CN105647186A - Temperature-sensitive color change raw material for preparing rubber for connector sleeves - Google Patents
Temperature-sensitive color change raw material for preparing rubber for connector sleeves Download PDFInfo
- Publication number
- CN105647186A CN105647186A CN201610123775.7A CN201610123775A CN105647186A CN 105647186 A CN105647186 A CN 105647186A CN 201610123775 A CN201610123775 A CN 201610123775A CN 105647186 A CN105647186 A CN 105647186A
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- parts
- rubber
- raw material
- color change
- temperature
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- 239000002994 raw material Substances 0.000 title claims abstract description 23
- 229920001971 elastomer Polymers 0.000 title claims abstract description 19
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 9
- OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 9
- 239000004793 Polystyrene Substances 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004595 color masterbatch Substances 0.000 claims abstract description 9
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 9
- 229920001194 natural rubber Polymers 0.000 claims abstract description 9
- 229920002223 polystyrene Polymers 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 9
- 239000004945 silicone rubber Substances 0.000 claims abstract description 9
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 9
- 239000011593 sulfur Substances 0.000 claims abstract description 9
- 238000002845 discoloration Methods 0.000 claims description 9
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims description 8
- 239000008119 colloidal silica Substances 0.000 claims description 8
- 239000003517 fume Substances 0.000 claims description 8
- CAAULPUQFIIOTL-UHFFFAOYSA-L methyl phosphate(2-) Chemical compound COP([O-])([O-])=O CAAULPUQFIIOTL-UHFFFAOYSA-L 0.000 claims description 8
- 238000005562 fading Methods 0.000 abstract description 7
- 230000003712 anti-aging effect Effects 0.000 abstract 2
- 239000006229 carbon black Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- VONWDASPFIQPDY-UHFFFAOYSA-N dimethyl methylphosphonate Chemical compound COP(C)(=O)OC VONWDASPFIQPDY-UHFFFAOYSA-N 0.000 abstract 1
- 238000002474 experimental method Methods 0.000 description 16
- 230000004075 alteration Effects 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 208000037656 Respiratory Sounds Diseases 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 229910052724 xenon Inorganic materials 0.000 description 4
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 4
- 238000010792 warming Methods 0.000 description 3
- 230000032683 aging Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a temperature-sensitive color change raw material for preparing rubber for connector sleeves. The temperature-sensitive color change raw material for preparing the rubber for the connector sleeves comprises, by weight, 45-87 parts of silicone rubber, 21-35 parts of natural rubber, 20-40 parts of nitrile rubber, 10-13 parts of polystyrene wax, 1-1.3 parts of color master batch, 0.3-6 parts of temperature-sensitive color change powder, 79 parts of gas-phase white carbon black, 10-14 parts of sulfur, 2-8 parts of accelerators D, 10-16 parts of dimethyl methyl phosphonate and 2-7 parts of anti-aging agents 4010NA. The temperature-sensitive color change raw material has the advantages that the temperature-sensitive color change raw material is controlled by the temperatures, is anti-aging and is free of fading and long in service life, color change is vivid and obvious, and the like.
Description
Technical field
The present invention relates to a kind of rubber raw materials, specifically a kind of temperature sensing color changing swagelok rubber.
Background technology
Power cable plays extremely important effect in urban distribution network, and it not only carries the task of carrying electric energy for user, is also power network compensation reactive power simultaneously. But the ratio shared in electrical network along with power cable is growing, the properly functioning of power system is caused ill effect by high power cable fault rate, therefore power cable temperature everywhere must be carried out monitoring in real time, early warning, to guarantee the healthy operation of electric power system.
Many use warming pasters at present, cable is identified mark, but it is coated with warming color outside currently used warming paster multidigit plastics paster to be made, it is subject to the impacts such as dampness, temperature, daylight, easily aging, fade, fade, fuel after fading easily trickles with steam, affects cable outward appearance and impact judges.
Summary of the invention
The technical problem to be solved is to provide a kind of quality of rubber materials and has temperature-sensing discoloration function and the temperature sensing color changing swagelok using time length, fading poor.
For solving above-mentioned technical problem, the technical scheme is that a kind of temperature sensing color changing swagelok rubber configuration raw material, be made up of the raw material of following weight portion: silicone rubber: 45-87 part, natural rubber: 21-35 part, nitrile rubber: 20-40 part, polystyrene wax: 10-13 part, color masterbatch: 1-1.3 part, heat discoloration powder: 0.3-6 part, fume colloidal silica: 79 parts, sulfur: 10-14 part, diphenylguanidine: 2-8 part, methyl-phosphoric acid dimethyl ester: 10-16 part, antioxidant 4010NA: 2-7 part.
As preferred technical scheme, described a kind of temperature sensing color changing swagelok rubber configuration raw material, is made up of following raw material: silicone rubber: 66 parts, natural rubber: 28 parts, nitrile rubber: 30 parts, polystyrene wax: 11.5 parts, color masterbatch: 1.15 parts, heat discoloration powder: 0.45 part, fume colloidal silica: 79 parts, sulfur: 12 parts, diphenylguanidine: 5 parts, methyl-phosphoric acid dimethyl ester: 13 parts, antioxidant 4010NA: 4.5 parts.
Owing to have employed technique scheme, a kind of temperature sensing color changing swagelok rubber configuration raw material, is made up of following raw material: silicone rubber: 45-87 part, natural rubber: 21-35 part, nitrile rubber: 20-40 part, polystyrene wax: 10-13 part, color masterbatch: 1-1.3 part, heat discoloration powder: 0.3-6 part, fume colloidal silica: 79 parts, sulfur: 10-14 part, diphenylguanidine: 2-8 part, methyl-phosphoric acid dimethyl ester: 10-16 part, antioxidant 4010NA: 2-7 part;The method have the advantages that
1, temperature controlled, variable color is vivid, hence it is evident that, there is the advantage such as aging resistance, colour-fast, long service life.
2, carry out xenon arc lamp according to GB/T16422.2-3, GB/T20028, GB/10125 standard, ultraviolet light, heat, salt fog senile experiment meet national standard, and without fading and fade phenomenon, and the rubber after above-mentioned experiment is carried out high/low temperature circulation variable color experiment, aberration contrast �� E��0.9 before and after 200000 times.
3, wearability test, uses and subdues machine, carry out subduing test, more than 90,000 times, crackle 5.9mm, carries out high/low temperature circulation variable color experiment, aberration contrast �� E��0.6 before and after 200000 times.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1
A kind of temperature sensing color changing swagelok rubber configuration raw material, is made up of following raw material:
Silicone rubber: 45 parts, natural rubber: 21 parts, nitrile rubber: 20 parts, polystyrene wax: 10 parts, color masterbatch: 1 part, heat discoloration powder: 0.3 part, fume colloidal silica: 79 parts, sulfur: 10 parts, diphenylguanidine: 2 parts, methyl-phosphoric acid dimethyl ester: 10 parts, antioxidant 4010NA: 2 parts.
1, carry out xenon arc lamp according to GB/T16422.2-3, GB/T20028, GB/10125 standard, ultraviolet light, heat, salt fog senile experiment meet national standard, and without fading and fade phenomenon, and the rubber after above-mentioned experiment is carried out high/low temperature circulation variable color experiment, aberration contrast �� E��0.9 before and after 200000 times.
2, wearability test, uses and subdues machine, carry out subduing test, more than 90,000 times, crackle 5.9mm, carries out high/low temperature circulation variable color experiment, aberration contrast �� E��0.6 before and after 200000 times.
Embodiment 2
A kind of temperature sensing color changing swagelok rubber configuration raw material, is made up of following raw material:
Silicone rubber: 87 parts, natural rubber: 35 parts, nitrile rubber: 40 parts, polystyrene wax: 13 parts, color masterbatch: 1.3 parts, heat discoloration powder: 6 parts, fume colloidal silica: 79 parts, sulfur: 14 parts, diphenylguanidine: 8 parts, methyl-phosphoric acid dimethyl ester: 16 parts, antioxidant 4010NA: 7 parts.
1, carry out xenon arc lamp according to GB/T16422.2-3, GB/T20028, GB/10125 standard, ultraviolet light, heat, salt fog senile experiment meet national standard, and without fading and fade phenomenon, and the rubber after above-mentioned experiment is carried out high/low temperature circulation variable color experiment, aberration contrast �� E��0.9 before and after 200000 times.
2, wearability test, uses and subdues machine, carry out subduing test, more than 90,000 times, crackle 5.9mm, carries out high/low temperature circulation variable color experiment, aberration contrast �� E��0.6 before and after 200000 times.
Embodiment 3
A kind of temperature sensing color changing swagelok rubber configuration raw material, is made up of following raw material:
Silicone rubber: 66 parts, natural rubber: 28 parts, nitrile rubber: 30 parts, polystyrene wax: 11.5 parts, color masterbatch: 1.15 parts, heat discoloration powder: 0.45 part, fume colloidal silica: 79 parts, sulfur: 12 parts, diphenylguanidine: 5 parts, methyl-phosphoric acid dimethyl ester: 13 parts, antioxidant 4010NA: 4.5 parts.
1, carry out xenon arc lamp according to GB/T16422.2-3, GB/T20028, GB/10125 standard, ultraviolet light, heat, salt fog senile experiment meet national standard, and without fading and fade phenomenon, and the rubber after above-mentioned experiment is carried out high/low temperature circulation variable color experiment, aberration contrast �� E��0.9 before and after 200000 times.
2, wearability test, uses and subdues machine, carry out subduing test, more than 90,000 times, crackle 5.9mm, carries out high/low temperature circulation variable color experiment, aberration contrast �� E��0.6 before and after 200000 times.
The foregoing is only the schematic detailed description of the invention of the present invention, be not limited to the scope of the present invention. Any those skilled in the art, equivalent variations done under without departing from the design of the present invention and the premise of principle and amendment, all should belong to the scope of protection of the invention.
Claims (2)
1. a temperature sensing color changing swagelok rubber configuration raw material, it is characterized in that, be made up of the raw material of following weight portion: silicone rubber: 45-87 part, natural rubber: 21-35 part, nitrile rubber: 20-40 part, polystyrene wax: 10-13 part, color masterbatch: 1-1.3 part, heat discoloration powder: 0.3-6 part, fume colloidal silica: 79 parts, sulfur: 10-14 part, diphenylguanidine: 2-8 part, methyl-phosphoric acid dimethyl ester: 10-16 part, antioxidant 4010NA: 2-7 part.
2. a kind of temperature sensing color changing swagelok rubber configuration raw material as claimed in claim 1, it is characterized in that, be made up of the raw material of following weight portion: silicone rubber: 66 parts, natural rubber: 28 parts, nitrile rubber: 30 parts, polystyrene wax: 11.5 parts, color masterbatch: 1.15 parts, heat discoloration powder: 0.45 part, fume colloidal silica: 79 parts, sulfur: 12 parts, diphenylguanidine: 5 parts, methyl-phosphoric acid dimethyl ester: 13 parts, antioxidant 4010NA: 4.5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610123775.7A CN105647186A (en) | 2016-03-04 | 2016-03-04 | Temperature-sensitive color change raw material for preparing rubber for connector sleeves |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610123775.7A CN105647186A (en) | 2016-03-04 | 2016-03-04 | Temperature-sensitive color change raw material for preparing rubber for connector sleeves |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105647186A true CN105647186A (en) | 2016-06-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610123775.7A Pending CN105647186A (en) | 2016-03-04 | 2016-03-04 | Temperature-sensitive color change raw material for preparing rubber for connector sleeves |
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| Country | Link |
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| CN (1) | CN105647186A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108250759A (en) * | 2016-12-29 | 2018-07-06 | 深圳市沃尔核材股份有限公司 | A kind of irreversible heat discoloration cable accessory is warned with self-adhesive tape and preparation method thereof |
| CN108485081A (en) * | 2018-04-16 | 2018-09-04 | 山东迪龙电缆有限公司 | A kind of temperature sensing color changing swagelok rubber configuration raw material |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102286162A (en) * | 2011-06-20 | 2011-12-21 | 沈阳天荣电缆材料有限公司 | Preparation method of deep sea cable filling strip |
| CN103554541A (en) * | 2013-11-11 | 2014-02-05 | 镇江苏惠乳胶制品有限公司 | Glove with color change function and preparation method thereof |
| CN103779013A (en) * | 2012-10-17 | 2014-05-07 | 特变电工股份有限公司 | Temperature indicating cable |
| CN104194349A (en) * | 2014-07-29 | 2014-12-10 | 安徽伊法拉电力科技有限公司 | Thermo-sensitive early warming insulting protecting cover material |
| CN104448434A (en) * | 2014-11-20 | 2015-03-25 | 安徽渡江电缆集团有限公司 | High-flame-retardance modified nitrile rubber cable material |
| CN105086011A (en) * | 2015-08-26 | 2015-11-25 | 安徽华峰电缆集团有限公司 | Anti-extrusion cable |
| CN105295322A (en) * | 2015-10-28 | 2016-02-03 | 合肥学院 | Thermosensitive off-color material for FDM and preparation method of thermosensitive off-color material |
-
2016
- 2016-03-04 CN CN201610123775.7A patent/CN105647186A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102286162A (en) * | 2011-06-20 | 2011-12-21 | 沈阳天荣电缆材料有限公司 | Preparation method of deep sea cable filling strip |
| CN103779013A (en) * | 2012-10-17 | 2014-05-07 | 特变电工股份有限公司 | Temperature indicating cable |
| CN103554541A (en) * | 2013-11-11 | 2014-02-05 | 镇江苏惠乳胶制品有限公司 | Glove with color change function and preparation method thereof |
| CN104194349A (en) * | 2014-07-29 | 2014-12-10 | 安徽伊法拉电力科技有限公司 | Thermo-sensitive early warming insulting protecting cover material |
| CN104448434A (en) * | 2014-11-20 | 2015-03-25 | 安徽渡江电缆集团有限公司 | High-flame-retardance modified nitrile rubber cable material |
| CN105086011A (en) * | 2015-08-26 | 2015-11-25 | 安徽华峰电缆集团有限公司 | Anti-extrusion cable |
| CN105295322A (en) * | 2015-10-28 | 2016-02-03 | 合肥学院 | Thermosensitive off-color material for FDM and preparation method of thermosensitive off-color material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108250759A (en) * | 2016-12-29 | 2018-07-06 | 深圳市沃尔核材股份有限公司 | A kind of irreversible heat discoloration cable accessory is warned with self-adhesive tape and preparation method thereof |
| CN108485081A (en) * | 2018-04-16 | 2018-09-04 | 山东迪龙电缆有限公司 | A kind of temperature sensing color changing swagelok rubber configuration raw material |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB02 | Change of applicant information |
Inventor after: Chen Ming Inventor after: Liu Liyuan Inventor after: Meng Xiangjun Inventor after: Wang Shaohua Inventor after: Lv Xin Inventor after: Guan Tao Inventor after: Wang Yu Inventor after: Wang Jian Inventor after: Wu Chao Inventor after: Yang Xiaohong Inventor before: Wang Wenwen |
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| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20161214 Address after: Dongguan Street in Zhucheng City in Shandong province Weifang City No. 2 262200 Applicant after: ZHUCHENG POWER SUPPLY COMPANY, STATE GRID SHANDONG ELECTRIC POWER COMPANY Applicant after: State Grid Shandong Electric Power Company Weifang Power Supply Company Applicant after: State Power Networks Co Address before: Dongguan Street Zhucheng City 262200 Shandong city of Weifang province No. 2 in Shandong Zhucheng city power supply company Applicant before: Wang Wenwen |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160608 |
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| RJ01 | Rejection of invention patent application after publication |