CN105600852A - Dyeing waste water treating agent and preparation method thereof - Google Patents
Dyeing waste water treating agent and preparation method thereof Download PDFInfo
- Publication number
- CN105600852A CN105600852A CN201610196420.0A CN201610196420A CN105600852A CN 105600852 A CN105600852 A CN 105600852A CN 201610196420 A CN201610196420 A CN 201610196420A CN 105600852 A CN105600852 A CN 105600852A
- Authority
- CN
- China
- Prior art keywords
- dyeing
- treatment
- preparation
- printing wastewaters
- printing
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
Abstract
The invention provides a preparation method of a dyeing waste water treating agent, comprising the following steps: (1) mixing bentonite, corn starch and wheat starch uniformly, adding water and extruding into particles 1-2mm in diameter; (2) calcining the particles obtained in step (1) for 5-7h, cooling to room temperature; (3) mixing the calcined particles with an acrylamide solution and stirring; (4) adding an initiator into the mixture system to initiate polyreaction, then adding a cross-linking agent to initiate cross linking reaction to obtain a mixture; and (5) baking the mixture in step (4) to obtain the dyeing waste water treating agent. The dyeing waste water treating agent provided by the invention fully utilizes the expandability and absorbability of the bentonite, has strong absorption on chroma, phosphorus, heavy metal ions, organic matters and the like, and can be used as a purifying agent in waste water treatment.
Description
Technical field
The invention belongs to printing technology field, be specifically related to a kind for the treatment of of dyeing/printing wastewaters and preparation method thereof.
Background technology
Though dyestuff has very strong acute virus action unlike agricultural chemicals, people dye at azo dyes, anthraquinoneThe kind of finding tool mutagenicity and carcinogenesis in material, kiton colors, the catabolite of dyestuff mostly also is benzidineDeng some carcinogenic aromatic compounds. Dyestuff is as the stable organic compound of a class formation, have antiacid, alkali resistant,The characteristic such as anti-light, antimicrobial has longer demurrage in environment, and the dyestuff of extremely low concentration in water body, also can shadowRing the normal function of receiving water body, to aquatic microorganisms and also toxic effect of fish, make whole aquatic ecosystemDiversity declines. Therefore the negative effect of Dyes on Environment is not only its colourity and COD, but also is that it is rightThe potential hazard of human health and growth and development of plants and animals. Thereby waste water containing dye is China's main noxious industry at presentOne of waste water, is also the difficult point of sewage disposal, and dyestuff and treatment of dyeing wastewater are the important contents of Environmental Engineering research.
At present mainly contain adsorption bleaching, redox decolouring, coagulation decoloration processing etc. for the method for the treatment of of dyeing wastewater,Ion-exchange decolouring, milipore filter decolouring and biological decolouring technology are also carried out to certain research both at home and abroad. But, traditionCoagulation decoloration process waste water, resulting cost is higher, and is invalid to some special high-concentration printing and dyeing wastewaters etc.The too high operating costs such as oxidation-reduction method, ion-exchange, ultrafiltrationmembrane process also affected said method in practice shouldWith. Therefore, existing method is considered to have from economy, technical and usability for the various discoloration methods of dyeing waste waterCertain deficiency. Most of printworks still adopt charcoal absorption decolouring, but active carbon has selectively dyestuff, valencyLattice are higher, and regeneration difficulty, is restricted in the application aspect dyeing waste water adsorption bleaching, is generally only applied to concentration lowerTreatment of dyeing wastewater or advanced treating.
Therefore, need badly a kind of with low cost, treatment of dyeing/printing wastewaters that treatment effect is good is provided.
Summary of the invention
Goal of the invention: the treatment of dyeing/printing wastewaters that a kind for the treatment of effect is good is provided.
Technical scheme: the preparation method for the treatment of of dyeing/printing wastewaters, comprises the steps:
(1) ratio that is 15:10:2 by bentonite, cornstarch, wheaten starch according to mass ratio mixes, and addsWater is squeezed into the particle that diameter is 1~2mm;
(2) particle obtaining in step (1) is placed under 500~600 DEG C of conditions and calcines 5~7h, be cooled to room temperature;
(3) particle after calcining is mixed with acrylamide solution, stir;
(4) in step (3) mixed system, add initator, initiated polymerization, then add crosslinking agent, cross-linking reaction,Obtain mixture;
(5) mixture in step (4) is dried, obtain treatment of dyeing/printing wastewaters.
Bentonite main component is montmorillonite, is a kind of function admirable, the clay that economic worth is higher, range of application is widerResource. Bentonite is as the important nonmetallic mineral of a class, through lot of domestic and foreign scholar's joint research for many years, moreMore demonstrate the feasibility of applying in field of Environment Protection. Research shows, bentonite, particularly modified product have higherIon exchangeable, larger dilatancy and adsorptivity preferably, to the colourity in water, phosphorus, heavy metal ion, haveMachine thing etc. all has stronger suction-operated, can be used as the cleanser of sewage disposal.
As preferably, in described acrylamide solution, the concentration of acrylamide is 10~50g/L.
As preferably, described stirring, whipping temp is 30~45 DEG C, mixing time is 2~5h.
As preferably, described initator is peroxidized t-butyl perbenzoate or cumyl peroxide.
As preferably, the addition of described initator is 5~8g/L.
As preferably, the reaction temperature of polymerisation is 45~65 DEG C, and the reaction time of polymerisation is 4~8h.
As preferably, described crosslinking agent is N hydroxymethyl acrylamide.
As preferably, the addition of described crosslinking agent is 1~3g/L.
As preferably, the reaction temperature of described cross-linking reaction is 35~55 DEG C, and the reaction time of cross-linking reaction is 2~6h.
The treatment of dyeing/printing wastewaters that the preparation method of above-mentioned treatment of dyeing/printing wastewaters prepares is in protection scope of the present inventionWithin.
Beneficial effect:
Treatment of dyeing/printing wastewaters prepared by the present invention has that preparation method is simple, high treating effect.
Detailed description of the invention
According to following embodiment, the present invention may be better understood. But, those skilled in the art will readily understand, realExecute routine described content only for the present invention is described, and should also can not limit in claims described in detailThe present invention.
Embodiment 1:
(1) ratio that is 15:10:2 by bentonite, cornstarch, wheaten starch according to mass ratio mixes, and addsWater is squeezed into the particle that diameter is 1~2mm;
(2) particle obtaining in step (1) is placed under 500~600 DEG C of conditions and calcines 5~7h, be cooled to room temperature;
(3) particle after calcining is mixed with 40g/L acrylamide solution, stir;
(4) in step (3) mixed system, add peroxidized t-butyl perbenzoate, react 4h at 50 DEG C, then add N-hydroxylMethacrylamide, reacts 4h at 45 DEG C;
(5) mixture in step (4) is dried, obtain treatment of dyeing/printing wastewaters.
Embodiment 2:
(1) ratio that is 15:10:2 by bentonite, cornstarch, wheaten starch according to mass ratio mixes, and addsWater is squeezed into the particle that diameter is 1~2mm;
(2) particle obtaining in step (1) is placed under 520 DEG C of conditions and calcines 6h, be cooled to room temperature;
(3) particle after calcining is mixed with 50g/L acrylamide solution, mixed proportion is that 1kg:8L stirs;
(4) in step (3) mixed system, add peroxidized t-butyl perbenzoate, react 6h at 60 DEG C, then add N-hydroxylMethacrylamide, reacts 2h at 50 DEG C;
(5) mixture in step (4) is dried, obtain treatment of dyeing/printing wastewaters.
Embodiment 3:
(1) ratio that is 15:10:2 by bentonite, cornstarch, wheaten starch according to mass ratio mixes, and addsWater is squeezed into the particle that diameter is 1~2mm;
(2) particle obtaining in step (1) is placed under 550 DEG C of conditions and calcines 3h, be cooled to room temperature;
(3) particle after calcining is mixed with 20g/L acrylamide solution, mixed proportion is that 1kg:8L stirs;
(4) in step (3) mixed system, add peroxidized t-butyl perbenzoate, react 5h at 50 DEG C, then add N-hydroxylMethacrylamide, reacts 3h at 45 DEG C;
(5) mixture in step (4) is dried, obtain treatment of dyeing/printing wastewaters.
Embodiment 4:
(1) ratio that is 15:10:2 by bentonite, cornstarch, wheaten starch according to mass ratio mixes, and addsWater is squeezed into the particle that diameter is 1~2mm;
(2) particle obtaining in step (1) is placed under 600 DEG C of conditions and calcines 4h, be cooled to room temperature;
(3) particle after calcining is mixed with 10g/L acrylamide solution, mixed proportion is that 1kg:8L stirs;
(4) in step (3) mixed system, add peroxidized t-butyl perbenzoate, react 5h at 40 DEG C, then add N-hydroxylMethacrylamide, reacts 3h at 45 DEG C;
(5) mixture in step (4) is dried, obtain treatment of dyeing/printing wastewaters.
Claims (10)
1. a preparation method for treatment of dyeing/printing wastewaters, is characterized in that, comprises the steps:
(1) ratio that is 15:10:2 by bentonite, cornstarch, wheaten starch according to mass ratio mixes, and addsWater is squeezed into the particle that diameter is 1~2mm;
(2) particle obtaining in step (1) is placed under 500~600 DEG C of conditions and calcines 5~7h, be cooled to room temperature;
(3) particle after calcining is mixed with acrylamide solution, stir;
(4) in step (3) mixed system, add initator, initiated polymerization, then add crosslinking agent, cross-linking reaction,Obtain mixture;
(5) mixture in step (4) is dried, obtain treatment of dyeing/printing wastewaters.
2. the preparation method for the treatment of of dyeing/printing wastewaters according to claim 1, is characterized in that, in step (3),In described acrylamide solution, the concentration of acrylamide is 10~50g/L.
3. the preparation method for the treatment of of dyeing/printing wastewaters according to claim 1, is characterized in that, in step (3),Described stirring, whipping temp is 30~45 DEG C, mixing time is 2~5h.
4. the preparation method for the treatment of of dyeing/printing wastewaters according to claim 1, is characterized in that, in step (3),Described initator is peroxidized t-butyl perbenzoate or cumyl peroxide.
5. the preparation method for the treatment of of dyeing/printing wastewaters according to claim 1, is characterized in that, in step (3),The addition of described initator is 5~8g/L.
6. the preparation method for the treatment of of dyeing/printing wastewaters according to claim 1, is characterized in that, in step (3),The reaction temperature of polymerisation is 45~65 DEG C, and the reaction time of polymerisation is 4~8h.
7. the preparation method for the treatment of of dyeing/printing wastewaters according to claim 1, is characterized in that, in step (3),Described crosslinking agent is N hydroxymethyl acrylamide.
8. the preparation method for the treatment of of dyeing/printing wastewaters according to claim 1, is characterized in that, in step (3),The addition of described crosslinking agent is 1~3g/L.
9. the preparation method for the treatment of of dyeing/printing wastewaters according to claim 1, is characterized in that, in step (3),The reaction temperature of described cross-linking reaction is 35~55 DEG C, and the reaction time of cross-linking reaction is 2~6h.
10. the treatment of dyeing/printing wastewaters that the preparation method of the arbitrary described treatment of dyeing/printing wastewaters of claim 1~9 prepares.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107413309A (en) * | 2017-05-31 | 2017-12-01 | 山东华潍膨润土有限公司 | Multifunctional and composite type adsorbent for heavy metal and preparation method thereof |
CN110510697A (en) * | 2019-08-23 | 2019-11-29 | 上海市农业科学院 | A method of water body Malachite Green is handled using rice straw biology carbon adsorbent |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100861178B1 (en) * | 2007-06-02 | 2008-09-30 | 조동현 | The flocculant and decolant composition for waste water treatment and the production method thereof |
CN104261528A (en) * | 2014-09-10 | 2015-01-07 | 瑞安市普罗生物科技有限公司 | Flocculating agent as well as preparation method and application thereof |
CN104773784A (en) * | 2015-04-28 | 2015-07-15 | 阳原县仁恒精细粘土有限责任公司 | Printing and dyeing wastewater treatment agent |
-
2016
- 2016-03-31 CN CN201610196420.0A patent/CN105600852A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100861178B1 (en) * | 2007-06-02 | 2008-09-30 | 조동현 | The flocculant and decolant composition for waste water treatment and the production method thereof |
CN104261528A (en) * | 2014-09-10 | 2015-01-07 | 瑞安市普罗生物科技有限公司 | Flocculating agent as well as preparation method and application thereof |
CN104773784A (en) * | 2015-04-28 | 2015-07-15 | 阳原县仁恒精细粘土有限责任公司 | Printing and dyeing wastewater treatment agent |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107413309A (en) * | 2017-05-31 | 2017-12-01 | 山东华潍膨润土有限公司 | Multifunctional and composite type adsorbent for heavy metal and preparation method thereof |
CN107413309B (en) * | 2017-05-31 | 2020-07-17 | 山东华潍膨润土有限公司 | Multifunctional composite heavy metal ion adsorbent and preparation method thereof |
CN110510697A (en) * | 2019-08-23 | 2019-11-29 | 上海市农业科学院 | A method of water body Malachite Green is handled using rice straw biology carbon adsorbent |
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Application publication date: 20160525 |