CN105694248A - TPE (thermal plastic elastomer) and application thereof - Google Patents
TPE (thermal plastic elastomer) and application thereof Download PDFInfo
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- CN105694248A CN105694248A CN201610157817.9A CN201610157817A CN105694248A CN 105694248 A CN105694248 A CN 105694248A CN 201610157817 A CN201610157817 A CN 201610157817A CN 105694248 A CN105694248 A CN 105694248A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
- C08J2323/28—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Road Paving Structures (AREA)
Abstract
The invention relates to a TPE (thermal plastic elastomer) and application thereof, and belongs to the technical field of the macromolecular TPE. The TPE is characterized by being prepared by adding the following raw materials in parts by weight into an internal mixer to be subjected to 105-DEG C internal mixing: 90 to 110 parts of chlorinated polyethylene, 10 to 20 parts of calcium carbonate, 0.5 to 1.5 parts of cross-linking agents, 0.3 to 1.5 parts of accessory ingredients, 0.3 to 1.5 parts of zinc oxide and 1.5 to 2.1 parts of azodicarbonamide. The TPE has the characteristics of aging resistance, color change avoidance, flame-retardant performance, high tensile strength and the like, and can be applied to runway color particles, lawn color particles, lawn buffer ground pads and prefabricated runway coiled materials.
Description
Technical field
The present invention relates to a kind of TPE elastomer and application thereof, belong to macromolecule thermoplastic elastomer technical field。
Background technology
Thermoplastic elastomer (TPE), is the elasticity under room temperature with rubber, has a class elastomer of plasticization molding under high temperature。Thermoplastic elastomers has the physical and mechanical properties of vulcanite and the performance of technical process of thermoplastic, is a kind of novel high polymer material between rubber and resin, is often called third generation rubber by people。
There are some defects in TPE elastomer, its thermostability is not so good as rubber, and along with temperature rising, physical property declines by a big margin, thus the scope of application is restricted。Meanwhile, compression, rebound elasticity, the equivalent rubber of durability are compared poor, and price is also often higher than similar rubber。But generally speaking, the advantage of TPE is still very prominent, shortcoming is then among updating, and as the rubber novel material of a kind of energy-conserving and environment-protective, development prospect is very good。
EPDM granule and EPDM granule ageing resistace, color fastness, hot strength, the demand that can not normally meet high-end athletic ground fire-retardant, elastic for athletic ground, rebound degree, resist tension impact that ground fractures brings, color fading, particle aging etc. after 1 year bring a lot of drawback to athletic ground, lawn granule mostly with black rubber particles filled, highly seasoned not environmentally。Place, lawn promotes for elasticity and the cushion effect on lawn, and Prefabricated runway is another upgrading on athletic ground, the more environmentally-friendly product in high-end athletic ground。
Summary of the invention
The invention discloses a kind of TPE elastomer, this TPE elastomer have not aging, not complexion changed, the characteristic such as fire-retardant, hot strength is high, can be applicable to runway color grains, lawn color grains, lawn cushioned floor mat, Prefabricated runway coiled material。
What the present invention adopted the specific scheme is that
A kind of TPE elastomer, is joined in banbury by the raw material of following mass fraction, prepares through 105 degree of internally mixes: chlorinated polyethylene 90-110, calcium carbonate 10-20, cross-linking agent 0.5-1.5, auxiliary agent 0.3-1.5, zinc oxide 0.3-1.5, azodicarbonamide 1.5-2.1。
Preferably, it is joined in banbury by the raw material of following mass fraction, prepares through 105 degree of internally mixes: chlorinated polyethylene 100, calcium carbonate 15, cross-linking agent 1, auxiliary agent 0.5, zinc oxide 0.5, azodicarbonamide 1.5。
Wherein, cross-linking agent is crosslinking agent B IPB, and its Chinese name is called dual-tert-butyl peroxy isopropyl base benzene;Auxiliary agent is TAIC, and its Chinese name is called Triallyl isocyanurate;Both can directly commercially be commercially available。
TPE elastomer of the present invention can be applicable to lawn cushioned floor mat, Prefabricated runway coiled material;Runway color grains, lawn color grains is applied also for by adding pigment。
Wherein, the application in runway color grains of the described TPE elastomer, comprise the steps:
(1) raw material of following mass fraction is prepared: chlorinated polyethylene 90-110, calcium carbonate 10-20, cross-linking agent 0.5-1.5, auxiliary agent 0.3-1.5, zinc oxide 0.3-1.5, azodicarbonamide 1.5-2.1, pigment 1-2。
(2) raw material that step (1) prepares is joined in banbury, through banbury to 105 degree internally mix, begin to pratise entrance film-discharging machine then through mill。
(3) according to foaming vulcanizer grinding tool cutting sample block, and sample block is heated to 180 DEG C carry out foaming sulfuration 15 minutes, then through cutting disintegrating machine do the color grains of 2-3 millimeter for court and runway cover。
Wherein, described pigment can require to select conventional pigment according to the color producing product, for instance during preparation green particles, it is possible to selects iron oxide green or titanium chrome green as pigment。
TPE elastomer application in the color grains of lawn, comprises the steps:
(1) raw material of following mass fraction is prepared: chlorinated polyethylene 90-110, calcium carbonate 10-20, cross-linking agent 0.5-1.5, auxiliary agent 0.3-1.5, zinc oxide 0.3-1.5, azodicarbonamide 1.5-2.1, pigment 1-2。
(2) raw material that step (1) prepares is joined in banbury, through banbury to 105 degree internally mix, cut into strip with cutter standby。
(3) strip begun to pratise being put into extruder, the strip of extrusion diameter 2 millimeters carries out Water Cutting, makes TPE lawn color grains。
Wherein, described pigment can require to select conventional pigment according to the color producing product, for instance during preparation green particles, it is possible to selects iron oxide green or titanium chrome green as pigment。
TPE elastomer application in the cushioned floor mat of lawn, comprises the steps:
(1) raw material of following mass fraction is prepared: chlorinated polyethylene 90-110, calcium carbonate 10-20, cross-linking agent 0.5-1.5, auxiliary agent 0.3-1.5, zinc oxide 0.3-1.5, azodicarbonamide 1.5-2.1。
(2) raw material that step (1) prepares is joined in banbury, through banbury to 105 degree internally mix, stand-by after slice。
(3) after the mixture cutting obtained in step (2), enter foaming vulcanizer, set density seamer and form foaming coiled and do cushioned floor mat。
TPE elastomer application in Prefabricated runway coiled material, comprises the steps:
(1) raw material of following mass fraction is prepared: chlorinated polyethylene 90-110, calcium carbonate 10-20, cross-linking agent 0.5-1.5, auxiliary agent 0.3-1.5, zinc oxide 0.3-1.5, azodicarbonamide 1.5-2.1。
(2) raw material that step (1) prepares is joined in banbury, through banbury to 105 degree internally mix, then begin to pratise with mill。
(3) set size after beginning to pratise, make Prefabricated runway coiled material。
The invention have the advantage that TPE elastomer of the present invention have not aging, not complexion changed, the characteristic such as fire-retardant, hot strength is high。Can be applicable to the aspects such as runway color grains, lawn color grains, lawn cushioned floor mat, Prefabricated runway coiled material。
Detailed description of the invention
Embodiment 1
Prepare the raw material of following mass fraction: chlorinated polyethylene 100, calcium carbonate 15, cross-linking agent 1, auxiliary agent 0.5, zinc oxide 0.5, azodicarbonamide 1.5。
The raw material of above-mentioned mass fraction is joined in banbury, makes TPE elastomer through 105 degree of internally mixes。
Embodiment 2
Prepare the raw material of following mass fraction: chlorinated polyethylene 90, calcium carbonate 10, cross-linking agent 0.5, auxiliary agent 0.3, zinc oxide 0.3, azodicarbonamide 1.5。
The raw material of above-mentioned mass fraction is joined in banbury, makes TPE elastomer through 105 degree of internally mixes。
Embodiment 3
Prepare the raw material of following mass fraction: chlorinated polyethylene 110, calcium carbonate 20, cross-linking agent 1.5, auxiliary agent 1.5, zinc oxide 1.5, azodicarbonamide 2.1。
The raw material of above-mentioned mass fraction is joined in banbury, makes TPE elastomer through 105 degree of internally mixes。
Embodiment 1 is the preferred version of the present invention。
TPE elastomer in embodiment 1 is made the TPE granule that particle diameter is 1-3mm。TPE granule is carried out environmental protection tests。
Table 1 is the environmental protection tests of embodiment 1TPE granule
Table 1
By the ratio of the TPE granule of above-described embodiment 1 with binding agent 1:5 by weight, mixing and stirring, compacting paves and makes lamellar, and its aging resistance degree and physical property are detected。
Table 2 is the particle aging testing inspection of embodiment 1
Table 2
Table 3 is the physical property detection of embodiment 1
Claims (7)
1. a TPE elastomer, it is characterised in that described TPE elastomer is joined in banbury by the raw material of following mass fraction, prepares through 105 degree of internally mixes:
Chlorinated polyethylene 90-110
Calcium carbonate 10-20
Cross-linking agent 0.5-1.5
Auxiliary agent 0.3-1.5
Zinc oxide 0.3-1.5
Azodicarbonamide 1.5-2.1。
2. TPE elastomer according to claim 1, it is characterised in that described TPE elastomer is joined in banbury by the raw material of following mass fraction, prepares through 105 degree of internally mixes:
Chlorinated polyethylene 100
Calcium carbonate 15
Cross-linking agent 1
Auxiliary agent 0.5
Zinc oxide 0.5
Azodicarbonamide 1.5。
3. the TPE elastomer according to claim 1 or claim 2, it is characterised in that described cross-linking agent is crosslinking agent B IPB, auxiliary agent is TAIC。
4. the TPE elastomer application in the cushioned floor mat of lawn, it is characterised in that comprise the steps:
(1) raw material of following mass fraction is prepared: chlorinated polyethylene 90-110, calcium carbonate 10-20, cross-linking agent 0.5-1.5, auxiliary agent 0.3-1.5, zinc oxide 0.3-1.5, azodicarbonamide 1.5-2.1;
(2) raw material that step (1) prepares is joined in banbury, through banbury to 105 degree internally mix, stand-by after slice;
(3) after the mixture cutting obtained in step (2), enter foaming vulcanizer, set density seamer and form foaming coiled and do cushioned floor mat。
5. the TPE elastomer application in Prefabricated runway coiled material, it is characterised in that comprise the steps:
(1) raw material of following mass fraction is prepared: chlorinated polyethylene 90-110, calcium carbonate 10-20, cross-linking agent 0.5-1.5, auxiliary agent 0.3-1.5, zinc oxide 0.3-1.5, azodicarbonamide 1.5-2.1;
(2) raw material that step (1) prepares is joined in banbury, through banbury to 105 degree internally mix, then begin to pratise with mill;
(3) set size after beginning to pratise, make Prefabricated runway coiled material。
6. the TPE elastomer application in runway color grains, it is characterised in that comprise the steps:
(1) raw material of following mass fraction is prepared: chlorinated polyethylene 90-110, calcium carbonate 10-20, cross-linking agent 0.5-1.5, auxiliary agent 0.3-1.5, zinc oxide 0.3-1.5, azodicarbonamide 1.5-2.1, pigment 1-2;
(2) raw material that step (1) prepares is joined in banbury, through banbury to 105 degree internally mix, begin to pratise entrance film-discharging machine then through mill;
(3) according to foaming vulcanizer grinding tool cutting sample block, and sample block is heated to 180 DEG C carry out foaming sulfuration 15 minutes, then through cutting disintegrating machine do the color grains of 2-3 millimeter for court and runway cover。
7. the TPE elastomer application in the color grains of lawn, it is characterised in that comprise the steps:
(1) raw material of following mass fraction is prepared: chlorinated polyethylene 90-110, calcium carbonate 10-20, cross-linking agent 0.5-1.5, auxiliary agent 0.3-1.5, zinc oxide 0.3-1.5, azodicarbonamide 1.5-2.1, pigment 1-2;
(2) raw material that step (1) prepares is joined in banbury, through banbury to 105 degree internally mix, cut into strip with cutter standby;
(3) strip begun to pratise being put into extruder, the strip of extrusion diameter 2 millimeters carries out Water Cutting, makes TPE lawn color grains。
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107880409A (en) * | 2016-09-29 | 2018-04-06 | 青岛科技大学 | A kind of bumper and absorbing shock plastic grains and preparation method |
CN107880410A (en) * | 2016-09-29 | 2018-04-06 | 青岛科技大学 | A kind of fretting map Precasting synthetic surface track |
CN107880412A (en) * | 2016-09-29 | 2018-04-06 | 青岛科技大学 | A kind of preparation method of high-elastic environment friendly plastic rubber runway particle |
CN107880411A (en) * | 2016-09-29 | 2018-04-06 | 青岛科技大学 | A kind of fretting map environmental protection lawn particle |
CN107880403A (en) * | 2016-09-29 | 2018-04-06 | 青岛科技大学 | A kind of ageing-resistant environmentally friendly lawn particle |
CN108440822A (en) * | 2018-03-16 | 2018-08-24 | 南京工程学院 | Thermoplastic expanded particles filled plastic cement race track of one kind and preparation method thereof |
CN108822417A (en) * | 2018-07-18 | 2018-11-16 | 合肥峰腾节能科技有限公司 | A kind of rubber flame-retarded thermal insulation material and preparation method thereof |
CN109651827A (en) * | 2018-12-21 | 2019-04-19 | 南京工程学院 | Prefabricated plastic cement race track of full recoverable environmental protection type thermoplasticity and preparation method thereof |
CN110761145A (en) * | 2019-11-28 | 2020-02-07 | 上海元业体育科技有限公司 | Plastic track coiled material with anti-skid function and preparation method thereof |
CN111205657A (en) * | 2020-03-18 | 2020-05-29 | 玖德隆机械(昆山)有限公司 | Prefabricated plastic track coiled material and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050081980A1 (en) * | 2001-02-23 | 2005-04-21 | Phat Cushion Llc | Foam cushion and method of making and using the same |
CN102975324A (en) * | 2012-10-22 | 2013-03-20 | 青岛科技大学 | Preparation method for waste sealing strip rubber powder/rubber type chlorinated polyethylene blending foaming material |
CN103012981A (en) * | 2012-12-13 | 2013-04-03 | 福建永悦科技有限公司 | Material for rubber forming shoes and preparation method of material |
CN103194950A (en) * | 2013-04-28 | 2013-07-10 | 陈行忠 | Novel thermoplastic elastomer composite self-adhesion sport field paving coiled material and manufacture process thereof |
CN104927215A (en) * | 2015-02-06 | 2015-09-23 | 青岛科技大学 | Wear-resistant and flame-retardant plastic track |
-
2016
- 2016-03-18 CN CN201610157817.9A patent/CN105694248A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050081980A1 (en) * | 2001-02-23 | 2005-04-21 | Phat Cushion Llc | Foam cushion and method of making and using the same |
CN102975324A (en) * | 2012-10-22 | 2013-03-20 | 青岛科技大学 | Preparation method for waste sealing strip rubber powder/rubber type chlorinated polyethylene blending foaming material |
CN103012981A (en) * | 2012-12-13 | 2013-04-03 | 福建永悦科技有限公司 | Material for rubber forming shoes and preparation method of material |
CN103194950A (en) * | 2013-04-28 | 2013-07-10 | 陈行忠 | Novel thermoplastic elastomer composite self-adhesion sport field paving coiled material and manufacture process thereof |
CN104927215A (en) * | 2015-02-06 | 2015-09-23 | 青岛科技大学 | Wear-resistant and flame-retardant plastic track |
Non-Patent Citations (3)
Title |
---|
中国建筑防水材料工业协会: "《建筑防水工作手册》", 30 September 1994, 中国建筑工业出版社 * |
张春红等编: "《高分子材料》", 28 February 2016, 北京航空航天大学出版社 * |
葛涛等编著: "《功能性塑料母料生产技术》", 30 June 2006, 中国轻工业出版社 * |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107880409A (en) * | 2016-09-29 | 2018-04-06 | 青岛科技大学 | A kind of bumper and absorbing shock plastic grains and preparation method |
CN107880410A (en) * | 2016-09-29 | 2018-04-06 | 青岛科技大学 | A kind of fretting map Precasting synthetic surface track |
CN107880412A (en) * | 2016-09-29 | 2018-04-06 | 青岛科技大学 | A kind of preparation method of high-elastic environment friendly plastic rubber runway particle |
CN107880411A (en) * | 2016-09-29 | 2018-04-06 | 青岛科技大学 | A kind of fretting map environmental protection lawn particle |
CN107880403A (en) * | 2016-09-29 | 2018-04-06 | 青岛科技大学 | A kind of ageing-resistant environmentally friendly lawn particle |
CN107880412B (en) * | 2016-09-29 | 2021-02-09 | 青岛科技大学 | Preparation method of high-elasticity environment-friendly plastic track particles |
CN108440822A (en) * | 2018-03-16 | 2018-08-24 | 南京工程学院 | Thermoplastic expanded particles filled plastic cement race track of one kind and preparation method thereof |
CN108822417A (en) * | 2018-07-18 | 2018-11-16 | 合肥峰腾节能科技有限公司 | A kind of rubber flame-retarded thermal insulation material and preparation method thereof |
CN109651827A (en) * | 2018-12-21 | 2019-04-19 | 南京工程学院 | Prefabricated plastic cement race track of full recoverable environmental protection type thermoplasticity and preparation method thereof |
CN109651827B (en) * | 2018-12-21 | 2021-08-13 | 南京工程学院 | Fully-recyclable environment-friendly thermoplastic prefabricated plastic track and preparation method thereof |
CN110761145A (en) * | 2019-11-28 | 2020-02-07 | 上海元业体育科技有限公司 | Plastic track coiled material with anti-skid function and preparation method thereof |
CN111205657A (en) * | 2020-03-18 | 2020-05-29 | 玖德隆机械(昆山)有限公司 | Prefabricated plastic track coiled material and preparation method thereof |
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