CN105621777A - Nano magnetic powder catalytic oxidation and wastewater treatment system - Google Patents

Nano magnetic powder catalytic oxidation and wastewater treatment system Download PDF

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Publication number
CN105621777A
CN105621777A CN201610090509.9A CN201610090509A CN105621777A CN 105621777 A CN105621777 A CN 105621777A CN 201610090509 A CN201610090509 A CN 201610090509A CN 105621777 A CN105621777 A CN 105621777A
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China
Prior art keywords
magnetic powder
unit
catalytic oxidation
photochemical catalytic
nano
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CN201610090509.9A
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Chinese (zh)
Inventor
骆佳豪
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Jinhua Zhichan Wuyuan Information Technology Co Ltd
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Jinhua Zhichan Wuyuan Information Technology Co Ltd
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Priority to CN201610090509.9A priority Critical patent/CN105621777A/en
Publication of CN105621777A publication Critical patent/CN105621777A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • C02F1/325Irradiation devices or lamp constructions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/34Treatment of water, waste water, or sewage with mechanical oscillations
    • C02F1/36Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/48Treatment of water, waste water, or sewage with magnetic or electric fields
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/32Details relating to UV-irradiation devices
    • C02F2201/322Lamp arrangement
    • C02F2201/3227Units with two or more lamps
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/32Details relating to UV-irradiation devices
    • C02F2201/322Lamp arrangement
    • C02F2201/3228Units having reflectors, e.g. coatings, baffles, plates, mirrors
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/10Photocatalysts

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Catalysts (AREA)
  • Physical Water Treatments (AREA)

Abstract

The invention discloses a nano magnetic powder catalytic oxidation and wastewater treatment system, comprising a pre-treatment unit, a primary filter unit, a secondary filtration unit and a photo-catalytic oxidation unit. The upper portion of the pre-treatment unit is provided with a nano magnetic powder feeder and the inner bottom is provided with a stirring device, the upper portion of the primary filter unit is provided with a magnetic drum and a magnetic powder recycling device, this system also comprises an ultrasonic separator, a feed end of the ultrasonic separator is connected with the magnetic powder recycling device through a conveying belt, a discharge end of the ultrasonic separator is connected above the pre-treatment unit through an obliquely arranged guide channel, and the lower portion of the ultrasonic separator is also provided with a dirt outlet. Suspension in wastewater is trapped by using nano magnetic powder, magnetic powder with pollutants adsorbed thereto is collected under the action of the magnetic drum, the pollutants adsorbed to the nano magnetic powder are washed and separated under action of ultrasonic, ultrasonic washing greatly reduces water consumption in the backwash regeneration process, improves wastewater treatment efficiency and saves resources.

Description

A kind of nano-magnetic powder photochemical catalytic oxidation sewage disposal system
Technical field
The invention belongs to environmental protection technical field, be specifically related to a kind of nano-magnetic powder photochemical catalytic oxidation sewage disposal system.
Background technology
The deep bed sand filter based on adsorption that what current application was more is is filter medium with quartz sand. Its agent structure is to have supporting layer in cylindrical tank, is sand filter bed on supporting layer, and sand filter bed is heterogeneous body fixing hole gap structure. There are big cobble, little cobble, big stone, handstone, coarse sand, medium sand etc. from bottom to top, namely so-called " bed course ", belong to non-effective adsorption layer. On main body fine sand layer, for active adsorption layer, filter bed top also has a sizable headspace. Water inlet before one filter is arranged at the outer top of filter tank, and water out after a filter is arranged at bottom. Upper entering and lower leaving during filtration, bottom in and top out during backwash, the two is same flow process, each other reverse process.
The subject matter existed: one is that filtering accuracy is low general not up to standard. Two is adsorb easy desorption difficulty. Filter bed structure complexity belongs to again fixing hole gap structure, and therefore easily, desorption and regeneration is very difficult in absorption. Filter bed easily causes blocking, it is generally required to improve displacement flush after blocking, owing to the filter bed degree of depth is half tank, the first half is slack tank, although filter bed belongs to fixing hole gap structure, but whole filter bed stability extreme difference, often cause the mixed layer of heterogeneous body filter bed to lose efficacy during flushing, recover very difficult, therefore can affect production. Three is to extremely inadaptable containing polymer and Organic substance sewage.
After plugged filter, from back flush, the impurity filtered on filter material is rinsed out, it is possible to recover its strainability, in prior art, the regeneration rate of filter element is poor, and in backwash process, water demand is relatively big, and the flushing sewage quantity that need to discharge increases accordingly, need to improve.
Titanium dioxide optical catalyst material can produce the hole of highly active strong reducing property electronics and positively charged strong oxidizing property under light source activation, so that the Organic substance in solution occurs a series of oxidation-reduction reaction to degrade, the most little molecular organic pollutants of decomposable asymmetric choice net. Titanium dioxide is as photocatalyst applications in the process of waste water, and compared with other sewage disposal technologies, it has lot of advantages: safe and stable, waste water treatment efficiency is high, non-secondary pollution etc. But photochemical catalytic oxidation link of the prior art, owing to sewage is in flow process, it is subject to the restriction of container, cause that current are limited with effective contact area of photocatalyst, it is necessary to find suitable method, solves effectively to utilize ultraviolet source improve its photo-catalysis capability and increase the technical problem of current and effective contact area of photocatalyst.
Summary of the invention
It is an object of the invention to provide a kind of sewage disposal system, with the problem solving to propose in above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme: a kind of sewage disposal system, including pretreatment unit 1, primary filter unit 2, cascade filtration unit 3 and photochemical catalytic oxidation unit 4, described pretreatment unit 1 is open-top receptacle, bottom is provided with water inlet 5, this pretreatment unit 1 top is provided with nano-magnetic powder delivery device 6 and inside bottom is provided with agitating device 7, this pretreatment unit 1 is connected with primary filter unit 2 by pipeline, this primary filter unit 2 top is provided with magnetic drum 8 and magnetic powder recovering device 9, this magnetic powder recovering device 9 is arranged on magnetic drum 8 and is connected by connection member, it is provided with water pump 10 between the pipeline that described primary filter unit 2 is connected with cascade filtration unit 3, the water side at described cascade filtration unit 3 top is connected to the water inlet end bottom photochemical catalytic oxidation unit 4 by pipeline, the water side at this photochemical catalytic oxidation unit 4 top is connected to outlet 15 by pipeline, described cascade filtration unit 3 is internal fills activated carbon 11, the inwall of described photochemical catalytic oxidation unit 4 also covers and is provided with reflector layer 12, this photochemical catalytic oxidation unit 4 is internally provided with snakelike bulkhead 13, this bulkhead 13 is coated with photocatalysis film layer, and among the gap of bulkhead 13, it is provided with ultra-violet lamp 14, , the lateral wall of described photochemical catalytic oxidation unit 4 is provided with paired ultrasonic transducer 20, this sewage disposal system also includes ultrasonic separation device 16, the feed end of described ultrasonic separation device 16 is connected by conveyer belt 17 with magnetic powder recovering device 9, the discharge end of ultrasonic separation device 16 is connected to the top of pretreatment unit 1 by the guide groove 18 being obliquely installed, described ultrasonic separation device 16 bottom is additionally provided with sewage draining exit 19.
Preferably, the photocatalysis film layer described baffles 13 surface arranged is composite titania material.
Preferably. Described reflector layer 12 is aluminium coat, silvering or reflective pad pasting.
Preferably, described conveyer belt 17 is made up of magnetic material.
Compared with prior art, the invention has the beneficial effects as follows:
1, the present invention adopts nano-magnetic powder to adsorb the float retaining in sewage, under the effect in the magnetic field of magnetic drum, collect the magnetic powder having adsorbed pollutant, import in ultrasonic separation device by conveyer belt, by the cleaning of the pollutant adsorbed on nano-magnetic powder and separate under hyperacoustic effect, pollutant are with a small amount of sewage discharge, recycle through the nano-magnetic powder of ultrasonic waves for cleaning, strengthen the absorption crown_interception of float and organic polymer in sewage, ultrasonic waves for cleaning greatly reduces the water consumption in backwash regenerative process, and then improve the efficiency of sewage disposal, nano-magnetic powder recycles and reduces consumptive material use, economize on resources.
2, the inwall of photochemical catalytic oxidation unit of the present invention also covers and is provided with reflector layer, this reflector layer effectively utilizes ultraviolet source to improve its photo-catalysis capability, snakelike bulkhead adds the distance that water is passed by a reservoir, thus increasing effective contact area of current and photocatalyst, the lateral wall of photochemical catalytic oxidation unit is provided with paired ultrasonic transducer, ultrasound wave is the sound wave that frequency is higher than 20000 hertz, its good directionality, penetration capacity is strong, the ultrasonic acoustic pressure that can produce positive and negative alternation when propagating, form jet, simultaneously because nonlinear effect can produce acoustic streaming and micro-acoustic streaming, increase stirring, diffusion, further increase effective contact area of current and photocatalyst, and then strengthen photochemical catalytic oxidation effect.
Accompanying drawing explanation
Fig. 1 is present configuration schematic diagram.
In figure: 1 pretreatment unit, 2 primary filter unit, 3 cascade filtration unit, 4 photochemical catalytic oxidation unit, 5 water inlets, 6 nano-magnetic powder delivery devices, 7 agitating devices, 8 magnetic drums, 9 magnetic powder recovering devices, 10 water pumps, 11 activated carbons, 12 reflector layers, 13 bulkhead, 14 ultra-violet lamps, 15 outlets, 16 ultrasonic separation devices, 17 conveyer belts, 18 guide grooves, 19 sewage draining exits, 20 ultrasonic transducers.
Detailed description of the invention
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is only a part of embodiment of the present invention, rather than whole embodiments. Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art obtain under not making creative work premise, broadly fall into the scope of protection of the invention.
Refer to Fig. 1, the present invention provides a kind of embodiment: a kind of sewage disposal system, by pretreatment unit 1, primary filter unit 2, cascade filtration unit 3 and photochemical catalytic oxidation unit 4 form, described pretreatment unit 1 is open-top receptacle, bottom is provided with water inlet 5, this pretreatment unit 1 top is provided with nano-magnetic powder delivery device 6, and pretreatment unit 1 inside bottom is provided with agitating device 7, nano-magnetic powder is thrown in pretreatment unit 1, and be stirred by agitating device 7, nano-magnetic powder and sewage is made to be sufficiently mixed, the polymer making nano-magnetic powder adsorb fully and to retain in sewage and float,
This pretreatment unit 1 is connected with primary filter unit 2 by pipeline, this primary filter unit 2 top is provided with magnetic drum 8 and magnetic powder recovering device 9, this magnetic powder recovering device 9 is arranged on magnetic drum 8 and is connected by connection member, under the effect of magnetic drum 8, the magnetic powder being adsorbed with pollutant is collected and reclaims by magnetic powder recovering device 9, it is provided with water pump 10 between the pipeline that described primary filter unit 2 is connected with cascade filtration unit 3, the water purified through primary filter enters cascade filtration unit 3 by pipeline, described cascade filtration unit 3 is internal fills activated carbon 11, owing to its porous adsorbs the fine material in various water during filtration, remove larger molecular organics and heavy metal, synthetic detergent, the polluter such as antibacterial and virus,
The water side at described cascade filtration unit 3 top is connected to the water inlet end bottom photochemical catalytic oxidation unit 4 by pipeline, the inwall of described photochemical catalytic oxidation unit 4 also covers and is provided with reflector layer 12, this photochemical catalytic oxidation unit 4 is internally provided with snakelike bulkhead 13, this bulkhead 13 is coated with photocatalysis film layer, described photocatalysis film layer is composite titania material, what titanium oxide film layer was more stable is attached on baffles, increase robustness, and among the gap of bulkhead 13, it is provided with ultra-violet lamp 14, make the distance that raw water is walked in clean unit longer, increase the contact area of water and photocatalyst rete, described reflector layer 12 is aluminium coat, silvering, improve the exposure rate of ultraviolet light, improve reaction rate, strengthen clean-up effect further, thus improving clean-up effect, the lateral wall of described photochemical catalytic oxidation unit 4 is provided with paired ultrasonic transducer 20, ultrasound wave is the sound wave that frequency is higher than 20000 hertz, its good directionality, penetration capacity is strong, the ultrasonic acoustic pressure that can produce positive and negative alternation when propagating, and forms jet, simultaneously because nonlinear effect can produce acoustic streaming and micro-acoustic streaming, increase stirring, diffusion, further increase effective contact area of current and photocatalyst, and then strengthen photochemical catalytic oxidation effect, the water side at this photochemical catalytic oxidation unit 4 top is connected to outlet 15 by pipeline so that needs the water of purified treatment and each filter element to be fully contacted, reaches best filter effect,
This sewage disposal system also includes ultrasonic separation device 16, the feed end of described ultrasonic separation device 16 is connected by conveyer belt 17 with magnetic powder recovering device 9, described conveyer belt 17 is made up of magnetic material, the magnetic powder retaining pollutant is made to be easier to be adsorbed on conveyer belt 17, entrance ultrasonic separation device 16 it is conveyed efficiently thus more stable, the discharge end of ultrasonic separation device 16 is connected to the top of pretreatment unit 1 by the guide groove 18 being obliquely installed, described ultrasonic separation device 16 bottom is additionally provided with sewage draining exit 19, by the cleaning of the pollutant adsorbed on nano-magnetic powder and separate under hyperacoustic effect, pollutant are with a small amount of sewage discharge, the guide groove 18 passing through to be obliquely installed through the nano-magnetic powder of ultrasonic waves for cleaning is added in the sewage of pretreatment unit 1, carry out sewage disposal process next time, ultrasonic waves for cleaning reduces the water consumption in backwash regenerative process, and then improve the efficiency of sewage disposal, nano-magnetic powder recycles and reduces consumptive material use, economize on resources.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, being appreciated that and these embodiments can be carried out multiple change, amendment, replacement and modification without departing from the principles and spirit of the present invention, the scope of the present invention be defined by the appended.

Claims (4)

1. a nano-magnetic powder photochemical catalytic oxidation sewage disposal system, including pretreatment unit (1), primary filter unit (2), cascade filtration unit (3) and photochemical catalytic oxidation unit (4) etc., described pretreatment unit (1) is open-top receptacle, bottom is provided with water inlet (5), this pretreatment unit (1) top is provided with nano-magnetic powder delivery device (6) and inside bottom is provided with agitating device (7), this pretreatment unit (1) is connected with primary filter unit (2) by pipeline, this primary filter unit (2) top is provided with magnetic drum (8) and magnetic powder recovering device (9), this magnetic powder recovering device (9) is arranged on magnetic drum (8) and is connected by connection member, it is provided with water pump (10) between the pipeline that described primary filter unit (2) is connected with cascade filtration unit (3), the water side at described cascade filtration unit (3) top is connected to the water inlet end of photochemical catalytic oxidation unit (4) bottom by pipeline, the water side at this photochemical catalytic oxidation unit (4) top is connected to outlet (15) by pipeline, described cascade filtration unit (3) is internal fills activated carbon (11), it is characterized in that: the inwall of described photochemical catalytic oxidation unit (4) also covers and is provided with reflector layer (12), this photochemical catalytic oxidation unit (4) is internally provided with snakelike bulkhead (13), this bulkhead is coated with photocatalysis film layer on (13), and among the gap of bulkhead (13), it is provided with ultra-violet lamp (14), the lateral wall of described photochemical catalytic oxidation unit (4) is provided with paired ultrasonic transducer (20), this sewage disposal system also includes ultrasonic separation device (16), the feed end of described ultrasonic separation device (16) is connected by conveyer belt (17) with magnetic powder recovering device (9), the discharge end of ultrasonic separation device (16) is connected to the top of pretreatment unit (1) by the guide groove (18) being obliquely installed, described ultrasonic separation device (16) bottom is additionally provided with sewage draining exit (19).
2. nano-magnetic powder photochemical catalytic oxidation sewage disposal system according to claim 1, it is characterised in that: the photocatalysis film layer arranged on described baffles (13) surface is composite titania material.
3. nano-magnetic powder photochemical catalytic oxidation sewage disposal system according to claim 1, it is characterised in that: described reflector layer (12) is aluminium coat, silvering.
4. nano-magnetic powder photochemical catalytic oxidation sewage disposal system according to claim 1, it is characterised in that: described conveyer belt (17) is made up of magnetic material.
CN201610090509.9A 2016-02-18 2016-02-18 Nano magnetic powder catalytic oxidation and wastewater treatment system Pending CN105621777A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109179569A (en) * 2018-11-14 2019-01-11 四川中盛净源环保设备有限公司 A kind of processing organic wastewater with difficult degradation thereby oxidant cooperative photocatalysis oxidation reaction apparatus and application
CN112495398A (en) * 2020-11-27 2021-03-16 宜兴申联机械制造有限公司 Preparation process of fine nickel screen for catalytic degradation of organic pollution

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CN104528912A (en) * 2014-12-02 2015-04-22 河海大学 Photocatalysis device based on nano-grade magnetic titanium dioxide catalyst
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109179569A (en) * 2018-11-14 2019-01-11 四川中盛净源环保设备有限公司 A kind of processing organic wastewater with difficult degradation thereby oxidant cooperative photocatalysis oxidation reaction apparatus and application
CN112495398A (en) * 2020-11-27 2021-03-16 宜兴申联机械制造有限公司 Preparation process of fine nickel screen for catalytic degradation of organic pollution
CN112495398B (en) * 2020-11-27 2023-04-07 宜兴申联机械制造有限公司 Preparation process of fine nickel screen for catalytic degradation of organic pollution

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