CN105694090A - Foaming aid for foam plastics - Google Patents

Foaming aid for foam plastics Download PDF

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Publication number
CN105694090A
CN105694090A CN201610232184.3A CN201610232184A CN105694090A CN 105694090 A CN105694090 A CN 105694090A CN 201610232184 A CN201610232184 A CN 201610232184A CN 105694090 A CN105694090 A CN 105694090A
Authority
CN
China
Prior art keywords
foam plastics
parts
foaming aid
present
foaming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610232184.3A
Other languages
Chinese (zh)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Zhigu Ruituo Technology Service Co Ltd
Original Assignee
Wuxi Zhigu Ruituo Technology Service Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Zhigu Ruituo Technology Service Co Ltd filed Critical Wuxi Zhigu Ruituo Technology Service Co Ltd
Priority to CN201610232184.3A priority Critical patent/CN105694090A/en
Publication of CN105694090A publication Critical patent/CN105694090A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0028Use of organic additives containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102Azo-compounds
    • C08J9/103Azodicarbonamide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/04N2 releasing, ex azodicarbonamide or nitroso compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2369/00Characterised by the use of polycarbonates; Derivatives of polycarbonates

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

The invention relates to foam plastics. The foam plastics is made of, by weight, 50-150 parts of polycarbonate, 10-20 parts of trigger, 20-50 parts of foaming agent, 10-30 parts of foaming aid, and 1-10 parts of cross-linking agent. The foam plastics has excellent mechanical performance, heat resistance and contour processing, and is an ideal core layer material for engineering structure.

Description

A kind of foamed plastic blowing promotor
Technical field
The present invention relates to plastic applications, specifically, the present invention relates to a kind of foamed plastic blowing promotor。
Background technology
In order to reduce the weight of plastic product, it is common practice to add foaming agent in the feed, making plastics are formed continuously or discontinuously pore type structure, thus decreasing the use of raw material, reducing raw materials for production cost and product substance。Owing to foaming agent reacts in plastics-production process, pore type structure decreases weight on the one hand so that product becomes slim and graceful, on the other hand, also destroys original compact texture, reduces the structural strength of product, it is necessary to improve in intensity。
Summary of the invention
It is an object of the invention to provide a kind of foamed plastic blowing promotor。
In order to realize the purpose of the present invention, the present invention provides 4-((N-(2-luorobenzyl)-4-(2-fluorophenoxy) benzamido) methyl) benzoic acid purposes in preparing blowing promotor。
Preferably, described blowing promotor can make powder。
Foamed plastic of the present invention has the mechanical performance of excellence, heat resistance and moulding processability, is the desirable core material of engineering structure selection。
Detailed description of the invention
Below by way of the description of detailed description of the invention, the invention will be further described, but this is not limitation of the present invention, those skilled in the art's basic thought according to the present invention, various modifications may be made or improves, but without departing from the basic thought of the present invention, all within the scope of the present invention。
Embodiment 1
Weigh Merlon 80 kilograms, dibenzoyl peroxide 15 kilograms, azodicarbonamide 30 kilograms, 4-((N-(2-luorobenzyl)-4-(2-fluorophenoxy) benzamido) methyl) 20 kilograms of benzoic acid and Methacrylamide 5 kilograms, stir 5 hours with homogenizer, claret is presented to mixture, in implantation glass mould cavity and seal, it is placed in 80 DEG C of circulating water chennels and reacts 36 hours, it is subsequently placed in foaming workpiece, it is placed in electric heating constant-temperature blowing drying box together with foaming workpiece and foams, blowing temperature controls at 120 DEG C, foamed time is 30min, then at 120 DEG C and 150 DEG C, heat treatment is carried out 3 hours respectively, obtain described foamed plastic。
Embodiment 2
Prepare foamed plastic according to the mode identical with embodiment 1, be different in that and do not use 4-((N-(2-luorobenzyl)-4-(2-fluorophenoxy) benzamido) methyl) benzoic acid。
Experimental example
Testing hot strength according to GB/T1040-2006, specimen size is 150mm × 20mm × thickness of slab (8mm), rate of extension 5mm/min。On inspection, the hot strength 61.6Mpa of the sample of embodiment 1, the hot strength 33.3Mpa of the sample of embodiment 2, result compares, and difference has statistical significance (P < 0.05)。As can be seen here, the addition of blowing promotor substantially increases the stretching hardness of product。

Claims (2)

1.4-((N-(2-luorobenzyl)-4-(2-fluorophenoxy) benzamido) methyl) benzoic acid purposes in preparing blowing promotor。
2. purposes according to claim 1, it is characterised in that described blowing promotor can make powder。
CN201610232184.3A 2016-04-14 2016-04-14 Foaming aid for foam plastics Withdrawn CN105694090A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610232184.3A CN105694090A (en) 2016-04-14 2016-04-14 Foaming aid for foam plastics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610232184.3A CN105694090A (en) 2016-04-14 2016-04-14 Foaming aid for foam plastics

Publications (1)

Publication Number Publication Date
CN105694090A true CN105694090A (en) 2016-06-22

Family

ID=56216813

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610232184.3A Withdrawn CN105694090A (en) 2016-04-14 2016-04-14 Foaming aid for foam plastics

Country Status (1)

Country Link
CN (1) CN105694090A (en)

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Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20160622