CN105616192A - Color protection combination and product containing combination - Google Patents
Color protection combination and product containing combination Download PDFInfo
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- CN105616192A CN105616192A CN201511029050.3A CN201511029050A CN105616192A CN 105616192 A CN105616192 A CN 105616192A CN 201511029050 A CN201511029050 A CN 201511029050A CN 105616192 A CN105616192 A CN 105616192A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
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Abstract
The invention belongs to the field of cosmetics, and relates to a color protection combination, in particular to a color protection combination containing an ultraviolet absorbent and an antioxidant. The cosmetics containing the combination can be insolated outdoors in certain time, and the color cannot completely fade under the condition of receiving light and heat.
Description
Technical field
The invention belongs to cosmetic field, relate to a kind of color fixative compositions, more particularly, relate to a kind of color fixative compositions containing ultraviolet absorber and antioxidant.
Background technology
In the epoch of current brand consumption and personalized consumption, consumer buys commodity not merely in order to meet material demand, and more values individual sexual satisfaction and the spiritual happiness that commodity can bring to oneself, and this to show by packaging on sense organ. Wherein product is carried out the visual performance of realism by transparent wrapper, it is possible to allow consumer intuitively arrive the true appearance of content, produces more intensive visual impact and cogency, strengthens desire to purchase.
In today of like product function and profile " homogeneity " increasingly, color has become one of key element of difference product or brand. Colorful product total energy attracts the sight of consumer, excites desire to buy and improves the resolution of brand.
In sum, transparent wrapper is mixed coloured content and is more liked by consumer. But, the product of transparent wrapper producing, storage, sell and use link, it is easy to by the impact of light and heat, fade, variable color, active component oxidation. This heavy damage brand image in the minds of consumer, and then enterprise is caused heavy losses.
Cleaning and wash and protect product, such as shampoo and bath oil, typically contains anion surfactant for decontamination, foaming. Anionic surfactant molecules typically contains sulfate or sulfonate groups. When synthetic surfactant, except primary response sulfation and sulfonating reaction, also have a small amount of side reaction and occur, therefore can generate side reaction product. Exactly because the existence of these side reaction products, seriously cause fading of liquid cleaning product.
Research finds, when there are these side reaction products, the peroxide value (POV) of surfactant is higher. And when adding the antioxidant with POV value corresponding amount, the stability of pigment and flavouring agent has largely to be improved, but when adding excessive, pigment or spice worsen sometimes, occur seriously fade or produce bad smell.
Therefore, for the cleaning containing surfactant, wash and protect product, it is necessary to add proper amount of antioxidant, to strengthen the stability of pigment. Patent US4077911 discloses the use of 2,6-di-t-butyls to toluene and two kinds of antioxidants of Butylated hydroxyanisole, as the color fixative composition of detergent. Both antioxidants can form stable compositions with detergent, and without measuring the POV value of sample when using, can obtain excellent color fixative performance in the scope of 0.02-1.0wt%.
Scheme disclosed above is (50 DEG C) at high temperature, there is outstanding effect of color protection, but, they are for different pigments, and optimum makes consumption inconsistent. And for the experiment under high light, the pigment tested only has four kinds, it is impossible to learn the kind of pigment that color fixative covers. It is true that toluene can be become yellow by 2,6-di-t-butyls under light illumination.
Owing to scheme temperature disclosed above and illumination experiment are separately performed, it is difficult to imitate high temperature and exposure environment while of in true environment. So its color fixative in actual products is unknown. But, pigment fades and is mainly subject to the effect of solar irradiation, the especially effect of ultraviolet light. For the cosmetics of transparent wrapper, only add antioxidant and be difficult to obtain useful effect of color protection, be highly desirable to add ultraviolet absorber for preventing cosmetics from fading.
Ultraviolet absorber is a kind of light stabilizer, can absorb the ultraviolet part that the wavelength in sunlight is 290-460nm. At cosmetic industry, ultraviolet absorber is mainly used in sun-proof class cosmetics, in order to resist the ultraviolet injury to skin. Also have and fade in order to preventing for other cosmetics, washing product. Outstanding fade-proof ultraviolet absorber, should have the feature that the absorption ultraviolet that (1) can be strong; (2) light stability; (3) can be good at being dissolved in system; (4) heat stability; (5) low volatility; (6) nontoxic; (7) not with other substance reactions in system; (8) the kind of pigment scope being suitable for is wide.
Being difficult to have ultraviolet absorber to meet above all of feature, especially suitable kind of pigment scope is wide simultaneously. In different systems, for the ultraviolet absorber of different pigments, variety classes and various dose, the color fixative performance difference shown is big. WILLISG etc. (J.Soc.CosmeticUhemists, 17,553-570 (1966)) study discovery, variety classes, different amounts the different pigment that is suitable for of ultraviolet absorber. Such as purple 2,0.1% benzophenone-1 color fixative performance is more preferably; Blue 1, benzophenone-2 effect of color protection of 0.05% is better. And benzophenone can with green 1, the multiple pigment reactions such as green 5, green 8.
For different pigments, the ultraviolet absorber of variety classes, various dose need to be selected, be inconvenient for for producing. To in cleaning washing product, it is necessary to a kind of color fixative product, it is possible to solve problems with: (1) can prevent the pigment that the side reaction product in sulfate and alkylated reaction causes from fading simultaneously; (2) what air oxidation caused fade, variable color; (3) illumination, especially UV-induced fades; (4) the pigment ranging variety being suitable for is wide. In the product of transparent wrapper, it is especially desirable to such a color fixative compositions, and opaque products, it it is again the product liked the most of consumer.
Color fixative compositions provided by the invention, it is possible to prevent from washing protect product produce and sell, storage and use procedure in fade, variable color. This color fixative compositions not with the substance reaction in system, nontoxic, thermally-stabilised, in preferred proportion, most pigment is had significant protective effect.
Summary of the invention
An object of the present invention is in that to provide a kind of color fixative compositions, and said composition a period of time of can being exposed to the sun in the sun is colour-fast.
The two of the purpose of the present invention are in that to provide a kind of significant bath oil of fade-proof effect.
The three of the purpose of the present invention are in that to provide the preparation method of this bath composition.
The object of the invention is achieved through the following technical solutions:
Color fixative compositions
The invention provides a kind of color fixative compositions, it is characterised in that containing antioxidant and ultraviolet absorber:
Described color fixative compositions, it is characterized in that described antioxidant is sodium sulfite, magnesium L-ascorbyl-2-phosphate, sodium thiosulfate, NAP, 2,6 ditertiary butyl p cresol, butylated hydroxyarisol, tocopherol acetas, one or more combination in sodium pyrosulfite, it is preferable that 2,6 ditertiary butyl p cresol.
As a kind of preferred version, described antioxidant parts by weight are 0.01��1 part, it is preferable that 0.10��0.15 part.
2,6 ditertiary butyl p cresol is common antioxidant, at present, is mainly used in rubber and prevents ageing of rubber, also has and protects product for cosmetics and washing and prevent product oxidation, variable color and fade. The cleaning product effect effect of color protection that patent US4077911 discloses 2,6 ditertiary butyl p cresol and Butylated hydroxyanisole contains sulfate group and sulfonic acid group is good. Because 2,6 ditertiary butyl p cresol is to thermally-stabilised, stable existence in cleaning product system. But, 2,6-ditertbutylparacresol is unstable to illumination, meet light oneself meeting variable color itself, so, 2, color fixative effect of 6-ditertbutylparacresol cosmetics is limited, particularly in the product of transparent wrapper, it is difficult to give quite useful effect of color protection, and transparent wrapper is liked by consumer.
Through the study find that, after antioxidant and ultraviolet absorber are composite, all there is obvious color fixative for fading of causing of the factor such as illumination and temperature. Therefore, in the color fixative compositions of the present invention, possibly together with ultraviolet absorber.
Described color fixative compositions, it is characterized in that described ultraviolet absorber is OXYBENZONE, ethylhexyl methoxy cinnamate, benzophenone-2, ethylhexyl salicylate, avobenzone, 4-methyl benzylidene camphor, octocrilene, the one or more combination in Phenylbenzimidazolesulfonic acid, it is preferable that benzophenone-2.
As a kind of preferred version, described ultraviolet absorber parts by weight are 0.01��1 part, it is preferable that 0.08��0.12 part.
But, it is not that arbitrarily a kind of ultraviolet absorber is composite with antioxidant, all can obtain intended effect of color protection.
In one embodiment of this invention, adopt UVNUL MS-40 and 2,6 ditertiary butyl p cresol composite; UVNUL MS-40 and ethylhexyl methoxy cinnamate and 2,6 ditertiary butyl p cresol; Benzotriazole base butylbenzene natrium phenolsulfonicum and 2,6-ditertbutylparacresol is composite, bath oil containing light blue (light blue pigment in the embodiment of this programme be the most acid-fast a kind of pigment) pigment all in one day color thin out, and adopt benzophenone-2 and 2,6-ditertbutylparacresol is composite, even if composite well below other modes of parts by weight, also without discolouration phenomena occur in seven days.
It is therefore preferred that the color fixative compositions of the present invention selects 2,6 ditertiary butyl p cresol and benzophenone-2 composite.
Benzophenone is mainly used in sunscreen product, the opposing ultraviolet injury to skin. In bath oil, add benzophenone-2 composite as color fixative composition with 2,6 ditertiary butyl p cresol, still belong to the first time.
Through the study find that, benzophenone-2 can in the system of bath oil stable existence, and compensate for the deficiency that 2,6 ditertiary butyl p cresol effect of color protection under light illumination is limited. Meanwhile, benzophenone-2 is also spice fixastive, can give spice with sweet breath.
For different types of pigment, different antioxidants and ultraviolet absorber, optimum consumption should be inconsistent. When lower than a certain number, effect of color protection is limited, and higher than a certain number, not only cost increases, it is even more important that may cause variable color, fade. Optimal situation is, a kind of color fixative compositions, in preferred parts by weight, it is possible to be suitable for the pigment of major part kind.
In one embodiment of this invention, have selected the antioxidant of following number respectively and ultraviolet absorber is composite, 18 kinds of bath oils containing different pigments are tested.
From the foregoing, when the parts by weight of antioxidant 2,6 ditertiary butyl p cresol are 0.03 part, the number of ultraviolet absorber is from 0.05-0.20 part, in 18 kinds of pigments, except light blue does not fade in 7 days, all the other 17 kinds all occur in that and fade. When the parts by weight of ultraviolet absorber benzophenone-2 are 0.1 part, when the parts by weight of antioxidant 2,6 ditertiary butyl p cresol reach 0.1 part, in seven days, 17 kinds of bath oils not exclusively fade.
Colorant composition
The invention provides a kind of stable colorant composition, it is characterised in that containing color fixative compositions and pigment.
Described color fixative compositions, it is characterised in that contain:
(1) 0.01��1 part of antioxidant, it is preferable that 0.08��0.12 part;
(2) 0.01��1 parts of ultraviolet absorbers, it is preferable that 0.10��0.15 part.
Described antioxidant is sodium sulfite, magnesium L-ascorbyl-2-phosphate, sodium thiosulfate, NAP, 2,6 ditertiary butyl p cresol, butylated hydroxyarisol, tocopherol acetas, one or more in sodium pyrosulfite, it is preferable that 2,6 ditertiary butyl p cresol.
Described ultraviolet absorber is OXYBENZONE, ethylhexyl methoxy cinnamate, benzophenone-2, ethylhexyl salicylate, avobenzone, 4-methyl benzylidene camphor, octocrilene, one or more in Phenylbenzimidazolesulfonic acid, it is preferable that benzophenone-2.
Described colorant composition, it is characterised in that described pigment is lemon yellow, light blue, acid violet 43, yellow 10, acid blue 9, red 7, orange 4, green 3, Xylene Red 52, acid yellow 23, quinoline yellow, red 4, red 33, sunset yellow, light green, acid blue 80, carmine, one or both in red 28; Preferred lemon yellow, light blue, acid violet 43, yellow 10, acid blue 9, red 7, orange 4, green 3, Xylene Red 52, acid yellow 23, quinoline yellow, red 4, red 33, sunset yellow, light green, acid blue 80, carmine, one or both in red 28. Its parts by weight preferably 0.0001��0.005 part, more preferably 0.0005��0.001 part.
Colorant composition of the present invention, it is adaptable to cleaning product, wash and protect product and perfume etc., it is preferable that wash and protect product, it is preferred that bath oil.
Fade-proof bath oil
The invention provides a kind of fade-proof bath oil, it is characterised in that containing above-mentioned colorant composition.
In embodiment according to bath composition of the present invention, possibly together with polyoxyethylenated alcohol sodium sulfate.
As a kind of preferred embodiment, described polyoxyethylenated alcohol sodium sulfate parts by weight are 5��20 parts, it is preferable that 12��15 parts.
In example according to bath composition of the present invention, possibly together with sodium lauryl sulphate.
As a kind of preferred embodiment, described sodium lauryl sulphate parts by weight are 1��10 part, it is preferable that 1��3 part.
In example according to bath composition of the present invention, possibly together with cocos nucifera oil acyl CAB.
As a kind of preferred embodiment, described cocos nucifera oil acyl CAB parts by weight are 1��20 part, it is preferable that 3��5 parts.
In example according to bath composition of the present invention, possibly together with citric acid.
As a kind of preferred embodiment, described citric acid parts by weight are 0.01��0.5 part, it is preferable that 0.04��0.06 part.
In example according to bath composition of the present invention, possibly together with disodiumedetate.
As a kind of preferred embodiment, described disodiumedetate parts by weight are 0.01��0.2 part, it is preferable that 0.05��0.1 part.
In example according to bath composition of the present invention, possibly together with edible salt.
Fade-proof bath oil preparation method
The preparation method that present invention also offers a kind of fade-proof bath oil, specific as follows:
A: heat deionized water to 80��85 DEG C, stirring and dissolving after benzophenone-2 and 2,6 ditertiary butyl p cresol addition deionized water.
B: add polyoxyethylenated alcohol sodium sulfate, sodium lauryl sulphate and cocos nucifera oil acyl CAB in step A gained mixture, stir, be cooled to 45 DEG C,
C: be separately added into citric acid, disodiumedetate and pigment in step B gained mixture, dissolves completely, continues to add preservative, essence and edible salt stirring and dissolving.
Those skilled in the art is known, and ultraviolet absorber can prevent cosmetics from fading, but different systems, different pigments, the color fixative performance of different ultraviolet absorbers is inconsistent. There are some researches show the OXYBENZONE color fixative poor performance to red 33 in shampoo, and in perfume OXYBENZONE to acid emerald green blue AE substantially without color fixative performance. In the present invention also that different ultraviolet absorbers and antioxidant is composite. Finding through test, after adopting antioxidant benzophenone-2 and antioxidant 2,6 ditertiary butyl p cresol composite, color fixative performance is notable, and other complex composition effect of color protection are limited.
Present invention prior art is compared, and obtains following beneficial effect.
(1) wide suitable in pigment scope;
(2) all there is notable protection for fading of causing of the many factors such as high temperature, illumination, system side reaction.
Color fixative compositions provided by the invention, first by composite to ultraviolet absorber benzophenone-2 and antioxidant 2,6 ditertiary butyl p cresol, adds in bath oil, the COLOR FASTNESS PROBLEM of highly effective solution bath oil. Meanwhile, bath oil prepared by the present invention, possibly together with pigment, the desire to buy that can stimulate consumer, increases product sales volume. Bath oil prepared by the present invention is especially suitable for transparent wrapper, it is simple to consumer's direct feel is to the texture of bath oil. Bath gel foaming abundancy prepared by the present invention, easily rinse, the preparation method that uses simple to operation, it is simple to popularization and application. Meanwhile, it is wide that this bath composition is suitable for pigment scope, advantageously reduces producer's cost.
Detailed description of the invention
Further illustrating technical scheme below by way of specific embodiment, specific embodiment does not represent limiting the scope of the invention. Other people still fall within protection scope of the present invention according to made some the nonessential amendments of theory of the present invention and adjustment.
Embodiment 1
The preparation of bath composition of the present invention, is made up of the component of following weight percentage:
The preparation method of described bath composition is as follows:
A: heat deionized water to 80��85 DEG C, stirring and dissolving after benzophenone-2 and 2,6 ditertiary butyl p cresol addition deionized water.
B: add polyoxyethylenated alcohol sodium sulfate, sodium lauryl sulphate and cocos nucifera oil acyl CAB in step A gained mixture, stir, be cooled to 45 DEG C,
C: be separately added into citric acid, disodiumedetate and pigment in step B gained mixture, dissolves completely, continues to add preservative, essence and edible salt stirring and dissolving.
Embodiment 2
Different ultraviolet absorbers and the composite effect of color protection comparison of 2,6 ditertiary butyl p cresol
Preparing bath oil by the method for embodiment 1, be divided into A-E5 combination, be separately added into antioxidant as shown in table 1 and ultraviolet absorber, 0.0005 part of light blue is all added in five combinations, and all the other components are identical with embodiment 1.
The 5 groups of bath oils that will have configured, take 50mL respectively and be contained in the transparent PET plastic bottle of 50mL, seal, start to be placed on roof that afternoon 4 to tan by the sun, the experimental period of one day is calculated at 4 in the afternoon of second day, by that analogy, carrying out atmospheric exposure one week, every day, bath oil color situation of change was observed in timing. (outdoor mean temperature during experiment: 25��33 degree, fine).
By contrasting with the sample being placed on laboratory room temperature, judge the degree that color changes. Experimental result is as shown in table 1:
With antioxidant, the different ultraviolet absorber of table 1 prevents that composite effect of color protection contrasts
| Combination | Ultraviolet absorber (number)+antioxidant (number) | Discoloration |
| A | UVNUL MS-40 (0.5)+2,6 ditertiary butyl p cresol (0.1) | Within one day, color is thin out |
| B | UVNUL MS-40 (1)+2,6 ditertiary butyl p cresol (0.1) | Within one day, color is thin out |
| C | UVNUL MS-40 (1)+ethylhexyl methoxy cinnamate (0.5)+2,6 ditertiary butyl p cresol (0.1) | Within one day, color is thin out |
| D | Benzotriazole base butylbenzene natrium phenolsulfonicum (1)+2,6 ditertiary butyl p cresol (0.1) | Within one day, color is thin out |
| E | Benzophenone-2 (0.1)+2,6 ditertiary butyl p cresol (0.1) | Within seven days, do not fade |
As shown in Table 1, it is not that arbitrarily a kind of ultraviolet absorber is composite with antioxidant, all can obtain intended effect of color protection.
After combination E selects benzophenone-2 and 2,6 ditertiary butyl p cresol composite, even if parts by weight combine well below other, after being exposed to the sun seven days, color is not taken off; Other first day colors of combination are thin out, fade fast, and combination E is substantially better than other combinations, therefore benzophenone-2 has non-obvious effect of color protection with 2,6 ditertiary butyl p cresol is composite.
Embodiment 3
The fade-proof effect comparison of Different Weight number ultraviolet absorber
Preparing bath oil by the method for embodiment 1, be wherein divided into A, B, C tri-big group, often group comprises 18 kinds of bath oils containing different pigments, and wherein, A, B, C tri-groups adds the color fixative compositions of following parts by weight respectively:
A, B, C tri-group adds 0.0005 part of pigment respectively successively, and kind of pigment is as shown in table 2. All the other components are identical with embodiment 1.
The three groups of bath oils that will have configured, take 50mL respectively and be contained in the transparent PET plastic bottle of 50mL, seal, start to be placed on roof that afternoon 4 to tan by the sun, the experimental period of one day is calculated at 4 in the afternoon of second day, by that analogy, carry out atmospheric exposure one week, after seven days, observe bath oil color situation of change. (outdoor mean temperature during experiment: 25��33 degree, fine).
By contrasting with the sample being placed on laboratory room temperature, judge the degree that color changes. Shown in A, B, C tri-groups of experimental results respectively table 2, table 3 and table 4:
Table 2 combines the fade-proof effect of A
Note: 1. " " represents that color is not changed in
2. above pigment all uses register at international cosmetic pigment
Table 3 combines the fade-proof effect of B
Note: 1. " " represents that color is not changed in
2. above pigment all uses register at international cosmetic pigment
Table 4 combines the fade-proof effect of C
Note: 1. " " represents that color is not changed in
2. above pigment all uses register at international cosmetic pigment
By table 2, table 3, table 4 it can be seen that when the parts by weight of antioxidant 2,6 ditertiary butyl p cresol are 0.03 part, the parts by weight of ultraviolet absorber benzophenone-2 are from 0.05 to 0.20, all without effect of color protection.
Embodiment 4
The fade-proof effect comparison of antioxidant of Different Weight number
Preparing bath oil by the method for embodiment 1, be wherein divided into D, E, F tri-big group, often group comprises 18 kinds of bath oils containing different pigments, and wherein, wherein D, E, F tri-groups adds the color fixative compositions of following parts by weight respectively:
D, E, F tri-group adds 0.0005 part of pigment respectively successively, and kind of pigment is as shown in table 2. All the other components are identical with embodiment 1.
The three groups of bath oils that will have configured, take 50mL respectively and be contained in the transparent PET plastic bottle of 50mL, seal, start to be placed on roof that afternoon 4 to tan by the sun, the experimental period of one day is calculated at 4 in the afternoon of second day, by that analogy, carry out atmospheric exposure one week, after seven days, observe bath oil color situation of change. (outdoor mean temperature during experiment: 25��33 degree, fine).
By contrasting with the sample being placed on laboratory room temperature, judge the degree that color changes. Shown in D, E, F tri-groups of experimental results respectively table 5, table 6 and table 7:
Table 5 combines the fade-proof effect of D
Note: 1. " " represents that color is not changed in
2. above pigment all uses register at international cosmetic pigment
Table 6 combines the fade-proof effect of E
Note: 1. " " represents that color is not changed in
2. above pigment all uses register at international cosmetic pigment
Table 7 combines the fade-proof effect of F
Note: 1. " " represents that color is not changed in
2. above pigment all uses register at international cosmetic pigment
From table 5,6,7, when the parts by weight of ultraviolet absorber benzophenone-2 are 0.1 part, antioxidant 2, when the parts by weight of 6-ditertbutylparacresol are 0.05, in 18 kinds of pigments, 14 kinds of pigments fade, when antioxidant 2, when the parts by weight of 6-ditertbutylparacresol are 0.10-0.15, only a kind of pigment takes off completely.
The present invention adopts ultraviolet absorber benzophenone-2 and antioxidant 2,6 ditertiary butyl p cresol composite first. With other kinds of composite compared with, the color fixative compositions of the present invention has non-obvious effect of color protection. Meanwhile, the color fixative compositions of the present invention is in preferred scope, and the pigment scope being suitable for is wide, for 18 kinds of pigments of test, has 17 kinds of pigments not exclusively to take off after being exposed to the sun, and producer is without the antioxidant differently configured according to different pigments and ultraviolet absorber.
Claims (9)
1. a color fixative compositions, it is characterised in that containing ultraviolet absorber and antioxidant; Described ultraviolet absorber is OXYBENZONE, ethylhexyl methoxy cinnamate, benzophenone-2, ethylhexyl salicylate, avobenzone, 4-methyl benzylidene camphor, octocrilene, the one or more combination in Phenylbenzimidazolesulfonic acid, it is preferable that benzophenone-2;
Described antioxidant is sodium sulfite, magnesium L-ascorbyl-2-phosphate, sodium thiosulfate, NAP, 2,6 ditertiary butyl p cresol, butylated hydroxyarisol, tocopherol acetas, one or more in sodium pyrosulfite, it is preferable that 2,6 ditertiary butyl p cresol.
2. color fixative compositions as claimed in claim 1, is being characterised by the parts by weight respectively 0.01��1 part of ultraviolet absorber and antioxidant, 0.05��1 part, it is preferable that 0.08��0.12 part, 0.10��0.15 part.
3. colorant composition one kind stable, it is characterised in that containing color fixative compositions and pigment as described in right 1.
4. colorant composition as claimed in claim 3, it is characterised in that described pigment is lemon yellow, light blue, acid violet 43, yellow 10, acid blue 9, red 7, orange 4, green 3, Xylene Red 52, acid yellow 23, quinoline yellow, red 4, red 33, sunset yellow, light green, acid blue 80, carmine, one or both in red 28; Preferred lemon yellow, light blue, acid violet 43, yellow 10, acid blue 9, red 7, orange 4, green 3, Xylene Red 52, acid yellow 23, quinoline yellow, red 4, red 33, sunset yellow, light green, acid blue 80, one or both in carmine.
5. colorant composition as claimed in claim 3, it is characterised in that the parts by weight respectively 0.0001��0.005 part of pigment and color fixative compositions, 0.01��2 part, difference preferably 0.0005��0.001,0.18��0.27 part.
6. colorant composition as claimed in claim 3, its appropriate products is cleaning product, washes and protect product and perfume etc., it is preferred to washes and protects product, it is more preferred to, for bath oil.
7. a fade-proof bath oil, it is characterized in that described bath oil is containing, for example the colorant composition described in claim 3-5 any one, it is preferable that possibly together with polyoxyethylenated alcohol sodium sulfate, sodium lauryl sulphate, cocos nucifera oil acyl CAB, citric acid, disodiumedetate, edible salt; Its parts by weight are colorant composition 0.01-2 part respectively, polyoxyethylenated alcohol sodium sulfate 5��20 parts, sodium lauryl sulphate 1��10 part, cocos nucifera oil acyl CAB 1��20 part, citric acid 0.01��0.5 part, disodiumedetate 0.01��0.2 part and edible salt 0.1��3 part; Preferred parts by weight respectively, 0.18-0.27 part, 12��15 parts, 1��3 part, 3��5 parts, 0.04��0.06 part, 0.05��0.1 part and 1��2 part.
8. bath composition as claimed in claim 7, its feature is possibly together with preservative, essence and deionized water.
9. a preparation method for fade-proof bath oil, deionized water is heated to 80��85 DEG C by its feature DIYU, benzophenone-2 and 2, stirring and dissolving after 6-ditertbutylparacresol addition deionized water, add polyoxyethylenated alcohol sodium sulfate, sodium lauryl sulphate and cocos nucifera oil acyl CAB, stir, it is cooled to 45 DEG C, it is separately added into citric acid, disodiumedetate and pigment, dissolves completely, continue to add preservative, essence and edible salt to stir to being completely dissolved.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511029050.3A CN105616192A (en) | 2015-12-30 | 2015-12-30 | Color protection combination and product containing combination |
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| ES2776773A1 (en) * | 2019-01-31 | 2020-07-31 | Actigolden S L | COLOR AND ODOR PROTECTIVE COMPOSITION (Machine-translation by Google Translate, not legally binding) |
| CN112999113A (en) * | 2021-01-29 | 2021-06-22 | 广州卡迪莲化妆品科技有限公司 | Anti-fading toner and preparation method thereof |
| CN115836980A (en) * | 2023-01-06 | 2023-03-24 | 湖北美凯化工有限公司 | Color stabilizer and preparation method and application thereof |
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| ES2776773A1 (en) * | 2019-01-31 | 2020-07-31 | Actigolden S L | COLOR AND ODOR PROTECTIVE COMPOSITION (Machine-translation by Google Translate, not legally binding) |
| CN112999113A (en) * | 2021-01-29 | 2021-06-22 | 广州卡迪莲化妆品科技有限公司 | Anti-fading toner and preparation method thereof |
| CN112999113B (en) * | 2021-01-29 | 2022-11-01 | 广州卡迪莲化妆品科技有限公司 | Anti-fading toner and preparation method thereof |
| CN115836980A (en) * | 2023-01-06 | 2023-03-24 | 湖北美凯化工有限公司 | Color stabilizer and preparation method and application thereof |
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