulating properties。In order to overcome these shortcomings, it is thus proposed that adopt the materials such as aluminium oxide, carborundum, aluminium nitride to be filled with, but cost is still higher。
Summary of the invention
The present invention is in order to overcome the deficiency of above-mentioned technical problem, it is provided that a kind of high thermal conductivity graphene-based polycarbonate composite material, it is possible to be fully solved above-mentioned technical problem。
The technical scheme solving above-mentioned technical problem is as follows:
A kind of high thermal conductivity graphene-based polycarbonate composite material, by weight, including following components:
Described material with carbon element is one or more the compositions in the heat conduction white carbon black of zero dimension, one-dimensional carbon fiber or CNT, two-dimentional single-layer graphene or graphene microchip。
Described antioxidant is one or more in single phenol, bis-phenol, triphenol, hydroquinone, thiobisphenol。
Described plasticizer is one or more in Methyl Benzene-o-dicarboxylate, ethyl phthalate, O-phthalic propyl propionate, butyl phthalate, octyl phthalate。
Described coupling agent is one or more in KH550, KH560, KH570, KH580。
The preparation method of this high thermal conductivity graphene-based polycarbonate composite material, comprises the following steps:
(1) by the polypropylene mix homogeneously of material with carbon element, maleic anhydride graft, then again mix homogeneously with polycarbonate masterbatch, be finally sequentially added into antioxidant, plasticizer and coupling agent；
(2) by said mixture dry 6～10h at 120～150 DEG C；
(3) above-mentioned dried mixture is sent into double screw extruder extrusion, then by pelleter pelletize；Described double screw extruder each district temperature is at 170～250 DEG C, and screw speed is 10～40rpm, and feeding rotating speed is 6～10rpm, and pelleter rotating speed is 120～200rpm。
This high thermal conductivity graphene-based polycarbonate composite material can be used for sealed cabinet, motor coil, LED heat sink or electric-device housing field。
The present invention adopts material with carbon element that Merlon is modified, and adopts zero dimension, one-dimensional and Two-dimensional Carbon material to build three dimentional heat conduction network structure in polycarbonate matrix, increases the compatibility between Merlon and material with carbon element by the polypropylene of maleic anhydride graft。This new invention significantly reduces on the one hand the cost of filler, is adopt zero dimension, one-dimensional, two-dimensional material can be effectively improved the heat conductivility of Merlon to build three dimentional heat conduction network on the other hand。The composite of the present invention can be used for the fields such as sealed cabinet, motor coil, LED heat sink, electric-device housing。Preparation process of the present invention is continuous, technique simple, be suitable for large-scale production。
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is further detailed explanation。
Embodiment 1:
A kind of high thermal conductivity graphene-based polycarbonate composite material, by weight, including following components: polycarbonate masterbatch 50 parts；Heat conduction white carbon black 0.3 part, 0.3 part of carbon fiber, single-layer graphene 0.4 part；The polypropylene of maleic anhydride graft 2 parts；1 part of antioxidant list phenol；Plasticizer phthalic acid methyl ester 1 part；KH550 coupling agent 0.1 part。The preparation method of this high thermal conductivity graphene-based polycarbonate composite material, comprise the following steps: (1) is by the polypropylene mix homogeneously of material with carbon element, maleic anhydride graft, then again mix homogeneously with polycarbonate masterbatch, be finally sequentially added into antioxidant, plasticizer and coupling agent；(2) by said mixture dry 10h at 120 DEG C；(3) above-mentioned dried mixture is sent into double screw extruder extrusion, then by pelleter pelletize；Double screw extruder each district temperature is at 170 DEG C, and screw speed is 10rpm, and feeding rotating speed is 6rpm, and pelleter rotating speed is 120rpm。This composite can be used for sealed cabinet field。
Embodiment 2:
Take the polypropylene mix homogeneously of the maleic anhydride graft of the graphene microchip of 1 mass parts, the heat conduction white carbon black of 1 mass parts, the heat conduction carbon fiber of 0.1 mass parts, the single-layer graphene of 0.1 mass parts, 2 mass parts, add the polycarbonate masterbatch of 100 mass parts, mix homogeneously again, is eventually adding the coupling agent of the antioxidant of 2 mass parts, the plasticizer of 2 mass parts, 0.5 mass parts。Then above-mentioned raw materials is dried 6 hours at 120 DEG C, send into extrusion in double screw extruder, use pelleter pelletize。Screw rod each district temperature is: 230 DEG C of a district, 240 DEG C of 2nd district, 240 DEG C of 3rd district, 240 DEG C of 4th district, 240 DEG C of 5th district, head temperature 230 DEG C, screw speed is 20rpm。
Embodiment 3:
Take the polypropylene mix homogeneously of the maleic anhydride graft of the graphene microchip of 2 mass parts, the heat conduction white carbon black of 2 mass parts, the heat conduction carbon fiber of 0.1 mass parts, the single-layer graphene of 0.1 mass parts, 2 mass parts, add the polycarbonate masterbatch of 100 mass parts, mix homogeneously again, is eventually adding the coupling agent of the antioxidant of 2 mass parts, the plasticizer of 2 mass parts, 0.5 mass parts。Then above-mentioned raw materials is dried 6 hours at 120 DEG C, send into extrusion in double screw extruder, use pelleter pelletize。Screw rod each district temperature is: 230 DEG C of a district, 240 DEG C of 2nd district, 240 DEG C of 3rd district, 240 DEG C of 4th district, 240 DEG C of 5th district, head temperature 230 DEG C, screw speed is 20rpm。
Embodiment 4:
Take the polypropylene mix homogeneously of the maleic anhydride graft of the graphene microchip of 4 mass parts, the heat conduction carbon fiber of 0.1 mass parts, the single-layer graphene of 0.1 mass parts, 2 mass parts, add the polycarbonate masterbatch of 100 mass parts, mix homogeneously again, is eventually adding the coupling agent of the antioxidant of 2 mass parts, the plasticizer of 2 mass parts, 0.5 mass parts。Then above-mentioned raw materials is dried 6 hours at 120 DEG C, send into extrusion in double screw extruder, use pelleter pelletize。Screw rod each district temperature is: 230 DEG C of a district, 240 DEG C of 2nd district, 240 DEG C of 3rd district, 240 DEG C of 4th district, 240 DEG C of 5th district, head temperature 230 DEG C, screw speed is 20rpm。
Embodiment 5:
Take the polypropylene mix homogeneously of the maleic anhydride graft of the heat conduction white carbon black of 4 mass parts, the heat conduction carbon fiber of 0.1 mass parts, the single-layer graphene of 0.1 mass parts, 2 mass parts, add the polycarbonate masterbatch of 100 mass parts, mix homogeneously again, is eventually adding the coupling agent of the antioxidant of 2 mass parts, the plasticizer of 2 mass parts, 0.5 mass parts。Then above-mentioned raw materials is dried 6 hours at 120 DEG C, send into extrusion in double screw extruder, use pelleter pelletize。Screw rod each district temperature is: 230 DEG C of a district, 240 DEG C of 2nd district, 240 DEG C of 3rd district, 240 DEG C of 4th district, 240 DEG C of 5th district, head temperature 230 DEG C, screw speed is 20rpm。
Embodiment 6:
Take the polypropylene mix homogeneously of the maleic anhydride graft of the graphene microchip of 2 mass parts, the heat conduction white carbon black of 2 mass parts, the heat conduction carbon fiber of 0.5 mass parts, the single-layer graphene of 0.5 mass parts, 2 mass parts, add the polycarbonate masterbatch of 100 mass parts, mix homogeneously again, is eventually adding the coupling agent of the antioxidant of 2 mass parts, the plasticizer of 2 mass parts, 0.5 mass parts。Then above-mentioned raw materials is dried 6 hours at 120 DEG C, send into extrusion in double screw extruder, use pelleter pelletize。Screw rod each district temperature is: 230 DEG C of a district, 240 DEG C of 2nd district, 240 DEG C of 3rd district, 240 DEG C of 4th district, 240 DEG C of 5th district, head temperature 230 DEG C, screw speed is 20rpm。
Comparative example:
Take the Merlon of 100 mass parts, add the coupling agent of the antioxidant of 2 mass parts, the plasticizer of 2 mass parts, 0.5 mass parts。Then above-mentioned raw materials is dried 6 hours at 120 DEG C, send into extrusion in double screw extruder, use pelleter pelletize。Screw rod each district temperature is: 230 DEG C of a district, 240 DEG C of 2nd district, 240 DEG C of 3rd district, 240 DEG C of 4th district, 240 DEG C of 5th district, head temperature 230 DEG C, and screw speed is 20rpm, obtains as shown in table 1 below with the concrete outcome of embodiment 2-6:
By upper table 1 it can be seen that the heat conductivility of the composite of the three dimentional heat conduction network built by zero dimension, one-dimensional, Two-dimensional Carbon material is best, and having lacked the material of any dimension therein, heat conductivity can decline to some extent。
Embodiment 7:
A kind of high thermal conductivity graphene-based polycarbonate composite material, by weight, including following components: polycarbonate masterbatch 90 parts；Heat conduction white carbon black 1 part, CNT 2 parts, graphene microchip 2 parts；The polypropylene of maleic anhydride graft 5 parts；Antioxidant bis-phenol 2 parts, triphenol 3 parts；Plasticizer phthalic acid ethyl ester 2 parts, O-phthalic propyl propionate 3 parts；KH560 coupling agent 0.5 part, KH570 coupling agent 0.5 part。The preparation method of this high thermal conductivity graphene-based polycarbonate composite material, comprise the following steps: (1) is by the polypropylene mix homogeneously of material with carbon element, maleic anhydride graft, then again mix homogeneously with polycarbonate masterbatch, be finally sequentially added into antioxidant, plasticizer and coupling agent；(2) by said mixture dry 6h at 150 DEG C；(3) above-mentioned dried mixture is sent into double screw extruder extrusion, then by pelleter pelletize；Double screw extruder each district temperature is at 250 DEG C, and screw speed is 40rpm, and feeding rotating speed is 10rpm, and pelleter rotating speed is 200rpm。This composite can be used for motor coil field。
Embodiment 8:
A kind of high thermal conductivity graphene-based polycarbonate composite material, by weight, including following components: polycarbonate masterbatch 50～100 parts；Material with carbon element 1～5 part；The polypropylene of maleic anhydride graft 2～5 parts；Antioxidant 1～5 part；Plasticizer 1～5 part；Coupling agent 0.1～1 part。Described material with carbon element is the mixture of zero dimension filler, one-dimensional filler and two dimension filler, described zero dimension filler is heat conduction white carbon black, described one-dimensional filler is one or both the mixture in carbon fiber or CNT, and described two-dimentional filler is one or both mixture of single-layer graphene or graphene microchip。Described antioxidant is one or more in single phenol, bis-phenol, triphenol, hydroquinone, thiobisphenol。Described plasticizer is one or more in Methyl Benzene-o-dicarboxylate, ethyl phthalate, O-phthalic propyl propionate, butyl phthalate, octyl phthalate。Described coupling agent is one or more in KH550, KH560, KH570, KH580。The preparation method of this high thermal conductivity graphene-based polycarbonate composite material, it is characterised in that comprise the following steps:
(1) by the polypropylene mix homogeneously of material with carbon element, maleic anhydride graft, then again mix homogeneously with polycarbonate masterbatch, be finally sequentially added into antioxidant, plasticizer and coupling agent；
(2) by said mixture dry 6～10h at 120～150 DEG C；
(3) above-mentioned dried mixture is sent into double screw extruder extrusion, then by pelleter pelletize；Described double screw extruder each district temperature is at 170～250 DEG C, and screw speed is 10～40rpm, and feeding rotating speed is 6～10rpm, and pelleter rotating speed is 120～200rpm。
This composite can be used for sealed cabinet, motor coil, LED heat sink or electric-device housing field。
Embodiment 9:
A kind of high thermal conductivity graphene-based polycarbonate composite material, by weight, including following components: polycarbonate masterbatch 80 parts；Heat conduction white carbon black 0.5 part, 0.5 part of carbon fiber, CNT 1 part, single-layer graphene 0.5 part, graphene microchip 0.5 part；The polypropylene of maleic anhydride graft 4 parts；Antioxidant hydroquinone 3 parts；Plasticizer phthalic acid butyl ester 2 parts, octyl phthalate 2 parts；KH580 coupling agent 0.5 part。The preparation method of this high thermal conductivity graphene-based polycarbonate composite material, it is characterized in that, comprise the following steps: (1) is by the polypropylene mix homogeneously of material with carbon element, maleic anhydride graft, then again mix homogeneously with polycarbonate masterbatch, be finally sequentially added into antioxidant, plasticizer and coupling agent；(2) by said mixture dry 7h at 130 DEG C；(3) above-mentioned dried mixture is sent into double screw extruder extrusion, then by pelleter pelletize；Described double screw extruder each district temperature is at 200 DEG C, and screw speed is 30rpm, and feeding rotating speed is 7rpm, and pelleter rotating speed is 180rpm。This composite can be used for LED heat sink field。
Embodiment 10:
A kind of high thermal conductivity graphene-based polycarbonate composite material, by weight, including following components: polycarbonate masterbatch 60 parts；Heat conduction white carbon black 0.5 part, CNT 0.5 part, graphene microchip 1 part；The polypropylene of maleic anhydride graft 2.5 parts；Antioxidant hydroquinone 1 part, thiobisphenol 2 parts；Plasticizer phthalic acid methyl ester 1 part, octyl phthalate 1 part；KH550 coupling agent 0.7 part, KH580 coupling agent 0.2 part。The preparation method of this high thermal conductivity graphene-based polycarbonate composite material, comprise the following steps: (1) is by the polypropylene mix homogeneously of material with carbon element, maleic anhydride graft, then again mix homogeneously with polycarbonate masterbatch, be finally sequentially added into antioxidant, plasticizer and coupling agent；(2) by said mixture dry 9.5h at 145 DEG C；(3) above-mentioned dried mixture is sent into double screw extruder extrusion, then by pelleter pelletize；Described double screw extruder each district temperature is at 210 DEG C, and screw speed is 25rpm, and feeding rotating speed is 6rpm, and pelleter rotating speed is 125rpm。This composite can be used for electric-device housing field。
The present invention adopts material with carbon element that Merlon is modified, and adopts zero dimension, one-dimensional and Two-dimensional Carbon material to build three dimentional heat conduction network structure in polycarbonate matrix, increases the compatibility between Merlon and material with carbon element by the polypropylene of maleic anhydride graft。This new invention significantly reduces on the one hand the cost of filler, is adopt zero dimension, one-dimensional, two-dimensional material can be effectively improved the heat conductivility of Merlon to build three dimentional heat conduction network on the other hand。The composite of the present invention can be used for the fields such as sealed cabinet, motor coil, LED heat sink, electric-device housing。Preparation process of the present invention is continuous, technique simple, be suitable for large-scale production。
The above, be only presently preferred embodiments of the present invention, the present invention not does any pro forma restriction, any simple modification that above example is made by every technical spirit according to the present invention, equivalent variations, each falls within protection scope of the present invention。
Claims (7)
1. one kind high thermal conductivity graphene-based polycarbonate composite material, it is characterised in that by weight, including following components:
2. high thermal conductivity graphene-based polycarbonate composite material according to claim 1, it is characterized in that, described material with carbon element is the mixture of zero dimension filler, one-dimensional filler and two dimension filler, described zero dimension filler is heat conduction white carbon black, described one-dimensional filler is one or both the mixture in carbon fiber or CNT, and described two-dimentional filler is one or both mixture of single-layer graphene or graphene microchip。
3. high thermal conductivity graphene-based polycarbonate composite material according to claim 1, it is characterised in that described antioxidant is one or more in single phenol, bis-phenol, triphenol, hydroquinone, thiobisphenol。
4. high thermal conductivity graphene-based polycarbonate composite material according to claim 1, it is characterized in that, described plasticizer is one or more in Methyl Benzene-o-dicarboxylate, ethyl phthalate, O-phthalic propyl propionate, butyl phthalate, octyl phthalate。
5. high thermal conductivity graphene-based polycarbonate composite material according to claim 1, it is characterised in that described coupling agent is one or more in KH550, KH560, KH570, KH580。
6. the preparation method of the high thermal conductivity graphene-based polycarbonate composite material as described in any one of Claims 1 to 5, it is characterised in that comprise the following steps:
(1) by the polypropylene mix homogeneously of material with carbon element, maleic anhydride graft, then again mix homogeneously with polycarbonate masterbatch, be finally sequentially added into antioxidant, plasticizer and coupling agent；
(2) by said mixture dry 6～10h at 120～150 DEG C；
(3) above-mentioned dried mixture is sent into double screw extruder extrusion, then by pelleter pelletize；Described double screw extruder each district temperature is at 170～250 DEG C, and screw speed is 10～40rpm, and feeding rotating speed is 6～10rpm, and pelleter rotating speed is 120～200rpm。
7. the application of the high thermal conductivity graphene-based polycarbonate composite material as described in any one of Claims 1 to 5, it is characterised in that this composite can be used for sealed cabinet, motor coil, LED heat sink or electric-device housing field。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610168561.1A CN105694413B (en) | 2016-03-23 | 2016-03-23 | A kind of graphene-based polycarbonate composite material of high heat conduction and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610168561.1A CN105694413B (en) | 2016-03-23 | 2016-03-23 | A kind of graphene-based polycarbonate composite material of high heat conduction and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105694413A true CN105694413A (en) | 2016-06-22 |
| CN105694413B CN105694413B (en) | 2018-08-17 |
Family
ID=56232521
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610168561.1A Expired - Fee Related CN105694413B (en) | 2016-03-23 | 2016-03-23 | A kind of graphene-based polycarbonate composite material of high heat conduction and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105694413B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106366556A (en) * | 2016-09-23 | 2017-02-01 | 安徽科创电力科技有限公司 | High-performance electric appliance shell prepared by waste PC and ABS |
| CN106380776A (en) * | 2016-09-23 | 2017-02-08 | 安徽科创电力科技有限公司 | Waste and old electric appliance switch energy-saving regeneration process |
| CN108148336A (en) * | 2017-12-20 | 2018-06-12 | 博硕科技(江西)有限公司 | Halogen conduction TPE cable material and preparation method thereof |
| CN108177411A (en) * | 2017-12-29 | 2018-06-19 | 新奥石墨烯技术有限公司 | Mobile terminal backboard and preparation method thereof and mobile terminal |
| CN108215405A (en) * | 2017-12-29 | 2018-06-29 | 新奥石墨烯技术有限公司 | Mobile terminal backboard and preparation method thereof and mobile terminal |
| CN108495521A (en) * | 2018-03-30 | 2018-09-04 | 歌尔股份有限公司 | A kind of shell and preparation method thereof and electronic equipment |
| KR20220050258A (en) * | 2020-10-15 | 2022-04-25 | 주식회사 이케이씨 | Polycarbonate resin composition and article produced therefrom |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559109A (en) * | 2014-12-29 | 2015-04-29 | 东莞市奥能工程塑料有限公司 | Polycarbonate heat-conducting composite material and preparation method thereof |
| CN105273309A (en) * | 2015-10-26 | 2016-01-27 | 李修兵 | Anti-static and flame-retardant graphene-based polypropylene composite and preparation method thereof |
-
2016
- 2016-03-23 CN CN201610168561.1A patent/CN105694413B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559109A (en) * | 2014-12-29 | 2015-04-29 | 东莞市奥能工程塑料有限公司 | Polycarbonate heat-conducting composite material and preparation method thereof |
| CN105273309A (en) * | 2015-10-26 | 2016-01-27 | 李修兵 | Anti-static and flame-retardant graphene-based polypropylene composite and preparation method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106366556A (en) * | 2016-09-23 | 2017-02-01 | 安徽科创电力科技有限公司 | High-performance electric appliance shell prepared by waste PC and ABS |
| CN106380776A (en) * | 2016-09-23 | 2017-02-08 | 安徽科创电力科技有限公司 | Waste and old electric appliance switch energy-saving regeneration process |
| CN108148336A (en) * | 2017-12-20 | 2018-06-12 | 博硕科技(江西)有限公司 | Halogen conduction TPE cable material and preparation method thereof |
| CN108148336B (en) * | 2017-12-20 | 2020-07-03 | 博硕科技(江西)有限公司 | Halogen-free conductive TPE cable material and preparation method thereof |
| CN108177411A (en) * | 2017-12-29 | 2018-06-19 | 新奥石墨烯技术有限公司 | Mobile terminal backboard and preparation method thereof and mobile terminal |
| CN108215405A (en) * | 2017-12-29 | 2018-06-29 | 新奥石墨烯技术有限公司 | Mobile terminal backboard and preparation method thereof and mobile terminal |
| CN108495521A (en) * | 2018-03-30 | 2018-09-04 | 歌尔股份有限公司 | A kind of shell and preparation method thereof and electronic equipment |
| KR20220050258A (en) * | 2020-10-15 | 2022-04-25 | 주식회사 이케이씨 | Polycarbonate resin composition and article produced therefrom |
| KR102482344B1 (en) * | 2020-10-15 | 2023-01-13 | 주식회사 이케이씨 | Polycarbonate resin composition and article produced therefrom |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105694413B (en) | 2018-08-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105694413A (en) | High-thermal-conductivity graphene-based polycarbonate composite material and preparation method thereof | |
| CN101613480B (en) | Enhanced polybutylene terephthalate flame-retardant heat conduction material preparation method | |
| CN101645319B (en) | Environment-friendly heatproof composite elastic cable material for wires and cables and preparation method thereof | |
| CN103881213B (en) | A kind of modified poly ethylene CABLE MATERIALS and preparation method thereof | |
| CN108250747B (en) | Thermoplastic polyetherimide insulating and heat-conducting composite material and preparation method thereof | |
| CN104151706A (en) | Polypropylene composite material and preparation method thereof | |
| CN104610714B (en) | A kind of polybutylene terephthalate (PBT)/Merlon insulating heat-conductive composite and preparation method thereof | |
| CN104559150A (en) | Antistatic caprolactam heat-conducting material and preparation method thereof | |
| CN106147185B (en) | Conductive polycarbonate basal granule material, its preparation method and the application of the carbon nanomaterial containing multidimensional | |
| CN105199191B (en) | A kind of high tenacity heat conductive flame-retarding plastics and preparation method thereof | |
| CN105295317A (en) | High-temperature resistance and low-temperature resistance PBT heat conduction and heat dissipating material, preparation method and applications thereof | |
| CN105440665A (en) | Low-filling high-heat conductivity insulating nylon/polyphenyl ether alloy and preparation method thereof | |
| CN107523049A (en) | A kind of graphene macromolecule composite heat-conducting plastics and preparation method | |
| CN105385118A (en) | High-CTI-value flame-retardant and reinforced PBT (polybutylene terephthalate) composite material | |
| CN107446231A (en) | A kind of composite polyethylene material being modified jointly by graphene, CNT and fullerene and preparation method thereof | |
| CN104845127A (en) | Halogen-free flame-retardant modified PET/PTT/TPEE composite material | |
| CN106700218A (en) | Fluoropolymer heat-shrinkable sleeve and production method thereof | |
| CN104151789B (en) | A kind of low warpage, high pressure PBT modification class material and preparation method thereof | |
| CN106700253B (en) | A kind of low-contraction low-density PP material and preparation method thereof | |
| CN103819895B (en) | A kind of epoxide group modified graphite and heat conduction nylon composite materials and preparation thereof | |
| CN106147184A (en) | Low content CNT Merlon composite anti-static masterbatch and preparation method thereof | |
| CN105482263A (en) | Method for preparing heat-resistant and shrinkage-resistant polypropylene composite | |
| CN106118019A (en) | A kind of high-performance conductive engineering plastics | |
| CN105176021A (en) | Preparation method of high-impact-resistance polyethylene terephthalate particles | |
| CN107573651A (en) | A kind of polybutylene terephthalate (PBT)/makrolon insulating heat-conductive composite |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190506 Address after: 518000 Guangdong Province Guangming New District Baihuadong Zhongxinbao Low Carbon Technology Industrial Park A2 Building 401 Patentee after: Shenzhen New Carbon Technology Co., Ltd. Address before: 213000 No. 6 Xiangyun Road, West Taihu Science and Technology Industrial Park, Changzhou City, Jiangsu Province Patentee before: CHANGZHOU XICAI CARBON MATERIAL TECHNOLOGY CO., LTD. |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180817 Termination date: 20200323 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |