CN105602082A - High-strength transparent cable sheath material - Google Patents

High-strength transparent cable sheath material Download PDF

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Publication number
CN105602082A
CN105602082A CN201610152418.3A CN201610152418A CN105602082A CN 105602082 A CN105602082 A CN 105602082A CN 201610152418 A CN201610152418 A CN 201610152418A CN 105602082 A CN105602082 A CN 105602082A
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CN
China
Prior art keywords
parts
vinyl acetate
sheath material
cable sheath
ethylene
Prior art date
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Withdrawn
Application number
CN201610152418.3A
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Chinese (zh)
Inventor
邹黎清
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SUZHOU KEMAO ELECTRONIC MATERIAL TECHNOLOGY Co Ltd
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SUZHOU KEMAO ELECTRONIC MATERIAL TECHNOLOGY Co Ltd
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Priority to CN201610152418.3A priority Critical patent/CN105602082A/en
Publication of CN105602082A publication Critical patent/CN105602082A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853Vinylacetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • C08L83/08Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/46Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes silicones
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a high-strength transparent cable sheath material which comprises the following raw materials in parts by mass: 50-80 parts of ethylene-vinyl acetate copolymer containing 18-20% of vinyl acetate, 20-40 parts of polyethylene terephthalate-1,4-cyclohexanedimethanol, 1-2 parts of plasticizer cyclohexane 1,2-di(2-propylheptyl) diformate, 20-50 parts of nitrile silicone rubber, 5-12 parts of nano silicon dioxide, 3-8 parts of calcium carbonate, 2-6 parts of acrylonitrile-butadiene-styrene terpolymer, 0.1-0.2 part of potassium perfluorobutanesulfonate, 5-10 parts of paraffin oil and 0.2-0.6 part of reinforcing agent DH-3. The sheath material disclosed by the invention has good transparency; in use, troubleshooting for the wire shielding damage is easy to realize, and the tracking of parallel wires and a connector and a circuit is simpler and easy to implement; and the sheath material disclosed by the invention has good transparency as well as relatively high mechanical strength and comprehensive performance and good stability.

Description

A kind of high-strength transparence cable sheath material
Technical field
The present invention relates to cable rapidoprint field, be specifically related to a kind of high-strength transparence sheath material of cable external application.
Background technology
Electric wire is the carrier that electric power is carried and information is transmitted, and is widely used in industry, civilian electricity consumption facility. Electric wire is used in different environment or occasion, requires differently, and this has just proposed higher requirement to the cable cover(ing) being coated on outside cable. The major function of cable cover(ing) is mechanically to suffer to make it to lose the various situations of transfer function with the cable of electric upper protection transmission use is unlikely. Cable cover(ing) must be installing, continuing completes this defencive function with the whole service life of cable is interim. Within the service life phase of cable, sheath must protect cable core not make moist and other pollute, and the degree of protection will make the loop performance in cable core keep normal, once too much moisture or other pollutants enter cable core, transmission performance will severe exacerbation. This just requires cable cover(ing) to possess higher mechanical strength, inner toughness, in case produce cracking or damaged under rugged environment, causes cable to transmit not normal or generation potential safety hazard.
Cable sheath material of the prior art mostly is opaque sheath, although it is widely used, also exists and is not easy to damaged eliminating, parallel wire and the connector that carries out fault of electric wire shielding and the shortcoming such as circuit tracing is comparatively difficult; Existing transparent sheath mostly is simple and easy flexible plastic, and intensity is lower, can not meet the protection demand to cable.
Summary of the invention
For prior art deficiency, the invention provides a kind of high-strength transparence sheath material of cable external application.
The technical scheme that the present invention solves the problems of the technologies described above employing is: a kind of high-strength transparence cable sheath material, comprise the raw material of following mass fraction: 50 ~ 80 parts of the ethylene-vinyl acetate copolymers that vinyl acetate content is 18%~20%, PETG-1, 20 ~ 40 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1, 1 ~ 2 part of 2-dioctyl phthalate two (2-propyl group heptan) ester, 20 ~ 50 parts of nitrile silicone rubbers, 5 ~ 12 parts of nano silicons, 3 ~ 8 parts, calcium carbonate, 2 ~ 6 parts of styrene copolymers, 0.1 ~ 0.2 part of perfluoro butyl potassium sulfonate, 5 ~ 10 parts of paraffin oils, reinforcing agent DH-30.2 ~ 0.6 part.
Further, described a kind of high-strength transparence cable sheath material, comprise the raw material of following mass fraction: 65 parts of ethylene-vinyl acetate copolymers, PETG-1 that vinyl acetate content is 18%~20%, 30 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1,1 part of ester of 2-dioctyl phthalate two (2-propyl group heptan), 35 parts of nitrile silicone rubbers, 8 parts of nano silicons, 6 parts, calcium carbonate, 4 parts of styrene copolymers, 0.2 part of perfluoro butyl potassium sulfonate, 8 parts of paraffin oils, reinforcing agent DH-30.4 part.
Further, described a kind of high-strength transparence cable sheath material, its preparation method comprises the following steps:
1) be on the waiting list raw material according to described mass fraction;
2) raw material of being on the waiting list is fully mixed;
3) step 2 gained is mixed to material and be placed in double screw extruder, mixing at 160 ~ 190 DEG C, granulation, make finished product.
In the present invention, adopt the transparency good composite matrix as sheath material of ethylene-vinyl acetate copolymer, PETG-1,4-CHDM ester and nitrile silicone rubber, compound has good transparency and intensity preferably; The interpolation of raw material calcium carbonate can reduce the preparation cost of sheath material, improves the creep properties of goods, improves heat distortion temperature and the dimensional stability of goods; Raw material nano silica is for improving wearability, fold resistance, tensile strength, the ageing resistace of material system, and then intensity and the percentage elongation of raising sheath material, obtains wearability and the surperficial good cable cover(ing) of fineness; Benzene feedstock ethylene-dien terpolymer can make the impact strength of its goods improve, and can also improve the cold resistance of goods simultaneously; Reinforcing agent can increase the combination between the inorganic material such as calcium carbonate, nano silicon or filler and ethylene-vinyl acetate copolymer, PETG-1,4-CHDM ester and nitrile silicone rubber, and then reaches good mechanical strength.
To sum up, the beneficial effect that a kind of high-strength transparence cable sheath material provided by the invention possesses is: sheath material of the present invention has the good transparency, when use, be easy to electric wire shielding breakage to carry out the eliminating of fault, what make that parallel wire and connector and circuit tracing become is more simple to operation, especially more accurate, be not easy to application under the conditions such as dismounting maintenance and can bring larger convenience; Sheath material of the present invention has higher mechanical strength and combination property when having good transparency, have good stability, and embrittlement cracking occurs can not process under cold climate and install time, and wearability is better.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1: a kind of high-strength transparence cable sheath material, comprise the raw material of following mass fraction: 65 parts of ethylene-vinyl acetate copolymers, PETG-1 that vinyl acetate content is 18%~20%, 30 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1,1 part of ester of 2-dioctyl phthalate two (2-propyl group heptan), 35 parts of nitrile silicone rubbers, 8 parts of nano silicons, 6 parts, calcium carbonate, 4 parts of styrene copolymers, 0.2 part of perfluoro butyl potassium sulfonate, 8 parts of paraffin oils, reinforcing agent DH-30.4 part.
Embodiment 2: a kind of high-strength transparence cable sheath material, comprise the raw material of following mass fraction: 80 parts of ethylene-vinyl acetate copolymers, PETG-1 that vinyl acetate content is 18%~20%, 40 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1,2 parts of esters of 2-dioctyl phthalate two (2-propyl group heptan), 50 parts of nitrile silicone rubbers, 12 parts of nano silicons, 8 parts, calcium carbonate, 6 parts of styrene copolymers, 0.2 part of perfluoro butyl potassium sulfonate, 10 parts of paraffin oils, reinforcing agent DH-30.6 part.
Embodiment 3: a kind of high-strength transparence cable sheath material, comprise the raw material of following mass fraction: 50 parts of ethylene-vinyl acetate copolymers, PETG-1 that vinyl acetate content is 18%~20%, 20 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1,1 part of ester of 2-dioctyl phthalate two (2-propyl group heptan), 20 parts of nitrile silicone rubbers, 5 parts of nano silicons, 3 parts, calcium carbonate, 2 parts of styrene copolymers, 0.1 part of perfluoro butyl potassium sulfonate, 5 parts of paraffin oils, reinforcing agent DH-30.2 part.
Embodiment 4: a kind of high-strength transparence cable sheath material, comprise the raw material of following mass fraction: 50 parts of ethylene-vinyl acetate copolymers, PETG-1 that vinyl acetate content is 18%~20%, 40 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1,1 part of ester of 2-dioctyl phthalate two (2-propyl group heptan), 50 parts of nitrile silicone rubbers, 5 parts of nano silicons, 8 parts, calcium carbonate, 2 parts of styrene copolymers, 0.2 part of perfluoro butyl potassium sulfonate, 5 parts of paraffin oils, reinforcing agent DH-30.6 part.
Embodiment 5: a kind of high-strength transparence cable sheath material, comprise the raw material of following mass fraction: 80 parts of ethylene-vinyl acetate copolymers, PETG-1 that vinyl acetate content is 18%~20%, 20 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1,2 parts of esters of 2-dioctyl phthalate two (2-propyl group heptan), 20 parts of nitrile silicone rubbers, 12 parts of nano silicons, 3 parts, calcium carbonate, 6 parts of styrene copolymers, 0.1 part of perfluoro butyl potassium sulfonate, 10 parts of paraffin oils, reinforcing agent DH-30.2 part.
Embodiment 6: a kind of high-strength transparence cable sheath material, comprise the raw material of following mass fraction: 60 parts of ethylene-vinyl acetate copolymers, PETG-1 that vinyl acetate content is 18%~20%, 35 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1,1.5 parts of esters of 2-dioctyl phthalate two (2-propyl group heptan), 40 parts of nitrile silicone rubbers, 10 parts of nano silicons, 6 parts, calcium carbonate, 5 parts of styrene copolymers, 0.1 part of perfluoro butyl potassium sulfonate, 6 parts of paraffin oils, reinforcing agent DH-30.5 part.
A kind of high-strength transparence cable sheath material described in embodiment 1-6, its preparation method comprises the following steps:
1) be on the waiting list raw material according to described mass fraction;
2) raw material of being on the waiting list is fully mixed;
3) step 2 gained is mixed to material and be placed in double screw extruder, mixing at 160 ~ 190 DEG C, granulation, make finished product.
The high-strength transparence cable sheath material of embodiment 1-6 gained is carried out to performance test, and concrete outcome is as shown in the table; Wherein the transparency adopts range estimation, vicat softening temperature adopts GB/T1633-2000 to test, 20 DEG C of specific insulations adopt GB/T1410-2006 to test, and breakdown strength adopts GB1408-2006 to test, and hot strength adopts GB/T528-1998 to test.
Performance The transparency Vicat softening temperature/DEG C 20 DEG C of specific insulation/Ω m Breakdown strength/KV/mm Hot strength/MPa
Embodiment 1 Well 133 2.3×1012 18.8 16
Embodiment 2 Well 137 2.7×1012 18.3 16
Embodiment 3 Well 128 2.0×1012 18.5 17
Embodiment 4 Well 124 2.9×1012 17.8 19
Embodiment 5 Well 139 2.4×1012 18.9 15
Embodiment 6 Well 132 2.2×1012 18.7 16
Common PVC sheath Opaque 84 4.6×1010 10.2 15
The foregoing is only preferred embodiments of the present invention; protection scope of the present invention is not limited to this; within the technical scope that any those skilled in the art disclose in the present invention; be equal to and change or replace according to technical scheme of the present invention and inventive concept, within all should being encompassed in protection scope of the present invention.

Claims (6)

1. a high-strength transparence cable sheath material, it is characterized in that, comprise the raw material of following mass fraction: 50 ~ 80 parts of ethylene-vinyl acetate copolymers, PETG-1 that vinyl acetate content is 18%~20%, 20 ~ 40 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1,1 ~ 2 part of ester of 2-dioctyl phthalate two (2-propyl group heptan), 20 ~ 50 parts of nitrile silicone rubbers, 5 ~ 12 parts of nano silicons, 3 ~ 8 parts, calcium carbonate, 2 ~ 6 parts of styrene copolymers, 0.1 ~ 0.2 part of perfluoro butyl potassium sulfonate, 5 ~ 10 parts of paraffin oils, reinforcing agent DH-30.2 ~ 0.6 part.
2. a kind of high-strength transparence cable sheath material according to claim 1, it is characterized in that, comprise the raw material of following mass fraction: 65 parts of ethylene-vinyl acetate copolymers, PETG-1 that vinyl acetate content is 18%~20%, 30 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1,1 part of ester of 2-dioctyl phthalate two (2-propyl group heptan), 35 parts of nitrile silicone rubbers, 8 parts of nano silicons, 6 parts, calcium carbonate, 4 parts of styrene copolymers, 0.2 part of perfluoro butyl potassium sulfonate, 8 parts of paraffin oils, reinforcing agent DH-30.4 part.
3. a kind of high-strength transparence cable sheath material according to claim 1, it is characterized in that, comprise the raw material of following mass fraction: 80 parts of ethylene-vinyl acetate copolymers, PETG-1 that vinyl acetate content is 18%~20%, 40 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1,2 parts of esters of 2-dioctyl phthalate two (2-propyl group heptan), 50 parts of nitrile silicone rubbers, 12 parts of nano silicons, 8 parts, calcium carbonate, 6 parts of styrene copolymers, 0.2 part of perfluoro butyl potassium sulfonate, 10 parts of paraffin oils, reinforcing agent DH-30.6 part.
4. a kind of high-strength transparence cable sheath material according to claim 1, it is characterized in that, comprise the raw material of following mass fraction: 50 parts of ethylene-vinyl acetate copolymers, PETG-1 that vinyl acetate content is 18%~20%, 20 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1,1 part of ester of 2-dioctyl phthalate two (2-propyl group heptan), 20 parts of nitrile silicone rubbers, 5 parts of nano silicons, 3 parts, calcium carbonate, 2 parts of styrene copolymers, 0.1 part of perfluoro butyl potassium sulfonate, 5 parts of paraffin oils, reinforcing agent DH-30.2 part.
5. a kind of high-strength transparence cable sheath material according to claim 1, it is characterized in that, comprise the raw material of following mass fraction: 50 parts of ethylene-vinyl acetate copolymers, PETG-1 that vinyl acetate content is 18%~20%, 40 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1,1 part of ester of 2-dioctyl phthalate two (2-propyl group heptan), 50 parts of nitrile silicone rubbers, 5 parts of nano silicons, 8 parts, calcium carbonate, 2 parts of styrene copolymers, 0.2 part of perfluoro butyl potassium sulfonate, 5 parts of paraffin oils, reinforcing agent DH-30.6 part.
6. a kind of high-strength transparence cable sheath material according to claim 1, it is characterized in that, comprise the raw material of following mass fraction: 80 parts of ethylene-vinyl acetate copolymers, PETG-1 that vinyl acetate content is 18%~20%, 20 parts of 4-cyclohexanedimethanoester esters, plasticizer cyclohexane alkane 1,2 parts of esters of 2-dioctyl phthalate two (2-propyl group heptan), 20 parts of nitrile silicone rubbers, 12 parts of nano silicons, 3 parts, calcium carbonate, 6 parts of styrene copolymers, 0.1 part of perfluoro butyl potassium sulfonate, 10 parts of paraffin oils, reinforcing agent DH-30.2 part.
CN201610152418.3A 2016-03-17 2016-03-17 High-strength transparent cable sheath material Withdrawn CN105602082A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106317803A (en) * 2016-08-26 2017-01-11 张海棠 Environment-friendly transparent cable sheathing material
CN107699064A (en) * 2017-09-15 2018-02-16 苏州罗格特光电科技有限公司 A kind of transparent protective coating material of photovoltaic cell panel PET base notacorias and preparation method thereof
CN107722641A (en) * 2017-10-30 2018-02-23 天长市平康电子科技有限公司 A kind of wear-resistant sheath of Charger (portable round) connecting line
CN109149304A (en) * 2018-09-10 2019-01-04 深圳市坚果皮科技有限公司 A kind of data line using optical fiber luminescent

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104861553A (en) * 2014-10-16 2015-08-26 青岛欣展塑胶有限公司 Flame-retardation antistatic modified polytrimethylene terephthalate composite material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104861553A (en) * 2014-10-16 2015-08-26 青岛欣展塑胶有限公司 Flame-retardation antistatic modified polytrimethylene terephthalate composite material

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106317803A (en) * 2016-08-26 2017-01-11 张海棠 Environment-friendly transparent cable sheathing material
CN106317803B (en) * 2016-08-26 2018-07-20 张海棠 A kind of transparent and environment friendly cable sheathing material
CN107699064A (en) * 2017-09-15 2018-02-16 苏州罗格特光电科技有限公司 A kind of transparent protective coating material of photovoltaic cell panel PET base notacorias and preparation method thereof
CN107722641A (en) * 2017-10-30 2018-02-23 天长市平康电子科技有限公司 A kind of wear-resistant sheath of Charger (portable round) connecting line
CN109149304A (en) * 2018-09-10 2019-01-04 深圳市坚果皮科技有限公司 A kind of data line using optical fiber luminescent

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