CN105618163A - Resin regeneration method of condensate polishing high tower separation method regeneration system - Google Patents
Resin regeneration method of condensate polishing high tower separation method regeneration system Download PDFInfo
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- CN105618163A CN105618163A CN201610042573.XA CN201610042573A CN105618163A CN 105618163 A CN105618163 A CN 105618163A CN 201610042573 A CN201610042573 A CN 201610042573A CN 105618163 A CN105618163 A CN 105618163A
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Abstract
The invention relates to a resin regeneration method of a condensate polishing high tower separation method regeneration system. The resin regeneration method comprises the following steps: (1) separation regeneration process of resin; (2) conveying of the resin; (3) scrubbing and regeneration of the resin; and (4) mixing of the resin for later use. The resin regeneration method has the advantages that the control is facilitated, the cost is saved, and the discharge of acid-alkali wastewater is reduced.
Description
Technical field
The present invention relates to the resin regeneration method of a kind of condensate polishing treatment high tower separation technique regenerative system.
Background technology
The effect of condensed water precision processing system is in that to remove the trace mineral dissolved in condensation water, as: Fe, Cu, SiO2��Na+��Cl-Deng and a small amount of float and dissolved solid. These materials are likely to work with the metal in system in varied situations and cause too early destruction, or deposition is in systems, causes ineffective systems and mechanical damage. Therefore; meet high parameter; the requirement to boiler water quality of the heavy-duty generator group; make condensed water precision processing system really play protection therrmodynamic system, increase the effect of economic benefit, to condensed water precision processing system; design except apparatus body (particularly mixed bed); the selection of resin and proportioning, Steam Condenser Leak amount to be reduced to bottom line, it is often more important that will focus on the selection of resin separation renovation process. The operational effect of condensed water precision processing system also just depends on the selection separating regeneration scheme. The resin separation renovation process of the domestic condensed water precision processing system being currently running mainly has at present: ammoniation process, concentrated base floatation, middle extracting method, cone separating method, high tower separation technique etc. Wherein high tower separation technique system is a kind of scheme being most widely used in Power System in China condensed water precision processing system since 1993. In recent years, domestic existing 160 power plant, the condensed water precision processing system of 350 units applied this system.
High tower separation technique system is compared with other system, and its design principle is simpler, with only that the proportion of the waterpower principle of stratification and sun negative resin is different and positive negative resin is easily separated by resin particle diameter difference. High tower separation technique system includes: mixed bed unit, by-pass unit, recirculation pump unit, regeneration unit (three towers), flush water pump unit, roots blower unit, soda acid storage unit, soda acid metering units, valve, pipeline, resin, stored program controlled, instrument, electric etc.
Summary of the invention
It is an object of the invention to overcome above-mentioned deficiency, it is provided that one is beneficial to control, save cost, reduce the resin regeneration method of the condensate polishing treatment high tower separation technique regenerative system of acidic and alkaline waste water discharge capacity.
The object of the present invention is achieved like this:
A kind of resin regeneration method of condensate polishing treatment high tower separation technique regenerative system, it comprises the following steps:
Step one: resin separation regenerative process
In precision processing mixed bed, exhausted resin is admitted in knockout drum, first carry out primary air scouring, make separated from contaminants heavier on exhausted resin out, knockout drum is discharged with current, then upper cone body portion water is emptied, with the high-velocity flow of 44 ~ 50m/h from knockout drum bottom by resin bed holder to collecting region, top;
Reduce water flow velocity to positive resin critical dropping velocity, maintain a period of time, make most positive resin gather the boundary of cone and direct tube section, then reduce water flow velocity and make positive resin settle down, formation positive resin layer; Continue to reduce water flow velocity to negative resin critical dropping velocity, maintain a period of time, make negative resin assemble, reduce water flow velocity again, make negative resin settle down, form negative resin layer, finally the flow velocity of backwash water is gradually decrease to zero, makes that anterior resin is old at leisure lowers;
Step 2: the conveying of resin
First carrying negative resin, the delivery port of negative resin is positioned at above hybrid resin bed boundary about 250-500mm place, in order to stay certain positive resin as compound tree lipid layer, it is therefore an objective to prevent from carrying secretly in negative resin positive resin;
Carrying positive resin again, positive resin is sent to sun tank by the positive resin delivery port bottom knockout drum; The same compound tree lipid layer retaining 250-500mm, it is prevented that carry negative resin in positive resin secretly;
Step 3: resin is cleaned, regeneration
After positive resin and negative resin are respectively delivered to sun tank and cloudy tank, intake to resin bed height, air bump rinse operation, impurity is made to separate from resin surface, clean water while continuing to enter from sun tank and cloudy pot bottom captation, make the past rising of water in sun tank and cloudy tank, resin bed expands, when resin bed expands 50% water level, close sun tank and cloudy tank to idle discharge air valve, thus forming an air chamber having pressure in sun tank and cloudy tank, stop water inlet and air, open Regenerant apparatus valve and sun tank and cloudy pot bottom captation valve simultaneously, due to air chamber quick pressure releasing, impurity and broken resin is made quickly to go out with water,
Step 4: mixed with resin is standby
After positive resin and negative resin regeneration ending respectively, negative resin is transported to sun tank, and air mixing post rinse is standby.
Above-mentioned step one: reduce water flow velocity in resin separation regenerative process and divide 46m/h, 23m/h, 12m/h, 6m/h, 3m/h several stage to reduce.
Above-mentioned step one: the concrete grammar that the resin of resin separation regenerative process separates is as follows:
1.1, F.F. water stratification: after backwash terminates, regulates cloudy tank backwash/layering intake gate flow, carries out F.F. water stratification 10 minutes;
1.2, slow-motion water stratification: after F.F. water stratification terminates, regulates cloudy tank backwash/layering intake gate flow, continues slow-motion water stratification 20 minutes;
1.3, water-filling: after slow-motion water stratification terminates, after cloudy tank is carried out water-filling Zhiyin ullage valve water outlet by the cloudy tank backwash/layering drainage door of closedown, closes cloudy tank backwash/layering intake gate and the moon tank exhaust valve;
1.4, positive resin sends 1: open sun tank resin inlet door, backwash outlets door, inverted U-shaped drainage door, exhaust valve, opens cloudy tank backwash/layering intake gate, resin outlet door, CO2Entrance door carries out positive resin and sends operation;
1.5, after positive resin sends 2:20 minute, regulating cloudy tank backwash/layering intake gate flow, the cloudy tank backwash/layering drainage door of unlatching continued conveying positive resin after 1 minute, when resin boundary surface detects electric conductivity rising, stopping positive resin to send, closedown sun tank resin inlet door, backwash go out water valve, cloudy tank CO2Enter door;
1.6, mixed fat removes sealing chamber: open mixed fat conveying door, resin is delivered to sealing chamber by sealing chamber exhaust valve, closes cloudy tank backwash/layering intake gate, resin outlet door, backwash/layering drainage door after 1 minute;
1.7, rush fat to sealing chamber: open resin pipe flushing door, resin in pipeline is delivered to sealing chamber, after 1 minute, close mixed fat conveying door, sealing chamber exhaust valve;
1.8, fat is rushed to cloudy tank: open cloudy tank resin outlet door, exhaust valve, resin is sent into cloudy tank, after 1 minute, closes cloudy tank resin outlet door, exhaust valve;
1.9, fat is rushed to sun tank: open sun tank resin inlet goalkeeper's resin and send into sun tank, flushing door of blinding off a line after 1 minute, sun tank resin inlet door, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve, resin separates and terminates.
Above-mentioned step one: the concrete grammar of the positive resin regeneration of resin separation regenerative process is as follows:
2.1, inverted U-shaped draining: open inverted U-shaped drainage door, exhaust valve carries out inverted U-shaped draining 1 minute;
2.2, regeneration prepares: start personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve, opens sun tank and enters acid door, acid dilution water valve, prepares into acid;
2.3, enter acid: open solidifying acid meter pump discharge door, start the solidifying acid meter pump tank that faces south and enter acid 40 minutes;
2.4, displacement: enter after acid terminates, stop solidifying acid meter pump, close solidifying acid meter pump discharge door, terminate after carrying out displacement 22 minutes, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve, close sun tank and enter acid door, inverted U-shaped drainage door;
2.5, air bump rinse operation: open sun ullage gas access doors, backwash goes out water valve, starts solidifying Water fan, opens solidifying Water fan emptying door, close after 30 seconds, positive resin being carried out air bump rinse operation, cleans end and stop solidifying Water fan after 3 minutes, closedown sun ullage gas access doors, backwash go out water valve;
2.6, just wash: start personal regeneration pump, open personal regeneration pump discharge door, outlet regulating valve, open sun tank and just washing intake gate, bottom row water valve;
2.7, draining: after just washing 2 minutes, closes sun tank and is just washing intake gate, sun tank is carried out draining;
2.8, inverted U-shaped draining: after draining terminates, closes sun pot bottom drainage door, opens inverted U-shaped drainage door and carry out draining;
2.9, clean water level adjustment: after 1 minute, inverted U-shaped draining terminates, and closes inverted U-shaped drainage door, open sun tank and just washing after water level is adjusted by intake gate, close sun tank and just washing intake gate, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve;
2.10, air bump rinse operation: open sun ullage gas access doors, backwash goes out water valve, starts solidifying Water fan, opens solidifying Water fan emptying door, closes, resin is carried out air bump rinse operation after 30 seconds;
2.11, amount of makeup water: clean after terminating, stops solidifying Water fan, closes sun ullage gas access doors, opens sun tank backwash intake gate, starts personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve; Sun tank is carried out moisturizing and carries out backwash;
2.12, amount of makeup water: after backwash terminates, closedown sun tank backwash intake gate, backwash go out water valve, and unlatching sun tank is just being washed intake gate and proceeded amount of makeup water;
2.13, just wash: when closing sun tank exhaust valve, Kaiyang pot bottom drainage door after sun tank exhaust valve water outlet, sun tank is just washed;
2.14, just washing qualified: when be just washed till water outlet qualified after, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve, close sun tank and just washing intake gate, pot bottom drainage door.
Above-mentioned step one: the concrete grammar of the negative resin regeneration of resin separation regenerative process is as follows:
3.1, partial drainage: open cloudy pot bottom drainage door, exhaust valve, inverted U-shaped drainage door, carries out bottom discharge to cloudy tank, terminates to close cloudy pot bottom drainage door after 1 minute;
3.2, inverted U-shaped draining: continue inverted U-shaped draining 2 minutes;
3.3, regeneration prepares: start personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve, opens solidifying water feeding of heater door, solidifying water heater threeway heat control valve, opens cloudy tank and enters alkali door, prepares into alkali;
3.4, enter alkali: open solidifying alkali meter pump discharge door, start solidifying alkali meter pump, cloudy tank is entered alkali 38 minutes;
3.5, displacement: enter after alkali terminates, stop solidifying alkali meter pump, close solidifying alkali meter pump discharge door, negative resin is replaced;
3.6, air bump rinse operation: after replacing 19 minutes, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve, stop solidifying water heater heating, close solidifying water feeding of heater door, solidifying water heater threeway heat control valve, close cloudy tank and enter alkali door, inverted U-shaped drainage door, open cloudy ullage gas access doors, backwash/layering drainage door, start solidifying Water fan, open solidifying Water fan emptying door, close after 30 seconds and solidifying Water fan emptying door negative resin is cleaned;
3.7, just wash: clean after 3 minutes and terminate, stop solidifying Water fan, close cloudy ullage gas access doors, backwash/layering drainage door, start personal regeneration pump, open personal regeneration pump discharge door, outlet regulating valve, open cloudy tank and just washing intake gate, bottom row water valve, negative resin is just washed;
3.8, draining: after just washing 2 minutes, closes cloudy tank and is just washing intake gate, cloudy tank is carried out draining;
3.9, inverted U-shaped draining: after draining terminates, closes cloudy pot bottom drainage door, opens inverted U-shaped drainage door and carry out draining;
3.10, clean water level adjustment: after 1 minute, inverted U-shaped draining terminates, and closes inverted U-shaped drainage door, open cloudy tank and just washing after water level is adjusted by intake gate, close cloudy tank and just washing intake gate, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve;
3.11, air bump rinse operation: open cloudy ullage gas access doors, backwash/layering drainage door, starts solidifying Water fan, opens solidifying Water fan emptying door, closes solidifying Water fan emptying door resin is carried out air bump rinse operation after 30 seconds;
3.12, backwash: clean after terminating, stops solidifying Water fan, closes cloudy ullage gas access doors, exhaust valve, starts personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve, opens cloudy tank backwash/layering intake gate, negative resin is carried out backwash;
3.13, layering: after backwash 27 minutes, adjusts cloudy tank backwash/layering intake gate flow, continues resin carries out backwash layering 20 minutes;
3.14, amount of makeup water: after layering terminates, closes cloudy tank backwash/layering drainage door, opens cloudy tank exhaust valve and cloudy tank is carried out water level adjustment;
3.15, mixed fat removes sealing chamber: after amount of makeup water terminates, and closes cloudy tank exhaust valve, opens mixed fat conveying door, sealing chamber exhaust valve, cloudy tank resin outlet door, mixed fat is sent to sealing chamber;
3.16, resin pipe flushing: mixed fat is carried after terminating, closes mixed fat conveying door, sealing chamber exhaust valve, cloudy tank backwash/layering intake gate, and resin pipeline is rinsed by unlatching resin flushing of pipeline door, cloudy tank exhaust valve;
3.17, just washing: after resin flushing of pipeline terminates, close cloudy tank exhaust valve, resin outlet door, resin flushing of pipeline door, intake gate just washed by tank, negative resin is just washed by bottom row water valve to open the moon;
3.18, just washing qualified: when be just washed till water outlet qualified after, close cloudy tank and just washing intake gate, bottom row water valve.
Above-mentioned step 4: the yin and yang resin mixing of mixed with resin alternate processes and the concrete grammar of storage are as follows:
4.1, negative resin delivers to sun tank: open sun tank resin inlet door, backwash goes out water valve, exhaust valve, opens cloudy tank backwash/layering intake gate, resin outlet door, and negative resin is delivered to sun tank;
4.2, draining: after conveying terminates, stops personal regeneration pump, closes personal regeneration pump discharge door, outlet regulating valve, close sun tank resin inlet door, backwash goes out water valve, closes cloudy tank backwash/layering intake gate, resin outlet door, opens sun pot bottom drainage door and carries out draining;
4.3, backwash: sun pot bottom drainage door is closed in draining after terminating, starts personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve, opens sun tank backwash intake gate and carries out backwash;
4.4, air hybrid resin: backwash stops personal regeneration pump after 1 minute, close personal regeneration pump discharge door, outlet regulating valve, close sun tank backwash intake gate, open sun ullage gas access doors, backwash goes out water valve, start solidifying Water fan, open solidifying Water fan emptying door, close solidifying Water fan emptying door after 30 seconds and resin is mixed;
4.5, mixed fat draining: after mixing 10 minutes, opens sun pot bottom drainage door, mixed fat is carried out draining;
4.6, slow-motion water: draining closes sun ullage gas access doors after terminating, bottom row water valve, backwash go out water valve, opens sun tank and is just washing intake gate, sun tank is carried out slow-motion water;
4.7, water inlet soon: slow-motion water regulated after 3 minutes just washes intake gate flow, continues sun tank is carried out fast water inlet 6 minutes;
4.8, just wash: after water inlet end, close sun tank exhaust valve, open bottom row water valve, hybrid resin is just washed;
4.9, just washing qualified: when be just washed till water outlet qualified after, close sun tank just washing intake gate, bottom row water valve;
4.10, mixed fat removes cloudy tank: opens mixed fat and sends intake gate, mixed fat conveying door, cloudy tank resin outlet door, middle part drainage door, exhaust valve, backwash/layering drainage door back to, mixed fat is sent cloudy tank, backwash layering during in order to regeneration next time back to. .
Compared with prior art, the invention has the beneficial effects as follows:
The resin regeneration method of condensate polishing treatment high tower separation technique regenerative system of the present invention has and is beneficial to control, saves cost, the advantage reducing acidic and alkaline waste water discharge capacity.
Detailed description of the invention
The resin regeneration method of a kind of condensate polishing treatment high tower separation technique regenerative system that the present invention relates to, high tower separation technique system regeneration system includes resin knockout drum (abbreviation knockout drum), negative resin regenerating tank (be called for short cloudy tank), positive resin regenerating tank hold concurrently resin hold-up tank (being called for short sun tank) and waste water resin catcher.
The resin regeneration method of a kind of condensate polishing treatment high tower separation technique regenerative system comprises the following steps:
Step one: resin separation regenerative process
In precision processing mixed bed, exhausted resin is admitted in knockout drum, first carry out primary air scouring, make separated from contaminants heavier on exhausted resin out, knockout drum is discharged with current, then upper cone body portion water is emptied, with the high-velocity flow of 44 ~ 50m/h from knockout drum bottom by resin bed holder to collecting region, top.
Reduce water flow velocity (substantially dividing 46m/h, 23m/h, 12m/h, 6m/h, 3m/h several stage), to positive resin critical dropping velocity, maintain a period of time, most positive resin is made to gather the boundary of cone and direct tube section, reducing water flow velocity again makes positive resin settle down, and forms positive resin layer; Continue to reduce water flow velocity to negative resin critical dropping velocity, maintain a period of time, make negative resin assemble, reduce water flow velocity again, make negative resin settle down, form negative resin layer, finally the flow velocity of backwash water is gradually decrease to zero, makes that anterior resin is old at leisure lowers. (for making resin to settle in order, sedimentation velocity difference controls between 20 ~ 40m/h).
The resin separation regenerative process of this step one may be repeated, to ensure being completely separated of positive resin and negative resin, it is crucial that control suitable flow velocity and the critical dropping velocity that positive resin and negative resin can be made to settle respectively, (critical dropping velocity of resin can measuring in advance, but it is typically based on site specific to determine in debugging process, whole process can be completed by Automatic Program, discharge and being controlled by the flow control valve bottom knockout drum.
Step 2: the conveying of resin
First carrying negative resin, the delivery port of negative resin is positioned at above hybrid resin bed boundary about 250-500mm place, in order to stay certain positive resin as compound tree lipid layer, it is therefore an objective to prevent from carrying secretly in negative resin positive resin;
Carrying positive resin again, positive resin is sent to sun tank by the positive resin delivery port bottom knockout drum; The same compound tree lipid layer retaining 250-500mm, it is prevented that carry negative resin in positive resin secretly;
Step 3: resin is cleaned, regeneration
After positive resin and negative resin are respectively delivered to sun tank and cloudy tank, intake to resin bed height, air bump rinse operation, impurity is made to separate from resin surface, clean water while continuing to enter from sun tank and cloudy pot bottom captation, make the past rising of water in sun tank and cloudy tank, resin bed expands, when resin bed expands about 50% water level, close sun tank and cloudy tank to idle discharge air valve, thus forming an air chamber having pressure in sun tank and cloudy tank, stop water inlet and air, open Regenerant apparatus valve and sun tank and cloudy pot bottom captation valve simultaneously, due to air chamber quick pressure releasing, impurity and broken resin is made quickly to go out with water. operation is made to may be repeated, until resin is cleaned.
The gap-ratio shredded resin of Regenerant apparatus and underdrain device is big and less than granulate resin, so can discharge broken resin in rinse stage, retain whole resin, can guarantee that again regenerated liquid even into. Structure and rinsing step on this equipment eliminate impurity and broken resin, can prevent the delay of impurity and shredded resin in resin bed from destroying separation process and affecting regeneration effect. Because the precipitative properties of broken positive resin is similar to positive resin, remains in above resin bed when separating, be blended in positive resin, contact alkali during regeneration and be transformed into Na+Type resin, leaks Na in a large number in the mixed bed ammonia type stage after putting into operation+And make mixed bed be not normally functioning, it is greatly shortened cycle of operation.
Design in this structure, compared with " T tower " system, eliminates special resin treatment tank, operates more convenient and better effects if.
Step 4: mixed with resin is standby
After positive resin and negative resin regeneration ending respectively, negative resin is transported to sun tank, and air mixing post rinse is standby.
The control SYSTEM SUMMARY of whole system:
This control system adopts with sun tank station for control centre, namely by the picture at positive tank station and keyboard whole process system is monitored and controls, and control room does not set secondary meter dish.
Condensing water management room, being provided with the positive tank station of two identical equipment each other of kinetic energy, condensate polishing treatment mixed-bed system and shared regenerative system to every unit monitor and control. The screen at sun tank station can show technological process and measure parameter, and control object state also can show group parameter, when parameter off-limit alarm or control object fault or state change, can display in different colors. All monitored information all can print record.
Realized programme-control to field apparatus processing step by PLC, to pump, blower fan, valve electric interlock, the interlock protection etc. between each equipment. The control of system and program disclosure satisfy that whole process system requirement, the temperature of each sample point, pressure, flow, electric conductivity, silicate, Na ion concentration etc. can be monitored record, and system can be carried out malfunction coefficient, warning, interlocking.
This control system adopt automatically control, far behaviour and on the spot hands grasp the mode that combines, it is ensured that the reliability service of whole system. (1) when automatically controlling; by performing the PLC program consistent with technological requirement, implement the control to complete equipment and display by sun tank station, including the operation of system process; the automatic switchover of different process situation, autostop under the state of emergency, warning etc. (2) when far grasping, under the intervention of operator, it is achieved group control system runs and by computer keyboard, field apparatus realizes man-to-man remote operation. (3) on the spot hands grasp into, corresponding equipment solution from whole system is listed, and is operated on equipment on the spot by operator. Far being grasped automatic switching above on the spot or on the spot by remote behaviour automatically is all the smooth of unperturbed, say, that do not have the disorder in the disturbance or technological process that automatically control in the process of switching.
The resin regeneration method of above-mentioned a kind of condensate polishing treatment high tower separation technique regenerative system, a concrete embodiment is:
Step one: the concrete grammar of resin separation regenerative process
1, resin separates
1.1, F.F. water stratification: after backwash terminates, regulates cloudy tank backwash/layering intake gate flow, carries out F.F. water stratification 10 minutes.
1.2, slow-motion water stratification: after F.F. water stratification terminates, regulates cloudy tank backwash/layering intake gate flow, continues slow-motion water stratification 20 minutes.
1.3, water-filling: after slow-motion water stratification terminates, after cloudy tank is carried out water-filling Zhiyin ullage valve water outlet by the cloudy tank backwash/layering drainage door of closedown, closes cloudy tank backwash/layering intake gate and the moon tank exhaust valve.
1.4, positive resin sends 1: open sun tank resin inlet door, backwash outlets door, inverted U-shaped drainage door, exhaust valve, opens cloudy tank backwash/layering intake gate, resin outlet door, CO2Entrance door carries out positive resin and sends operation.
1.5, after positive resin sends 2:20 minute, regulating cloudy tank backwash/layering intake gate flow, the cloudy tank backwash/layering drainage door of unlatching continued conveying positive resin after 1 minute, when resin boundary surface detects electric conductivity rising, stopping positive resin to send, closedown sun tank resin inlet door, backwash go out water valve, cloudy tank CO2Enter door.
1.6, mixed fat removes sealing chamber: open mixed fat conveying door, resin is delivered to sealing chamber by sealing chamber exhaust valve, closes cloudy tank backwash/layering intake gate, resin outlet door, backwash/layering drainage door after 1 minute.
1.7, rush fat to sealing chamber: open resin pipe flushing door, resin in pipeline is delivered to sealing chamber, after 1 minute, close mixed fat conveying door, sealing chamber exhaust valve.
1.8, fat is rushed to cloudy tank: open cloudy tank resin outlet door, exhaust valve, resin is sent into cloudy tank, after 1 minute, closes cloudy tank resin outlet door, exhaust valve.
1.9, fat is rushed to sun tank: open sun tank resin inlet goalkeeper's resin and send into sun tank, flushing door of blinding off a line after 1 minute, sun tank resin inlet door, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve, resin separates and terminates.
2, positive resin regeneration
2.1, inverted U-shaped draining: open inverted U-shaped drainage door, exhaust valve carries out inverted U-shaped draining 1 minute.
2.2, regeneration prepares: start personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve, opens sun tank and enters acid door, acid dilution water valve, prepares into acid.
2.3, enter acid: open solidifying acid meter pump discharge door, start the solidifying acid meter pump tank that faces south and enter acid 40 minutes.
2.4, displacement: enter after acid terminates, stop solidifying acid meter pump, close solidifying acid meter pump discharge door, terminate after carrying out displacement 22 minutes, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve, close sun tank and enter acid door, inverted U-shaped drainage door.
2.5, air bump rinse operation: open sun ullage gas access doors, backwash goes out water valve, starts solidifying Water fan, opens solidifying Water fan emptying door, close after 30 seconds, positive resin being carried out air bump rinse operation, cleans end and stop solidifying Water fan after 3 minutes, closedown sun ullage gas access doors, backwash go out water valve.
2.6, just wash: start personal regeneration pump, open personal regeneration pump discharge door, outlet regulating valve, open sun tank and just washing intake gate, bottom row water valve.
2.7, draining: after just washing 2 minutes, closes sun tank and is just washing intake gate, sun tank is carried out draining.
2.8, inverted U-shaped draining: after draining terminates, closes sun pot bottom drainage door, opens inverted U-shaped drainage door and carry out draining.
2.9, clean water level adjustment: after 1 minute, inverted U-shaped draining terminates, and closes inverted U-shaped drainage door, open sun tank and just washing after water level is adjusted by intake gate, close sun tank and just washing intake gate, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve.
2.10, air bump rinse operation: open sun ullage gas access doors, backwash goes out water valve, starts solidifying Water fan, opens solidifying Water fan emptying door, closes, resin is carried out air bump rinse operation after 30 seconds.
2.11, amount of makeup water: clean after terminating, stops solidifying Water fan, closes sun ullage gas access doors, opens sun tank backwash intake gate, starts personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve. Sun tank is carried out moisturizing and carries out backwash.
2.12, amount of makeup water: after backwash terminates, closedown sun tank backwash intake gate, backwash go out water valve, and unlatching sun tank is just being washed intake gate and proceeded amount of makeup water.
2.13, just wash: when closing sun tank exhaust valve, Kaiyang pot bottom drainage door after sun tank exhaust valve water outlet, sun tank is just washed.
2.14, just washing qualified: when be just washed till water outlet qualified after, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve, close sun tank and just washing intake gate, pot bottom drainage door.
3, negative resin regeneration
3.1, partial drainage: open cloudy pot bottom drainage door, exhaust valve, inverted U-shaped drainage door, carries out bottom discharge to cloudy tank, terminates to close cloudy pot bottom drainage door after 1 minute.
3.2, inverted U-shaped draining: continue inverted U-shaped draining 2 minutes.
3.3, regeneration prepares: start personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve, opens solidifying water feeding of heater door, solidifying water heater threeway heat control valve, opens cloudy tank and enters alkali door, prepares into alkali.
3.4, enter alkali: open solidifying alkali meter pump discharge door, start solidifying alkali meter pump, cloudy tank is entered alkali 38 minutes.
3.5, displacement: enter after alkali terminates, stop solidifying alkali meter pump, close solidifying alkali meter pump discharge door, negative resin is replaced.
3.6, air bump rinse operation: after replacing 19 minutes, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve, stop solidifying water heater heating, close solidifying water feeding of heater door, solidifying water heater threeway heat control valve, close cloudy tank and enter alkali door, inverted U-shaped drainage door, open cloudy ullage gas access doors, backwash/layering drainage door, start solidifying Water fan, open solidifying Water fan emptying door, close after 30 seconds and solidifying Water fan emptying door negative resin is cleaned.
3.7, just wash: clean after 3 minutes and terminate, stop solidifying Water fan, close cloudy ullage gas access doors, backwash/layering drainage door, start personal regeneration pump, open personal regeneration pump discharge door, outlet regulating valve, open cloudy tank and just washing intake gate, bottom row water valve, negative resin is just washed.
3.8, draining: after just washing 2 minutes, closes cloudy tank and is just washing intake gate, cloudy tank is carried out draining.
3.9, inverted U-shaped draining: after draining terminates, closes cloudy pot bottom drainage door, opens inverted U-shaped drainage door and carry out draining.
3.10, clean water level adjustment: after 1 minute, inverted U-shaped draining terminates, and closes inverted U-shaped drainage door, open cloudy tank and just washing after water level is adjusted by intake gate, close cloudy tank and just washing intake gate, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve.
3.11, air bump rinse operation: open cloudy ullage gas access doors, backwash/layering drainage door, starts solidifying Water fan, opens solidifying Water fan emptying door, closes solidifying Water fan emptying door resin is carried out air bump rinse operation after 30 seconds.
3.12, backwash: clean after terminating, stops solidifying Water fan, closes cloudy ullage gas access doors, exhaust valve, starts personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve, opens cloudy tank backwash/layering intake gate, negative resin is carried out backwash.
3.13, layering: after backwash 27 minutes, adjusts cloudy tank backwash/layering intake gate flow, continues resin carries out backwash layering 20 minutes.
3.14, amount of makeup water: after layering terminates, closes cloudy tank backwash/layering drainage door, opens cloudy tank exhaust valve and cloudy tank is carried out water level adjustment.
3.15, mixed fat removes sealing chamber: after amount of makeup water terminates, and closes cloudy tank exhaust valve, opens mixed fat conveying door, sealing chamber exhaust valve, cloudy tank resin outlet door, mixed fat is sent to sealing chamber.
3.16, resin pipe flushing: mixed fat is carried after terminating, closes mixed fat conveying door, sealing chamber exhaust valve, cloudy tank backwash/layering intake gate, and resin pipeline is rinsed by unlatching resin flushing of pipeline door, cloudy tank exhaust valve.
3.17, just washing: after resin flushing of pipeline terminates, close cloudy tank exhaust valve, resin outlet door, resin flushing of pipeline door, intake gate just washed by tank, negative resin is just washed by bottom row water valve to open the moon.
3.18, just washing qualified: when be just washed till water outlet qualified after, close cloudy tank and just washing intake gate, bottom row water valve.
Step 4: the concrete grammar that mixed with resin is standby
4, yin and yang resin mixing and storage
4.1, negative resin delivers to sun tank: open sun tank resin inlet door, backwash goes out water valve, exhaust valve, opens cloudy tank backwash/layering intake gate, resin outlet door, and negative resin is delivered to sun tank.
4.2, draining: after conveying terminates, stops personal regeneration pump, closes personal regeneration pump discharge door, outlet regulating valve, close sun tank resin inlet door, backwash goes out water valve, closes cloudy tank backwash/layering intake gate, resin outlet door, opens sun pot bottom drainage door and carries out draining.
4.3, backwash: sun pot bottom drainage door is closed in draining after terminating, starts personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve, opens sun tank backwash intake gate and carries out backwash.
4.4, air hybrid resin: backwash stops personal regeneration pump after 1 minute, close personal regeneration pump discharge door, outlet regulating valve, close sun tank backwash intake gate, open sun ullage gas access doors, backwash goes out water valve, start solidifying Water fan, open solidifying Water fan emptying door, close solidifying Water fan emptying door after 30 seconds and resin is mixed.
4.5, mixed fat draining: after mixing 10 minutes, opens sun pot bottom drainage door, mixed fat is carried out draining.
4.6, slow-motion water: draining closes sun ullage gas access doors after terminating, bottom row water valve, backwash go out water valve, opens sun tank and is just washing intake gate, sun tank is carried out slow-motion water.
4.7, water inlet soon: slow-motion water regulated after 3 minutes just washes intake gate flow, continues sun tank is carried out fast water inlet 6 minutes.
4.8, just wash: after water inlet end, close sun tank exhaust valve, open bottom row water valve, hybrid resin is just washed.
4.9, just washing qualified: when be just washed till water outlet qualified after, close sun tank just washing intake gate, bottom row water valve.
4.10, mixed fat removes cloudy tank: opens mixed fat and sends intake gate, mixed fat conveying door, cloudy tank resin outlet door, middle part drainage door, exhaust valve, backwash/layering drainage door back to, mixed fat is sent cloudy tank, backwash layering during in order to regeneration next time back to.
Claims (6)
1. the resin regeneration method of a condensate polishing treatment high tower separation technique regenerative system, it is characterised in that it comprises the following steps:
Step one: resin separation regenerative process
In precision processing mixed bed, exhausted resin is admitted in knockout drum, first carry out primary air scouring, make separated from contaminants heavier on exhausted resin out, knockout drum is discharged with current, then upper cone body portion water is emptied, with the high-velocity flow of 44 ~ 50m/h from knockout drum bottom by resin bed holder to collecting region, top;
Reduce water flow velocity to positive resin critical dropping velocity, maintain a period of time, make most positive resin gather the boundary of cone and direct tube section, then reduce water flow velocity and make positive resin settle down, formation positive resin layer; Continue to reduce water flow velocity to negative resin critical dropping velocity, maintain a period of time, make negative resin assemble, reduce water flow velocity again, make negative resin settle down, form negative resin layer, finally the flow velocity of backwash water is gradually decrease to zero, makes that anterior resin is old at leisure lowers;
Step 2: the conveying of resin
First carrying negative resin, the delivery port of negative resin is positioned at above hybrid resin bed boundary about 250-500mm place, in order to stay certain positive resin as compound tree lipid layer, it is therefore an objective to prevent from carrying secretly in negative resin positive resin;
Carrying positive resin again, positive resin is sent to sun tank by the positive resin delivery port bottom knockout drum; The same compound tree lipid layer retaining 250-500mm, it is prevented that carry negative resin in positive resin secretly;
Step 3: resin is cleaned, regeneration
After positive resin and negative resin are respectively delivered to sun tank and cloudy tank, intake to resin bed height, air bump rinse operation, impurity is made to separate from resin surface, clean water while continuing to enter from sun tank and cloudy pot bottom captation, make the past rising of water in sun tank and cloudy tank, resin bed expands, when resin bed expands 50% water level, close sun tank and cloudy tank to idle discharge air valve, thus forming an air chamber having pressure in sun tank and cloudy tank, stop water inlet and air, open Regenerant apparatus valve and sun tank and cloudy pot bottom captation valve simultaneously, due to air chamber quick pressure releasing, impurity and broken resin is made quickly to go out with water,
Step 4: mixed with resin is standby
After positive resin and negative resin regeneration ending respectively, negative resin is transported to sun tank, and air mixing post rinse is standby.
2. the resin regeneration method of a kind of condensate polishing treatment high tower separation technique regenerative system according to claim 1, it is characterised in that step one: reduce water flow velocity in resin separation regenerative process and divide 46m/h, 23m/h, 12m/h, 6m/h, 3m/h several stage to reduce.
3. the resin regeneration method of a kind of condensate polishing treatment high tower separation technique regenerative system according to claim 1, it is characterised in that step one: the concrete grammar that the resin of resin separation regenerative process separates is as follows:
1.1, F.F. water stratification: after backwash terminates, regulates cloudy tank backwash/layering intake gate flow, carries out F.F. water stratification 10 minutes;
1.2, slow-motion water stratification: after F.F. water stratification terminates, regulates cloudy tank backwash/layering intake gate flow, continues slow-motion water stratification 20 minutes;
1.3, water-filling: after slow-motion water stratification terminates, after cloudy tank is carried out water-filling Zhiyin ullage valve water outlet by the cloudy tank backwash/layering drainage door of closedown, closes cloudy tank backwash/layering intake gate and the moon tank exhaust valve;
1.4, positive resin sends 1: open sun tank resin inlet door, backwash outlets door, inverted U-shaped drainage door, exhaust valve, opens cloudy tank backwash/layering intake gate, resin outlet door, CO2Entrance door carries out positive resin and sends operation;
1.5, after positive resin sends 2:20 minute, regulating cloudy tank backwash/layering intake gate flow, the cloudy tank backwash/layering drainage door of unlatching continued conveying positive resin after 1 minute, when resin boundary surface detects electric conductivity rising, stopping positive resin to send, closedown sun tank resin inlet door, backwash go out water valve, cloudy tank CO2Enter door;
1.6, mixed fat removes sealing chamber: open mixed fat conveying door, resin is delivered to sealing chamber by sealing chamber exhaust valve, closes cloudy tank backwash/layering intake gate, resin outlet door, backwash/layering drainage door after 1 minute;
1.7, rush fat to sealing chamber: open resin pipe flushing door, resin in pipeline is delivered to sealing chamber, after 1 minute, close mixed fat conveying door, sealing chamber exhaust valve;
1.8, fat is rushed to cloudy tank: open cloudy tank resin outlet door, exhaust valve, resin is sent into cloudy tank, after 1 minute, closes cloudy tank resin outlet door, exhaust valve;
1.9, fat is rushed to sun tank: open sun tank resin inlet goalkeeper's resin and send into sun tank, flushing door of blinding off a line after 1 minute, sun tank resin inlet door, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve, resin separates and terminates.
4. the resin regeneration method of a kind of condensate polishing treatment high tower separation technique regenerative system according to claim 1, it is characterised in that step one: the concrete grammar of the positive resin regeneration of resin separation regenerative process is as follows:
2.1, inverted U-shaped draining: open inverted U-shaped drainage door, exhaust valve carries out inverted U-shaped draining 1 minute;
2.2, regeneration prepares: start personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve, opens sun tank and enters acid door, acid dilution water valve, prepares into acid;
2.3, enter acid: open solidifying acid meter pump discharge door, start the solidifying acid meter pump tank that faces south and enter acid 40 minutes;
2.4, displacement: enter after acid terminates, stop solidifying acid meter pump, close solidifying acid meter pump discharge door, terminate after carrying out displacement 22 minutes, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve, close sun tank and enter acid door, inverted U-shaped drainage door;
2.5, air bump rinse operation: open sun ullage gas access doors, backwash goes out water valve, starts solidifying Water fan, opens solidifying Water fan emptying door, close after 30 seconds, positive resin being carried out air bump rinse operation, cleans end and stop solidifying Water fan after 3 minutes, closedown sun ullage gas access doors, backwash go out water valve;
2.6, just wash: start personal regeneration pump, open personal regeneration pump discharge door, outlet regulating valve, open sun tank and just washing intake gate, bottom row water valve;
2.7, draining: after just washing 2 minutes, closes sun tank and is just washing intake gate, sun tank is carried out draining;
2.8, inverted U-shaped draining: after draining terminates, closes sun pot bottom drainage door, opens inverted U-shaped drainage door and carry out draining;
2.9, clean water level adjustment: after 1 minute, inverted U-shaped draining terminates, and closes inverted U-shaped drainage door, open sun tank and just washing after water level is adjusted by intake gate, close sun tank and just washing intake gate, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve;
2.10, air bump rinse operation: open sun ullage gas access doors, backwash goes out water valve, starts solidifying Water fan, opens solidifying Water fan emptying door, closes, resin is carried out air bump rinse operation after 30 seconds;
2.11, amount of makeup water: clean after terminating, stops solidifying Water fan, closes sun ullage gas access doors, opens sun tank backwash intake gate, starts personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve; Sun tank is carried out moisturizing and carries out backwash;
2.12, amount of makeup water: after backwash terminates, closedown sun tank backwash intake gate, backwash go out water valve, and unlatching sun tank is just being washed intake gate and proceeded amount of makeup water;
2.13, just wash: when closing sun tank exhaust valve, Kaiyang pot bottom drainage door after sun tank exhaust valve water outlet, sun tank is just washed;
2.14, just washing qualified: when be just washed till water outlet qualified after, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve, close sun tank and just washing intake gate, pot bottom drainage door.
5. the resin regeneration method of a kind of condensate polishing treatment high tower separation technique regenerative system according to claim 1, it is characterised in that step one: the concrete grammar of the negative resin regeneration of resin separation regenerative process is as follows:
3.1, partial drainage: open cloudy pot bottom drainage door, exhaust valve, inverted U-shaped drainage door, carries out bottom discharge to cloudy tank, terminates to close cloudy pot bottom drainage door after 1 minute;
3.2, inverted U-shaped draining: continue inverted U-shaped draining 2 minutes;
3.3, regeneration prepares: start personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve, opens solidifying water feeding of heater door, solidifying water heater threeway heat control valve, opens cloudy tank and enters alkali door, prepares into alkali;
3.4, enter alkali: open solidifying alkali meter pump discharge door, start solidifying alkali meter pump, cloudy tank is entered alkali 38 minutes;
3.5, displacement: enter after alkali terminates, stop solidifying alkali meter pump, close solidifying alkali meter pump discharge door, negative resin is replaced;
3.6, air bump rinse operation: after replacing 19 minutes, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve, stop solidifying water heater heating, close solidifying water feeding of heater door, solidifying water heater threeway heat control valve, close cloudy tank and enter alkali door, inverted U-shaped drainage door, open cloudy ullage gas access doors, backwash/layering drainage door, start solidifying Water fan, open solidifying Water fan emptying door, close after 30 seconds and solidifying Water fan emptying door negative resin is cleaned;
3.7, just wash: clean after 3 minutes and terminate, stop solidifying Water fan, close cloudy ullage gas access doors, backwash/layering drainage door, start personal regeneration pump, open personal regeneration pump discharge door, outlet regulating valve, open cloudy tank and just washing intake gate, bottom row water valve, negative resin is just washed;
3.8, draining: after just washing 2 minutes, closes cloudy tank and is just washing intake gate, cloudy tank is carried out draining;
3.9, inverted U-shaped draining: after draining terminates, closes cloudy pot bottom drainage door, opens inverted U-shaped drainage door and carry out draining;
3.10, clean water level adjustment: after 1 minute, inverted U-shaped draining terminates, and closes inverted U-shaped drainage door, open cloudy tank and just washing after water level is adjusted by intake gate, close cloudy tank and just washing intake gate, stop personal regeneration pump, close personal regeneration pump discharge door, outlet regulating valve;
3.11, air bump rinse operation: open cloudy ullage gas access doors, backwash/layering drainage door, starts solidifying Water fan, opens solidifying Water fan emptying door, closes solidifying Water fan emptying door resin is carried out air bump rinse operation after 30 seconds;
3.12, backwash: clean after terminating, stops solidifying Water fan, closes cloudy ullage gas access doors, exhaust valve, starts personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve, opens cloudy tank backwash/layering intake gate, negative resin is carried out backwash;
3.13, layering: after backwash 27 minutes, adjusts cloudy tank backwash/layering intake gate flow, continues resin carries out backwash layering 20 minutes;
3.14, amount of makeup water: after layering terminates, closes cloudy tank backwash/layering drainage door, opens cloudy tank exhaust valve and cloudy tank is carried out water level adjustment;
3.15, mixed fat removes sealing chamber: after amount of makeup water terminates, and closes cloudy tank exhaust valve, opens mixed fat conveying door, sealing chamber exhaust valve, cloudy tank resin outlet door, mixed fat is sent to sealing chamber;
3.16, resin pipe flushing: mixed fat is carried after terminating, closes mixed fat conveying door, sealing chamber exhaust valve, cloudy tank backwash/layering intake gate, and resin pipeline is rinsed by unlatching resin flushing of pipeline door, cloudy tank exhaust valve;
3.17, just washing: after resin flushing of pipeline terminates, close cloudy tank exhaust valve, resin outlet door, resin flushing of pipeline door, intake gate just washed by tank, negative resin is just washed by bottom row water valve to open the moon;
3.18, just washing qualified: when be just washed till water outlet qualified after, close cloudy tank and just washing intake gate, bottom row water valve.
6. the resin regeneration method of a kind of condensate polishing treatment high tower separation technique regenerative system according to claim 1, it is characterised in that step 4: the yin and yang resin mixing of mixed with resin alternate processes and the concrete grammar of storage are as follows:
4.1, negative resin delivers to sun tank: open sun tank resin inlet door, backwash goes out water valve, exhaust valve, opens cloudy tank backwash/layering intake gate, resin outlet door, and negative resin is delivered to sun tank;
4.2, draining: after conveying terminates, stops personal regeneration pump, closes personal regeneration pump discharge door, outlet regulating valve, close sun tank resin inlet door, backwash goes out water valve, closes cloudy tank backwash/layering intake gate, resin outlet door, opens sun pot bottom drainage door and carries out draining;
4.3, backwash: sun pot bottom drainage door is closed in draining after terminating, starts personal regeneration pump, opens personal regeneration pump discharge door, outlet regulating valve, opens sun tank backwash intake gate and carries out backwash;
4.4, air hybrid resin: backwash stops personal regeneration pump after 1 minute, close personal regeneration pump discharge door, outlet regulating valve, close sun tank backwash intake gate, open sun ullage gas access doors, backwash goes out water valve, start solidifying Water fan, open solidifying Water fan emptying door, close solidifying Water fan emptying door after 30 seconds and resin is mixed;
4.5, mixed fat draining: after mixing 10 minutes, opens sun pot bottom drainage door, mixed fat is carried out draining;
4.6, slow-motion water: draining closes sun ullage gas access doors after terminating, bottom row water valve, backwash go out water valve, opens sun tank and is just washing intake gate, sun tank is carried out slow-motion water;
4.7, water inlet soon: slow-motion water regulated after 3 minutes just washes intake gate flow, continues sun tank is carried out fast water inlet 6 minutes;
4.8, just wash: after water inlet end, close sun tank exhaust valve, open bottom row water valve, hybrid resin is just washed;
4.9, just washing qualified: when be just washed till water outlet qualified after, close sun tank just washing intake gate, bottom row water valve;
4.10, mixed fat removes cloudy tank: opens mixed fat and sends intake gate, mixed fat conveying door, cloudy tank resin outlet door, middle part drainage door, exhaust valve, backwash/layering drainage door back to, mixed fat is sent cloudy tank, backwash layering during in order to regeneration next time back to.
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CN113941375A (en) * | 2021-11-03 | 2022-01-18 | 江苏核电有限公司 | Positive bed regeneration method and device for condensate fine treatment system of nuclear power station |
CN114618595A (en) * | 2022-03-11 | 2022-06-14 | 山东钢铁集团永锋临港有限公司 | Novel efficient restoration technology for anion-cation resin |
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CN116196987A (en) * | 2023-02-21 | 2023-06-02 | 华能山东发电有限公司白杨河发电厂 | Condensate water refined resin regeneration method |
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