CN105586802A - Manufacturing method of Pinfeng base paper - Google Patents
Manufacturing method of Pinfeng base paper Download PDFInfo
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- CN105586802A CN105586802A CN201610091153.0A CN201610091153A CN105586802A CN 105586802 A CN105586802 A CN 105586802A CN 201610091153 A CN201610091153 A CN 201610091153A CN 105586802 A CN105586802 A CN 105586802A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
- D21H15/10—Composite fibres
- D21H15/12—Composite fibres partly organic, partly inorganic
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21G—CALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
- D21G1/00—Calenders; Smoothing apparatus
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/17—Ketenes, e.g. ketene dimers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
- D21H17/29—Starch cationic
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/72—Coated paper characterised by the paper substrate
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
Abstract
The invention discloses a manufacturing method of Pinfeng base paper. The method comprises the following processing steps: pulping and preparing softwood pulp and hardwood pulp respectively; adding auxiliary materials; making wet paper sheets; carrying out pre-drying and surface sizing treatment; and carrying out post-drying, calendaring and finishing. Through research on slurry selection, slurry proportioning, a beating technology, a functional chemical additive added to the slurry and a digital printing assistant, measures of calendaring and the like are carried out by film-transfer surface sizing treatment by soft calendaring equipment; and the qualified Pinfeng base paper is manufactured by referring to related paper machine parameters. Compared with ordinary logistics label middle paper, the Pinfeng base paper has the advantages of low gram weight, high tensile strength, good internal bonding strength, high smoothness, low hygroscopic property, good surface strength, good digital printing effect, fine paper surface and good hand feeling, and is capable of completely replacing the ordinary logistics label middle paper and reducing the production cost for customers.
Description
Technical field
The present invention relates to the manufacture method of the rich body paper of a kind of product, the rich body paper of product is paper in a kind of logistic label newly developed, belongs to pulp technology for making paper.
Background technology
Along with electricity Shang company be the fast development of the third-party logistics Delivery Co., Ltd of electric business service, also drive the fast development of label paper industry simultaneously. What label paper industry speedup was the fastest at present is three layers of express label and logistic label, with 60% speed increase. So-called three layers of express label and logistic label, claim again three layers of adhesive sticker face list, ecommerce face list, for novel adhesive sticker face list, formed by three layers of facial tissue, middle paper and base stocks, be by after compound by special coating paper (or film and other paper) in high-grade temperature-sensitive plane materiel (or art paper plane materiel, carbonless paper plane materiel etc.) and logistic label again gluing dative Racine base stock (or other release liners) fit and form. Facial tissue, mainly taking heat-sensitive paper as main, is secondly art paper and carbonless paper; The current paper using kind of middle paper is more assorted, uses all wood paper more; Base stock mostly adopts Ge Laxin paper, and small part is used other paper kind. According to statistics for doing approximately 1,000,000 tons/year of the total consumptions of various paper in label paper facial tissue and intermediate layer. Wherein in logistic label, paper is about 200,000 tons.
In the logistic label of domestic use, the present situation of paper is that kind is more assorted, taking all wood paper product as main, also has some products containing DIP slurry and straw pulp; These product technology contents are not high, and product specification is on the low side, mainly have following quality problems: 1. digital printing of low quality (ink consumption is large, pattern and word unintelligible), ink set is not firm, rate of drying is slow; 2. paper tensile strength is less than normal, and interlayer adhesion is little, and in logistic label, paper is easily torn to shreds in the time of normal use; 3. the coarse intensity of paper surface is low, planarization is poor, and after printing, painting isolation oil or PVA cost are high; 4. mill run is quantitatively bigger than normal, single forming label high expensive, and logistics transportation expense is high.
Summary of the invention
The object of this invention is to provide a kind of quantitatively low, tensile strength is high, internal bond strength good, smoothness is high, water imbibition is little, surface strength is good, digital printing is effective, paper is fine and smooth, good hand touch, can substitute paper in common logistic label completely, thereby the manufacture method of the rich body paper of product reducing production costs for client.
The technical solution used in the present invention is: the manufacture method of the rich body paper of a kind of product, comprise use softwood pulp, hardwood pulp through making beating respectively, with slurry and auxiliary material adds, l Water Paper page is manufactured paper with pulp, front dry, top sizing processing, after the processing step such as dry, press polish ornamenting, it is characterized in that:
(1) sulfate bleaching needle-point leaf pulp, sulfate bleached hardwood pulp, three kinds of slurry weight proportionings of chemi-mechanical pulp are: sulfate bleaching needle-point leaf pulp: sulfate bleached hardwood pulp: chemi-mechanical pulp=(18～20%): (76～70%): (6～10%), the beating degree of three kinds of slurries: softwood pulp 60～650SR; Hardwood pulp 60～650SR; Chemi-mechanical pulp 55～600SR；
(2) supplementary product consumption is: (a) AKD:15～20kg/ ton paper; (b) filler: 140～150kg/ ton paper; (c) cationic starch in slurry: 15～20kg/ ton paper, retention agent PAM:0.3～0.4kg/ ton paper, organic fine particles: 0.2～0.25kg/ ton paper, bentonite: 2～2.5kg/ ton paper;
(3) glue-applying technique: surface sizing starch 40～55kg/ ton paper, sizing material concentration 14%; Solid Organic toner 4～6kg/ ton paper, butter 8～12kg/ ton paper; Two sides top sizing one side is controlled at 1.5～2g/m2, page tension force 220N/m before applying glue portion2, page tension force 200N/m after applying glue portion2；
(4) other parameters of paper machine: network speed 1280m/min, top net dehydrating amount 27%, head box opening degree of slice lip 9.7mm, one line ball pressure: 900kN/m, two line ball pressure: 900kN/m, curling tension force: 400kN/m, rolling condition: 120～130 DEG C of left and right of calender steel rod temperature, linear pressure is 75～80kN/m;
(6) the rich body paper of product is quantitative: 41～50g/m2, moisture 5.0～6.0%, form and aspect raw white ISO, longitudinally fracture length >=7.0Km, internal bond strength >=400J/m2, ash content≤15%, smoothness mean value >=100S, water imbibition is little≤22g/m2, lateral extensometer shrinkage≤3.0%, it is good that thickness is stable, formation of sheet is good, surface strength is good, outward appearance is fine and smooth, touch feeling is good, planarization is good, body paper hides performance after isolating oil or be coated with PVA through digital printing, painting, develops the color full.
The weight ratio that adds of Solid Organic toner of the present invention and butter is 1:1～3, and the mode that adds is to join in gelatinized starch solution, wherein after mixing: butter is one or more in magnesium chloride, calcium chloride, sodium chloride.
Because the present situation of paper in the logistic label of domestic use is that kind is more assorted, taking all wood paper product as main, also have some products containing DIP slurry and straw pulp; These product technology contents are not high, product specification is on the low side (outward appearance has dust, smoothness is low, surface strength is poor, surface exquisiteness, digital printing weak effect etc. not), quantitatively general paper high expensive (as: 60 grams of products in (60 grams is main above) bigger than normal, single label, 6000 yuan/ton of prices, every square of cost is 0.360 yuan).
Applicant is in order to find one quantitatively low, tensile strength is high, internal bond strength is good, smoothness is high, water imbibition is little, surface strength is good, digital printing is effective, paper exquisiteness, good hand touch, can substitute the rich body paper of product of paper in common logistic label completely, paper---the rich body paper of-product in the logistic label that starts to develop for 2015, main research and innovation: the requirement of (i) falling cost according to client, research and develop in low quantitative logistic label paper product (under the prerequisite that meets instructions for use, develop the rich body paper of low quantitative product), both reduced paper using amount, having saved again logistics transportation expense has reached client and has fallen cost object. (ii) from slurry selection, beating process and paper technology research and innovation, the product quality of the rich body paper of product of PM9 exploitation significantly better than common label in paper, main research comprises: 1. study grout structure, taking commodity sulfate bleached wood pulp as primary raw material, add a small amount of high quality machine to starch to improve page thickness and deflection. in common label, paper product generally contains part reed pulp, straw pulp or Deinking Pulp, and paper has dust and rubbish. 2. study best wet end furnish, chamber handsheet and the research with slurry of paper machine by experiment, determines best wet end furnish scope----softwood pulp: hardwood pulp: change machine slurry=(18～20): (76～70): (6～10). 3. study best beating degree control range, in order to allow the rich body paper of low quantitative product reach equal intensity index, we are from the beating process research of starting with, by adopting shiny beating mode test of many times to regulate beating degree and laboratory handsheet to detect tensile strength and the internal bond strength of paper, finally determine that best beating degree control range is (as broad-leaved slurry beating degree control 60～650SR, needle slurry beating degree control 60～650SR), reached the object that improves tensile strength, internal bond strength and the evenness of paper. 4. the addition (mill run cationic starch addition is 8～10kg/ ton paper, and the addition of the rich body paper of product is brought up to 15～20kg/ ton paper) of cationic starch in research slurry, also can obviously improve paper internal bond strength. 5. adopt film transitional surface applying glue equipment to carry out top sizing processing, after groping by many experiments research, add ink printing set class chemicals, as organic color-fixing agent, butter (magnesium chloride, calcium chloride, sodium chloride) etc., choose 1～3 kind of chemicals, after mixing according to the different proportioning in 1:1～3, join in gelatinized starch solution, can effectively improve digital printing effect, ink set and the ink setting speed of paper in logistic label; Control one side resin added at 1.5～2g/m2, can improve preferably paper sheet stiffness, paper surface properties and printing performance. 6. study the dryer temperature curve of paper machine water desorption curve and drying section, wet end vacuum and drying section dryer temperature to paper machine regulate and optimize, and make best dewatering process parameter; Adopt the mode of soft calender and increase press polish linear pressure and improve paper smoothness. Therefore the rich body paper of product has good planarization. (iii) product structure innovation transition, promotes company's profitability (respond the call of company, product structure is made the transition to industrial paper by Cultural Paper, and the rich body paper rate of gross profit of product is apparently higher than company's existing product); Also reduced the production cost of client's logistic label, be an industrial paper new product that is worth exploitation simultaneously.
The paper machine that the application adopts is PM9 paper machine, has given full play to the equipment advantage of foreign paper machine, can on the basis that meets Customer Quality requirement, reduce production costs simultaneously. PM9 is the high speed paper production line from external a complete set of of introducing with the leading level in the world, with respect to common paper machine, the product of PM9 paper machine has following advantage: wet end sheet forming is good, evenness is good, longitudinal basis weight fluctuation is little, with the comparison of same grammes per square metre product, there is the advantages such as tensile strength is large, surface strength is high, the fine and smooth property of paper is good.
Several features of the rich body paper of product are exactly: brisement quantitatively less than normal, longitudinal is grown up (>=7.0Km), the little (≤22g/m of water imbibition2), the large (>=400J/m of internal bond strength2), smoothness high (>=100s), formation of sheet is good, outward appearance is fine and smooth, planarization is good, touch feeling is good etc., body paper, to hide performance through digital printing, after being coated with isolation oil or being coated with PVA good, develops the color full. Good with the isolation effect of base stock Ge Laxin paper.
The present invention is by selecting slurry, wet end furnish, beating process, the functionalized chemical auxiliary agent and the digital printing auxiliary agent that in slurry, add are studied, adopt film transitional surface applying glue processing, carry out the measures such as press polish by soft calendaring equipment, carry out to produce the rich body paper of qualified product with reference to relevant paper machine parameter, compared with paper in common logistic label, the rich body paper of product has quantitatively low, tensile strength is high, internal bond strength is good, smoothness is high, water imbibition is little, surface strength is good, digital printing is effective, paper exquisiteness, good hand touch, can substitute paper in common logistic label completely, and can reduce production costs for client, company is optimized product structure and to promote company's profitability significant.
Detailed description of the invention
According to specific embodiment, the invention will be further described below:
Embodiment 1:
By softwood pulp, (beating degree is controlled at 60～620SR), (beating degree is controlled at 60～62 to hardwood pulp0SR) and change machine slurry (beating degree is controlled at 55～570SR) three kinds of slurries carry out with slurry in the ratio of 18%:72%:10%, add the pearl filler of 145～150kg/ ton paper, add 18～20kg/ ton paper AKD sizing agent, add cationic starch in 15～16kg/ ton paper pulp, add 0.35～0.4kg/ ton paper retention agent, add 0.22～0.25kg/ ton paper cationic organic particles, add 2.3～2.5kg/ ton paper modified alta-mud, be mixed with the approach flow that raw white has been diluted, carry out double dewatering by folded net, guarantee fiber dispersion is even, in length and breadth to fiber alignment in order and be uniformly distributed, l Water Paper page enters after press section unipress, the page that is dried to mass dryness fraction 95% before entering enters applying glue portion, adopts film branch mode to carry out top sizing processing (top sizing sizing material main component comprises: several chemicals of maize oxidized starch, improvement ink printing and set) to paper, control one side resin added at 1.5～2.0g/m2, l Water Paper page after treatment enters rear dry processing; After dry processing later, mass dryness fraction enters soft press-polishing machine ornamenting processing at 94～95% page, and calender steel rider temperature is controlled at 125 DEG C, and press polish linear pressure is controlled at 80KN/m; After press polish, paper is batched, can obtain is quantitatively 50g/m2The rich body paper of product, its leading indicator: moisture (5.0～6.0%), longitudinally fracture length (>=7.0Km), internal bond strength (>=400J/m2), ash content (≤15%), smoothness mean value (>=100S), water imbibition (≤22g/m2), lateral extensometer shrinkage (≤3.0%), thickness is stable. The rich body paper of paper in qualified logistic label------product can be produced according to above technique, the quality requirement of paper in logistic label industry can be met completely.
Embodiment 2:
By softwood pulp, (beating degree is controlled at 63～650SR), (beating degree is controlled at 63～65 to hardwood pulp0SR) and change machine slurry (beating degree is controlled at 55～570SR) three kinds of slurries carry out with slurry in the ratio of 20%:74%:6%, add the pearl filler of 140～145kg/ ton paper, add 15～18kg/ ton paper AKD sizing agent, add cationic starch in 18～20kg/ ton paper pulp, add 0.30～0.35kg/ ton paper retention agent, add 0.20～0.22kg/ ton paper cationic organic particles, add 2.0～2.2kg/ ton paper modified alta-mud, be mixed with the approach flow that raw white has been diluted, carry out double dewatering by folded net, guarantee fiber dispersion is even, in length and breadth to fiber alignment in order and be uniformly distributed, l Water Paper page enters after press section unipress, the page that is dried to mass dryness fraction 95% before entering enters applying glue portion, adopts film branch mode to carry out top sizing processing (top sizing sizing material main component comprises: several chemicals of maize oxidized starch, improvement ink printing and set) to paper, control one side resin added at 1.5～2.0g/m2, l Water Paper page after treatment enters rear dry processing; After dry processing later, mass dryness fraction enters soft press-polishing machine ornamenting processing at 94～95% page, and calender steel rider temperature is controlled at 120 DEG C, and press polish linear pressure is controlled at 75KN/m; After press polish, paper is batched, can obtain is quantitatively 41g/m2The rich body paper of product, its leading indicator: moisture (5.0～6.0%), longitudinally fracture length (>=7.0Km), internal bond strength (>=400J/m2), ash content (≤15%), smoothness mean value (>=100S), water imbibition (≤22g/m2), lateral extensometer shrinkage (≤3.0%), thickness is stable. The rich body paper of paper in qualified logistic label------product can be produced according to above technique, the quality requirement of paper in logistic label industry can be met completely.
Claims (2)
1. a manufacture method for the rich body paper of product, includes and uses softwood pulp, hardwood pulp, chemi-mechanical pulp to join to copy, through webpage shaping, squeezing, front dry, top sizing, after dry, press polish finishing process step, it is characterized in that:
(1) sulfate bleaching needle-point leaf pulp, sulfate bleached hardwood pulp, three kinds of slurry weight proportionings of chemi-mechanical pulp are: sulfate bleaching needle-point leaf pulp: sulfate bleached hardwood pulp: chemi-mechanical pulp=(18～20%): (76～70%): (6～10%), the beating degree of three kinds of slurries: softwood pulp 60～650SR; Hardwood pulp 60～650SR; Chemi-mechanical pulp 55～600SR；
(2) supplementary product consumption is: (a) AKD:15～20kg/ ton paper; (b) filler: 140～150kg/ ton paper; (c) cationic starch in slurry: 15～20kg/ ton paper, retention agent PAM:0.3～0.4kg/ ton paper, organic fine particles: 0.2～0.25kg/ ton paper, bentonite: 2～2.5kg/ ton paper;
(3) glue-applying technique: surface sizing starch 40～55kg/ ton paper, sizing material concentration 14%; Solid Organic toner 4～6kg/ ton paper, butter 8～12kg/ ton paper; Two sides top sizing one side is controlled at 1.5～2g/m2, page tension force 220N/m before applying glue portion2, page tension force 200N/m after applying glue portion2；
(4) other parameters of paper machine: network speed 1280m/min, top net dehydrating amount 27%, head box opening degree of slice lip 9.7mm, one line ball pressure: 900kN/m, two line ball pressure: 900kN/m, curling tension force: 400kN/m, rolling condition: 120～130 DEG C of left and right of calender steel rod temperature, linear pressure is 75～80kN/m;
(6) the rich body paper of product is quantitative: 41～50g/m2, moisture 5.0～6.0%, form and aspect raw white ISO, longitudinally fracture length >=7.0Km, internal bond strength >=400J/m2, ash content≤15%, smoothness mean value >=100S, water imbibition is little≤22g/m2, lateral extensometer shrinkage≤3.0%, it is good that thickness is stable, formation of sheet is good, surface strength is good, outward appearance is fine and smooth, touch feeling is good, planarization is good, body paper hides performance after isolating oil or be coated with PVA through digital printing, painting, develops the color full.
2. according to the manufacture method of the rich body paper of product described in right 1, it is characterized by: the weight ratio that adds of described Solid Organic toner and butter is 1:1～3, the mode that adds is to join in gelatinized starch solution, wherein after mixing: butter is one or more in magnesium chloride, calcium chloride, sodium chloride.
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| CN106245415A (en) * | 2016-08-26 | 2016-12-21 | 岳阳林纸股份有限公司 | A kind of manufacture method of glassine paper |
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