CN105602637A - Fuel gas assistant capable of reducing harmful substance in automobile exhaust - Google Patents

Fuel gas assistant capable of reducing harmful substance in automobile exhaust Download PDF

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Publication number
CN105602637A
CN105602637A CN201610019497.0A CN201610019497A CN105602637A CN 105602637 A CN105602637 A CN 105602637A CN 201610019497 A CN201610019497 A CN 201610019497A CN 105602637 A CN105602637 A CN 105602637A
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CN
China
Prior art keywords
parts
fuel
harmful substance
vehicle exhaust
assistants
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610019497.0A
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Chinese (zh)
Inventor
车春玲
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Shandong Lianxing Energy Group Co Ltd
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Shandong Lianxing Energy Group Co Ltd
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Publication date
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Priority to CN201610019497.0A priority Critical patent/CN105602637A/en
Publication of CN105602637A publication Critical patent/CN105602637A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/04Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/14Use of additives to fuels or fires for particular purposes for improving low temperature properties
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1266Inorganic compounds nitrogen containing compounds, (e.g. NH3)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/195Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/223Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/24Organic compounds containing sulfur, selenium and/or tellurium
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00Specifically adapted fuels
    • C10L2270/02Specifically adapted fuels for internal combustion engines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention provides a fuel gas assistant capable of reducing harmful substance in automobile exhaust. The fuel gas assistant is prepared from combustion improver, antioxidant, surfactant, fuel detergent additive and pour point reducer, and is capable of improving diesel detergency, cold flow, inoxidizability and corrosion resistance greatly while improving combustion performance of fuel to achieve complete combustion of fuel and further reducing emission and carbon deposition. Zero emission of part of waste gas can be achieved.

Description

Reduce the fuel assistants of vehicle exhaust harmful substance
Technical field
The invention belongs to additive agent field, relate to fuel assistants, relate in particular to a kind of fuel assistants that reduces vehicle exhaust harmful substance.
Background technology
Along with improving constantly of people's life, people have had higher requirement to environment, and protection of the environment has become everybody pet phrase now. Environmental pollution comprises air pollution, exhaust pollution and Air-pollution From Combustion etc., and people's home-use car constantly increases, and environment has been caused to great impact.
In order to reduce the discharge capacity of vehicle exhaust, develop the fuel assistants that reduces vehicle exhaust harmful substance, existing fuel assistants is reducing do in motor vehicle exhaust emission amount very bad, although can reduce the harmful substance of vehicle exhaust, but its reduction is lower, and treatment effect is also bad.
Summary of the invention
The present invention is directed to above-mentioned prior art fuel assistants and reducing do in motor vehicle exhaust emission amount very bad, although can reduce the harmful substance of vehicle exhaust, but its reduction is lower, and treatment effect is the problem such as bad also, the invention provides a kind of fuel assistants that reduces vehicle exhaust harmful substance
In order to achieve the above object, the technical solution used in the present invention is, a kind of fuel assistants that reduces vehicle exhaust harmful substance, and described fuel assistants is prepared from by combustion adjuvant, antioxidant, surfactant, fuel oil cleaning agent, pour-point depressant combination.
As preferably, described fuel assistants is made up of the raw material of following deal proportioning: 20~30 parts of combustion adjuvants, 10~15 parts of antioxidants, 3~5 parts, surfactant, 35~45 parts of fuel oil cleaning agents, 28~40 parts of pour-point depressants.
As preferably, described fuel assistants is made up of the raw material of following deal proportioning: 28 parts of combustion adjuvants, 15 parts of antioxidants, 5 parts, surfactant, 43 parts of fuel oil cleaning agents, 38 parts of pour-point depressants.
As preferably, described combustion adjuvant adopts at least one in itroparaffin compound, alcohol compound, neopelex, DBSA, potassium chlorate and potassium nitrate.
As preferably, described antioxidant adopts the mixture of shielding phenol and arylamine, described mixture adopts BHT, LEP, PNX, DODPA, diphenylamines antioxidant (DPA), phenyl one α mono-naphthylamines antioxidant (PANA) and derivative thereof, 4.4 1 di-2-ethylhexylphosphine oxides (2,6 one di-tert-butylphenols), 2,2 monothios two (4,6 one di-tert-butylphenols), at least one in the di-iso-octyldiphenylamine of modification, N mono-phenyl one α mono-naphthylamines, 3,7 one diisooctyl phenthazine (DOPTZ).
As preferably, described surfactant adopts the sulfuration of organic sulfur compound, characteristic metal and vulcanizes at least one in organic copolymer salt, benzene sulfonic acid sodium salt, softex kw more.
As preferably, described fuel oil cleaning agent adopts at least one in the mixture of ethyl tetramine, polyisobutene, vinyl bis-stearamides, glyceryl tristearate and polyetheramine.
As preferably, described fuel assistants is made up of the raw material of following mass fraction: 28 parts, potassium nitrate, 15 parts, diphenylamines antioxidant, 5 parts of organic sulfur compounds, 43 parts of ethyl tetramines, 38 parts of ethene-vinyl acetate co-polymers.
As preferably, concrete grammar is, after diphenylamines antioxidant, organic sulfur compound and ethene-vinyl acetate co-polymer are mixed, then mixes with potassium nitrate, finally mixes only even bright with ethyl tetramine.
Compared with prior art, advantage of the present invention and good effect be,
1, the present invention can improve diesel cleaning, low temperature flow, non-oxidizability and Corrosion Protection, improves oil inflame performance simultaneously, makes full combustion of fuel, and discharge capacity further reduces, and carbon distribution still less, wherein has part waste gas material can reach zero-emission.
Detailed description of the invention
In order more clearly to understand above-mentioned purpose of the present invention, feature and advantage, below in conjunction with embodiment, the present invention will be further described. It should be noted that, in the situation that not conflicting, the feature in the application's embodiment and embodiment can combine mutually.
Set forth in the following description a lot of details so that fully understand the present invention, still, the present invention can also adopt and be different from other modes described here and implement, and therefore, the present invention is not limited to the restriction of the specific embodiment of prospectus below.
The preparation method of fuel assistants of the present invention is,
After diphenylamines antioxidant, organic sulfur compound and ethene-vinyl acetate co-polymer are mixed, then mix with potassium nitrate, finally mix only evenly bright with ethyl tetramine.
If without specified otherwise, following examples all adopt above-mentioned preparation method.
Efficiency of combustion definition, matter that unit of fuel is flammable burning institute liberated heat accounts for the percentage of the flammable matter caloric value of unit of fuel.
Now we to choose optimum pharmaceutical formulation be that example illustrates usefulness situation of the present invention, be below two kinds or two kinds of different additives of content more than preparation, listed several groups representative.
Embodiment 1, additive A, potassium nitrate 20g, diphenylamines antioxidant 10g, 3 parts of organic sulfur compounds, 35 parts of ethyl tetramines, 28 parts of ethene-vinyl acetate co-polymers.
Embodiment 2, additive B, 22 parts, potassium nitrate, 11 parts, diphenylamines antioxidant, 4 parts of organic sulfur compounds, 38 parts of ethyl tetramines, 30 parts of ethene-vinyl acetate co-polymers.
Embodiment 3, addition of C, 25 parts, potassium nitrate, 12 parts, diphenylamines antioxidant, 5 parts of organic sulfur compounds, 40 parts of ethyl tetramines, 33 parts of ethene-vinyl acetate co-polymers.
Embodiment 4, additive D, 28 parts, potassium nitrate, 13 parts, diphenylamines antioxidant, 5 parts of organic sulfur compounds, 41 parts of ethyl tetramines, 35 parts of ethene-vinyl acetate co-polymers
Embodiment 5, additive E, 28 parts, potassium nitrate, 15 parts, diphenylamines antioxidant, 5 parts of organic sulfur compounds, 43 parts of ethyl tetramines, 38 parts of ethene-vinyl acetate co-polymers
Embodiment 6, additive F, 30 parts, potassium nitrate, 14 parts, diphenylamines antioxidant, 5 parts of organic sulfur compounds, 45 parts of ethyl tetramines, 40 parts of ethene-vinyl acetate co-polymers
We weigh up the additive of the composition of above-mentioned different formulation contents 2g and add in the fuel oil sample that 15kg is different, draw respectively its efficiency of combustion.
Table 1
ByIn tableThe data obtained is known, the fuel assistants that the present invention studies, otherwise it is much lower not add in the exhaust emissions amount of fuel assistants CO content, can improve 5%~7% than existing fuel assistants.
The above; it is only preferred embodiment of the present invention; it is not the restriction of the present invention being made to other form; the equivalent embodiment that any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified as equivalent variations is applied to other field; but every technical solution of the present invention content that do not depart from; any simple modification, equivalent variations and the remodeling above embodiment done according to technical spirit of the present invention, still belong to the protection domain of technical solution of the present invention.

Claims (10)

1. a fuel assistants that reduces vehicle exhaust harmful substance, is characterized in that, described fuel assistants is prepared from by combustion adjuvant, antioxidant, surfactant, fuel oil cleaning agent, pour-point depressant combination.
2.According to claimThe fuel assistants of the minimizing vehicle exhaust harmful substance described in 1, is characterized in that, described fuel assistants is made up of the raw material of following deal proportioning: 20~30 parts of combustion adjuvants, 10~15 parts of antioxidants, 3~5 parts, surfactant, 35~45 parts of fuel oil cleaning agents, 28~40 parts of pour-point depressants.
3.According to claimThe fuel assistants of the minimizing vehicle exhaust harmful substance described in 2, is characterized in that, described fuel assistants is made up of the raw material of following deal proportioning: 28 parts of combustion adjuvants, 15 parts of antioxidants, 5 parts, surfactant, 43 parts of fuel oil cleaning agents, 38 parts of pour-point depressants.
4.According to claimThe fuel assistants of the minimizing vehicle exhaust harmful substance described in 3, is characterized in that, described combustion adjuvant adopts at least one in itroparaffin compound, alcohol compound, neopelex, DBSA, potassium chlorate and potassium nitrate.
5.According to claimThe fuel assistants of the minimizing vehicle exhaust harmful substance described in 4, it is characterized in that, described antioxidant adopts the mixture of shielding phenol and arylamine, described mixture adopts BHT, LEP, PNX, DODPA, diphenylamines antioxidant (DPA), phenyl one α mono-naphthylamines antioxidant (PANA) and derivative thereof, 4.4 1 di-2-ethylhexylphosphine oxides (2,6 one di-tert-butylphenols), 2,2 monothios two (4,6 one di-tert-butylphenols), at least one in the di-iso-octyldiphenylamine of modification, N mono-phenyl one α mono-naphthylamines, 3,7 one diisooctyl phenthazine (DOPTZ).
6.According to claimThe fuel assistants of the minimizing vehicle exhaust harmful substance described in 5, is characterized in that, described surfactant adopts the sulfuration of organic sulfur compound, characteristic metal and vulcanizes at least one in organic copolymer salt, benzene sulfonic acid sodium salt, softex kw more.
7.According to claimThe fuel assistants of the minimizing vehicle exhaust harmful substance described in 6, is characterized in that, at least one in the mixture of described fuel oil cleaning agent employing ethyl tetramine, polyisobutene, vinyl bis-stearamides, glyceryl tristearate and polyetheramine.
8.According to claimThe fuel assistants of the minimizing vehicle exhaust harmful substance described in 7, is characterized in that, described pour-point depressant adopts at least one in ethene-vinyl acetate co-polymer, vegetable fatty acid and glycerine.
9.According to claimThe fuel assistants of the minimizing vehicle exhaust harmful substance described in 8, is characterized in that, described fuel assistants is made up of the raw material of following mass fraction: 28 parts, potassium nitrate, 15 parts, diphenylamines antioxidant, 5 parts of organic sulfur compounds, 43 parts of ethyl tetramines, 38 parts of ethene-vinyl acetate co-polymers.
10.According to claimThe preparation method of the fuel assistants of the minimizing vehicle exhaust harmful substance described in 9, concrete grammar is, after diphenylamines antioxidant, organic sulfur compound and ethene-vinyl acetate co-polymer are mixed, then mix with potassium nitrate, finally mix only evenly bright with ethyl tetramine.
CN201610019497.0A 2016-01-13 2016-01-13 Fuel gas assistant capable of reducing harmful substance in automobile exhaust Pending CN105602637A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107011958A (en) * 2017-05-31 2017-08-04 李朋国 Petrochemical engineering auxiliary agent

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103194282A (en) * 2013-04-08 2013-07-10 黄河三角洲京博化工研究院有限公司 Diesel composite additive
CN103820176A (en) * 2012-11-16 2014-05-28 季爱英 Multi-functional diesel additive
CN103911191A (en) * 2013-01-09 2014-07-09 美国能源有限公司 Diesel oil additive and its preparation method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103820176A (en) * 2012-11-16 2014-05-28 季爱英 Multi-functional diesel additive
CN103911191A (en) * 2013-01-09 2014-07-09 美国能源有限公司 Diesel oil additive and its preparation method
CN103194282A (en) * 2013-04-08 2013-07-10 黄河三角洲京博化工研究院有限公司 Diesel composite additive

Non-Patent Citations (1)

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Title
见百熙: "《浮选药剂》", 31 August 1981, 冶金工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107011958A (en) * 2017-05-31 2017-08-04 李朋国 Petrochemical engineering auxiliary agent
CN107011958B (en) * 2017-05-31 2018-08-28 中山市绿浪助剂有限公司 A kind of petrochemical additive

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Application publication date: 20160525