CN105585722A - High-strength polyurethane film - Google Patents

High-strength polyurethane film Download PDF

Info

Publication number
CN105585722A
CN105585722A CN201510959719.2A CN201510959719A CN105585722A CN 105585722 A CN105585722 A CN 105585722A CN 201510959719 A CN201510959719 A CN 201510959719A CN 105585722 A CN105585722 A CN 105585722A
Authority
CN
China
Prior art keywords
accounts
polyurethane film
strength
fibre
dihydroxyacetone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510959719.2A
Other languages
Chinese (zh)
Inventor
周喜峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hongyuan Jiangsu New Material Science And Technology Ltd
Original Assignee
Hongyuan Jiangsu New Material Science And Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hongyuan Jiangsu New Material Science And Technology Ltd filed Critical Hongyuan Jiangsu New Material Science And Technology Ltd
Priority to CN201510959719.2A priority Critical patent/CN105585722A/en
Publication of CN105585722A publication Critical patent/CN105585722A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203Polyhydroxy compounds
    • C08G18/3206Polyhydroxy compounds aliphatic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a high-strength polyurethane film which comprises a polyurethane coating located on the uppermost layer, a bonding agent located in the middle and an inorganic fiber layer located on the lowermost layer. The polyurethane coating is formed by, by mass, 66%-72% of diisocyanate and 28%-34% of dihydroxy acetone through addition polymerization, and the inorganic fiber layer is prepared by mixing, by mass, 55%-65% of glass fibers and 35%-45% of ceramic fibers. In this way, the high-strength polyurethane film has the advantages of being high in strength and ductility and resistant to wear, and the use value is improved.

Description

A kind of high-strength polyurethane film
Technical field
The present invention relates to a kind of macromolecular material, particularly a kind of high-strength polyurethane film.
Background technology
Along with the adjustment of expanding economy and the structure of rural undertaking, China's all trades and professions constantly rise to the market demand of plastic sheeting, wherein, polyurethane film because of its superior performance and environmental protection concept day by day welcomed by the people, polyurethane film not only can with various cloth pastings, can also produce clear-cut by the method for vacuum thermoforming, the product of dimensionally stable, then, in the process using, polyurethane film is due to undercapacity, and usually occur that film ruptures, the phenomenon of damage.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of high-strength polyurethane film, can possess and have high strength, high ductibility, wear-resisting advantage, improves use value.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of high-strength polyurethane film is provided, comprise: the polyurethane coating that is positioned at the superiors, be positioned at middle adhesive and be positioned at undermost inorganic fibre mat, described polyurethane coating is formed by vulcabond and dihydroxyacetone (DHA) addition polymerization, calculate according to mass percent, described vulcabond accounts for 66-72%, described dihydroxyacetone (DHA) accounts for 28-34%, described inorganic fibre mat is mixed by glass fibre and ceramic fibre, calculate according to mass percent, described glass fibre accounts for 55-65%, described ceramic fibre accounts for 35-45%.
In a preferred embodiment of the present invention, described adhesive is pressure sensitive adhesive.
In a preferred embodiment of the present invention, in described polyurethane coating, the concrete proportioning of composition is: described vulcabond accounts for 69%, and described dihydroxyacetone (DHA) accounts for 31%.
In a preferred embodiment of the present invention, in described inorganic fibre mat, the concrete proportioning of composition is: described glass fibre accounts for 60%, and described ceramic fibre accounts for 40%.
The invention has the beneficial effects as follows: the present invention possesses and has high strength, high ductibility, wear-resisting advantage, improves use value.
Detailed description of the invention
Below preferred embodiment of the present invention is described in detail, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that, protection scope of the present invention is made to more explicit defining.
Embodiment 1:
A kind of high-strength polyurethane film, comprise: be positioned at the polyurethane coating of the superiors, adhesive in the middle of being positioned at and be positioned at undermost inorganic fibre mat, described adhesive is pressure sensitive adhesive, described polyurethane coating is formed by vulcabond and dihydroxyacetone (DHA) addition polymerization, calculate according to mass percent, described vulcabond accounts for 66%, described dihydroxyacetone (DHA) accounts for 34%, described inorganic fibre mat is mixed by glass fibre and ceramic fibre, calculate according to mass percent, described glass fibre accounts for 55%, and described ceramic fibre accounts for 45%.
Embodiment 2:
A kind of high-strength polyurethane film, comprise: be positioned at the polyurethane coating of the superiors, adhesive in the middle of being positioned at and be positioned at undermost inorganic fibre mat, described adhesive is pressure sensitive adhesive, described polyurethane coating is formed by vulcabond and dihydroxyacetone (DHA) addition polymerization, calculate according to mass percent, described vulcabond accounts for 72%, described dihydroxyacetone (DHA) accounts for 28%, described inorganic fibre mat is mixed by glass fibre and ceramic fibre, calculate according to mass percent, described glass fibre accounts for 65%, and described ceramic fibre accounts for 35%.
Embodiment 3:
A kind of high-strength polyurethane film, comprise: be positioned at the polyurethane coating of the superiors, adhesive in the middle of being positioned at and be positioned at undermost inorganic fibre mat, described adhesive is pressure sensitive adhesive, described polyurethane coating is formed by vulcabond and dihydroxyacetone (DHA) addition polymerization, calculate according to mass percent, described vulcabond accounts for 69%, described dihydroxyacetone (DHA) accounts for 31%, described inorganic fibre mat is mixed by glass fibre and ceramic fibre, calculate according to mass percent, described glass fibre accounts for 60%, and described ceramic fibre accounts for 40%.
Be different from prior art, the present invention possesses and has high strength, high ductibility, wear-resisting advantage, improves use value.
The foregoing is only embodiments of the invention; not thereby limit the scope of the claims of the present invention; every equivalent structure or conversion of equivalent flow process that utilizes description of the present invention to do; or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.

Claims (4)

1. a high-strength polyurethane film, it is characterized in that, comprise: be positioned at the polyurethane coating of the superiors, adhesive in the middle of being positioned at and be positioned at undermost inorganic fibre mat, described polyurethane coating is formed by vulcabond and dihydroxyacetone (DHA) addition polymerization, calculate according to mass percent, described vulcabond accounts for 66-72%, described dihydroxyacetone (DHA) accounts for 28-34%, described inorganic fibre mat is mixed by glass fibre and ceramic fibre, calculate according to mass percent, described glass fibre accounts for 55-65%, and described ceramic fibre accounts for 35-45%.
2. high-strength polyurethane film according to claim 1, is characterized in that, described adhesive is pressure sensitive adhesive.
3. high-strength polyurethane film according to claim 1, is characterized in that, in described polyurethane coating, the concrete proportioning of composition is: described vulcabond accounts for 69%, and described dihydroxyacetone (DHA) accounts for 31%.
4. high-strength polyurethane film according to claim 1, is characterized in that, in described inorganic fibre mat, the concrete proportioning of composition is: described glass fibre accounts for 60%, and described ceramic fibre accounts for 40%.
CN201510959719.2A 2015-12-21 2015-12-21 High-strength polyurethane film Pending CN105585722A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510959719.2A CN105585722A (en) 2015-12-21 2015-12-21 High-strength polyurethane film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510959719.2A CN105585722A (en) 2015-12-21 2015-12-21 High-strength polyurethane film

Publications (1)

Publication Number Publication Date
CN105585722A true CN105585722A (en) 2016-05-18

Family

ID=55925649

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510959719.2A Pending CN105585722A (en) 2015-12-21 2015-12-21 High-strength polyurethane film

Country Status (1)

Country Link
CN (1) CN105585722A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102070768A (en) * 2010-12-06 2011-05-25 安徽好思家涂料有限公司 Water-soluble polyurethane for wood lacquer and preparation method thereof
CN104859247A (en) * 2015-05-25 2015-08-26 江苏宏远新材料科技有限公司 Polyurethane film for gloves
CN104924792A (en) * 2015-05-25 2015-09-23 江苏宏远新材料科技有限公司 Polyurethane film for shoes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102070768A (en) * 2010-12-06 2011-05-25 安徽好思家涂料有限公司 Water-soluble polyurethane for wood lacquer and preparation method thereof
CN104859247A (en) * 2015-05-25 2015-08-26 江苏宏远新材料科技有限公司 Polyurethane film for gloves
CN104924792A (en) * 2015-05-25 2015-09-23 江苏宏远新材料科技有限公司 Polyurethane film for shoes

Similar Documents

Publication Publication Date Title
AR103002A1 (en) MIXTURE FILM OF WATER SOLUBLE POLYLINOL ALCOHOL, RELATED METHODS AND RELATED ARTICLES
BR112018000804A2 (en) high performance lignin-acrylonitrile polymer blend materials
CN104277724B (en) The special sizing agent of a kind of thermoplastic PVC table tennis
BR112015026923A2 (en) process for the production of polymer composites, polymer composites and use of polymer composites
CN104262722A (en) High-rigidity rubber material formula
CN103571118A (en) Resin composition for optical material and method for production thereof
CN105585722A (en) High-strength polyurethane film
CN107756992A (en) Polymeric membrane composite carbon fiber leather cloth and preparation method thereof
MY194366A (en) Enhancement of Reinforcing Fibers, Their Applications, and Methods of Making Same
CN107841875A (en) aqueous polyurethane slurry
CN102850954B (en) Cord fabric rubber containing hexamethylolmelamine hexamethyl ether (HMMM)
CN101705621A (en) Water-based PU matte surface finishing agent for synthetic leather
WO2015002355A1 (en) Thermoplastic polyurethane hot-melt film
WO2012131009A8 (en) Polymeric formulations with chemically adjustable rheology for the manufacture of prepregs and articles made of composite material
CN205890022U (en) TPU film
CN106188426B (en) A kind of film-forming agent for glass fiber injection yarn and preparation method thereof
PH12020550087A1 (en) Curable composition, sealing material composition, and adhesive composition
CN102877308A (en) Water-based PU surface passivator for artificial leather
CN104419350A (en) Adhesive for plate surface
CN106893198A (en) Plastics preparation method
CN108976699A (en) A kind of engineering plastics for mold
CN110431373A (en) Three-dimensionally shaped product
CN204640988U (en) A kind of three layers of vacuum diaphragm for polymer matrix composites application
CN106366956A (en) High-viscosity adhesive for table tennis balls
CN103589352A (en) High-binding-property high-strength stripping adhesive tape

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20160518

RJ01 Rejection of invention patent application after publication