CN105669144B - A method of preparing inorganic clad plate using dealkalize red mud and red mud iron selection tailings - Google Patents

A method of preparing inorganic clad plate using dealkalize red mud and red mud iron selection tailings Download PDF

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Publication number
CN105669144B
CN105669144B CN201610009329.3A CN201610009329A CN105669144B CN 105669144 B CN105669144 B CN 105669144B CN 201610009329 A CN201610009329 A CN 201610009329A CN 105669144 B CN105669144 B CN 105669144B
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China
Prior art keywords
red mud
dealkalize
iron selection
selection tailings
sulphate aluminium
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Expired - Fee Related
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CN201610009329.3A
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Chinese (zh)
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CN105669144A (en
Inventor
段广彬
张秀芝
王文龙
刘宗明
侯清月
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University of Jinan
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University of Jinan
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Priority to CN201610009329.3A priority Critical patent/CN105669144B/en
Priority claimed from CN201410285626.1A external-priority patent/CN104119052B/en
Publication of CN105669144A publication Critical patent/CN105669144A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention discloses a kind of methods preparing inorganic clad plate using dealkalize red mud and red mud iron selection tailings, which is characterized in that includes the dispensing of following parts by weight:Sulphate aluminium cement 200-250, dealkalize red mud 300-400, red mud iron selection tailings 350-400, polyacrylonitrile fibre 10 20 and water 60 100.The present invention is prepared using the technique of compression moulding, is conserved in air using dealkalize red mud, red mud iron selection tailings, polyacrylonitrile fibre as primary raw material using sulphate aluminium cement as gelling agent.The inorganic composite plate of preparation has the excellent specific properties such as lightweight, high-strength, sound insulation, fire-retardant, shock resistance; it can be widely applied to Discussion on architecture wall; composite plate consumption Industrial Solid Waste amount is big, is conducive to energy saving, environmental protection, and can be that building energy saving field develop new plate product.

Description

A method of preparing inorganic clad plate using dealkalize red mud and red mud iron selection tailings
Technical field
The present invention relates to novel wall material fields, in particular, being related to a kind of selecting iron tail using dealkalize red mud and red mud The method that mine prepares inorganic clad plate.
Background technology
The comprehensive utilization of resources and building energy conservation of trade waste have become the fundamental state policy in China, therefore, utilize The New Building Materials that large trade waste development meets compound national standard are extremely urgent, also have become vast scientific research Worker's inescapable responsibility.
Inorganic composite materials are built since it has many advantages, such as that performance is stable, deformation coefficient is small, anti-aging property is strong The extensive concern of industry inside and outside wall board application.Therefore, the composite plate prepared by the solid inorganic materials such as red mud is applied to wall material In material, there is extensive popularizing application prospect.
Currently, with China's industrial technology and expanding economy, large Industrial Solid Waste bulk deposition such as red mud.Only with red mud For, accumulative volume of cargo in storage is up to 2.8 hundred million tons within 2014.These solid wastes are less than recycling, land occupation, waste of resource, Environmental pollution and security risk are easily caused again, and huge loss is brought to the production, life and the development of the national economy of the people.
Invention content
The technical problem to be solved in the present invention is to provide a kind of prepared using dealkalize red mud and red mud iron selection tailings it is inorganic multiple The method of plywood, energy saving, environmental protection.
A method of preparing inorganic clad plate using dealkalize red mud and red mud iron selection tailings, which is characterized in that including such as The dispensing of lower parts by weight:Sulphate aluminium cement 200-250, red mud iron selection tailings 350-400, gathers dealkalize red mud 300-400 Dralon 10-20 and water 60-100, includes the following steps:
(1) boric acid retarder will be added in sulphate aluminium cement;
(2) it is powdered, diameier control by the processing of dry, broken and grinding by dealkalize red mud and red mud iron selection tailings System is tailed in 80 microns of square hole screens not higher than 10%;
(4) using dealkalize red mud, red mud iron selection tailings and polyacrylonitrile fibre as primary raw material, boric acid retarder will be added Sulphate aluminium cement as gelling agent, stirred evenly after adding water and water-reducing agent, at room temperature, use briquetting pressure for 1.5- 2.5MPa, compression moulding plank;
(5) it conserves in air, densification composite plate is made, according to construction needs, cut according to size requirements.
Compared with prior art, the advantages and positive effects of the present invention are:The present invention is using sulphate aluminium cement as glue Solidifying agent is prepared using dealkalize red mud, red mud iron selection tailings, polyacrylonitrile fibre as primary raw material using the technique of compression moulding, It is conserved in air.The inorganic composite plate of preparation has the excellent specific properties such as lightweight, high-strength, sound insulation, fire-retardant, shock resistance, can It is widely used in Discussion on architecture wall, composite plate consumption Industrial Solid Waste amount is big, is conducive to energy saving, environmental protection, and can New plate product is developed for building energy saving field.
Description of the drawings
Fig. 1 is the structural schematic diagram of the inorganic clad plate of the present invention.
Fig. 2 is the inorganic clad plate production process of the present invention.
Specific implementation mode
The present invention is further described in detail with preferred embodiment below in conjunction with the accompanying drawings.
Embodiment one
Take 200 kilograms of sulphate aluminium cement, 300 kilograms of dealkalize red mud, 350 kilograms of red mud iron selection tailings, polyacrylonitrile fine Boric acid retarder will be added in 60 kilograms of 10 kilograms of dimension and water in sulphate aluminium cement, boric acid retarder accounts for alumino-silicate cement weight The 0.2% of amount, sulphate aluminium cement select the cement of the model R.SAC 42.5 of Qufu Zhonglian Cement Co., Ltd.'s production.It will Sulphate aluminium cement, dealkalize red mud and the processing of red mud iron selection tailings are powdered, and diameier requires 80 microns of square hole screens to tail over Not higher than 10%;Using dealkalize red mud, red mud iron selection tailings and polyacrylonitrile fibre as primary raw material, boric acid retarder will be added Sulphate aluminium cement as gelling agent, stirred evenly after adding water and water-reducing agent, wherein water-reducing agent accounts for sulphate aluminium cement, de- The 0.6% of alkali red mud, red mud iron selection tailings, polyacrylonitrile fibre and water total weight uses briquetting pressure for 1.5- at room temperature 2.5Mpa, compression moulding plank.The size of inorganic clad plate of the present invention is 600mm × 200mm × 90mm, with reference to GB/T23451- 2009《Light partition board for building》Standard carries out technical performance test, test result such as table 1.
Table 1
Inspection project Unit Measured data
Shock resistance The plate face flawless after the experiment of 5 Secondary Shocks
Bending strength/ MPa 8.8
Mean compressive strength/ MPa 50.4
Coefficient of softing 0.92
Surface density/ kg/m3 88
Moisture content % 6
Hanging force Free from flaw
Frost resistance 15 Frozen-thawed cycled flawlesses, surface are unchanged
Combustibility rank A1
Embodiment two
Take sulphate aluminium cement 250 kilograms (numbers), 400 kilograms of dealkalize red mud, 400 kilograms of red mud iron selection tailings, poly- third Boric acid retarder will be added in 20 kilograms of alkene nitrile fiber and water double centner in sulphate aluminium cement, boric acid retarder accounts for alumino-silicate The 0.2% of cement weight, sulphate aluminium cement select the model R.SAC's 42.5 of Qufu Zhonglian Cement Co., Ltd.'s production Cement.It is powdered by the processing of sulphate aluminium cement, dealkalize red mud and red mud iron selection tailings, diameier requires 80 microns of square holes It tails over not higher than 10%;Using dealkalize red mud, red mud iron selection tailings and polyacrylonitrile fibre as primary raw material, boric acid will be added The sulphate aluminium cement of retarder is stirred evenly as gelling agent after adding water and water-reducing agent, wherein water-reducing agent accounts for aluminium sulfate water The 0.6% of mud, dealkalize red mud, red mud iron selection tailings, polyacrylonitrile fibre and water total weight, at room temperature, using briquetting pressure For 1.5-2.5Mpa, compression moulding plank.
Using the solid wastes such as dealkalize red mud prepare building body in external application compact inorganic composite plate size be 1000mm × 400mm × 90mm, with reference to GB/T23451-2009《Light partition board for building》Standard carries out technical performance test, test knot Fruit such as table 2.
Embodiment three
Take 225 kilograms of sulphate aluminium cement, 350 kilograms of dealkalize red mud, 375 kilograms of red mud iron selection tailings, polyacrylonitrile fine 80 kilograms of 15 kilograms of dimension and water.Boric acid retarder will be added in sulphate aluminium cement, boric acid retarder accounts for alumino-silicate cement weight The 0.2% of amount, sulphate aluminium cement select the cement of the model R.SAC 42.5 of Qufu Zhonglian Cement Co., Ltd.'s production.It will Sulphate aluminium cement, dealkalize red mud and the processing of red mud iron selection tailings are powdered, and diameier requires 80 microns of square hole screens to tail over Not higher than 10%;Using dealkalize red mud, red mud iron selection tailings and polyacrylonitrile fibre as primary raw material, boric acid retarder will be added Sulphate aluminium cement as gelling agent, stirred evenly after adding water and water-reducing agent, wherein water-reducing agent accounts for sulphate aluminium cement, de- The 0.6% of alkali red mud, red mud iron selection tailings, polyacrylonitrile fibre and water total weight uses briquetting pressure for 1.5- at room temperature 2.5MPa, compression moulding plank.
The size of external application compact inorganic composite plate is in the building body prepared using industrial residue firing sulphate aluminium cement 800mm × 300mm × 90mm, with reference to GB/T23451-2009《Light partition board for building》Standard carries out technical performance survey Examination, test result such as table 3.
Inspection project Unit Measured data
Shock resistance The plate face flawless after the experiment of 5 Secondary Shocks
Bending strength/ MPa 9.2
Mean compressive strength/ MPa 51.2
Coefficient of softing 0.91
Surface density/ kg/m3 84
Moisture content % 7
Hanging force Free from flaw
Frost resistance 15 Frozen-thawed cycled flawlesses, surface are unchanged
Combustibility rank A1
Certainly, above description is not limitation of the present invention, and the present invention is also not limited to the example above, the art The variations, modifications, additions or substitutions that those of ordinary skill is made in the essential scope of the present invention also belong to the guarantor of the present invention Protect range.

Claims (1)

1. a kind of method preparing inorganic clad plate using dealkalize red mud and red mud iron selection tailings, which is characterized in that including such as The dispensing of lower parts by weight:Sulphate aluminium cement 200-250, dealkalize red mud 300-400, red mud iron selection tailings 350-400, Polyacrylonitrile fibre 10-20 and water 60-100, includes the following steps:
(1) boric acid retarder will be added in sulphate aluminium cement;
(2) it is powdered, diameier control by the processing of dry, broken and grinding by dealkalize red mud and red mud iron selection tailings It is tailed over not higher than 10% in 80 microns of square hole screens;
(3) using dealkalize red mud, red mud iron selection tailings and polyacrylonitrile fibre as primary raw material, boric acid retarder will be added Sulphate aluminium cement is stirred evenly as gelling agent after adding water and water-reducing agent, at room temperature, uses briquetting pressure for 1 .5- 2.5MPa, compression moulding plank;
(4) it conserves in air, densification composite plate is made, according to construction needs, cut according to size requirements;
The inorganic clad plate of preparation is applied to Discussion on architecture wall.
CN201610009329.3A 2014-06-24 2014-06-24 A method of preparing inorganic clad plate using dealkalize red mud and red mud iron selection tailings Expired - Fee Related CN105669144B (en)

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CN201610009329.3A CN105669144B (en) 2014-06-24 2014-06-24 A method of preparing inorganic clad plate using dealkalize red mud and red mud iron selection tailings
CN201410285626.1A CN104119052B (en) 2014-06-24 2014-06-24 A kind of utilize dealkalize red mud and red mud iron selection tailings to prepare inorganic clad plate and preparation method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107555901A (en) * 2017-09-08 2018-01-09 肇庆高新区恒泰信息服务有限公司 A kind of method that building board is made using solid waste

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101891406A (en) * 2010-07-12 2010-11-24 山东大学 Method for preparing cement with red mud and desulfurized gypsum
CN102336543A (en) * 2011-05-16 2012-02-01 北京翰高兄弟科技发展有限公司 Red mud permeable brick and preparation method thereof
CN102926526A (en) * 2012-11-15 2013-02-13 李兴江 Red mud smoke exhaustion air flue, production method thereof and special mould

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101891406A (en) * 2010-07-12 2010-11-24 山东大学 Method for preparing cement with red mud and desulfurized gypsum
CN102336543A (en) * 2011-05-16 2012-02-01 北京翰高兄弟科技发展有限公司 Red mud permeable brick and preparation method thereof
CN102926526A (en) * 2012-11-15 2013-02-13 李兴江 Red mud smoke exhaustion air flue, production method thereof and special mould

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