CN1056199C - Organic dye monochromatic dyeing method for anodized aluminum alloy - Google Patents
Organic dye monochromatic dyeing method for anodized aluminum alloy Download PDFInfo
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- CN1056199C CN1056199C CN94104526A CN94104526A CN1056199C CN 1056199 C CN1056199 C CN 1056199C CN 94104526 A CN94104526 A CN 94104526A CN 94104526 A CN94104526 A CN 94104526A CN 1056199 C CN1056199 C CN 1056199C
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- dyeing
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- organic dye
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- 238000004043 dyeing Methods 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 13
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 5
- 239000000975 dye Substances 0.000 claims description 31
- 238000010186 staining Methods 0.000 claims description 10
- 239000012530 fluid Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 6
- 238000007743 anodising Methods 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000002203 pretreatment Methods 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 2
- 230000000295 complement effect Effects 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 abstract description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 238000007447 staining method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- WXHLLJAMBQLULT-UHFFFAOYSA-N 2-[[6-[4-(2-hydroxyethyl)piperazin-1-yl]-2-methylpyrimidin-4-yl]amino]-n-(2-methyl-6-sulfanylphenyl)-1,3-thiazole-5-carboxamide;hydrate Chemical compound O.C=1C(N2CCN(CCO)CC2)=NC(C)=NC=1NC(S1)=NC=C1C(=O)NC1=C(C)C=CC=C1S WXHLLJAMBQLULT-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000012505 colouration Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- 239000004312 hexamethylene tetramine Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
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Abstract
A monochromatic dyeing method of organic dye for anodized aluminium alloy is carried out by loading and hanging pre-treating workpiece, carrying out first dyeing for 0.8-1.5min under the conditions of pH 4.5-5.5 and temperature 50-60 deg.C, not reaching required color, carrying out second dyeing for 18-22s and 0.8-1.2min under the conditions of pH 4.2-4.8 and temperature 50-60 deg.C, not reaching required color, regulating dye, pH, temperature and time according to the second dyeing process condition, carrying out multiple dyeing until required color is closed and dried.
Description
The present invention relates to a kind of unicolor chemical staining method, particularly a kind of organic dye solid shade dyeing method, it is applicable to that no substantive dyestuff such as aluminium and alloy anodized film thereof dye unicolor occasion.
In background technology, dying unicolor organic dye dyeing method is confined to single substantive dyestuff and dyes true qualities, as dying black with nigrosine, with alizarin look red colouration etc., and it is still unresolved always that employing chemical staining methods such as dark brown, bronze-colored, grass green, fairy green are dyeed, and can only be undertaken by adopting colorize method, be faint in color so exist, defectives such as cost height for overcoming these defectives, are dyed unicolor organic dye dyeing method to no substantive dyestuff and are developed.
The purpose of this invention is to provide a kind of organic dye solid shade dyeing method that can dye any monochrome, color clear, Anodising aluminium alloy that cost is low.
The object of the present invention is achieved like this:
It comprises that product dress extension carries out pre-treatment and washing, also comprises:
The chromophore of at first using different organic dye can absorb the absorption and the interference of light principle of different light waves and light, according to required color, determines to make behind body color and the complementary colors staining fluid of different colours in contiguous two or three organic dye on color ring,
To immerse in first kind of staining fluid through the clean back of the product water washing of anodic oxidation treatment then, pH value be 4.5-5.5, temperature be carry out under 50-60 ℃ the condition for the time 0.8-1.5min the dyeing first time and wash,
Before utilizing oxide film after a kind of staining fluid dyeing, not seal again, still have the multiple adsorb ability and add the painted characteristic of layer, to carrying out not reaching after the dyeing first time product of required color, it is immersed in second kind of staining fluid, at pH value is 4.2-4.8, temperature be under 50-60 ℃ the condition to secondary and repeatedly painted product carry out respectively for the time 18-22s, 0.8-1.2min second time dyeing and washing, do not reach the product of required color yet, make suitable technological test by painted processing condition for the second time and adjust dyestuff, pH value, repeatedly dye again after the temperature and time scope and wash, after reaching required monochrome, seal, oven dry.
Fig. 1 is applied to once painted process flow sheet for the present invention.
Fig. 2 is applied to secondary or repeatedly painted process flow sheet for the present invention.
Fig. 3 is the synoptic diagram of organic dye color ring of the present invention.
Below in conjunction with accompanying drawing, the present invention is done to describe further:
Product dress extension carries out pre-treatment and comprises electrochemical deoiling → heat, cold wash → 20 Rare nitric acid of-35% is washed → cold wash → chemical polishing → secondary cold wash → 40-60 The red fuming nitric acid (RFNA) of % is washed → secondary cold wash → sulphuric acid anodizing. Chemical polishing soln In can add a small amount of sulfosalicylic acid and hexamethylenetetramine is made corrosion inhibiter, through removing Product surface after oil, pickling, chemical polishing are processed should be even, bright, anode Oxidation technology requires to press: sulfuric acid 200 grams per liters, voltage 14-16 volt, current density 1. 5-2.5A/dm2, the time, 25-35min controlled, the product after anodic oxidation To wash 20-40S with the flowing cool water pendulum, preferably without ammonia neutralization, because residual ammonia The aqueous solution is bigger to the impact of the pH value of dyeing liquor, really will be with ammonia neutralization, in With after must clean up. Before dyeing, do not use in addition bare-handed contact product, To avoid affecting the uniformity of dye layer. In dyeing course, the pH value meeting of dye liquor Progressively raise, therefore will often test the pH value of dye liquor, if higher available 1: 1 vinegar Acid solution is regulated, and dye liquor is through repeatedly regulating the poststaining effect when bad or contaminated, Should in time change.
Sealing can adopt hot distilled water or steam to carry out, and the hot distilled water closure temperature is 90-100 ℃, the time is 5-10min, and the temperature of vapour seal is 95-110 ℃, Time is 15-30min. Oven dry can be carried out in temperature is 50-60 ℃ scope.
The compound method of dyeing liquor is for to place respectively container with load weighted dyestuff, , stirring with its furnishing pasty state or be stirred to whole profit temperature with deionization or distilled water Lower heating is boiled to 4-5min, and cooled and filtered is then the good dye liquor difference of filter Pour in the staining trough, the volume that adding distil water or deionized water to required system is joined, Regulate the dyeing liquor pH value with 1: 1 acetum under stirring, dye liquor is heated to technology Given temperature can come into operation after trial dyeing is qualified.
Enumerate pH value, temperature and time processing parameter that several application the present invention dye unicolor corresponding organic dye and its staining fluid of preparing below:
Embodiment one (dying dark brown):
2.0-2.5g/l 0.1-0.2g/lPH 4.5-5.0 50-60℃ 0.8-1.2min ( ) : 0.5-1.0g/l 0.08-0.12g/lPH 5.0-5.5 50-60℃ 1-1.5min ( ) :: 0.25-0.35g/l 0.05-0.06g/lPH 4.5-5.0 55-60℃ 1-1.2min: 0.25-0.3g/l 0.08-1.0g/l 0.05-0.08g/l PH 4.5-4.8 50-55℃ 18-22s ( ) :: 0.6-1.0g/l 0.1-0.15g/lPH 5.0-5.5 50-60℃ 1-1.5min: 0.25-0.35g/l 0.1-0.15g/l 0.08-0.12g/l PH 4.2-4.8 50-60℃ 0.8-1.2min: 0.25-0.3g/l 0.15-0.2g/lPH 4.5-5.0 50-60℃ 10-20S
The present invention compares the good effect that produces with background technology: 1, can dye arbitrarily monochromatic. 2, color clear. 3, cost is low.
Claims (1)
1, a kind of organic dye solid shade dyeing method of Anodising aluminium alloy, it comprises that product dress extension carries out pre-treatment and washing, is characterized in that it also comprises:
The chromophore of at first using different organic dye can absorb the absorption and the interference of light principle of different light waves and light, according to required color, determines to make behind body color and the complementary colors staining fluid of different colours in contiguous two or three organic dye on color ring,
To immerse in first kind of staining fluid through the clean back of the product water washing of anodic oxidation treatment then, pH value be 4.5-5.5, temperature be carry out under 50-60 ℃ the condition for the time 0.8-1.5min the dyeing first time and wash,
Before utilizing oxide film after a kind of staining fluid dyeing, not seal again, still have the multiple adsorb ability and add the painted characteristic of layer, to carrying out not reaching after the dyeing first time product of required color, it is immersed in second kind of staining fluid, at pH value is 4.2~4.8, temperature be under 50-60 ℃ the condition to secondary dyeing and repeatedly painted product carry out respectively for the time 18-22s, 0.8-1.2min second time dyeing and washing, do not reach the product of required color yet, make suitable technological test by painted processing condition for the second time and adjust dyestuff, pH value, repeatedly dye again after the temperature and time scope and wash, after reaching required monochrome, seal, oven dry.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN94104526A CN1056199C (en) | 1994-04-27 | 1994-04-27 | Organic dye monochromatic dyeing method for anodized aluminum alloy |
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CN94104526A CN1056199C (en) | 1994-04-27 | 1994-04-27 | Organic dye monochromatic dyeing method for anodized aluminum alloy |
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CN1110996A CN1110996A (en) | 1995-11-01 |
CN1056199C true CN1056199C (en) | 2000-09-06 |
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CN94104526A Expired - Fee Related CN1056199C (en) | 1994-04-27 | 1994-04-27 | Organic dye monochromatic dyeing method for anodized aluminum alloy |
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CN106867275B (en) * | 2017-01-09 | 2019-05-17 | 广东长盈精密技术有限公司 | The colouring method of the aluminium alloy dyeing preparation method of black dyes, aluminium alloy |
CN112813700A (en) * | 2021-01-26 | 2021-05-18 | 滁州霞客无染彩色纺有限公司 | Textile dyeing process |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3825213A1 (en) * | 1988-07-25 | 1990-02-08 | Henkel Kgaa | METHOD FOR ADSORPTIVELY COLORING ANODICALLY PRODUCED SURFACES |
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- 1994-04-27 CN CN94104526A patent/CN1056199C/en not_active Expired - Fee Related
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3825213A1 (en) * | 1988-07-25 | 1990-02-08 | Henkel Kgaa | METHOD FOR ADSORPTIVELY COLORING ANODICALLY PRODUCED SURFACES |
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