CN105693942A - Novel acrylic-based resin material applied to mineral-filled type polymer composite and production technology of novel acrylic-based resin material - Google Patents
Novel acrylic-based resin material applied to mineral-filled type polymer composite and production technology of novel acrylic-based resin material Download PDFInfo
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- CN105693942A CN105693942A CN201610255753.6A CN201610255753A CN105693942A CN 105693942 A CN105693942 A CN 105693942A CN 201610255753 A CN201610255753 A CN 201610255753A CN 105693942 A CN105693942 A CN 105693942A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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Abstract
The invention discloses a novel acrylic-based resin material applied to a mineral-filled type polymer composite. The novel acrylic-based resin material is prepared from, by weight, 21.31-23.31 parts of PMMA, 71.57-73.57 parts of MMA, 3.04-3.60 parts of EGDMA, 1.0-1.49 parts of stearic acid, 0.5-0.6 part of 58# fully-refined paraffin wax and 0.0046-0.0050 part of 6-tertiary butyl-2,4-cresol. According to the novel acrylic-based resin material applied to the mineral-filled type polymer composite, the physical property, the hardness, the deformation degree and the processing forms of an acrylic-based product can be effectively improved, the reaction temperature can be lowered, and the reaction speed can be increased. Meanwhile, the invention further discloses a production technology of the acrylic-based resin material.
Description
Technical field
The present invention relates to filler material and manufacture field, particularly a kind of novel refined gram force resin material being applied to mineral-filled polymer composite and production technology thereof。
Background technology
Refined gram force, is again PMMA or acrylic, is derived from English acrylic (acrylic plastics)。Chemical name is polymethyl methacrylate, is a kind of exploitation important plastic macromolecule material earlier, has the good transparency, chemical stability and weatherability, easy dyeing, easily processing, attractive appearance, has a wide range of applications in building industry。
Study in the 8th page of gelation to MMA/EGDMA copolymer/colloidal sol change, crosslink density etc. of China's Master's thesis " preparation of modified organic glass, structure and performance study ", increase along with cross-linking agent, crosslink density increases, and system gel/colloidal sol productivity ratio dramatically increases。
A kind of modified organic glass disclosed in Chinese patent application CN201310610493.6, the following raw material including according to mass fraction meter: polymethyl methacrylate powder 78-85 part, polystyrene resin 20-35 part, maleic anhydride inoculated polypropylene 0.5-0.8 part, esters of silicon acis 1-2 part, stearic acid 0.5-1 part, silicon powder 1-2 part；Described silicon powder is 1000 orders。This modified organic glass has good thermostability, wearability, ageing resistace and impact resistance, and compared with common lucite, its impact strength improves 18%, and hot strength improves 15%, is resistant to 150 DEG C of high temperature；Outdoor use deforms and without be full of cracks for 6 months without variable color, nothing。
A kind of lucite tube disclosed in Chinese patent application CN201210459641.4, it is made up of the raw material of following weight proportion, methyl methacrylate 80～120, azodiisobutyronitrile 0.02～0.03, peroxy dicarbonate diisopropyl fat 0.02～0.03, dibutyl phthalate (DBP) 5～8, stearic acid 0.5～2。With monomers methyl methacrylate for base stock, adopt the polymethyl methacrylate pipe that body centrifugal polymerization method produces, i.e. lucite tube, its transparency is high, light transmittance is more than 92%, and than silica glass on high 10%, refraction index is that 1.49 relative densities are only 1.18。The lucite tube of the present invention has toughness and the resistance to ag(e)ing of excellence, and heat decomposition temperature, more than 200 DEG C, when using temperature less than 80 DEG C, is resistant to the chemical drugss such as diluted acid alkali, oils and fats。
The preparation method that Chinese patent application CN200810205005.2 discloses a kind of acrylic artificial stone, wherein, acryl resin set of monomers becomes methyl methacrylate, isobornyl methacrylate, neopentyl glycol dimethacrylate, methacrylic acid 1,3 butylene glycol ester, trimethylolpropane trimethacrylate。It has the beneficial effect that glossiness is high。
Although the acrylic in lucite or artificial stone has been carried out effective modified by such scheme, but its product hardness, degree of deformation, processability are to be improved, and such scheme (generally requires that reaction temperature is more than 70 DEG C to preparation temperature requirement is higher, the reaction temperature of Chinese patent application CN201210459641.4 is higher than 90 DEG C), and in preparation process, response speed is slow。
Summary of the invention
It is an object of the invention to provide and a kind of can be effectively improved the physical property of acrylic, hardness, degree of deformation, processability, and reduction reaction temperature improves the novel refined gram force resin material being applied to mineral-filled polymer composite of response speed, the invention also discloses the production technology of this refined gram force resin material simultaneously。
The technical scheme is that a kind of novel refined gram force resin material being applied to mineral-filled polymer composite, following parts by weight of component be prepared from:
PMMA21.31～23.31 part
MMA71.57～73.57 part
EGDMA3.04～3.60 part
Stearic acid 1.0～1.49 parts
58# fully-refined paraffin wax 0.55～0.6 part
6 0.0046～0.0050 part of the tert-butyl group-2,4-cresol。
In the above-mentioned novel refined gram force resin material being applied to mineral-filled polymer composite, following parts by weight of component is prepared from:
PMMA21.31～23.31 part
MMA71.57～73.57 part
EGDMA3.04～3.60 part
Stearic acid 1.0～1.49 parts
58# fully-refined paraffin wax 0.55～0.6 part
6 0.0046～0.0050 part of the tert-butyl group-2,4-cresol。
N-dodecyl mercaptan 0.4～0.6 part
Tributyl phosphite 1 part
Methyl ethyl ketone peroxide 0.6～0.8 part
HEMA phosphoesterase 30 .85～1 part。
Wherein, the molecular weight of described PMMA is preferably 105000～110000。
Another object of the present invention is in that to provide the production technology of the above-mentioned novel refined gram force resin material being applied to mineral-filled polymer composite, comprises the following steps:
Step 1: by formula to the MMA adding required weight accurate in reactor, start stirring paddle；
Step 2: open heat medium system, to reactor heat supply；
Step 3: accurately put into PMMA, stearic acid, TBX and melted 58# fully-refined paraffin wax by weight needed for formula in still, and control temperature in the kettle between 50-65 DEG C；
Step 4: after material is completely dissolved in still, by material temperature drop to 30-40 DEG C, accurately adds EGDMA by weight needed for formula, insulated and stirred 1-2 hour, adjust viscosity to standard value detection qualified after filter fill。
In the above-mentioned production technology of novel refined gram force resin material being applied to mineral-filled polymer composite, also include step 5:
Product step 4 obtained is proportionally added into n-dodecyl mercaptan, methyl ethyl ketone peroxide, HEMA phosphate ester and tributyl phosphite when preparing sheet material；
Wherein, being the PMMA of 100 weight portions, MMA, EGDMA, stearic acid, 58# fully-refined paraffin wax compared to total amount, described n-dodecyl mercaptan is 0.4 part；Tributyl phosphite is 1 part；Methyl ethyl ketone peroxide is 0.8 part；HEMA phosphate ester is 0.85 part。
Beneficial effects of the present invention is as follows:
The formula of the present invention increases EDGMA to improve hardness and the plasticity of naval stores；Increase HEMA phosphate ester, improve the processability of product；Reduce n-dodecyl mercaptan, methyl ethyl ketone peroxide adding proportion, when reducing production, ambient temperature is required tighter problem；Use tributyl phosphite, make product reaction more fierce, improve product exothermic temperature, improve reaction conversion ratio, use stearic acid, it is simple to product stripping。
At process aspect, the addition of each material of strict control is smooth, controls reaction temperature in relatively low temperature。
By above-mentioned improvement, the product of the present invention is effectively improved the hardness of acrylic, deformation rate, processing type, and reduces reaction temperature raising response speed。
Detailed description of the invention
Below in conjunction with detailed description of the invention, technical scheme is described in further detail, but does not constitute any limitation of the invention。
Specific embodiment 1:
Step 1: by formula to the MMA adding required weight accurate in reactor, start stirring paddle；
Step 2: open heat medium system, to reactor heat supply；
Step 3: by weight needed for formula to accurately put in still PMMA, stearic acid, 2,4-DI-tert-butylphenol compounds and melted 58# fully-refined paraffin wax, and control temperature in the kettle at about 60 DEG C；
Step 4: after material is completely dissolved in still, by material temperature drop to 35 DEG C, accurately adds EGDMA by weight needed for formula, insulated and stirred 1-2 hour, adjust viscosity to standard value detection qualified after filter fill, obtain acryl resin。
Step 5: after acryl resin step 4 obtained mixes with aluminium hydroxide, is proportionally added into n-dodecyl mercaptan, methyl ethyl ketone peroxide, HEMA phosphate ester and tributyl phosphite；The concrete operations of making sheet are: by acryl resin, after aluminium hydroxide and mill base prepare slurry according to sheet material formula proportion, it is proportionally added into n-dodecyl mercaptan according to amount of resin, methyl ethyl ketone peroxide, after HEMA phosphate ester stirs, utilize vacuum that by dosing pump, slurry suction vacuum pouring machine material chamber is pumped into casting machine sky casting machine by tributyl phosphite simultaneously, material is cast in equably on production line conveyer belt after making it stir in casting machine, it is made to cut after curing molding in conveyer belt running, baking, seamless, sanding, finished product sheet material is obtained after water mill。
The part by weight of acryl resin and aluminium hydroxide is: 29:71；
Wherein, above-mentioned each raw material composition is particularly as follows: PMMA21.31kg
MMA72.57kg
EGDMA3.04kg
Stearic acid 1.49kg
58# fully-refined paraffin wax 0.59kg
6 tert-butyl group-2,4-cresol 0.0046kg。
N-dodecyl mercaptan 0.4kg
Tributyl phosphite 1kg
Methyl ethyl ketone peroxide 0.8kg
HEMA phosphoesterase 30 .85kg。
Specific embodiment 2:
Step 1: by formula to the MMA adding required weight accurate in reactor, start stirring paddle；
Step 2: open heat medium system, to reactor heat supply；
Step 3: accurately put into PMMA, stearic acid, 6 tert-butyl group-2,4-xylenol and melted 58# fully-refined paraffin wax by weight needed for formula in still, and control temperature in the kettle between 65 DEG C；
Step 4: after material is completely dissolved in still, by material temperature drop to 40 DEG C, accurately adds EGDMA by weight needed for formula, insulated and stirred 1-2 hour, adjust viscosity to standard value detection qualified after filter fill, obtain acryl resin。
Step 5: after acryl resin step 4 obtained mixes with aluminium hydroxide, is proportionally added into n-dodecyl mercaptan, methyl ethyl ketone peroxide, HEMA phosphate ester and tributyl phosphite；The concrete operations of making sheet are: by acryl resin, after aluminium hydroxide and mill base prepare slurry according to sheet material formula proportion, it is proportionally added into n-dodecyl mercaptan according to amount of resin, methyl ethyl ketone peroxide, after HEMA phosphate ester stirs, utilize vacuum that by dosing pump, slurry suction vacuum pouring machine material chamber is pumped into casting machine sky casting machine by tributyl phosphite simultaneously, material is cast in equably on production line conveyer belt after making it stir in casting machine, it is made to cut after curing molding in conveyer belt running, baking, seamless, sanding, finished product sheet material is obtained after water mill。
The part by weight of acryl resin and aluminium hydroxide is: 30:70；
Wherein, above-mentioned each raw material composition is particularly as follows: PMMA22.31kg
MMA71.57kg
EGDMA3.3kg
Stearic acid 1.2kg
58# fully-refined paraffin wax 0.59kg
6 tert-butyl group-2,4-cresol 0.0048kg
N-dodecyl mercaptan 0.5kg
Tributyl phosphite 1kg
Methyl ethyl ketone peroxide 0.6kg
HEMA phosphate ester 1kg。
Specific embodiment 3:
Step 1: by formula to the MMA adding required weight accurate in reactor, start stirring paddle；
Step 2: open heat medium system, to reactor heat supply；
Step 3: accurately put into PMMA, stearic acid, 6 tert-butyl group-2,4-xylenol and melted 58# fully-refined paraffin wax by weight needed for formula in still, and control temperature in the kettle between 55 DEG C；
Step 4: after material is completely dissolved in still, by material temperature drop to 30 DEG C, accurately adds EGDMA by weight needed for formula, insulated and stirred 1-2 hour, adjust viscosity to standard value detection qualified after filter fill, obtain acryl resin。
Step 5: after acryl resin step 4 obtained mixes with aluminium hydroxide, is proportionally added into n-dodecyl mercaptan, methyl ethyl ketone peroxide, HEMA phosphate ester and tributyl phosphite；The concrete operations of making sheet are: by acryl resin, after aluminium hydroxide and mill base prepare slurry according to sheet material formula proportion, it is proportionally added into n-dodecyl mercaptan according to amount of resin, methyl ethyl ketone peroxide, after HEMA phosphate ester stirs, utilize vacuum that by dosing pump, slurry suction vacuum pouring machine material chamber is pumped into casting machine sky casting machine by tributyl phosphite simultaneously, material is cast in equably on production line conveyer belt after making it stir in casting machine, it is made to cut after curing molding in conveyer belt running, baking, seamless, sanding, finished product sheet material is obtained after water mill。
The part by weight of acryl resin and aluminium hydroxide is: 33:67；
Wherein, above-mentioned each raw material composition is particularly as follows: PMMA23.31kg
MMA73.57kg
EGDMA3.6kg
Stearic acid 1.0kg
58# fully-refined paraffin wax 0.59kg
6 tert-butyl group-2,4-cresol 0.0048kg
N-dodecyl mercaptan 0.6kg
Tributyl phosphite 1kg
Methyl ethyl ketone peroxide 0.7kg
HEMA phosphoesterase 30 .9kg。
Comparative example 1:
After acryl resin, aluminium hydroxide and mill base are prepared slurry according to sheet material formula proportion, according to amount of resin be proportionally added into n-dodecyl mercaptan, methyl ethyl ketone peroxide, 1227 stir after, utilize vacuum that by dosing pump, slurry suction vacuum pouring machine material chamber is pumped into casting machine sky casting machine by tributyl phosphite simultaneously, material is cast in equably on production line conveyer belt after making it stir in casting machine so that it is in conveyer belt running, after curing molding, after cutting, baking, seamless, sanding, water mill, obtain finished product sheet material。
Wherein: the ratio of resin and aluminium hydroxide is: 30:70
Above-mentioned each raw material composition particularly as follows:
Old acryl resin 100kg (PMMA:21kg；MMA:71.74；Trimethylolpropane trimethacrylate: 5.31kg；Stearic acid: 1.90kg；58# fully-refined paraffin wax 0.63kg；6 tert-butyl group-2,4-cresol 0.004kg)
N-dodecyl mercaptan 0.8kg
Tributyl phosphite 1.2kg
Methyl ethyl ketone peroxide 1.2kg
(12270.2kg dodecyl dimethyl benzyl ammonium chloride)
Performance test
Test plate property
1, sheet material hardness test
Method of testing: GB/T-3854 " reinforced plastics Ba Keer hardness measuring method "；
Test result:
The sheet material hardness of embodiment 1-3 is 65～68。
The sheet material hardness of comparative example 1 is 55～60。
2, processing characteristics test
Method of testing: product is tailored into 60*300mm batten, put into the baking oven of high temperature (100-150 DEG C), toast 1.5-2 hour, do bend test, batten one end, particularly as follows: take out in baking oven after batten softens completely, is first fixed on the wooden circular dies side that diameter is 200mm by crooked experiment, then is prolonged by batten after circular arc bends to mould opposite side and fix the other end, after batten cool down completely, take off batten, and observe product surface situation of change:
After the sheet material of embodiment 1 to 3 toasts 100 minutes in 150 DEG C of baking ovens, 180 ° of bendings, without variable color, blushing, are done in surface, interior outside all without white, turn white, crackle occur, its stable hot-forming temperature can reach 140 DEG C, and bending effect is good。
After the sheet material of comparative example 1 toasts 90 minutes in 120 DEG C of baking ovens, there is slight blushing on surface, does 180 ° of bendings, and turning white substantially in outside, there is crackle at edge, and its hot-forming temperature is lower than 120 DEG C, and bending effect is poor。
3, the test of degree of deformation
Method of testing: be placed on by Product Level on glass plate check-out console, detects its transversely deforming situation with Steel Ruler and feeler gauge。
The degree of deformation of the sheet material of embodiment 1 to 3 is 0.8-1.5mm, it is necessary to explanation: degree of deformation refers to sheet material transversely deforming situation, and namely the width deformation of 760mm is 0.8-1.5mm。
The degree of deformation of the sheet material of comparative example 1 is 5-7mm。
The above-described presently preferred embodiments of the present invention that is only, all any amendment, equivalent replacement and improvement etc. made within the scope of the spirit and principles in the present invention, should be included within protection scope of the present invention。
Claims (5)
1. the novel refined gram force resin material being applied to mineral-filled polymer composite, it is characterised in that: it is prepared from by following parts by weight of component:
PMMA21.31～23.31 part
MMA71.57～73.57 part
EGDMA3.04～3.60 part
Stearic acid 1.0～1.49 parts
58# fully-refined paraffin wax 0.55～0.6 part
6 0.0046～0.0050 part of the tert-butyl group-2,4-cresol。
2. the novel refined gram force resin material being applied to mineral-filled polymer composite according to claim 1, it is characterised in that: it is prepared from by following parts by weight of component:
PMMA21.31～23.31 part
MMA71.57～73.57 part
EGDMA3.04～3.60 part
Stearic acid 1.0～1.49 parts
58# fully-refined paraffin wax 0.55～0.6 part
6 0.0046～0.0050 part of the tert-butyl group-2,4-cresol。
N-dodecyl mercaptan 0.4～0.6 part
Tributyl phosphite 1 part
Methyl ethyl ketone peroxide 0.6～0.8 part
HEMA phosphoesterase 30 .85～1 part。
3. the novel refined gram force resin material being applied to mineral-filled polymer composite according to claim 1 and 2, it is characterised in that: the molecular weight of described PMMA is 105000～110000。
4. the production technology of the novel refined gram force resin material being applied to mineral-filled polymer composite as claimed in claim 1 or 2, it is characterised in that: comprise the following steps:
Step 1: by formula to the MMA adding required weight accurate in reactor, start stirring paddle；
Step 2: open heat medium system, to reactor heat supply；
Step 3: accurately put into PMMA, stearic acid, 6 tert-butyl group-2,4-cresol and melted 58# fully-refined paraffin wax by weight needed for formula in still, and control temperature in the kettle between 50-65 DEG C；
Step 4: after material is completely dissolved in still, by material temperature drop to 30-40 DEG C, accurately adds EGDMA by weight needed for formula, insulated and stirred 1-2 hour, adjust viscosity to standard value detection qualified after filter fill。
5. the production technology of the novel refined gram force resin material being applied to mineral-filled polymer composite according to claim 4, it is characterised in that: also include step 5:
Product step 4 obtained is proportionally added into n-dodecyl mercaptan, methyl ethyl ketone peroxide, HEMA phosphate ester and tributyl phosphite when preparing sheet material；
Wherein, being the PMMA of 100 weight portions, MMA, EGDMA, stearic acid, 58# fully-refined paraffin wax compared to total amount, described n-dodecyl mercaptan is 0.4～0.6 part；Tributyl phosphite is 1 part；Methyl ethyl ketone peroxide is 0.6～0.8 part；HEMA phosphate ester is 0.85～1 part。
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109438615A (en) * | 2018-11-15 | 2019-03-08 | 张金娥 | High-intensitive acryl plates and its preparation process |
| CN109485779A (en) * | 2018-10-12 | 2019-03-19 | 张金娥 | A kind of high-strength water-resistance acryl plates |
| CN109485780A (en) * | 2018-10-12 | 2019-03-19 | 张金娥 | Acryl plates and its preparation process |
| CN115974455A (en) * | 2022-12-15 | 2023-04-18 | 清远戈兰迪高分子材料有限公司 | Ultraviolet aging resistant quartz stone plate and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1012184A (en) * | 1962-06-11 | 1965-12-08 | Rohm & Haas | Resinous compositions |
| CN1993299A (en) * | 2004-08-12 | 2007-07-04 | Lg化学株式会社 | Resin composition comprising styrene-methylmethacrylate copolymer, artificial marble produced using the same, and the process for producing the artificial marble using the same |
| CN101362814A (en) * | 2008-07-23 | 2009-02-11 | 郑德龙 | Prepolymer of room temperature curable yakeli resin for artificial marble manufacture |
| CN101570413A (en) * | 2008-12-30 | 2009-11-04 | 上海新天和树脂有限公司 | Acrylic artificial stone and method for preparing same |
| US20120091618A1 (en) * | 2010-10-19 | 2012-04-19 | Binhussain Mohammed A | Synthetic composition of marble and method of production |
| CN103189327A (en) * | 2010-10-19 | 2013-07-03 | 乐金华奥斯株式会社 | Synthetic acrylic marble having pearl-containing pattern and method of producing the same |
| CN104926198A (en) * | 2015-06-17 | 2015-09-23 | 必图实业（东莞）有限公司 | Preparation method for novel quartz stone plate |
-
2016
- 2016-04-22 CN CN201610255753.6A patent/CN105693942A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1012184A (en) * | 1962-06-11 | 1965-12-08 | Rohm & Haas | Resinous compositions |
| CN1993299A (en) * | 2004-08-12 | 2007-07-04 | Lg化学株式会社 | Resin composition comprising styrene-methylmethacrylate copolymer, artificial marble produced using the same, and the process for producing the artificial marble using the same |
| CN101362814A (en) * | 2008-07-23 | 2009-02-11 | 郑德龙 | Prepolymer of room temperature curable yakeli resin for artificial marble manufacture |
| CN101570413A (en) * | 2008-12-30 | 2009-11-04 | 上海新天和树脂有限公司 | Acrylic artificial stone and method for preparing same |
| US20120091618A1 (en) * | 2010-10-19 | 2012-04-19 | Binhussain Mohammed A | Synthetic composition of marble and method of production |
| CN103189327A (en) * | 2010-10-19 | 2013-07-03 | 乐金华奥斯株式会社 | Synthetic acrylic marble having pearl-containing pattern and method of producing the same |
| CN104926198A (en) * | 2015-06-17 | 2015-09-23 | 必图实业（东莞）有限公司 | Preparation method for novel quartz stone plate |
Non-Patent Citations (3)
| Title |
|---|
| 于威廉: "《高分子电介质化学》", 31 July 1980, 机械工业出版社 * |
| 张治国: "《塑料高分子溶液成型技术问答》", 31 January 2012, 印刷工业出版社 * |
| 裘正隆: "《购销员实用手册》", 30 April 1991, 上海科学技术出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109485779A (en) * | 2018-10-12 | 2019-03-19 | 张金娥 | A kind of high-strength water-resistance acryl plates |
| CN109485780A (en) * | 2018-10-12 | 2019-03-19 | 张金娥 | Acryl plates and its preparation process |
| CN109485779B (en) * | 2018-10-12 | 2021-04-16 | 龙南新涛亚克力科技有限公司 | High-strength waterproof acrylic sheet |
| CN109485780B (en) * | 2018-10-12 | 2021-06-22 | 湖州久益有机玻璃有限公司 | Acrylic sheet and preparation process thereof |
| CN109438615A (en) * | 2018-11-15 | 2019-03-08 | 张金娥 | High-intensitive acryl plates and its preparation process |
| CN115974455A (en) * | 2022-12-15 | 2023-04-18 | 清远戈兰迪高分子材料有限公司 | Ultraviolet aging resistant quartz stone plate and preparation method thereof |
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