CN105602171A - Anion releasing artificial marble material and manufacturing technology thereof - Google Patents

Anion releasing artificial marble material and manufacturing technology thereof Download PDF

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Publication number
CN105602171A
CN105602171A CN201510559035.3A CN201510559035A CN105602171A CN 105602171 A CN105602171 A CN 105602171A CN 201510559035 A CN201510559035 A CN 201510559035A CN 105602171 A CN105602171 A CN 105602171A
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CN
China
Prior art keywords
anion
releasing
agent
additive
negative ion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510559035.3A
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Chinese (zh)
Inventor
李青山
李柏峰
刘焕萍
张超辉
王万琪
张妮
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BEIJING SENYUAN HUACHENG TECHNOLOGY DEVELOPMENT Co Ltd
Original Assignee
BEIJING SENYUAN HUACHENG TECHNOLOGY DEVELOPMENT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BEIJING SENYUAN HUACHENG TECHNOLOGY DEVELOPMENT Co Ltd filed Critical BEIJING SENYUAN HUACHENG TECHNOLOGY DEVELOPMENT Co Ltd
Priority to CN201510559035.3A priority Critical patent/CN105602171A/en
Publication of CN105602171A publication Critical patent/CN105602171A/en
Pending legal-status Critical Current

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  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to an anion releasing artificial marble material and a manufacturing technology thereof. According to the invention, ANION series anion additive series ultrafine powder able to release anions is employed to create an ANION series anion additive, the additive is added into polyurethane, polyether, polystyrene, polyvinyl chloride and other high polymer materials so as to successfully produce anion releasing aquatic functional materials. The anion releasing ANION series ultrafine powder has very good dispersibility in combined materials, and has no technical defect in a machining process.

Description

Anion releasing artificial marble material and manufacturing technology thereof
Technical field:
The invention belongs to material, chemical, gardens, building, decoration, gift, house ornamentation, interior trim, health, field of Environment Protection.
Background technology:
Along with the raising day by day of human civilization, activity in production, particularly modernization, industrialization degree, environmental pollution is also more and more tighterHeavy, particularly people thirst for graceful environment, so various environment friendly decorative material, functional Shui nationality material arise at the historic moment. AnionMore and more be subject to scientific worker's attention to improving the aquatic animal decoration material of people's living environment, particularly anion releasing.Negative aeroion is called " air vitamin " or " long-living element ", and the anion number that maintains health of people is: 1000-2000Individual/cm3. The people of live and work in modernization air-conditioning and construction thing for a long time, usually can feel unhappiness, lethargic sleep, weak, evilThe heart, headache, dizzy dusk, operating efficiency and physical condition obviously decline, and research shows, causes the reason of this phenomenon with emptyIn gas, the concentration of anion is closely related. Along with developing rapidly and the continuous progress of high-tech of material science, people just constantlyExploitation, development have anion releasing gardens, decoration, gift, automotive trim, room decorating and spring function material etc., toolThere is the anion releasing Shui nationality material of health care to be more and more valued by the people.
Study discovery through us: the Anna's serial anionic additive difficult to understand by initiatives such as opal, tourmaline, sea-gull stones has oneFixed deodorizing, suction taste; Antibacterial, diseases prevention; The health care of anion releasing. We adopt coarse crushing, the ultra-fine grinding of air-flow methodWith the process route that wet grinding combines, technology is in the past just 6 kinds of natural crystal preparations such as Nenjiang opal, tourmalineBecome micron-sized super fine. Natural minerals such as sea-gull stones is prepared into micron-sized super fine by the present invention. This modificationSuper fine there is the functions such as anion releasing, sterilization, deodorizing, can be widely used in the macromolecular material such as rubber, plasticsIn, also can be used in the aquatic animals material such as unsaturated-resin, polyurethane. The present invention adopts the skies such as sea-gull stone capable of releasing negative ionSo mineral are prepared into micron-sized serial superfine powder, have formulated the serial anion releasing in Anna Austria-3 by the method for doping and blendingAdditive, joins in the macromolecular materials such as polyurethane, polyethers, polystyrene, polyvinyl chloride, unsaturated-resin, successfullyProduce the Shui nationality functional material with anion releasing. The super fine of Anna's series difficult to understand capable of releasing negative ion is in combination materialThere is extraordinary dispersiveness, in process, do not have any defective workmanship.
After the ore ultra-fine grindings such as sea-gull stone, further grind modification and formulate into the serial anion interpolation in Anna Austria-3Agent, adds in Shui nationality functional material, can anion releasing, and do not affect other performance of Shui nationality functional material, to peopleHealth be highly profitable. The negative ion concentration of anion Shui nationality functional material is about 2.0 × 103Individual/cm3Above. Reach cityConcentration more than park anion. Just be equivalent to the concentration that people takes a walk in Urban Parks, anion Shui nationality functional material can be at any timeFollow in people at one's side, the environment of leisure or the space of rest, application very extensively: as fish jar, artificial hillock and Household ornamentProduct, the in-built jewelry in automobile, steamer, large-scale activity place, as top bery, ditch, fountain, bathtub, fish jar etc.; Medical products,As humidifier, sickroom supply etc.; Filtering material, as air conditioner filter, material for water treatment etc.; Other material. Like this, with regard to energyMake the people natural space that is enclosed in anion constantly, played the mankind have been brought into the product of following that have constantly anionGood living space of fine quality, creates tasteless automobile, tasteless guest room, tasteless environment etc.
Summary of the invention:
Invention formula: unsaturated polyester (UP): 10-100; Benzoyl peroxide: 0.2-4; Dimethylaniline: 0.1-4; StyreneOr polymethyl methacrylate resin: 3-55; Anna serial anionic additive: 0.1-30 difficult to understand; Auxiliary agent: 0-10; Mill base:0-20; Promoter: 0.1-3.
Technique: first will in unsaturated polyester (UP), add anionic additive, auxiliary agent, color paste deployment to become required anion raw material A,Together with the B material forming with styrene, initator, promoter etc. again, react moulding at preprepared mould. Anion addsAgent is rare talent's series anionic additive. Auxiliary agent comprises: softening agent, wetting agent, scratch agent, remover etc.
Concrete Application Example:
Formula:
Drying condition: 30-50 DEG C × 90s
Embodiment 1, invention formula: unsaturated polyester (UP): 20; Benzoyl peroxide: 0.6; Dimethylaniline: 0.4; Styrene:35; Anna's serial anionic additive difficult to understand: 3.0; Auxiliary agent: 0-10; Mill base: 10; Promoter: 0.3.
Technique: stir after 20-30 second, join in 2 liters of moulds. 2000/cm of anion3
Embodiment 2, invention formula: unsaturated polyester (UP): 10; Benzoyl peroxide: 0.8; Dimethylaniline: 0.4; Metering systemAcid methyl esters resin: 25; Anna's serial anionic additive difficult to understand: 3.0; Auxiliary agent: 0-10; Mill base: 10; Promoter: 0.1-3.
Technique: stir after 20-30 second, join in 2 liters of moulds. 2000-10000/cm3.
Embodiment 3, invention formula: unsaturated polyester (UP): 20; Benzoyl peroxide: 0.6; Dimethylaniline: 0.4; Styrene:35; Anna's serial anionic additive difficult to understand: 3.0; Auxiliary agent: 0; Mill base: 10; Promoter: 0.3.
Technique: stir after 20-30 second, join in 2 liters of moulds. 2000/cm of anion3
Embodiment 4, invention formula: unsaturated polyester (UP): 10; Benzoyl peroxide: 0.8; Dimethylaniline: 0.4; Metering systemAcid methyl esters resin: 25; Anna's serial anionic additive difficult to understand: 3.0; Auxiliary agent: 0-10; Mill base: 10; Promoter: 0.1-3.
Technique: stir after 20-30 second, join in 2 liters of moulds. 2000/cm3.
Embodiment 5, invention formula: unsaturated polyester (UP): 10; Benzoyl peroxide: 0.6; Dimethylaniline: 0.4; Styrene:35; Anna's serial anionic additive difficult to understand: 3.0; Auxiliary agent: 0-10; Mill base: 10; Promoter: 0.3.
Technique: stir after 20-30 second, join in 2 liters of moulds. 2000/cm of anion3
Embodiment 6, invention formula: unsaturated polyester (UP): 10; Benzoyl peroxide: 0.8; Dimethylaniline: 0.4; Metering systemAcid methyl esters resin: 25; Anna's serial anionic additive difficult to understand: 0; Auxiliary agent: 0-10; Mill base: 10; Promoter: 0.1-3.Technique: stir after 20-30 second, join in 2 liters of moulds. 1000/cm3Below.

Claims (6)

1. anion releasing artificial marble material and manufacturing technology thereof, is characterized in that: it is by following qualityThe raw material of proportioning is made, formula: invention formula: unsaturated polyester (UP) 10-100; Benzoyl peroxide0.2-4; Dimethylaniline 0.1-4; Styrene or polymethyl methacrylate resin 3-55; Anna's series difficult to understand is negativeIonic additive 0.1-30; Auxiliary agent 0-10; Mill base 0-20; Promoter 0.1-3.
2. be to meet according to the chemical reagent such as unsaturated polyester (UP), benzoyl peroxide described in claims 1The macromolecular material of national standard and raw material, can be natural goods modification, also can synthesize.
3. be Anna's serial anionic additive difficult to understand according to the anion releasing additive described in claims 1,It is characterized in that the natural minerals that contains nano-pore, add unsaturated polyester (UP) to and can emit anion and exist1000/cm3Above, the foaming elastic material of negative ion-releasing function is emitted anion at 1000/cm3WithOn.
4. comprise according to the auxiliary agent described in claims 1: softening agent, colouring agent, color-fixing agent, thickener,Wetting agent, scratch agent etc., catalyst is dimethyl Bian amine etc.
5. technique: first will in PPG or PEPA, add anionic additive, auxiliary agent, mill base,Be deployed into the foaming elastic material A liquid of required negative ion-releasing function, then react with B liquid such as cyanatesPrepare the foaming elastic material of negative ion-releasing function.
According to the technology for preparing foaming elastic materials of the negative ion-releasing function described in claims 1 at sandSend out, the purposes of the aspect such as bedding, furniture, car and boat interior trim.
CN201510559035.3A 2015-09-06 2015-09-06 Anion releasing artificial marble material and manufacturing technology thereof Pending CN105602171A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510559035.3A CN105602171A (en) 2015-09-06 2015-09-06 Anion releasing artificial marble material and manufacturing technology thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510559035.3A CN105602171A (en) 2015-09-06 2015-09-06 Anion releasing artificial marble material and manufacturing technology thereof

Publications (1)

Publication Number Publication Date
CN105602171A true CN105602171A (en) 2016-05-25

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Country Status (1)

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CN (1) CN105602171A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107189270A (en) * 2017-06-20 2017-09-22 郑州铁路职业技术学院 The outer rock stratum of fluorescence and preparation method and the antificielle landscape using the outer rock stratum of the fluorescence

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107189270A (en) * 2017-06-20 2017-09-22 郑州铁路职业技术学院 The outer rock stratum of fluorescence and preparation method and the antificielle landscape using the outer rock stratum of the fluorescence

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Application publication date: 20160525

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