CN105591166A - Power generation device based on carbon material and manufacturing method thereof - Google Patents

Power generation device based on carbon material and manufacturing method thereof Download PDF

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Publication number
CN105591166A
CN105591166A CN201410576692.4A CN201410576692A CN105591166A CN 105591166 A CN105591166 A CN 105591166A CN 201410576692 A CN201410576692 A CN 201410576692A CN 105591166 A CN105591166 A CN 105591166A
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China
Prior art keywords
carbon element
element layer
volatile liquid
trt
electrode
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CN201410576692.4A
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Chinese (zh)
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CN105591166B (en
Inventor
周军
郭万林
丁天朋
薛国斌
李嘉
徐莹
殷俊
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Nanjing University of Aeronautics and Astronautics
Huazhong University of Science and Technology
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Nanjing University of Aeronautics and Astronautics
Huazhong University of Science and Technology
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Application filed by Nanjing University of Aeronautics and Astronautics, Huazhong University of Science and Technology filed Critical Nanjing University of Aeronautics and Astronautics
Priority to CN201410576692.4A priority Critical patent/CN105591166B/en
Priority to PCT/CN2014/092295 priority patent/WO2016061870A1/en
Publication of CN105591166A publication Critical patent/CN105591166A/en
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    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02N—ELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
    • H02N3/00—Generators in which thermal or kinetic energy is converted into electrical energy by ionisation of a fluid and removal of the charge therefrom
    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02N—ELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
    • H02N11/00—Generators or motors not provided for elsewhere; Alleged perpetua mobilia obtained by electric or magnetic means
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

The invention discloses a power generation device based on a carbon material. The power generating device includes a power generation assembly and a volatile liquid. The power generation assembly includes an electrically-insulating carrier sheet, a first electrode and a second electrode which are arranged on the surface of the carrier sheet and are not crossed with each other, and a carbon material layer which is totally deposited between the two electrodes to form an electric conductive path therewith. One end of the carbon material layer is always soaked in the volatile liquid and the other end is exposed outside the volatile liquid. By means of the difference of interaction between the liquid, when the liquid is gasified and is separated from the carbon material, and the carbon material in different zones between the two electrodes, potential difference is formed between the two electrodes. The invention also discloses a related preparation method. The device achieves continuous high-voltage electricity energy output by means of the interaction between the volatile liquid and the carbon material, and is especially suitable for special applications without illumination or without demand on external mechanical movement.

Description

A kind of TRT and manufacture method thereof based on material with carbon element
Technical field
The invention belongs to generation of electricity by new energy apparatus field, more specifically, relate to a kind of based on material with carbon elementTRT and manufacture method thereof.
Background technology
In recent years, along with the aggravation gradually of continuous decrease and the environmental problem of fossil fuel, green energyResearch and the application of source device have obtained vigorous growth, comprise solar cell, wind-driven generator,Thermoelectric conversion element, novel electromechanical energy transducer etc. But further research shows, above-mentioned newThe application scenario of energy generating equipment is still subject to some restrictions, and for example solar cell is in the time of unglazed photographCannot work; Novel electromechanical energy transducer needs extraneous mechanical movement to carry out work. Therefore, howIn unglazed photograph and the environment without extraneous mechanical movement, producing electric energy is just becoming energy field and is meriting attentionImportant technological problems.
Summary of the invention
For above defect or the Improvement requirement of prior art, the invention provides a kind of based on material with carbon elementTRT and manufacture method thereof, wherein by its key component as material with carbon element layer, volatility liquidBody, electrode setting mode and working mechanism are studied, should be able to effectively utilize mutually volatile liquid withThe interaction of material with carbon element realizes the output of lasting high voltage electric energy, be particularly useful for unglazed photograph andWithout the certain applications of extraneous mechanical movement.
For achieving the above object, according to one aspect of the present invention, provide a kind of based on material with carbon elementTRT, this TRT comprises electrification component and volatile liquid, it is characterized in that:
Described electrification component comprise electric insulation slide glass, be arranged on this slide glass surface mutually disjointOne electrode and the second electrode, and be arranged on equally the material with carbon element layer on this carrier surface, wherein this carbonMaterial is selected from one or more in carbon black, CNT, carbon granule or Graphene, and is deposited onOn slide glass, interconnect and form material with carbon element layer, whole material with carbon element layer is overlapped on described the first electrode in additionAnd between the second electrode, and form conductive path with these two electrodes; Begin in one end of described material with carbon element layerImmerse eventually described volatile liquid, the other end is exposed to the environment outside described volatile liquid surfaceIn; In this way, in use, due to surface tension and self gasification of liquid, volatile liquidCan constantly move to other one end from immersing end along material with carbon element layer, utilize liquid in the zones of different of two endsGasification depart from time and material with carbon element between interactional difference, make shape between the first electrode and the second electrodeBecome electrical potential difference.
As further preferably, described volatile liquid is preferably the aqueous solution of pure water, salt and hasMachine solvent etc.
As further preferably, described electrode needs seal isolation solution.
As further preferably, above-mentioned TRT can also comprise temperature control unit, humidity controlUnit processed, the gentle pressure-controlled of wind speed control module unit, wherein temperature control unit is used for improving volatilizationProperty liquid residing environment temperature, humidity controlling unit is wet for reducing the residing environment of volatile liquidDegree, wind speed control module is for improving the flow rate of gas on described volatile liquid surface, air pressure controlUnit processed is for reducing the residing ambient pressure of described volatile liquid, in this way, acting in conjunction withJust improve the output electric energy of TRT.
According to another aspect of the present invention, provide a kind of for the preparation of the TRT based on material with carbon elementMethod, it is characterized in that, the method comprises the following steps:
(a) preparation process of electrification component:
The slide glass that is selected from electrically insulating material is made to suitable shape, by clean its surface cleaning, thenAdopt conductive material to make two mutually disjoint electrodes on its surface;
(b) preparation process of material with carbon element layer:
Material with carbon element is deposited on slide glass, makes material with carbon element be interconnected to form material with carbon element layer, and wholeMaterial with carbon element layer is overlapped between two electrodes, and forms with it conductive path;
(c) number of assembling steps:
Material with carbon element layer one end immersed to volatile liquid all the time, and the other end is exposed to described volatility liquidIn environment outside surface, complete thus the preparation process of whole TRT.
As further preferably, in step (b), described material with carbon element layer also comprises annealing in processOperation, to improve the electric fan-out capability of material with carbon element layer.
As further preferably, in step (b), after forming described material with carbon element layer, preferablyAlso comprise and adopt plasma that it is carried out and is processed, improve the mutual work between volatile liquid and material with carbon elementUse intensity.
In general, the above technical scheme of conceiving by the present invention compared with prior art, mainPossess following technological merit:
1, pass through its key component as the set-up mode of material with carbon element layer, volatile liquid and two electrodesStudy with working mechanism, test shows, in use, due to the surface tension of liquid andSelf gasifies, and volatile liquid can constantly move to other one end from immersing end along material with carbon element layer, profitWith in the zones of different of two ends liquid gasification depart from time and material with carbon element between interactional difference, make firstBetween electrode and the second electrode, form electrical potential difference.
2, study by the generation type to material with carbon element layer and subsequent treatment thereof, can with high efficiency,The mode of being convenient to manipulation forms material with carbon element on slide glass surface, and it is defeated to obtain relatively high and stable electric energyGo out;
3, according to TRT compact overall structure of the present invention, be easy to preparation, electric energy output continues steadyFixed, and whole preparation process is also very convenient, with low cost, and be conducive to large batch of processing systemMake, thereby be particularly useful for unglazed photograph and the certain applications without extraneous mechanical movement.
Brief description of the drawings
Fig. 1 is the apparatus structure schematic diagram according to the preferred embodiment of the present invention;
Fig. 2 is the dress that is respectively 2.5 centimetres and 1 centimetre according to the length and width of structural design shown in Fig. 1Put and carry out voltage-time signal figure that actual test obtains;
In institute's drawings attached, identical Reference numeral is used for representing identical element or structure, wherein:
11-slide glass 12-electrode 13-material with carbon element layer 14-volatile liquid
Detailed description of the invention
In order to make object of the present invention, technical scheme and advantage clearer, below in conjunction with accompanying drawingAnd embodiment, the present invention is further elaborated. Should be appreciated that described herein concreteEmbodiment only, in order to explain the present invention, is not intended to limit the present invention. In addition described,Involved technical characterictic in each embodiment of the present invention just can as long as do not form to conflict each otherMutually to combine.
Fig. 1 is the apparatus structure schematic diagram according to the preferred embodiment of the present invention. As shown in Figure 1, thisElectric installation mainly comprises electrification component and volatile liquid 14, and wherein electrification component comprises slide glass 11 (examplesAs the one in glass, quartz and the electrically insulating material taking pottery as representative), be deposited thereon faceTwo electrodes 12 and material with carbon element layer 13, wherein material with carbon element layer 13 is interconnected and is formed by material with carbon element,And whole material with carbon element layer is overlapped between described the first electrode and the second electrode, and with these two electrodesForm conductive path. Volatile liquid 14 can be suitable volatile solution that possesses, and it can be wavedSend out and can with material with carbon element parent profit, as preferably, in the present invention having adopted the water-soluble of pure water, saltLiquid and organic solvent etc., these liquid show all can play good generating effect after tested.
Material with carbon element layer 13 one end are immersed to volatile liquid 14 all the time, and the other end is exposed to described volatilizationIn environment outside property liquid surface, form thus a kind of dress that can automatically obtain energy from liquidPut. In use, due to the surface tension of liquid and self gasification, volatile liquid can be constantly alongMaterial with carbon element layer moves to other one end from immersing end, while utilizing zones of different interior liquid gasification in two ends to depart fromAnd interactional difference between material with carbon element, makes to form electrical potential difference between the first electrode and the second electrode. ;
To specifically describe according to the technological process for the manufacture of above-mentioned TRT of the present invention below, shouldMethod mainly comprises the following steps:
(a) preparation process of electrification component:
The slide glass that is selected from electrically insulating material is made to suitable shape, by clean its surface cleaning, thenAdopt conductive material to make two mutually disjoint electrodes on its surface;
(b) preparation process of material with carbon element layer:
Material with carbon element is deposited on slide glass, makes material with carbon element be interconnected to form material with carbon element layer, and wholeMaterial with carbon element layer is overlapped between two electrodes, and forms with it conductive path;
(c) number of assembling steps:
Selected material with carbon element layer one end immersed to volatile liquid all the time, and the other end is exposed to described volatilizationIn environment outside property liquid, complete thus the preparation process of whole TRT.
To above the obtained TRT based on material with carbon element be carried out to actual test below. As Fig. 2Shown in, even if at unglazed photograph with in without the mechanically operated situation in any external world, design according to the present inventionLength and width be respectively the voltage that the device of 2.5 centimetres and 1 centimetre exports still can be at short noticeReach 1 volt, and can keep for a long time, thereby proved according to real value of the present invention and divedUtilization prospect.
Those skilled in the art will readily understand, the foregoing is only preferred embodiment of the present invention,Not in order to limit the present invention, all any amendments of doing within the spirit and principles in the present invention, etc.With replacement and improvement etc., within all should being included in protection scope of the present invention.

Claims (6)

1. the TRT based on material with carbon element, this TRT comprises electrification component and volatility liquidBody, is characterized in that:
Described electrification component comprise electric insulation slide glass, be arranged on this slide glass surface mutually disjointOne electrode and the second electrode, and be arranged on equally the material with carbon element layer on this carrier surface, wherein this carbonMaterial is selected from one or more in carbon black, CNT, carbon granule or Graphene, and is deposited onOn slide glass, interconnect and form material with carbon element layer, whole material with carbon element layer is overlapped on described the first electrode in additionAnd between the second electrode, and form conductive path with these two electrodes; Begin in one end of described material with carbon element layerImmerse eventually described volatile liquid, the other end is exposed to the environment outside described volatile liquid surfaceIn; In this way, in use, due to surface tension and self gasification of liquid, volatile liquidCan constantly move to other one end from immersing end along material with carbon element layer, utilize liquid in the zones of different of two endsGasification depart from time and material with carbon element between interactional difference, make shape between the first electrode and the second electrodeBecome electrical potential difference.
2. TRT as claimed in claim 1, is characterized in that, described volatile liquid is preferredFor the aqueous solution and the organic solvent etc. of pure water, salt.
3. TRT as claimed in claim 1 or 2, is characterized in that, above-mentioned TRT alsoPreferably include temperature control unit, humidity controlling unit, the gentle pressure-controlled of wind speed control module unit,Wherein temperature control unit is used for improving the residing environment temperature of volatile liquid, and humidity controlling unit is usedIn reducing the residing ambient humidity of volatile liquid, wind speed control module is used for improving described volatility liquidThe flow rate of gas of surface, air pressure control module is for reducing the residing ring of described volatile liquidBorder air pressure, in this way, acting in conjunction is to improve the output electric energy of TRT.
4. for the preparation of a method for the TRT based on material with carbon element, it is characterized in that the methodComprise the following steps:
(a) preparation process of electrification component:
The slide glass that is selected from electrically insulating material is made to suitable shape, by clean its surface cleaning, thenAdopt conductive material to make two mutually disjoint electrodes on its surface;
(b) preparation process of material with carbon element layer:
Material with carbon element is deposited on slide glass, makes material with carbon element be interconnected to form material with carbon element layer, and wholeMaterial with carbon element layer is overlapped between two electrodes, and forms with it conductive path;
(c) number of assembling steps:
Material with carbon element layer one end immersed to volatile liquid all the time, and the other end is exposed to described volatility liquidIn environment outside surface, complete thus the preparation process of whole TRT.
5. method as claimed in claim 4, is characterized in that, in step (b), and described carbonMaterial layer also comprises the operation of annealing in process, to improve the electric fan-out capability of material with carbon element layer.
6. method as claimed in claim 5, is characterized in that, in step (b), is formingAfter described material with carbon element layer, preferably also comprise and adopt plasma that it is carried out and is processed, improve volatility liquidInteraction strength between body and material with carbon element.
CN201410576692.4A 2014-10-24 2014-10-24 A kind of TRT and its manufacture method based on carbon material Active CN105591166B (en)

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CN201410576692.4A CN105591166B (en) 2014-10-24 2014-10-24 A kind of TRT and its manufacture method based on carbon material
PCT/CN2014/092295 WO2016061870A1 (en) 2014-10-24 2014-11-26 Carbon material-based power generation device and method for manufacturing same

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110417295A (en) * 2019-07-23 2019-11-05 大连理工大学 A kind of power generating device based on liquid evaporation

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070248767A1 (en) * 2006-04-19 2007-10-25 Asm Japan K.K. Method of self-cleaning of carbon-based film
JP2011154914A (en) * 2010-01-28 2011-08-11 Nsk Ltd Power generation element
CN102307024A (en) * 2011-06-21 2012-01-04 南京航空航天大学 Graphene-based fluid power generating device for fluctuation sensing device
CN102647113A (en) * 2012-04-23 2012-08-22 许子寒 Graphene power-generation device
WO2012169826A2 (en) * 2011-06-10 2012-12-13 동국대학교 산학협력단 Electricity generating device using a nanowire

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204190653U (en) * 2014-10-24 2015-03-04 华中科技大学 A kind of Blast Furnace Top Gas Recovery Turbine Unit (TRT) based on volatile liquid

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070248767A1 (en) * 2006-04-19 2007-10-25 Asm Japan K.K. Method of self-cleaning of carbon-based film
JP2011154914A (en) * 2010-01-28 2011-08-11 Nsk Ltd Power generation element
WO2012169826A2 (en) * 2011-06-10 2012-12-13 동국대학교 산학협력단 Electricity generating device using a nanowire
CN102307024A (en) * 2011-06-21 2012-01-04 南京航空航天大学 Graphene-based fluid power generating device for fluctuation sensing device
CN102647113A (en) * 2012-04-23 2012-08-22 许子寒 Graphene power-generation device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110417295A (en) * 2019-07-23 2019-11-05 大连理工大学 A kind of power generating device based on liquid evaporation

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