CN105599383A - Metal net anti-explosive vacuum thermal insulation glass and preparing method thereof - Google Patents

Metal net anti-explosive vacuum thermal insulation glass and preparing method thereof Download PDF

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Publication number
CN105599383A
CN105599383A CN201510996388.XA CN201510996388A CN105599383A CN 105599383 A CN105599383 A CN 105599383A CN 201510996388 A CN201510996388 A CN 201510996388A CN 105599383 A CN105599383 A CN 105599383A
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China
Prior art keywords
layer
glassy
glassy layer
glass
explosion
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CN201510996388.XA
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Chinese (zh)
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CN105599383B (en
Inventor
顾黎明
徐峰
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TAICANG YAOHUA GLASS CO Ltd
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TAICANG YAOHUA GLASS CO Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/02Layer formed of wires, e.g. mesh
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/061Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/20Inorganic coating
    • B32B2255/205Metallic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/412Transparent

Abstract

The invention provides metal net anti-explosive vacuum thermal insulation glass and a preparing method thereof. The glass comprises a glass layer comprising a first glass layer, a second glass layer and a third glass layer from top to bottom, a glue clamping layer arranged between the first glass layer and the second glass layer, a metal net embedded into the glue clamping layer, an infrared reflection layer arranged at the upper surface of the third glass layer, a strain protection layer arranged at the upper surface of the infrared reflection layer, a sealing layer coating one side of the glass layer along a direction vertical to the glass layer, a protection layer longitudinally coating the outer side of the sealing layer, and a group of supporters arranged between the second glass layer and the strain protection layer. Thermal insulation and anti-explosive performances of the vacuum glass are effectively improved.

Description

A kind of wire netting explosion-proof vacuum heat insulation glass and preparation method thereof
Technical field
The invention belongs to building material technical field, particularly, relate to a kind of wire netting explosion-proof vacuum heat insulation glass and preparation method thereof.
Background technology
Glass is all very high materials of a kind of transparency, intensity and hardness, is chemical inertness in surroundings, also can not work with biology. Therefore, its purposes is very extensive. Vacuum glass has the unrivaled advantage of other glass aspect sound insulation, insulation, and thinner, and weight is relatively light. From physics general knowledge, heat transmission usually occurs between contactant, and two glass plates up and down of vacuum glass do not contact each other, and the support in encapsulant and the vacuum chamber of circumference of vacuum glass all adopts heat-insulating material, and heat conducting composition is very little; Meanwhile, the annular seal space in the middle of levels glass is vacuum state, and vacuum is higher, and gas molecula number is fewer, and the convection action of gas molecule is less, and heat insulation effect is better. But due to technical limitations, vacuum glass cannot be accomplished to vacuumize completely, has affected to a certain extent its heat insulation effect. Meanwhile, for common dual-layer vacuum glass, the thickness of glass of its explosion-proof performance and use is relevant, and thicker its anti-self-destruction performance of glassy layer is better, but cost also can increase simultaneously.
To this, mainly there is following patent in China at present.
Patent publication No.: CN1559950A discloses a kind of for shellproof explosion-proof high heat insulation performance glass such as building, automobile, trains, comprise at least one deck vacuum layer, in described vacuum layer, establish support column and getter, two sides in vacuum layer arrange respectively glassy layer, establish edge sealing scolder in the periphery of layer glass, it is characterized in that outer surface at one deck glassy layer is at least by compound another glassy layer of doubling layer. Structure of the present invention, processing step simply, rationally, have been broken through conventional thought, reach the viable process technology that realizes said structure, the product vacuum of producing is good, have good heat insulation, sound insulation value, and it is shellproof, explosion-proof performance index is higher, product percent of pass is high. But this invention is only used the mode of composite intermediate layer glass to solve vacuum glass Explosion-Proof, easily cause thickness of glass larger on the one hand, need on the other hand to use compound glass compound, consumptive material is serious, and its heat-insulating property is not very good.
Summary of the invention
For solving the problem of above-mentioned existence, the object of the present invention is to provide a kind of wire netting explosion-proof vacuum heat insulation glass and preparation method thereof.
For achieving the above object, the technical solution used in the present invention is: a kind of wire netting explosion-proof vacuum heat insulation glass and preparation method thereof, comprising: glassy layer, comprising: the first glassy layer of stacked setting from top to bottom, the second glassy layer, the 3rd glassy layer; Doubling layer, is arranged between the first glassy layer and the second glassy layer; Wire netting, is embedded in doubling layer; Infrared reflecting layer, is arranged at the 3rd glassy layer upper surface; Stress overcoat, is arranged at infrared reflecting layer upper surface; Sealant, is coated in described glassy layer surrounding along the direction of vertical glassy layer; Protective layer, is longitudinally coated on described sealant outside; One group of supporter, is arranged between the second glassy layer and stress overcoat.
Further, described doubling layer material can be PVB or EVA.
Separately, described infrared reflecting layer comprises: base layer, is arranged at described the 3rd glassy layer upper surface; Metal level is gold layer, silver layer or electrum layer; The first high refractive index layer, is arranged between described metal level and base layer, is selected from one or more in following oxide skin(coating): indium tin oxide layer, titanium dioxide layer, zirconia layer, stannic oxide layer, indium oxide layer; The second high refractive index layer, is arranged at described metal level upper surface, is selected from one or more in following oxide skin(coating): indium tin oxide layer, titanium dioxide layer, zirconia layer, stannic oxide layer, indium oxide layer.
Separately have, described sealant is refractory seals glue-line.
Again, described stress overcoat and protective layer are teflon layer.
Have, described base layer is PET film matrix, PC matrix, PI matrix, PP matrix, PTFE matrix or PA matrix again.
And above support is for for glass dust supporter, this glass dust supporter comprises that weight counts the glass dust of 86-94% and weight and count the organic solvent of 6-14%.
Further, a kind of preparation method of doubling explosion-proof vacuum heat insulation glass, comprises the steps: 1) get the first glassy layer, the second glassy layer, the 3rd glassy layer; 2) choose PVB or EVA, by double screw extruder granulation, then make required doubling layer by the method for extrusion molding, and wire netting is embedded wherein; 3) the first glassy layer and the second glassy layer are cleaned up, then order is stacked successively, is followed successively by from top to down: the first glassy layer, doubling layer, the second glassy layer; Under negative pressure of vacuum, heat, apply and keep pressure, make doubling thoroughly melt described the first glassy layer and the second glassy layer is bonded together and complete deaeration, described heating-up temperature is 152-158 DEG C, and described applied pressure is 2.5-4.5kg/cm2, the time that described pressure maintains is 25-30min; 4) adopt showering means to form the base layer of infrared reflecting layer at the 3rd glassy layer upper surface, and then deposit successively the first high refracting layer, metal level and the second high refracting layer from bottom to top at base layer, form four-layer structure film; 5) on infrared reflecting layer, spray a ply stress protective layer; 6) on stress protective layer, lay supporter, then place the second glassy layer and close sheet, in four side seam gaps, fill refractory seals glue and form sealant; The glass closing after sheet is put into heating furnace, enter stove and be warming up to 100oC-500oC; 7) in stove, vacuumize, or vacuumize outward at stove, be evacuated to below 0.1Pa, then be cooled to below the melt temperature of refractory seals glue; 8) outside sealant, showering protective layer makes wire netting explosion-proof vacuum heat insulation glass.
Beneficial effect of the present invention is: by adding metal level, make vacuum glass have explosion-resistance characteristic, even glass breaking, fragment also can not splash everywhere, has strengthened the security that vacuum glass uses; By adding infrared reflecting layer, infra-red radiation that can usable reflection glass both sides, avoids vacuum glass both sides to carry out heat exchange, strengthens the heat insulation and preservation effect of vacuum glass, can allow natural daylight incident simultaneously, ensures the transparency of vacuum glass; Add stress overcoat, can prevent that infrared reflecting layer is out of shape because of vacuum pressure; Sealant, by whole glassy layer sealing, has not only ensured vacuum-tightness, also can prevent from infiltrating air in the middle of infrared reflecting layer and glassy layer, to cause infrared reflecting layer oxidation; Add layer protective layer outward at sealant, can avoid sealant because of accident or rub causing breakage.
Brief description of the drawings
Fig. 1 is the structural representation of a kind of wire netting explosion-proof vacuum heat insulation glass provided by the present invention and preparation method thereof.
Fig. 2 is the structural representation of the infrared protective layer of a kind of wire netting explosion-proof vacuum heat insulation glass provided by the present invention and preparation method thereof.
Detailed description of the invention
Following examples are used for illustrating the present invention, but can not be used for limiting the scope of the invention.
With reference to Fig. 1 ~ Fig. 2, a kind of wire netting explosion-proof vacuum heat insulation glass provided by the present invention and preparation method thereof, comprising: glassy layer 1, comprising: the first glassy layer 11 of stacked setting from top to bottom, the second glassy layer 12, the 3rd glassy layer 13; Doubling layer 2, is arranged between the first glassy layer 11 and the second glassy layer 12; Wire netting 3, is embedded in doubling layer 2; Infrared reflecting layer 4, is arranged at the 3rd glassy layer 13 upper surfaces; Stress overcoat 8, is arranged at infrared reflecting layer 4 upper surfaces; Sealant 5, is coated in described glassy layer 1 surrounding along the direction of vertical glassy layer 1; Protective layer 6, is longitudinally coated on described sealant 5 outsides; One group of supporter 7, is arranged between the second glassy layer 12 and stress overcoat 8.
Further, described doubling layer 2 material can be PVB or EVA.
Separately, described infrared reflecting layer 4 comprises: base layer 41, is arranged at described the 3rd glassy layer 13 upper surfaces; Metal level 43 is gold layer, silver layer or electrum layer; The first high refractive index layer 42, is arranged between described metal level 43 and base layer 41, is selected from one or more in following oxide skin(coating): indium tin oxide layer, titanium dioxide layer, zirconia layer, stannic oxide layer, indium oxide layer; The second high refractive index layer 44, is arranged at described metal level 43 upper surfaces, is selected from one or more in following oxide skin(coating): indium tin oxide layer, titanium dioxide layer, zirconia layer, stannic oxide layer, indium oxide layer.
Separately have, described sealant 5 is refractory seals glue-line.
Again, described stress overcoat 8 and protective layer 6 are teflon layer.
Have, described base layer 41 is PET film matrix, PC matrix, PI matrix, PP matrix, PTFE matrix or PA matrix again.
And above support 7 is for being glass dust supporter, this glass dust supporter comprises that weight counts the glass dust of 86-94% and weight and count the organic solvent of 6-14%.
Further, a kind of preparation method of doubling explosion-proof vacuum heat insulation glass, comprises the steps: 1) get the first glassy layer 11, the second glassy layer 12, the 3rd glassy layer 13; 2) choose PVB or EVA, by double screw extruder granulation, then make required doubling layer 2 by the method for extrusion molding, and wire netting 3 is embedded wherein; 3) the first glassy layer 11 and the second glassy layer 12 are cleaned up, then order is stacked successively, is followed successively by from top to down: the first glassy layer 11, doubling layer 2, the second glassy layer 12; Under negative pressure of vacuum, heat, apply and keep pressure, make doubling thoroughly melt described the first glassy layer 11 and the second glassy layer 12 is bonded together and complete deaeration, described heating-up temperature is 152-158 DEG C, and described applied pressure is 2.5-4.5kg/cm2, the time that described pressure maintains is 25-30min; 4) adopt showering means to form the base layer 41 of infrared reflecting layer at the 3rd glassy layer 13 upper surfaces, and then deposit successively the first high refracting layer 42, metal level 43 and the second high refracting layer 44 from bottom to top at base layer, form four-layer structure film; 5) on infrared reflecting layer 4, spray a ply stress protective layer 8; 6) on stress protective layer, lay supporter 7, then place the second glassy layer 12 and close sheet, in four side seam gaps, fill refractory seals glue and form sealant 5; The glass closing after sheet is put into heating furnace, enter stove and be warming up to 100oC-500oC; 7) in stove, vacuumize, or vacuumize outward at stove, be evacuated to below 0.1Pa, then be cooled to below the melt temperature of refractory seals glue; 8) outside sealant, showering protective layer 6 makes wire netting explosion-proof vacuum heat insulation glass.
The beneficial effect of the present embodiment is: by adding metal level, make vacuum glass have explosion-resistance characteristic, even glass breaking, fragment also can not splash everywhere, has strengthened the security that vacuum glass uses; By adding infrared reflecting layer, infra-red radiation that can usable reflection glass both sides, avoids vacuum glass both sides to carry out heat exchange, strengthens the heat insulation and preservation effect of vacuum glass, can allow natural daylight incident simultaneously, ensures the transparency of vacuum glass; Add stress overcoat, can prevent that infrared reflecting layer is out of shape because of vacuum pressure; Sealant, by whole glassy layer sealing, has not only ensured vacuum-tightness, also can prevent from infiltrating air in the middle of infrared reflecting layer and glassy layer, to cause infrared reflecting layer oxidation; Add layer protective layer outward at sealant, can avoid sealant because of accident or rub causing breakage.
It should be noted that, above embodiment is only unrestricted in order to technical scheme of the present invention to be described. Although the present invention is had been described in detail with reference to preferred embodiment, those of ordinary skill in the art is to be understood that, can modify or be equal to replacement the technical scheme of invention, and not depart from the scope of technical solution of the present invention, it all should be encompassed in claim scope of the present invention.

Claims (8)

1. wire netting explosion-proof vacuum heat insulation glass and preparation method thereof, is characterized in that, comprising: glassy layer, comprising: the first glassy layer of stacked setting from top to bottom, the second glassy layer, the 3rd glassy layer; Doubling layer, is arranged between the first glassy layer and the second glassy layer; Wire netting, is embedded in doubling layer; Infrared reflecting layer, is arranged at the 3rd glassy layer upper surface; Stress overcoat, is arranged at infrared reflecting layer upper surface; Sealant, is coated in described glassy layer surrounding along the direction of vertical glassy layer; Protective layer, is longitudinally coated on described sealant outside; One group of supporter, is arranged between the second glassy layer and stress overcoat.
2. a kind of wire netting explosion-proof vacuum heat insulation glass according to claim 1 and preparation method thereof, is characterized in that, described doubling layer material can be PVB or EVA.
3. a kind of wire netting explosion-proof vacuum heat insulation glass according to claim 1 and preparation method thereof, is characterized in that, described infrared reflecting layer comprises: base layer, is arranged at described the 3rd glassy layer upper surface; Metal level is gold layer, silver layer or electrum layer; The first high refractive index layer, is arranged between described metal level and base layer, is selected from one or more in following oxide skin(coating): indium tin oxide layer, titanium dioxide layer, zirconia layer, stannic oxide layer, indium oxide layer; The second high refractive index layer, is arranged at described metal level upper surface, is selected from one or more in following oxide skin(coating): indium tin oxide layer, titanium dioxide layer, zirconia layer, stannic oxide layer, indium oxide layer.
4. a kind of wire netting explosion-proof vacuum heat insulation glass according to claim 1 and preparation method thereof, is characterized in that, described sealant is refractory seals glue-line.
5. a kind of wire netting explosion-proof vacuum heat insulation glass according to claim 1 and preparation method thereof, is characterized in that, described stress overcoat and protective layer are teflon layer.
6. a kind of wire netting explosion-proof vacuum heat insulation glass according to claim 1 and preparation method thereof, is characterized in that, described base layer is PET film matrix, PC matrix, PI matrix, PP matrix, PTFE matrix or PA matrix.
7. a kind of doubling explosion-proof vacuum heat insulation glass according to claim 1 and preparation method thereof, it is characterized in that, above support is for for glass dust supporter, and this glass dust supporter comprises that weight counts the glass dust of 86-94% and weight and count the organic solvent of 6-14%.
8. the preparation method of a kind of doubling explosion-proof vacuum heat insulation glass according to claim 1, is characterized in that, comprises the steps: 1) get the first glassy layer, the second glassy layer, the 3rd glassy layer; 2) choose PVB or EVA, by double screw extruder granulation, then make required doubling layer by the method for extrusion molding, and wire netting is embedded wherein; 3) the first glassy layer and the second glassy layer are cleaned up, then order is stacked successively, is followed successively by from top to down: the first glassy layer, doubling layer, the second glassy layer; Under negative pressure of vacuum, heat, apply and keep pressure, make doubling thoroughly melt described the first glassy layer and the second glassy layer is bonded together and complete deaeration, described heating-up temperature is 152-158 DEG C, and described applied pressure is 2.5-4.5kg/cm2, the time that described pressure maintains is 25-30min; 4) adopt showering means to form the base layer of infrared reflecting layer at the 3rd glassy layer upper surface, and then deposit successively the first high refracting layer, metal level and the second high refracting layer from bottom to top at base layer, form four-layer structure film; 5) on infrared reflecting layer, spray a ply stress protective layer; 6) on stress protective layer, lay supporter, then place the second glassy layer and close sheet, in four side seam gaps, fill refractory seals glue and form sealant; The glass closing after sheet is put into heating furnace, enter stove and be warming up to 100oC-500oC; 7) in stove, vacuumize, or vacuumize outward at stove, be evacuated to below 0.1Pa, then be cooled to below the melt temperature of refractory seals glue; 8) outside sealant, showering protective layer makes wire netting explosion-proof vacuum heat insulation glass.
CN201510996388.XA 2015-12-28 2015-12-28 A kind of metal mesh explosion-proof vacuum heat insulation glass and preparation method thereof Active CN105599383B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
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CN106761237A (en) * 2016-12-23 2017-05-31 钦州市中玻玻璃有限责任公司 A kind of interlayer composite glass
US20200071221A1 (en) * 2016-12-10 2020-03-05 Lcrt Pty Ltd Methods and systems for processing glass and methods for reinforcing glass products
CN111016340A (en) * 2019-12-30 2020-04-17 鲁米星特种玻璃科技股份有限公司 All-weather, one-way and visible bulletproof and explosion-proof glass and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20200071221A1 (en) * 2016-12-10 2020-03-05 Lcrt Pty Ltd Methods and systems for processing glass and methods for reinforcing glass products
CN106761237A (en) * 2016-12-23 2017-05-31 钦州市中玻玻璃有限责任公司 A kind of interlayer composite glass
CN111016340A (en) * 2019-12-30 2020-04-17 鲁米星特种玻璃科技股份有限公司 All-weather, one-way and visible bulletproof and explosion-proof glass and preparation method thereof

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