CN105670561A - Safe environment-friendly heating water antitheft drug and preparing method thereof - Google Patents
Safe environment-friendly heating water antitheft drug and preparing method thereof Download PDFInfo
- Publication number
- CN105670561A CN105670561A CN201610110524.5A CN201610110524A CN105670561A CN 105670561 A CN105670561 A CN 105670561A CN 201610110524 A CN201610110524 A CN 201610110524A CN 105670561 A CN105670561 A CN 105670561A
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- CN
- China
- Prior art keywords
- antitheft
- heating water
- medicament
- safety
- environmental protection
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
- C02F5/145—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus combined with inorganic substances
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention relates to a safe environment-friendly heating water antitheft drug and a preparing method thereof. The method comprises the following steps: adding allicin proportionally into a stirring kettle A, heating to 50-80 DEG C, adding auxiliaries, and stirring for 15-60min till uniform mixing to obtain a mixed solution A; adding a corrosion and scale inhibitor into a stirring kettle B, heating to 50-80 DEG C, adding the mixed solution A, and stirring at high speed for 30min to disperse the materials to obtain the safe environment-friendly heating water antitheft drug. The drug and the preparing method have the beneficial effects: 1, no waste is generated in the whole process, clean production and environment protection with zero emission are realized, environment friendliness is realized, and no toxicity and pollution exist; 2, the antitheft drug uses the allicin as the main odor agent and is environment-friendly without toxicity; 3, the corrosion and scale inhibitor is added, so that the allicin and the corrosion and scale inhibitor are matched for use, and achieve certain protection for the pipeline of a heating system.
Description
Technical field
The invention belongs to heating water anti-theft agent field, particularly relate to a kind of antitheft medicament of safety and environmental protection heating water and preparation method thereof.
Background technology
At present, often occurring user privately to steal in the area of heating and put heating water, cause that boiler water level declines, not only add the heat cost of heating enterprise, and have a strong impact on overall heating effect, heating department is also without good solution.
Antitheft medicament relevant in the market is all much adopt thio-alcohol, and such as ethyl mercaptan and butyl mercaptan, but thiol class substance is toxic big and pipeline has certain corrosive shortcoming.
Summary of the invention
The technical problem to be solved is: for the problems referred to above, the invention provides a kind of antitheft medicament of safety and environmental protection heating water added in heating water and preparation method thereof, this antitheft medicament of safety and environmental protection heating water is added to the water and has a kind of unjoyful bionic poisonless abnormal smells from the patient of making us, and this heating water can be made to develop the color according to customer requirement.
The present invention solves that problem set forth above be the technical scheme is that
The preparation method of a kind of antitheft medicament of safety and environmental protection heating water, comprises the following steps:
A) in stirred tank A, first add garlicin in proportion, be warming up to 50~80 DEG C, add auxiliary agent, stir 15~60 minutes to mix homogeneously, obtain mixed liquor A;
B) adding corrosion inhibiting and descaling agent in stirred tank B, be warming up to 50~80 DEG C, add mixed liquor A, high-speed stirred makes material dispersion in 30 minutes, obtains the antitheft medicament of safety and environmental protection heating water.
In described step a), described reaction temperature is at 60~70 DEG C.
In described step b), described reaction temperature is at 55~65 DEG C.
The mass ratio of described garlicin and corrosion inhibiting and descaling agent is (15~70): 50.
In described corrosion inhibiting and descaling agent, it is ATMP: 10-24%, methyl benzotriazazole: 1-3%, 1-hydroxy ethylidene-1,1-diphosphonic acid: 8-15, hydrolytic polymaleic anhydride: 2-8%, imidazoline quaternary ammonium salt: 2-6%, sodium hydroxide: 1-5%, water: 40-65% that each component accounts for the mass percent of described corrosion inhibiting and descaling agent gross mass.
Described auxiliary agent includes emulsifying agent.
Described emulsifying agent is the one in OP-10, NP-10, NPE-10 or combination in any.
The present invention provides a kind of antitheft medicament of safety and environmental protection heating water, and preparation method by mentioned earlier prepares.
The beneficial effects of the present invention is: 1, the whole technique of the present invention does not produce garbage, it is achieved that cleaning produces and environmental protection is without discharge, environmentally friendly, nontoxic pollution-free. 2, this antitheft medicament uses garlicin to be main body odorant agent, environment-protecting asepsis evil. 3, with the addition of corrosion inhibiting and descaling agent so that garlicin and corrosion inhibiting and descaling agent with the use of, the pipeline of heating system is played a kind of protective effect.
Detailed description of the invention
In order to be further appreciated by the present invention, embodiments of the invention are further illustrated below.
Embodiment 1
Stirred tank A adds the garlicin of 150 kilograms, is warming up to 70 DEG C, add auxiliary agent 20 kilograms, stir 30 minutes to mix homogeneously, obtain mixed liquor A;
Adding corrosion inhibiting and descaling agent 500 kilograms in stirred tank B, be warming up to 65 DEG C, add mixed liquor A, high-speed stirred makes material dispersion in 30 minutes, obtains the antitheft medicament of safety and environmental protection heating water.
Described corrosion inhibiting and descaling agent is made up of the component of following mass percent:
ATMP: 18%, methyl benzotriazazole: 2%, 1-hydroxy ethylidene-1,1-diphosphonic acid: 10, hydrolytic polymaleic anhydride: 7%, imidazoline quaternary ammonium salt: 4%, sodium hydroxide: 4%, water: 55%.
Embodiment 2
Stirred tank A adds the garlicin of 300 kilograms, is warming up to 60 DEG C, add auxiliary agent 40 kilograms, stir 30 minutes to mix homogeneously;
Stirred tank B adds corrosion inhibiting and descaling agent 250 kilograms, is warming up to 55 DEG C, adds mixed liquor A, 30 minutes material dispersions of high-speed stirred, obtain the antitheft medicament of safety and environmental protection heating water.
Described corrosion inhibiting and descaling agent is made up of the component of following mass percent:
ATMP: 20%, methyl benzotriazazole: 2%, 1-hydroxy ethylidene-1,1-diphosphonic acid: 13, hydrolytic polymaleic anhydride: 5%, imidazoline quaternary ammonium salt: 5%, sodium hydroxide: 5%, water: 50%.
Having the beneficial effects that of this detailed description of the invention: 1, do not produce garbage in the whole technique of the present invention, it is achieved that cleaning produces and environmental protection is without discharge, environmentally friendly, nontoxic pollution-free. 2, this antitheft medicament uses garlicin to be main body odorant agent, environment-protecting asepsis evil. 3, with the addition of corrosion inhibiting and descaling agent so that garlicin and corrosion inhibiting and descaling agent with the use of, the pipeline of heating system is played a kind of protective effect.
Specific embodiments of the invention are not construed as limiting the invention, the analog structure of every employing present invention and change, all in protection scope of the present invention.
Claims (6)
1. a preparation method for the antitheft medicament of safety and environmental protection heating water, comprises the following steps:
A) in stirred tank A, first add garlicin in proportion, be warming up to 50~80 DEG C, add auxiliary agent, stir 15~60 minutes to mix homogeneously, obtain mixed liquor A;
B) adding corrosion inhibiting and descaling agent in stirred tank B, be warming up to 50~80 DEG C, add mixed liquor A, high-speed stirred makes material dispersion in 30 minutes, obtains the antitheft medicament of safety and environmental protection heating water.
2. the preparation method of a kind of antitheft medicament of safety and environmental protection heating water as claimed in claim 1, it is characterised in that: in described step a), described reaction temperature is at 60~70 DEG C.
3. the preparation method of a kind of antitheft medicament of safety and environmental protection heating water as claimed in claim 2, it is characterised in that: in described step b), described reaction temperature is at 55~65 DEG C.
4. the preparation method of a kind of antitheft medicament of safety and environmental protection heating water as claimed in claim 1, it is characterised in that: the mass ratio of described garlicin and corrosion inhibiting and descaling agent is (15~70): 50.
5. the preparation method of a kind of antitheft medicament of safety and environmental protection heating water as claimed in claim 4, it is characterized in that: in described corrosion inhibiting and descaling agent, it is ATMP: 10-24%, methyl benzotriazazole: 1-3%, 1-hydroxy ethylidene-1,1-diphosphonic acid: 8-15, hydrolytic polymaleic anhydride: 2-8%, imidazoline quaternary ammonium salt: 2-6%, sodium hydroxide: 1-5%, water: 40-65% that each component accounts for the mass percent of described corrosion inhibiting and descaling agent gross mass.
6. the antitheft medicament of safety and environmental protection heating water, the preparation method described in any one of claim 1-5 prepares.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610110524.5A CN105670561A (en) | 2016-02-29 | 2016-02-29 | Safe environment-friendly heating water antitheft drug and preparing method thereof |
Applications Claiming Priority (1)
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CN201610110524.5A CN105670561A (en) | 2016-02-29 | 2016-02-29 | Safe environment-friendly heating water antitheft drug and preparing method thereof |
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CN105670561A true CN105670561A (en) | 2016-06-15 |
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CN201610110524.5A Pending CN105670561A (en) | 2016-02-29 | 2016-02-29 | Safe environment-friendly heating water antitheft drug and preparing method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108224545A (en) * | 2018-01-02 | 2018-06-29 | 辽宁大学 | Antitheft additive of boiler heating water and its preparation method and application |
CN108383250A (en) * | 2018-03-27 | 2018-08-10 | 仝建乐 | A kind of boiler network anti-corrosion corrosion and scale inhibition disperser and preparation method thereof |
CN108485724A (en) * | 2018-05-30 | 2018-09-04 | 中冶京诚工程技术有限公司 | Artificial gas scale inhibition system and slow release descaling method |
CN109401728A (en) * | 2018-11-29 | 2019-03-01 | 廊坊萍锅炉保养工程有限公司 | A kind of non-corrosive nontoxic peculiar smell agent of the anti-lost water of pipe network |
Citations (5)
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CN1253914A (en) * | 1999-02-01 | 2000-05-24 | 田洪发 | Method for preventing heating water of boiler from illegal using |
CN1267872A (en) * | 1999-03-19 | 2000-09-27 | 中国科学院化工冶金研究所 | Method of preventing illegal use of circular water in boiler heating system |
CN1559918A (en) * | 2004-03-05 | 2005-01-05 | 赵玉俊 | Multifunctonal peculiar smell colour changing agent |
CN102010077A (en) * | 2010-12-29 | 2011-04-13 | 李秀宁 | Non-phosphate anti-incrustation corrosion inhibitor and preparation process thereof |
CN104449562A (en) * | 2014-12-03 | 2015-03-25 | 田洪太 | Boiler heating water anti-theft agent and preparation method thereof |
-
2016
- 2016-02-29 CN CN201610110524.5A patent/CN105670561A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1253914A (en) * | 1999-02-01 | 2000-05-24 | 田洪发 | Method for preventing heating water of boiler from illegal using |
CN1267872A (en) * | 1999-03-19 | 2000-09-27 | 中国科学院化工冶金研究所 | Method of preventing illegal use of circular water in boiler heating system |
CN1559918A (en) * | 2004-03-05 | 2005-01-05 | 赵玉俊 | Multifunctonal peculiar smell colour changing agent |
CN102010077A (en) * | 2010-12-29 | 2011-04-13 | 李秀宁 | Non-phosphate anti-incrustation corrosion inhibitor and preparation process thereof |
CN104449562A (en) * | 2014-12-03 | 2015-03-25 | 田洪太 | Boiler heating water anti-theft agent and preparation method thereof |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108224545A (en) * | 2018-01-02 | 2018-06-29 | 辽宁大学 | Antitheft additive of boiler heating water and its preparation method and application |
CN108383250A (en) * | 2018-03-27 | 2018-08-10 | 仝建乐 | A kind of boiler network anti-corrosion corrosion and scale inhibition disperser and preparation method thereof |
CN108485724A (en) * | 2018-05-30 | 2018-09-04 | 中冶京诚工程技术有限公司 | Artificial gas scale inhibition system and slow release descaling method |
CN108485724B (en) * | 2018-05-30 | 2023-09-26 | 中冶京诚工程技术有限公司 | Artificial gas scale inhibition system and slow release scale removal method |
CN109401728A (en) * | 2018-11-29 | 2019-03-01 | 廊坊萍锅炉保养工程有限公司 | A kind of non-corrosive nontoxic peculiar smell agent of the anti-lost water of pipe network |
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Application publication date: 20160615 |