CN105584179A - Low-temperature shrink film and preparation method thereof - Google Patents
Low-temperature shrink film and preparation method thereof Download PDFInfo
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- CN105584179A CN105584179A CN201610017633.2A CN201610017633A CN105584179A CN 105584179 A CN105584179 A CN 105584179A CN 201610017633 A CN201610017633 A CN 201610017633A CN 105584179 A CN105584179 A CN 105584179A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0018—Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/40—Applications of laminates for particular packaging purposes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
- B32B2307/404—Multi-coloured
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/04—Polyethylene
- B32B2323/046—LDPE, i.e. low density polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/10—Polypropylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Laminated Bodies (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Abstract
The invention provides a low-temperature shrink film. The low-temperature shrink film comprises PE (polyethylene) layers in the middle and PP (polypropylene) layers on upper and lower surface layers and is prepared from raw materials in parts by weight as follows: 50-80 parts of PE and 20-40 parts of PP. Raw materials of each of the three PE layers comprise LLDPE (linear low density polyethylene) 2045G, LLDPE 4203 and LLDPE OF07. The low-temperature shrink film adopts three PE layers in the middle and two PP layers on surfaces, each PE layer is formed through press fit of films made of three materials, the PP layer material on the surfaces contains a lubricant, and the low-temperature shrink film has excellent low-temperature shrink effect.
Description
Technical field
The invention belongs to packaging material field, be specifically related to a kind of low-temperature shrink film and preparation method thereof.
Background technology
Shrink film is mainly used in the packaging in transport and the sales process of multiple product, Main Function make firmly, hide andProtection product, shrink film must have certain paracentesis resistance, good shrinkage and certain shrinkage stress. Often can aborningRun into such problem, some product can not be packed through high temperature, and shrink film needs certain temperature shrinkage effect ability brightAobvious, so will receive the welcome in market if research and develop a kind of shrink film that contractive effect is good under cryogenic conditions.
Summary of the invention
Object of the present invention is mainly for the problems of the prior art, and a kind of low-temperature shrink film and preparation side thereof are now providedMethod.
For realizing object of the present invention, the invention provides following technical scheme:
A kind of low-temperature shrink film, the PE layer in the middle of comprising and the PP layer on upper and lower two top layers composition, made by following Raw material processing, eachRaw material weight umber is as follows:
PE50-80;
PP20-40。
Described PE layer comprises three layers, and the raw material of 3 layers is LLDPE2045G, LLDPE4203 and LLDPEOF07, each formerExpect that shared part by weight is:
LLDPE2045G20-50;
LLDPE420320-50
LLDPEOF070.2-5。
PP layer raw material comprises FS6612L and ABP0F0-I, and parts by weight are:
FS6612L20-40;
ABP0F0-I0.5-2;
SPOF070.1-0.5。
The thickness of described 2 layers of PP layer is 0.5-5 μ m, and the gross thickness of PE layer is 7-10 μ m.
A preparation method for low-temperature shrink film, step is: a, batch mixing, by PE expect LLDPE2045G, LLDPE4203 andLLDPEOF07, material proportionally mixes; PP is expected to FS6612L, ABP0F0-I and IL2582SC proportionally mix,B, under the condition of 150 DEG C-200 DEG C, PE material is extruded stretch and is made PE film, then under the condition of 150 DEG C-200 DEG C by PPMaterial is extruded to stretch and is made PP film; C, by 2 layers of PP film outside, 3 layers of PE film are at the interior high temperature hot pressing that passes through 200 DEG C-300 DEG CForm laminated film; Laminated film is carried out sided corona treatment by d, cooling, and rolling makes low-temperature shrink film of the present invention.
The invention has the advantages that:
1, in the middle of low-temperature shrink film of the present invention, adopt three layers of PE layer, surperficial two-layer PP layer, wherein PE layer is that 3 kinds of material films are pressedClose and form, in the PP layer raw material on surface, comprise the ABP0F0-I with lubricant effect, the low-temperature shrink film coefficient of friction makingLittle.
2, in preparation method of the present invention, adopt and extrude respectively 3 layers of PE film and 2 layers of PP film, then pass through hot pressing pressing,The low-temperature shrink film transparent effect making is good, and proof stress is strong.
Detailed description of the invention
In order to illustrate in greater detail the present invention, provide the following example of preparing. But scope of the present invention is not limited to this.
Embodiment 1
Get raw material and weight is as follows:
LLDPE2045G3300g;
LLDPE42033500g
LLDPEOF07200g。
FS6612L2960g;
ABP0F0-I20g;
SPOF0730g;
Preparation process is: a, batch mixing, PE is expected to LLDPE2045G, LLDPE4203 and LLDPEOF07, and material proportionally entersRow mixes; PP is expected to FS6612L, ABP0F0-I and IL2582SC proportionally mix, b, general under the condition of 150 DEG C-200 DEG CPE material is extruded to stretch and is made PE film, then PP material is extruded to stretch under the condition of 150 DEG C-200 DEG C and makes PP film; C, generalOutside, 3 layers of PE film form laminated film at the interior high temperature hot pressing that passes through 250 DEG C to 2 layers of PP film; Laminated film is carried out electricity by dDizzy processing, cooling, rolling, makes the low-temperature shrink film of embodiment 1.
Embodiment 2
Get raw material and weight is as follows:
LLDPE2045G3500g;
LLDPE42033500g;
LLDPEOF07150g;
FS6612L2810g;
ABP0F0-I15g;
SPOF0730g;
Preparation process is: a, batch mixing, PE is expected to LLDPE2045G, LLDPE4203 and LLDPEOF07, and material proportionally entersRow mixes; PP is expected to FS6612L, ABP0F0-I and IL2582SC proportionally mix, b, general under the condition of 150 DEG C-200 DEG CPE material is extruded to stretch and is made PE film, then PP material is extruded to stretch under the condition of 150 DEG C-200 DEG C and makes PP film; C, generalOutside, 3 layers of PE film form laminated film at the interior high temperature hot pressing that passes through 280 DEG C to 2 layers of PP film; Laminated film is carried out electricity by dDizzy processing, cooling, rolling, makes the low-temperature shrink film of embodiment 2.
Embodiment 3
Get raw material and weight is as follows:
LLDPE2045G3800g;
LLDPE42033200g
LLDPEOF07200g。
FS6612L2760g;
ABP0F0-I30g;
SPOF0730g;
Preparation process is: a, batch mixing, PE is expected to LLDPE2045G, LLDPE4203 and LLDPEOF07, and material proportionally entersRow mixes; PP is expected to FS6612L, ABP0F0-I and IL2582SC proportionally mix, b, general under the condition of 150 DEG C-200 DEG CPE material is extruded to stretch and is made PE film, then PP material is extruded to stretch under the condition of 150 DEG C-200 DEG C and makes PP film; C, generalOutside, 3 layers of PE film form laminated film at the interior high temperature hot pressing that passes through 300 DEG C to 2 layers of PP film; Laminated film is carried out electricity by dDizzy processing, cooling, rolling, makes the low-temperature shrink film of embodiment 3.
Embodiment 4
Get raw material and weight is as follows:
LLDPE2045G3600g;
LLDPE42033300g
LLDPEOF07300g。
FS6612L3000g;
ABP0F0-I10g;
SPOF0730g;
Preparation process is: a, batch mixing, PE is expected to LLDPE2045G, LLDPE4203 and LLDPEOF07, and material proportionally entersRow mixes; PP is expected to FS6612L, ABP0F0-I and IL2582SC proportionally mix, b, general under the condition of 150 DEG C-200 DEG CPE material is extruded to stretch and is made PE film, then PP material is extruded to stretch under the condition of 150 DEG C-200 DEG C and makes PP film; C, generalOutside, 3 layers of PE film form laminated film at the interior high temperature hot pressing that passes through 220 DEG C to 2 layers of PP film; Laminated film is carried out electricity by dDizzy processing, cooling, rolling, makes the low-temperature shrink film of embodiment 4.
Low-temperature shrink film prepared by embodiment 1-4 carries out performance test, and result is as follows:
Performance | Unit | Method of testing | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
Toughness | N/mm2 | ASTM-D882A | 350/410 | 360/450 | 350/440 | 400/480 |
Hot strength | N/mm2 | ASTM/882 | 100/100 | 100/100 | 105/105 | 110/110 |
Limit of stretch | % | ASTM/882 | 105/105 | 110/110 | 105/105 | 115/115 |
Sealing-strength | g/cm3 | internal | 900 | 1130 | 1025 | 1250 |
Tear-proof degree | g/cm3 | ASTM-D1938 | 9.5 | 13.8 | 11.5 | 14.2 |
Coefficient of friction | ADIM | ASTM-D1894 | 0.26 | 0.15 | 0.28 | 0.26 |
60 DEG C of shrinkage factors | % | ASTM-D2732 | 66/68 | 58/60 | 62/65 | 60/62 |
Can learn by above embodiment, the present invention compared with prior art, in hot strength and the constant prerequisite of toughnessUnder, sealing-strength and low-temperature shrink rate have obvious advantage, especially 2,60 DEG C of shrinkage factor the bests of embodiment, 4 groups of embodimentLow-temperature shrink rate be obviously better than existing shrink film, there is obvious advantage.
The above, be only preferably detailed description of the invention of the present invention, but protection scope of the present invention is not limited to this,In the technical scope that any those of ordinary skill in the art disclose in the present invention, the variation that can expect easily or replacement, all answerWithin being encompassed in protection scope of the present invention. Therefore, protection scope of the present invention should be as the criterion with the protection domain of claim.
Claims (5)
1. a low-temperature shrink film, the PE layer in the middle of comprising and the PP layer on upper and lower two top layers composition, is characterized in that: by former belowMaterial processing makes, and each raw material weight umber is as follows:
PE50-80;
PP20-40。
2. low-temperature shrink film according to claim 1, is characterized in that: described PE layer comprises three layers, and the raw material of 3 layers isLLDPE2045G, LLDPE4203 and LLDPEOF07, the shared part by weight of each raw material is:
LLDPE2045G20-50;
LLDPE420320-50
LLDPEOF070.2-5。
3. low-temperature shrink film according to claim 1, is characterized in that: PP layer raw material comprises FS6612L and ABP0F0-I,Parts by weight are:
FS6612L20-40;
ABP0F0-I0.5-2;
SPOF070.1-0.5。
4. low-temperature shrink film according to claim 3, is characterized in that: the thickness of described 2 layers of PP layer is 0.5-5 μ m, PEThe gross thickness of layer is 7-10 μ m.
5. a preparation method for the low-temperature shrink film described in claim 1-4 any one, step is: a, batch mixing, PE is expectedLLDPE2045G, LLDPE4203 and LLDPEOF07, material proportionally mixes; PP is expected to FS6612L, ABP0F0-I and IL2582SC proportionally mix, and b, PE material are extruded stretch and are made PE film, then under the condition of 150 DEG C-200 DEG CUnder the condition of 150 DEG C-200 DEG C, PP material is extruded to stretch and make PP film; C, by 2 layers of PP film outside, 3 layers of PE film are interiorForm laminated film by the high temperature hot pressings of 200 DEG C-300 DEG C; Laminated film is carried out sided corona treatment by d, cooling, and rolling makesLow-temperature shrink film described in claim 1-4 any one.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107759835A (en) * | 2016-08-17 | 2018-03-06 | 张德发 | A kind of environment-friendly type shrink film of high flexibility |
CN109159519A (en) * | 2018-09-11 | 2019-01-08 | 嘉兴鹏翔包装材料有限公司 | A kind of high sealing-strength bidirection stretching polyolefine heat-shrinkable film |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007088092A1 (en) * | 2006-02-02 | 2007-08-09 | Basell Polyolefine Gmbh | Multilayer thermoshrinkable films |
CN101049749A (en) * | 2007-04-20 | 2007-10-10 | 上海紫泉标签有限公司 | Heat shrinkage film of high transparent multilaminar polyethylene |
CN103087423A (en) * | 2011-11-07 | 2013-05-08 | 中国石油化工股份有限公司 | Composition for polymer film and polymer film and multilayer film |
CN203945765U (en) * | 2014-05-06 | 2014-11-19 | 东莞市华宇包装有限公司 | The sliding shrinkable film of POF heat for a kind of packing |
-
2016
- 2016-01-12 CN CN201610017633.2A patent/CN105584179A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007088092A1 (en) * | 2006-02-02 | 2007-08-09 | Basell Polyolefine Gmbh | Multilayer thermoshrinkable films |
CN101049749A (en) * | 2007-04-20 | 2007-10-10 | 上海紫泉标签有限公司 | Heat shrinkage film of high transparent multilaminar polyethylene |
CN103087423A (en) * | 2011-11-07 | 2013-05-08 | 中国石油化工股份有限公司 | Composition for polymer film and polymer film and multilayer film |
CN203945765U (en) * | 2014-05-06 | 2014-11-19 | 东莞市华宇包装有限公司 | The sliding shrinkable film of POF heat for a kind of packing |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107759835A (en) * | 2016-08-17 | 2018-03-06 | 张德发 | A kind of environment-friendly type shrink film of high flexibility |
CN109159519A (en) * | 2018-09-11 | 2019-01-08 | 嘉兴鹏翔包装材料有限公司 | A kind of high sealing-strength bidirection stretching polyolefine heat-shrinkable film |
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